A Universal Seeding Strategy to Synthesize Single Atom Catalysts on 2D Materials for Electrocatalytic Applications

Zhao, Shiyong; Chen, Guangxu; Zhou, Guangmin; Yin, Li‐Chang; Veder, Jean‐Pierre; Johannessen, Bernt; Saunders, Martin; Yang, Shi‐Ze; De Marco, Roland; Liu, Chang; Jiang, San Ping

doi:10.1002/adfm.201906157

Title: A Universal Seeding Strategy to Synthesize Single Atom Catalysts on 2D Materials for Electrocatalytic Applications

Authors:

Zhao, Shiyong ^[1]; Chen, Guangxu ^[2]; Zhou, Guangmin ^[2]; Yin, Li‐Chang ^[3]; Veder, Jean‐Pierre ^[4]; Johannessen, Bernt ^[5]; Saunders, Martin ^[6]; Yang, Shi‐Ze ^[7]; De Marco, Roland ^[8]; Liu, Chang ^[3];

^[1]

Fuels and Energy Technology Institute &, WA School of Mines: MineralsEnergy and Chemical EngineeringCurtin University Perth Western Australia 6102 Australia
Department of Materials Science and EngineeringStanford University Stanford CA 94305 USA
Advanced Carbon DivisionShenyang National Laboratory for Materials ScienceInstitute of Metal ResearchChinese Academy of Sciences Shenyang Liaoning 110016 China
John de Laeter CentreCurtin University Perth Western Australia 6102 Australia
Australian Synchrotron Clayton Victoria 3168 Australia
Centre for MicroscopyCharacterization and Analysis (CMCA) and School of Molecular SciencesThe University of Western Australia Perth Western Australia 6009 Australia
Materials Science and Technology DivisionOak Ridge National Laboratory Oak Ridge TN 37831 USA
School of Chemistry and Molecular BiosciencesThe University of Queensland Brisbane Queensland 4072 Australia, Faculty of ScienceHealth, Education and EngineeringUniversity of Sunshine Coast Maroochydore DC Queensland 4558 Australia

Publication Date:: 2019-11-14

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1580282

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Advanced Functional Materials

Additional Journal Information:: Journal Name: Advanced Functional Materials Journal Volume: 30 Journal Issue: 6; Journal ID: ISSN 1616-301X

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Zhao, Shiyong, Chen, Guangxu, Zhou, Guangmin, Yin, Li‐Chang, Veder, Jean‐Pierre, Johannessen, Bernt, Saunders, Martin, Yang, Shi‐Ze, De Marco, Roland, Liu, Chang, and Jiang, San Ping. A Universal Seeding Strategy to Synthesize Single Atom Catalysts on 2D Materials for Electrocatalytic Applications.  Germany: N. p., 2019. 
        Web.  doi:10.1002/adfm.201906157.

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                    Zhao, Shiyong, Chen, Guangxu, Zhou, Guangmin, Yin, Li‐Chang, Veder, Jean‐Pierre, Johannessen, Bernt, Saunders, Martin, Yang, Shi‐Ze, De Marco, Roland, Liu, Chang, & Jiang, San Ping. A Universal Seeding Strategy to Synthesize Single Atom Catalysts on 2D Materials for Electrocatalytic Applications.  Germany.  doi:https://doi.org/10.1002/adfm.201906157

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                    Zhao, Shiyong, Chen, Guangxu, Zhou, Guangmin, Yin, Li‐Chang, Veder, Jean‐Pierre, Johannessen, Bernt, Saunders, Martin, Yang, Shi‐Ze, De Marco, Roland, Liu, Chang, and Jiang, San Ping. Thu .  
        "A Universal Seeding Strategy to Synthesize Single Atom Catalysts on 2D Materials for Electrocatalytic Applications".  Germany.  doi:https://doi.org/10.1002/adfm.201906157.

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@article{osti_1580282,

  title        = {A Universal Seeding Strategy to Synthesize Single Atom Catalysts on 2D Materials for Electrocatalytic Applications},

  author       = {Zhao, Shiyong and Chen, Guangxu and Zhou, Guangmin and Yin, Li‐Chang and Veder, Jean‐Pierre and Johannessen, Bernt and Saunders, Martin and Yang, Shi‐Ze and De Marco, Roland and Liu, Chang and Jiang, San Ping},

  abstractNote = {},

  doi          = {10.1002/adfm.201906157},

  journal      = {Advanced Functional Materials},

  number       = 6,

  volume       = 30,

  place        = {Germany},

  year         = {2019},

  month        = {11}

}

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DOI: https://doi.org/10.1002/adfm.201906157

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Title: A Universal Seeding Strategy to Synthesize Single Atom Catalysts on 2D Materials for Electrocatalytic Applications

Citation Formats

Cluster–surface interaction: From soft landing to implantation journal, October 2011

Bottom-up precise synthesis of stable platinum dimers on graphene journal, October 2017

Metal–Organic Frameworks for Electrocatalytic Reduction of Carbon Dioxide journal, October 2015

Fine Size Control of Platinum on Carbon Nanotubes: From Single Atoms to Clusters journal, January 2006

Single-Atom Pt as Co-Catalyst for Enhanced Photocatalytic H 2 Evolution journal, January 2016

Golden single-atomic-site platinum electrocatalysts journal, September 2018

Atomically Dispersed Transition Metals on Carbon Nanotubes with Ultrahigh Loading for Selective Electrochemical Carbon Dioxide Reduction journal, February 2018

Iron Single Atoms on Graphene as Nonprecious Metal Catalysts for High‐Temperature Polymer Electrolyte Membrane Fuel Cells journal, March 2019

Unsaturated edge-anchored Ni single atoms on porous microwave exfoliated graphene oxide for electrochemical CO2 journal, April 2019

Isolated Metal Atom Geometries as a Strategy for Selective Heterogeneous Hydrogenations journal, March 2012

A Polymer Encapsulation Strategy to Synthesize Porous Nitrogen-Doped Carbon-Nanosphere-Supported Metal Isolated-Single-Atomic-Site Catalysts journal, March 2018

Bottom-up synthesis of iron and nitrogen dual-doped porous carbon nanosheets for efficient oxygen reduction journal, January 2019

Catalysis by Supported Single Metal Atoms journal, November 2016

Scale-Up Biomass Pathway to Cobalt Single-Site Catalysts Anchored on N-Doped Porous Carbon Nanobelt with Ultrahigh Surface Area journal, July 2018

Molecule-Level g-C 3 N 4 Coordinated Transition Metals as a New Class of Electrocatalysts for Oxygen Electrode Reactions journal, February 2017

Single-Atom Electrocatalysts journal, October 2017

A General Approach to Preferential Formation of Active Fe–N x Sites in Fe–N/C Electrocatalysts for Efficient Oxygen Reduction Reaction journal, November 2016

Stabilization of Single Metal Atoms on Graphitic Carbon Nitride journal, January 2017

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set journal, October 1996

From ultrasoft pseudopotentials to the projector augmented-wave method journal, January 1999

Heterogeneous single-atom catalysis journal, May 2018

Direct transformation of bulk copper into copper single sites via emitting and trapping of atoms journal, October 2018

Atomically Dispersed Iron-Nitrogen Species as Electrocatalysts for Bifunctional Oxygen Evolution and Reduction Reactions journal, December 2016

Catalysis Applications of Size-Selected Cluster Deposition journal, November 2015

Single-Atom Pd 1 /Graphene Catalyst Achieved by Atomic Layer Deposition: Remarkable Performance in Selective Hydrogenation of 1,3-Butadiene journal, August 2015

Transition-Metal Single Atoms in a Graphene Shell as Active Centers for Highly Efficient Artificial Photosynthesis journal, December 2017

Enhanced electrocatalytic CO2 reduction via field-induced reagent concentration journal, August 2016

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Single-Atom Catalysts: A New Frontier in Heterogeneous Catalysis journal, April 2013

Single-atom Catalysis Using Pt/Graphene Achieved through Atomic Layer Deposition journal, May 2013

Fabrication of Single-Atom Catalysts with Precise Structure and High Metal Loading journal, October 2018

Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction journal, February 2018

The Current Performance of the Wide Range (90–2500 eV) Soft X-ray Beamline at the Australian Synchrotron conference, January 2010

Single-atom catalysis of CO oxidation using Pt1/FeOx journal, July 2011

A Molecular Surface Functionalization Approach to Tuning Nanoparticle Electrocatalysts for Carbon Dioxide Reduction journal, June 2016

A general route via formamide condensation to prepare atomically dispersed metal–nitrogen–carbon electrocatalysts for energy technologies journal, January 2019

Single Cobalt Atoms Anchored on Porous N-Doped Graphene with Dual Reaction Sites for Efficient Fenton-like Catalysis journal, August 2018

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A cocoon silk chemistry strategy to ultrathin N-doped carbon nanosheet with metal single-site catalysts journal, September 2018

A universal principle for a rational design of single-atom electrocatalysts journal, April 2018

Cluster–surface interaction: From soft landing to implantation
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Bottom-up precise synthesis of stable platinum dimers on graphene
journal, October 2017

Metal–Organic Frameworks for Electrocatalytic Reduction of Carbon Dioxide
journal, October 2015

Fine Size Control of Platinum on Carbon Nanotubes: From Single Atoms to Clusters
journal, January 2006

Single-Atom Pt as Co-Catalyst for Enhanced Photocatalytic H ₂ Evolution
journal, January 2016

Golden single-atomic-site platinum electrocatalysts
journal, September 2018

Atomically Dispersed Transition Metals on Carbon Nanotubes with Ultrahigh Loading for Selective Electrochemical Carbon Dioxide Reduction
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Iron Single Atoms on Graphene as Nonprecious Metal Catalysts for High‐Temperature Polymer Electrolyte Membrane Fuel Cells
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Unsaturated edge-anchored Ni single atoms on porous microwave exfoliated graphene oxide for electrochemical CO2
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Isolated Metal Atom Geometries as a Strategy for Selective Heterogeneous Hydrogenations
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A Polymer Encapsulation Strategy to Synthesize Porous Nitrogen-Doped Carbon-Nanosphere-Supported Metal Isolated-Single-Atomic-Site Catalysts
journal, March 2018

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journal, November 2016

Scale-Up Biomass Pathway to Cobalt Single-Site Catalysts Anchored on N-Doped Porous Carbon Nanobelt with Ultrahigh Surface Area
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Molecule-Level g-C ₃ N ₄ Coordinated Transition Metals as a New Class of Electrocatalysts for Oxygen Electrode Reactions
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A General Approach to Preferential Formation of Active Fe–N _x Sites in Fe–N/C Electrocatalysts for Efficient Oxygen Reduction Reaction
journal, November 2016

Stabilization of Single Metal Atoms on Graphitic Carbon Nitride
journal, January 2017

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996

From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999

Heterogeneous single-atom catalysis
journal, May 2018

Direct transformation of bulk copper into copper single sites via emitting and trapping of atoms
journal, October 2018

Atomically Dispersed Iron-Nitrogen Species as Electrocatalysts for Bifunctional Oxygen Evolution and Reduction Reactions
journal, December 2016

Catalysis Applications of Size-Selected Cluster Deposition
journal, November 2015

Single-Atom Pd ₁ /Graphene Catalyst Achieved by Atomic Layer Deposition: Remarkable Performance in Selective Hydrogenation of 1,3-Butadiene
journal, August 2015

Transition-Metal Single Atoms in a Graphene Shell as Active Centers for Highly Efficient Artificial Photosynthesis
journal, December 2017

Enhanced electrocatalytic CO2 reduction via field-induced reagent concentration
journal, August 2016

Boosting oxygen reduction catalysis with abundant copper single atom active sites
journal, January 2018

Single-Atom Catalysts: A New Frontier in Heterogeneous Catalysis
journal, April 2013

Single-atom Catalysis Using Pt/Graphene Achieved through Atomic Layer Deposition
journal, May 2013

Fabrication of Single-Atom Catalysts with Precise Structure and High Metal Loading
journal, October 2018

Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction
journal, February 2018

The Current Performance of the Wide Range (90–2500 eV) Soft X-ray Beamline at the Australian Synchrotron
conference, January 2010

Single-atom catalysis of CO oxidation using Pt1/FeOx
journal, July 2011

A Molecular Surface Functionalization Approach to Tuning Nanoparticle Electrocatalysts for Carbon Dioxide Reduction
journal, June 2016

A general route via formamide condensation to prepare atomically dispersed metal–nitrogen–carbon electrocatalysts for energy technologies
journal, January 2019

Single Cobalt Atoms Anchored on Porous N-Doped Graphene with Dual Reaction Sites for Efficient Fenton-like Catalysis
journal, August 2018

Temperature-Controlled Selectivity of Hydrogenation and Hydrodeoxygenation in the Conversion of Biomass Molecule by the Ru ₁ /mpg-C ₃ N ₄ Catalyst
journal, August 2018

Accelerating water dissociation kinetics by isolating cobalt atoms into ruthenium lattice
journal, November 2018

Pd Single‐Atom Catalysts on Nitrogen‐Doped Graphene for the Highly Selective Photothermal Hydrogenation of Acetylene to Ethylene
journal, February 2019

N-doped carbon nanotubes containing a high concentration of single iron atoms for efficient oxygen reduction
journal, January 2018

A cocoon silk chemistry strategy to ultrathin N-doped carbon nanosheet with metal single-site catalysts
journal, September 2018

A universal principle for a rational design of single-atom electrocatalysts
journal, April 2018