Tomographic 3D Analysis of Reduction Displacement Reaction with Associated Formation of a Conductive Network in High Energy Primary Batteries

Bruck, Andrea M.; Li, Yue Ru; Brady, Alexander B.; Chuang, Andrew (Chihpin); Okasinski, John S.; Takeuchi, Kenneth J.; Takeuchi, Esther S.; Marschilok, Amy C.

doi:10.1149/2.0411914jes

Title: Tomographic 3D Analysis of Reduction Displacement Reaction with Associated Formation of a Conductive Network in High Energy Primary Batteries

Abstract

Hybrid Ag₂VO₂PO₄-CF_x battery electrodes with high energy and pulse performance were investigated in regards to their structural and morphological changes during electrochemical discharge. Reduction products of CF_x and Ag₂VO₂PO₄, carbon and Ag⁰, respectively, were identified via bulk laboratory X-ray diffraction and were characterized further by SEM-EDS to identify variations in Ag₂VO₂PO₄-Ag⁰ agglomerate distributions in the electrode. X-ray tomography was used to characterize the statistical formation and redistribution of these agglomerates at a higher discharge state. Using this technique, we observed the agglomerates within the electrode to increase from 20–40 μm³ to larger sizes (>500 μm³) upon discharge. These data were used to rationalize the changes in conductivity of the composite material upon galvanostatic discharge, as determined under high rate pulsatile discharge and impedance spectroscopy. As a result, both volumetric and spatial redistribution of the materials identified in this study provides insight toward the development and understanding of future high energy and high power primary batteries.

Authors:

Bruck, Andrea M. ^[1]; Li, Yue Ru ^[1]; Brady, Alexander B. ^[1]; Chuang, Andrew ^[2]; Okasinski, John S. ^[3];

^[1];

^[4];

^[4]

Stony Brook Univ., Stony Brook, NY (United States)
(Chihpin) [Argonne National Lab. (ANL), Lemont, IL (United States)
Argonne National Lab. (ANL), Lemont, IL (United States)
Stony Brook Univ., Stony Brook, NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)

Publication Date:: Thu Sep 19 00:00:00 EDT 2019

Research Org.:: Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2mt); Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division

OSTI Identifier:: 1580220

Report Number(s):: BNL-212442-2019-JAAM
Journal ID: ISSN 0013-4651

Grant/Contract Number:: SC0012704; SC0012673

Resource Type:: Accepted Manuscript

Journal Name:: Journal of the Electrochemical Society

Additional Journal Information:: Journal Volume: 166; Journal Issue: 14; Journal ID: ISSN 0013-4651

Publisher:: The Electrochemical Society

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE; batteries; Batteries - Lithium; carbon monofluoride; silver vanadium phosphorous oxide; tomography

Citation Formats


                    Bruck, Andrea M., Li, Yue Ru, Brady, Alexander B., Chuang, Andrew, Okasinski, John S., Takeuchi, Kenneth J., Takeuchi, Esther S., and Marschilok, Amy C. Tomographic 3D Analysis of Reduction Displacement Reaction with Associated Formation of a Conductive Network in High Energy Primary Batteries.  United States: N. p., 2019. 
Web.  doi:10.1149/2.0411914jes.

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                    Bruck, Andrea M., Li, Yue Ru, Brady, Alexander B., Chuang, Andrew, Okasinski, John S., Takeuchi, Kenneth J., Takeuchi, Esther S., & Marschilok, Amy C. Tomographic 3D Analysis of Reduction Displacement Reaction with Associated Formation of a Conductive Network in High Energy Primary Batteries.  United States.  https://doi.org/10.1149/2.0411914jes

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                    Bruck, Andrea M., Li, Yue Ru, Brady, Alexander B., Chuang, Andrew, Okasinski, John S., Takeuchi, Kenneth J., Takeuchi, Esther S., and Marschilok, Amy C. Thu .  
"Tomographic 3D Analysis of Reduction Displacement Reaction with Associated Formation of a Conductive Network in High Energy Primary Batteries".  United States.  https://doi.org/10.1149/2.0411914jes.  https://www.osti.gov/servlets/purl/1580220.

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@article{osti_1580220,

  title        = {Tomographic 3D Analysis of Reduction Displacement Reaction with Associated Formation of a Conductive Network in High Energy Primary Batteries},

  author       = {Bruck, Andrea M. and Li, Yue Ru and Brady, Alexander B. and Chuang, Andrew and Okasinski, John S. and Takeuchi, Kenneth J. and Takeuchi, Esther S. and Marschilok, Amy C.},

  abstractNote = {Hybrid Ag2VO2PO4-CFx battery electrodes with high energy and pulse performance were investigated in regards to their structural and morphological changes during electrochemical discharge. Reduction products of CFx and Ag2VO2PO4, carbon and Ag0, respectively, were identified via bulk laboratory X-ray diffraction and were characterized further by SEM-EDS to identify variations in Ag2VO2PO4-Ag0 agglomerate distributions in the electrode. X-ray tomography was used to characterize the statistical formation and redistribution of these agglomerates at a higher discharge state. Using this technique, we observed the agglomerates within the electrode to increase from 20–40 μm3 to larger sizes (>500 μm3) upon discharge. These data were used to rationalize the changes in conductivity of the composite material upon galvanostatic discharge, as determined under high rate pulsatile discharge and impedance spectroscopy. As a result, both volumetric and spatial redistribution of the materials identified in this study provides insight toward the development and understanding of future high energy and high power primary batteries.},

  doi          = {10.1149/2.0411914jes},

  journal      = {Journal of the Electrochemical Society},

  number       = 14,

  volume       = 166,

  place        = {United States},

  year         = {Thu Sep 19 00:00:00 EDT 2019},

  month        = {Thu Sep 19 00:00:00 EDT 2019}

}

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Title: Tomographic 3D Analysis of Reduction Displacement Reaction with Associated Formation of a Conductive Network in High Energy Primary Batteries

Abstract

Citation Formats

Batteries used to power implantable biomedical devices journal, December 2012

Lithium/Carbon Monofluoride (Li/CFx): A New Pacemaker Battery journal, November 1996

Dual-chemistry cathode system for high-rate pulse applications journal, August 2005

Hybrid cathode lithium batteries for implantable medical applications journal, November 2006

Mapping the Anode Surface-Electrolyte Interphase: Investigating a Life Limiting Process of Lithium Primary Batteries journal, February 2015

Electrochemical reduction of an Ag 2 VO 2 PO 4 particle: dramatic increase of local electronic conductivity journal, January 2015

Electrochemical Reduction of Silver Vanadium Phosphorus Oxide, Ag 2 VO 2 PO 4 : The Formation of Electrically Conductive Metallic Silver Nanoparticles journal, October 2009

Preparation and Electrochemistry of Silver Vanadium Phosphorous Oxide, Ag[sub 2]VO[sub 2]PO[sub 4] journal, January 2009

In situ visualization of Li/Ag2VP2O8 batteries revealing rate-dependent discharge mechanism journal, January 2015

Solid-State Synthesis and Characterization of Silver Vanadium Oxide for Use as a Cathode Material for Lithium Batteries journal, April 1994

Progress towards high-power Li/CF x batteries: electrode architectures using carbon nanotubes with CF x journal, January 2015

Electrical and thermal properties of fluorine-intercalated graphite fibers journal, March 1990

Simulation of Pulse Discharge of the Li–CF[sub x] System journal, January 2008

Hybrid Ag 2 VO 2 PO 4 /CF x as a High Capacity and Energy Cathode for Primary Batteries journal, January 2017

Multi-scale 3D investigations of a commercial 18650 Li-ion battery with correlative electron- and X-ray microscopy journal, July 2017

X-Ray Tomography for Lithium Ion Battery Research: A Practical Guide journal, July 2017

Multi-Scale Correlative Tomography of a Li-Ion Battery Composite Cathode journal, July 2016

Synchrotron X-ray Analytical Techniques for Studying Materials Electrochemistry in Rechargeable Batteries journal, September 2017

X-Ray Tomography of Porous, Transition Metal Oxide Based Lithium Ion Battery Electrodes journal, March 2013

Lithiation-Induced Dilation Mapping in a Lithium-Ion Battery Electrode by 3D X-Ray Microscopy and Digital Volume Correlation journal, November 2013

Combining operando synchrotron X-ray tomographic microscopy and scanning X-ray diffraction to study lithium ion batteries journal, June 2016

Investigating lithium-ion battery materials during overcharge-induced thermal runaway: an operando and multi-scale X-ray CT study journal, January 2016

Robust 3D Zn Sponges Enable High-Power, Energy-Dense Alkaline Batteries journal, December 2018

Multiscale characterization of a lithium/sulfur battery by coupling operando X-ray tomography and spatially-resolved diffraction journal, June 2017

Novel Topotactic Conversion of an Organically Templated Vanadyl Phosphate Framework into Layered Structures journal, January 2005

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NIH Image to ImageJ: 25 years of image analysis journal, June 2012

Silver vanadium diphosphate Ag2VP2O8: Electrochemistry and characterization of reduced material providing mechanistic insights journal, April 2013

Applications of Carbon Nanotubes in CF x Electrodes for High-power Li/CF x Batteries journal, January 2016

Structure of Carbon Monofluoride journal, December 1948

Using all energy in a battery journal, January 2015

Li/Ag 2 VO 2 PO 4 batteries: the roles of composite electrode constituents on electrochemistry journal, January 2016

Novel Topotactic Conversion of an Organically Templated Vanadyl Phosphate Framework into Layered Structures. journal, March 2005

Li/Ag 2 VO 2 PO 4 batteries: the roles of composite electrode constituents on electrochemistry journal, May 2017

Combining operando synchrotron X-ray tomographic microscopy and scanning X-ray diffraction to study lithium ion batteries text, January 2016

Batteries used to power implantable biomedical devices
journal, December 2012

Lithium/Carbon Monofluoride (Li/CFx): A New Pacemaker Battery
journal, November 1996

Dual-chemistry cathode system for high-rate pulse applications
journal, August 2005

Hybrid cathode lithium batteries for implantable medical applications
journal, November 2006

Mapping the Anode Surface-Electrolyte Interphase: Investigating a Life Limiting Process of Lithium Primary Batteries
journal, February 2015

Electrochemical reduction of an Ag ₂ VO ₂ PO ₄ particle: dramatic increase of local electronic conductivity
journal, January 2015

Electrochemical Reduction of Silver Vanadium Phosphorus Oxide, Ag ₂ VO ₂ PO ₄ : The Formation of Electrically Conductive Metallic Silver Nanoparticles
journal, October 2009

Preparation and Electrochemistry of Silver Vanadium Phosphorous Oxide, Ag[sub 2]VO[sub 2]PO[sub 4]
journal, January 2009

In situ visualization of Li/Ag2VP2O8 batteries revealing rate-dependent discharge mechanism
journal, January 2015

Solid-State Synthesis and Characterization of Silver Vanadium Oxide for Use as a Cathode Material for Lithium Batteries
journal, April 1994

Progress towards high-power Li/CF _x batteries: electrode architectures using carbon nanotubes with CF _x
journal, January 2015

Electrical and thermal properties of fluorine-intercalated graphite fibers
journal, March 1990

Simulation of Pulse Discharge of the Li–CF[sub x] System
journal, January 2008

Hybrid Ag ₂ VO ₂ PO ₄ /CF _x as a High Capacity and Energy Cathode for Primary Batteries
journal, January 2017

Multi-scale 3D investigations of a commercial 18650 Li-ion battery with correlative electron- and X-ray microscopy
journal, July 2017

X-Ray Tomography for Lithium Ion Battery Research: A Practical Guide
journal, July 2017

Multi-Scale Correlative Tomography of a Li-Ion Battery Composite Cathode
journal, July 2016

Synchrotron X-ray Analytical Techniques for Studying Materials Electrochemistry in Rechargeable Batteries
journal, September 2017

X-Ray Tomography of Porous, Transition Metal Oxide Based Lithium Ion Battery Electrodes
journal, March 2013

Lithiation-Induced Dilation Mapping in a Lithium-Ion Battery Electrode by 3D X-Ray Microscopy and Digital Volume Correlation
journal, November 2013

Combining operando synchrotron X-ray tomographic microscopy and scanning X-ray diffraction to study lithium ion batteries
journal, June 2016

Investigating lithium-ion battery materials during overcharge-induced thermal runaway: an operando and multi-scale X-ray CT study
journal, January 2016

Robust 3D Zn Sponges Enable High-Power, Energy-Dense Alkaline Batteries
journal, December 2018

Multiscale characterization of a lithium/sulfur battery by coupling operando X-ray tomography and spatially-resolved diffraction
journal, June 2017

Novel Topotactic Conversion of an Organically Templated Vanadyl Phosphate Framework into Layered Structures
journal, January 2005

High-energy x-ray scattering studies of battery materials
journal, June 2016

NIH Image to ImageJ: 25 years of image analysis
journal, June 2012

Silver vanadium diphosphate Ag2VP2O8: Electrochemistry and characterization of reduced material providing mechanistic insights
journal, April 2013

Applications of Carbon Nanotubes in CF _x Electrodes for High-power Li/CF _x Batteries
journal, January 2016

Structure of Carbon Monofluoride
journal, December 1948

Using all energy in a battery
journal, January 2015

Li/Ag ₂ VO ₂ PO ₄ batteries: the roles of composite electrode constituents on electrochemistry
journal, January 2016

Novel Topotactic Conversion of an Organically Templated Vanadyl Phosphate Framework into Layered Structures.
journal, March 2005

Li/Ag ₂ VO ₂ PO ₄ batteries: the roles of composite electrode constituents on electrochemistry
journal, May 2017

Combining operando synchrotron X-ray tomographic microscopy and scanning X-ray diffraction to study lithium ion batteries
text, January 2016