Interface effects on self-forming rechargeable Li/I2-based solid state batteries

Abraham, Alyson; Dunkin, Mikaela R.; Huang, Jianping; Zhang, Bingjie; Takeuchi, Kenneth J.; Takeuchi, Esther S.; Marschilok, Amy C.

doi:10.1557/mrc.2019.42

Title: Interface effects on self-forming rechargeable Li/I₂-based solid state batteries

Abstract

Solid state batteries are an emerging alternative to traditional liquid electrolyte cells that provide potential for safe and high-energy density power sources. This report describes a self-forming, solid state battery based on the Li/I₂ couple using an LiI-rich LiI(3-hydroxypropionitrile)₂ electrolyte (LiI–LiI(HPN)₂). As the negative and positive active materials are generated in situ, the solid electrolyte–current collector interfaces play a critical role in determining the electrochemical response of the battery. Furthermore, we report the investigation of solid electrolyte–current collector interfaces with a self-forming LiI–LiI(HPN)₂ solid electrolyte and the role of varying interface design in reducing resistance during cycling.

Authors:

Abraham, Alyson ^[1]; Dunkin, Mikaela R. ^[1]; Huang, Jianping ^[1]; Zhang, Bingjie ^[1]; Takeuchi, Kenneth J. ^[1]; Takeuchi, Esther S. ^[2];

^[2]

Stony Brook Univ., Stony Brook, NY (United States)
Stony Brook Univ., Stony Brook, NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)

Publication Date:: Fri Apr 26 00:00:00 EDT 2019

Research Org.:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

OSTI Identifier:: 1580218

Report Number(s):: BNL-212438-2019-JAAM
Journal ID: ISSN 2159-6859; applab

Grant/Contract Number:: SC0012704

Resource Type:: Accepted Manuscript

Journal Name:: MRS Communications

Additional Journal Information:: Journal Volume: 9; Journal Issue: 02; Journal ID: ISSN 2159-6859

Publisher:: Materials Research Society - Cambridge University Press

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE

Citation Formats


                    Abraham, Alyson, Dunkin, Mikaela R., Huang, Jianping, Zhang, Bingjie, Takeuchi, Kenneth J., Takeuchi, Esther S., and Marschilok, Amy C. Interface effects on self-forming rechargeable Li/I2-based solid state batteries.  United States: N. p., 2019. 
Web.  doi:10.1557/mrc.2019.42.

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                    Abraham, Alyson, Dunkin, Mikaela R., Huang, Jianping, Zhang, Bingjie, Takeuchi, Kenneth J., Takeuchi, Esther S., & Marschilok, Amy C. Interface effects on self-forming rechargeable Li/I2-based solid state batteries.  United States.  https://doi.org/10.1557/mrc.2019.42

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                    Abraham, Alyson, Dunkin, Mikaela R., Huang, Jianping, Zhang, Bingjie, Takeuchi, Kenneth J., Takeuchi, Esther S., and Marschilok, Amy C. Fri .  
"Interface effects on self-forming rechargeable Li/I2-based solid state batteries".  United States.  https://doi.org/10.1557/mrc.2019.42.  https://www.osti.gov/servlets/purl/1580218.

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@article{osti_1580218,

  title        = {Interface effects on self-forming rechargeable Li/I2-based solid state batteries},

  author       = {Abraham, Alyson and Dunkin, Mikaela R. and Huang, Jianping and Zhang, Bingjie and Takeuchi, Kenneth J. and Takeuchi, Esther S. and Marschilok, Amy C.},

  abstractNote = {Solid state batteries are an emerging alternative to traditional liquid electrolyte cells that provide potential for safe and high-energy density power sources. This report describes a self-forming, solid state battery based on the Li/I2 couple using an LiI-rich LiI(3-hydroxypropionitrile)2 electrolyte (LiI–LiI(HPN)2). As the negative and positive active materials are generated in situ, the solid electrolyte–current collector interfaces play a critical role in determining the electrochemical response of the battery. Furthermore, we report the investigation of solid electrolyte–current collector interfaces with a self-forming LiI–LiI(HPN)2 solid electrolyte and the role of varying interface design in reducing resistance during cycling.},

  doi          = {10.1557/mrc.2019.42},

  journal      = {MRS Communications},

  number       = 02,

  volume       = 9,

  place        = {United States},

  year         = {Fri Apr 26 00:00:00 EDT 2019},

  month        = {Fri Apr 26 00:00:00 EDT 2019}

}

Copy to clipboard

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Title: Interface effects on self-forming rechargeable Li/I2-based solid state batteries

Abstract

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Title: Interface effects on self-forming rechargeable Li/I₂-based solid state batteries

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