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Title: Assessing the impacts of dynamic soft-templates innate to switchable ionic liquids on nanoparticulate green rust crystalline structures

Abstract

This experimental and theoretical study investigates how dynamic solvation environments in switchable ionic liquids regulate the composition of nanoparticulate green rust. Here, a custom microfluidic device enables in situ X-ray absorption spectroscopy to elucidate characterization of the solvent structure and speciation of reaction intermediates of air-sensitive nanoparticles growing in solution.

Authors:
ORCiD logo [1]; ORCiD logo [1];  [1];  [1];  [1];  [2]; ORCiD logo [1]
  1. Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1580226
Alternate Identifier(s):
OSTI ID: 1562323
Report Number(s):
BNL-212440-2019-JAAM
Journal ID: ISSN 1359-7345; CHCOFS
Grant/Contract Number:  
SC0012704; AC05-76RL01830; 67038
Resource Type:
Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 55; Journal Issue: 75; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; switchable ionic liquids (SWILs); XAS; CO2 capture; solvent structure; SALVI; green rust

Citation Formats

Zheng, Jian, Yu, Xiao -Ying, Nguyen, Manh -Thuong, Lao, David, Zhu, Yifeng, Wang, Feng, and Heldebrant, David J. Assessing the impacts of dynamic soft-templates innate to switchable ionic liquids on nanoparticulate green rust crystalline structures. United States: N. p., 2019. Web. doi:10.1039/C9CC04581C.
Zheng, Jian, Yu, Xiao -Ying, Nguyen, Manh -Thuong, Lao, David, Zhu, Yifeng, Wang, Feng, & Heldebrant, David J. Assessing the impacts of dynamic soft-templates innate to switchable ionic liquids on nanoparticulate green rust crystalline structures. United States. doi:10.1039/C9CC04581C.
Zheng, Jian, Yu, Xiao -Ying, Nguyen, Manh -Thuong, Lao, David, Zhu, Yifeng, Wang, Feng, and Heldebrant, David J. Fri . "Assessing the impacts of dynamic soft-templates innate to switchable ionic liquids on nanoparticulate green rust crystalline structures". United States. doi:10.1039/C9CC04581C.
@article{osti_1580226,
title = {Assessing the impacts of dynamic soft-templates innate to switchable ionic liquids on nanoparticulate green rust crystalline structures},
author = {Zheng, Jian and Yu, Xiao -Ying and Nguyen, Manh -Thuong and Lao, David and Zhu, Yifeng and Wang, Feng and Heldebrant, David J.},
abstractNote = {This experimental and theoretical study investigates how dynamic solvation environments in switchable ionic liquids regulate the composition of nanoparticulate green rust. Here, a custom microfluidic device enables in situ X-ray absorption spectroscopy to elucidate characterization of the solvent structure and speciation of reaction intermediates of air-sensitive nanoparticles growing in solution.},
doi = {10.1039/C9CC04581C},
journal = {ChemComm},
number = 75,
volume = 55,
place = {United States},
year = {2019},
month = {8}
}

Journal Article:
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This content will become publicly available on August 30, 2020
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