Novel twin-perovskite nanocomposite of Ba–Ce–Fe–Co–O as a promising triple conducting cathode material for protonic ceramic fuel cells
Abstract
A stable twin-perovskite nanocomposite of Ba–Ce–Fe–Co–O was synthesized by a one-pot Pechini synthesis method. This discovery has opened a new avenue in the development of high-performance cathodes for protonic ceramic fuel cells (PCFCs). The symmetrical cells showed relatively low cathode area-specific resistance compared with existing the state-of-the-art PCFC cathodes. Furthermore, the single cells demonstrated a low polarization resistance of 0.075 Ω cm² and a high peak power density of 335 mW cm² at 700 °C under an Air/H2 gradient.
- Authors:
-
- Clemson University, SC (United States)
- (Joshua) [Clemson University, SC (United States)
- Publication Date:
- Research Org.:
- Clemson Univ., SC (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Hydrogen Fuel Cell Technologies Office (HFTO); USDOE
- OSTI Identifier:
- 2202861
- Alternate Identifier(s):
- OSTI ID: 1580185
- Grant/Contract Number:
- EE0008428
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Power Sources
- Additional Journal Information:
- Journal Volume: 450; Journal ID: ISSN 0378-7753
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 08 HYDROGEN
Citation Formats
Zhao, Zeyu, Cui, Jiang, Zou, Minda, Mu, Shenglong, Huang, Hua, Meng, Yuqing, He, Kai, Brinkman, Kyle S., and Tong, Jianhua. Novel twin-perovskite nanocomposite of Ba–Ce–Fe–Co–O as a promising triple conducting cathode material for protonic ceramic fuel cells. United States: N. p., 2019.
Web. doi:10.1016/j.jpowsour.2019.227609.
Zhao, Zeyu, Cui, Jiang, Zou, Minda, Mu, Shenglong, Huang, Hua, Meng, Yuqing, He, Kai, Brinkman, Kyle S., & Tong, Jianhua. Novel twin-perovskite nanocomposite of Ba–Ce–Fe–Co–O as a promising triple conducting cathode material for protonic ceramic fuel cells. United States. https://doi.org/10.1016/j.jpowsour.2019.227609
Zhao, Zeyu, Cui, Jiang, Zou, Minda, Mu, Shenglong, Huang, Hua, Meng, Yuqing, He, Kai, Brinkman, Kyle S., and Tong, Jianhua. Mon .
"Novel twin-perovskite nanocomposite of Ba–Ce–Fe–Co–O as a promising triple conducting cathode material for protonic ceramic fuel cells". United States. https://doi.org/10.1016/j.jpowsour.2019.227609. https://www.osti.gov/servlets/purl/2202861.
@article{osti_2202861,
title = {Novel twin-perovskite nanocomposite of Ba–Ce–Fe–Co–O as a promising triple conducting cathode material for protonic ceramic fuel cells},
author = {Zhao, Zeyu and Cui, Jiang and Zou, Minda and Mu, Shenglong and Huang, Hua and Meng, Yuqing and He, Kai and Brinkman, Kyle S. and Tong, Jianhua},
abstractNote = {A stable twin-perovskite nanocomposite of Ba–Ce–Fe–Co–O was synthesized by a one-pot Pechini synthesis method. This discovery has opened a new avenue in the development of high-performance cathodes for protonic ceramic fuel cells (PCFCs). The symmetrical cells showed relatively low cathode area-specific resistance compared with existing the state-of-the-art PCFC cathodes. Furthermore, the single cells demonstrated a low polarization resistance of 0.075 Ω cm² and a high peak power density of 335 mW cm² at 700 °C under an Air/H2 gradient.},
doi = {10.1016/j.jpowsour.2019.227609},
journal = {Journal of Power Sources},
number = ,
volume = 450,
place = {United States},
year = {Mon Dec 23 00:00:00 EST 2019},
month = {Mon Dec 23 00:00:00 EST 2019}
}
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Works referenced in this record:
Enhanced Sulfur and Coking Tolerance of a Mixed Ion Conductor for SOFCs: BaZr0.1Ce0.7Y0.2–xYbxO3–δ
journal, October 2009
- Yang, L.; Wang, S.; Blinn, K.
- Science, Vol. 326, Issue 5949, p. 126-129
Highly durable, coking and sulfur tolerant, fuel-flexible protonic ceramic fuel cells
journal, May 2018
- Duan, Chuancheng; Kee, Robert J.; Zhu, Huayang
- Nature, Vol. 557, Issue 7704
Exceptional power density and stability at intermediate temperatures in protonic ceramic fuel cells
journal, February 2018
- Choi, Sihyuk; Kucharczyk, Chris J.; Liang, Yangang
- Nature Energy, Vol. 3, Issue 3
A 5 × 5 cm2 protonic ceramic fuel cell with a power density of 1.3 W cm–2 at 600 °C
journal, August 2018
- An, Hyegsoon; Lee, Hae-Weon; Kim, Byung-Kook
- Nature Energy, Vol. 3, Issue 10
Mixed-Conducting Perovskites as Cathode Materials for Protonic Ceramic Fuel Cells: Understanding the Trends in Proton Uptake
journal, July 2018
- Zohourian, Reihaneh; Merkle, Rotraut; Raimondi, Giulia
- Advanced Functional Materials, Vol. 28, Issue 35
Hydration Properties and Rate Determining Steps of the Oxygen Reduction Reaction of Perovskite-Related Oxides as H + -SOFC Cathodes
journal, January 2012
- Grimaud, A.; Mauvy, F.; Bassat, J. M.
- Journal of The Electrochemical Society, Vol. 159, Issue 6
Characterization and evaluation of BaCo0.7Fe0.2Nb0.1O3−δ as a cathode for proton-conducting solid oxide fuel cells
journal, January 2012
- Lin, Ye; Zhou, Wei; Sunarso, Jaka
- International Journal of Hydrogen Energy, Vol. 37, Issue 1
Triple-Conducting Layered Perovskites as Cathode Materials for Proton-Conducting Solid Oxide Fuel Cells
journal, August 2014
- Kim, Junyoung; Sengodan, Sivaprakash; Kwon, Goeun
- ChemSusChem, Vol. 7, Issue 10
A mixed proton, oxygen ion, and electron conducting cathode for SOFCs based on oxide proton conductors
journal, January 2010
- Yang, Lei; Liu, Ze; Wang, Shizhong
- Journal of Power Sources, Vol. 195, Issue 2
A novel cathode material BaCe0.4Sm0.2Co0.4O3−δ for proton conducting solid oxide fuel cell
journal, October 2011
- Zhang, Cuijuan; Zhao, Hailei
- Electrochemistry Communications, Vol. 13, Issue 10
Cathode processes and materials for solid oxide fuel cells with proton conductors as electrolytes
journal, January 2010
- Peng, Ranran; Wu, Tianzhi; Liu, Wei
- Journal of Materials Chemistry, Vol. 20, Issue 30
A new oxygen reduction electrocatalyst of barium lanthanide cobaltate for composite cathodes of proton-conducting ceramic fuel cells
journal, January 2018
- Matsui, Toshiaki; Manriki, Kohei; Miyazaki, Kazunari
- Journal of Materials Chemistry A, Vol. 6, Issue 29
Enhancing grain boundary ionic conductivity in mixed ionic–electronic conductors
journal, April 2015
- Lin, Ye; Fang, Shumin; Su, Dong
- Nature Communications, Vol. 6, Issue 1
Layer-structured LiNi0.8Co0.2O2: A new triple (H+/O2−/e−) conducting cathode for low temperature proton conducting solid oxide fuel cells
journal, February 2016
- Fan, Liangdong; Su, Pei-Chen
- Journal of Power Sources, Vol. 306
In situ formation of a 3D core-shell and triple-conducting oxygen reduction reaction electrode for proton-conducting SOFCs
journal, May 2018
- Zhang, Zhenbao; Wang, Jian; Chen, Yubo
- Journal of Power Sources, Vol. 385
Time-dependent performance changes in LSCF-infiltrated SOFC cathodes: The role of nano-particle coarsening
journal, April 2011
- Shah, Megna; Voorhees, Peter W.; Barnett, Scott A.
- Solid State Ionics, Vol. 187, Issue 1
A promising cathode for intermediate temperature protonic ceramic fuel cells: BaCo0.4Fe0.4Zr0.2O3−δ
journal, January 2013
- Shang, Meng; Tong, Jianhua; O'Hayre, Ryan
- RSC Advances, Vol. 3, Issue 36, p. 15769-15775
Evaluation of SrSc0.175Nb0.025Co0.8O3-δ perovskite as a cathode for proton-conducting solid oxide fuel cells: The possibility of in situ creating protonic conductivity and electrochemical performance
journal, January 2018
- Zhu, Ankang; Zhang, Guilin; Wan, Tingting
- Electrochimica Acta, Vol. 259
A Dual-Phase Ceramic Membrane with Extremely High H 2 Permeation Flux Prepared by Autoseparation of a Ceramic Precursor
journal, July 2016
- Cheng, Shunfan; Wang, Yanjie; Zhuang, Libin
- Angewandte Chemie International Edition, Vol. 55, Issue 36
Nanomaterials for solid oxide fuel cells: A review
journal, February 2018
- Abdalla, Abdalla M.; Hossain, Shahzad; Azad, Atia T.
- Renewable and Sustainable Energy Reviews, Vol. 82
Gd- and Pr-based double perovskite cobaltites as oxygen electrodes for proton ceramic fuel cells and electrolyser cells
journal, October 2015
- Strandbakke, Ragnar; Cherepanov, Vladimir A.; Zuev, Andrey Yu.
- Solid State Ionics, Vol. 278