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Title: Heteroatom substituted zeolite FAU with ultralow Al contents for liquid-phase oxidation catalysis


Titanium-substituted FAU stabilizes aromatic alkenes to greater extents than BEA and mesoporous silica.

ORCiD logo [1];  [1];  [2];  [1]
  1. Department of Chemical and Biomolecular Engineering, University of Illinois at Urbana-Champaign, Urbana, USA
  2. NMR/EPR Laboratory, School of Chemical Sciences, University of Illinois at Urbana-Champaign, Urbana, USA
Publication Date:
Sponsoring Org.:
OSTI Identifier:
Grant/Contract Number:  
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Catalysis Science and Technology
Additional Journal Information:
Journal Name: Catalysis Science and Technology Journal Volume: 10 Journal Issue: 3; Journal ID: ISSN 2044-4753
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom

Citation Formats

Bregante, Daniel T., Tan, Jun Zhi, Sutrisno, Andre, and Flaherty, David W. Heteroatom substituted zeolite FAU with ultralow Al contents for liquid-phase oxidation catalysis. United Kingdom: N. p., 2020. Web. doi:10.1039/C9CY01886G.
Bregante, Daniel T., Tan, Jun Zhi, Sutrisno, Andre, & Flaherty, David W. Heteroatom substituted zeolite FAU with ultralow Al contents for liquid-phase oxidation catalysis. United Kingdom. doi:10.1039/C9CY01886G.
Bregante, Daniel T., Tan, Jun Zhi, Sutrisno, Andre, and Flaherty, David W. Mon . "Heteroatom substituted zeolite FAU with ultralow Al contents for liquid-phase oxidation catalysis". United Kingdom. doi:10.1039/C9CY01886G.
title = {Heteroatom substituted zeolite FAU with ultralow Al contents for liquid-phase oxidation catalysis},
author = {Bregante, Daniel T. and Tan, Jun Zhi and Sutrisno, Andre and Flaherty, David W.},
abstractNote = {Titanium-substituted FAU stabilizes aromatic alkenes to greater extents than BEA and mesoporous silica.},
doi = {10.1039/C9CY01886G},
journal = {Catalysis Science and Technology},
number = 3,
volume = 10,
place = {United Kingdom},
year = {2020},
month = {2}

Journal Article:
Free Publicly Available Full Text
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DOI: 10.1039/C9CY01886G

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Works referenced in this record:

Delaminated zeolite precursors as selective acidic catalysts
journal, November 1998

  • Corma, A.; Fornes, V.; Pergher, S. B.
  • Nature, Vol. 396, Issue 6709, p. 353-356
  • DOI: 10.1038/24592

Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report)
journal, October 2015

  • Thommes, Matthias; Kaneko, Katsumi; Neimark, Alexander V.
  • Pure and Applied Chemistry, Vol. 87, Issue 9-10
  • DOI: 10.1515/pac-2014-1117

Synthesis of Niobium Silicate Molecular Sieves of the MFI Structure:  Evidence for Framework Incorporation of the Niobium Ion
journal, December 1998

  • Prakash, A. M.; Kevan, Larry
  • Journal of the American Chemical Society, Vol. 120, Issue 50
  • DOI: 10.1021/ja982262v

Influence of Hydrophilicity on the Snβ-Catalyzed Baeyer-Villiger Oxidation of Cyclohexanone with Aqueous Hydrogen Peroxide
journal, December 2016

Synthesis and characterization of tantalum silicalite molecular sieves with MFI structure
journal, September 1999

Beyond shape selective catalysis with zeolites: Hydrophobic void spaces in zeolites enable catalysis in liquid water
journal, January 2013

  • Gounder, Rajamani; Davis, Mark E.
  • AIChE Journal, Vol. 59, Issue 9, p. 3349-3358
  • DOI: 10.1002/aic.14016

Influence of confining environment polarity on ethanol dehydration catalysis by Lewis acid zeolites
journal, September 2018

Ta(V)-Single Site BEA Zeolite by Two-Step Postsynthesis Method: Preparation and Characterization
journal, February 2010

Controlled insertion of tin atoms into zeolite framework vacancies and consequences for glucose isomerization catalysis
journal, December 2016

Monosaccharide and disaccharide isomerization over Lewis acid sites in hydrophobic and hydrophilic molecular sieves
journal, December 2013

Distinct Catalytic Reactivity of Sn Substituted in Framework Locations and at Defect Grain Boundaries in Sn-Zeolites
journal, May 2019

Nanostructured Nb 2 O 5 catalysts
journal, January 2012

High-silica Hβ zeolites for catalytic hydration of hydrophobic epoxides and alkynes in water
journal, December 2018

Improving Stability of Zeolites in Aqueous Phase via Selective Removal of Structural Defects
journal, March 2016

  • Prodinger, Sebastian; Derewinski, Miroslaw A.; Vjunov, Aleksei
  • Journal of the American Chemical Society, Vol. 138, Issue 13
  • DOI: 10.1021/jacs.5b12785

Stability of Zeolites in Aqueous Phase Reactions
journal, August 2017

Characterization and catalytic activity of titanium containing SSZ-33 and aluminum-free zeolite beta
journal, August 1996

The Role of Outer-Sphere Surface Acidity in Alkene Epoxidation Catalyzed by Calixarene−Ti(IV) Complexes
journal, December 2007

  • Notestein, Justin M.; Andrini, Leandro R.; Requejo, Felix G.
  • Journal of the American Chemical Society, Vol. 129, Issue 50
  • DOI: 10.1021/ja074614g

Post-synthetic preparation of Sn-, Ti- and Zr-beta: a facile route to water tolerant, highly active Lewis acidic zeolites
journal, January 2014

  • Wolf, Patrick; Hammond, Ceri; Conrad, Sabrina
  • Dalton Transactions, Vol. 43, Issue 11
  • DOI: 10.1039/c3dt52972j

Pyridine and ammonia as probes for FTIR analysis of solid acid catalysts
journal, January 1996

  • Barzetti, Tommy; Selli, Elena; Moscotti, Daniele
  • Journal of the Chemical Society, Faraday Transactions, Vol. 92, Issue 8
  • DOI: 10.1039/ft9969201401

UV Resonance Raman Spectroscopic Identification of Titanium Atoms in the Framework of TS-1 Zeolite
journal, August 1999

Cooperative Effects between Hydrophilic Pores and Solvents: Catalytic Consequences of Hydrogen Bonding on Alkene Epoxidation in Zeolites
journal, January 2019

  • Bregante, Daniel T.; Johnson, Alayna M.; Patel, Ami Y.
  • Journal of the American Chemical Society, Vol. 141, Issue 18
  • DOI: 10.1021/jacs.8b12861

Experimental criterion for the absence of artifacts in the measurement of rates of heterogeneous catalytic reactions
journal, November 1982

  • Madon, Rostam J.; Boudart, Michel
  • Industrial & Engineering Chemistry Fundamentals, Vol. 21, Issue 4, p. 438-447
  • DOI: 10.1021/i100008a022

Direct synthesis of H2O2 on PdZn nanoparticles: The impact of electronic modifications and heterogeneity of active sites
journal, December 2018

Studies on the Catalytic-Oxidation of Alkanes and Alkenes by Titanium Silicates
journal, September 1994

  • Khouw, C. B.; Dartt, C. B.; Labinger, J. A.
  • Journal of Catalysis, Vol. 149, Issue 1
  • DOI: 10.1006/jcat.1994.1285

Preparation of B-free Ti-MWW through reversible structural conversion
journal, April 2002

  • Wu, Peng; Tatsumi, Takashi
  • Chemical Communications, Issue 10
  • DOI: 10.1039/b201170k

An Ethoxy Intermediate in Ethanol Dehydration on Brønsted Acid Sites in Zeolite
journal, June 2005

  • Kondo, Junko N.; Ito, Keiichi; Yoda, Eisuke
  • The Journal of Physical Chemistry B, Vol. 109, Issue 21
  • DOI: 10.1021/jp050721q

Interrogating the Lewis Acidity of Metal Sites in Beta Zeolites with 15 N Pyridine Adsorption Coupled with MAS NMR Spectroscopy
journal, December 2016

  • Gunther, William R.; Michaelis, Vladimir K.; Griffin, Robert G.
  • The Journal of Physical Chemistry C, Vol. 120, Issue 50
  • DOI: 10.1021/acs.jpcc.6b07811

Lewis Acid Zeolites for Biomass Conversion: Perspectives and Challenges on Reactivity, Synthesis, and Stability
journal, June 2016

Periodic Trends in Olefin Epoxidation over Group IV and V Framework-Substituted Zeolite Catalysts: A Kinetic and Spectroscopic Study
journal, May 2017

  • Bregante, Daniel T.; Flaherty, David W.
  • Journal of the American Chemical Society, Vol. 139, Issue 20
  • DOI: 10.1021/jacs.7b01422

A procedure for the preparation of Ti-Beta zeolites for catalytic epoxidation with hydrogen peroxide
journal, January 2014

  • Tang, Bo; Dai, Weili; Sun, Xiaoming
  • Green Chem., Vol. 16, Issue 4
  • DOI: 10.1039/C3GC42534G

Mechanistic Study on the Lewis Acid Catalyzed Synthesis of 1,3-Butadiene over Ta-BEA Using Modulated Operando DRIFTS-MS
journal, September 2016

Consequences of Confinement for Alkene Epoxidation with Hydrogen Peroxide on Highly Dispersed Group 4 and 5 Metal Oxide Catalysts
journal, February 2018

  • Bregante, Daniel T.; Thornburg, Nicholas E.; Notestein, Justin M.
  • ACS Catalysis, Vol. 8, Issue 4
  • DOI: 10.1021/acscatal.7b03986

Computational characterization of zeolite porous networks: an automated approach
journal, January 2011

  • First, Eric L.; Gounaris, Chrysanthos E.; Wei, James
  • Physical Chemistry Chemical Physics, Vol. 13, Issue 38
  • DOI: 10.1039/c1cp21731c

Dehydration of Ethanol into Ethylene over Solid Acid Catalysts
journal, December 2005

Direct Synthesis and Characterization of Hydrophobic Aluminum-Free Ti−Beta Zeolite
journal, January 1998

  • Blasco, T.; Camblor, M. A.; Corma, A.
  • The Journal of Physical Chemistry B, Vol. 102, Issue 1
  • DOI: 10.1021/jp973288w

Solvation and acid strength effects on catalysis by faujasite zeolites
journal, February 2012

Kinetic and spectroscopic evidence for reaction pathways and intermediates for olefin epoxidation on Nb in *BEA
journal, April 2017

Deactivation mechanisms of tin-zeolites in biomass conversions
journal, January 2016

  • Lari, G. M.; Dapsens, P. Y.; Scholz, D.
  • Green Chemistry, Vol. 18, Issue 5
  • DOI: 10.1039/C5GC02147B

Conduction and Valence Band Positions of Ta 2 O 5 , TaON, and Ta 3 N 5 by UPS and Electrochemical Methods
journal, February 2003

  • Chun, Wang-Jae; Ishikawa, Akio; Fujisawa, Hideki
  • The Journal of Physical Chemistry B, Vol. 107, Issue 8
  • DOI: 10.1021/jp027593f

Sn-zeolite beta as a heterogeneous chemoselective catalyst for Baeyer–Villiger oxidations
journal, July 2001

  • Corma, Avelino; Nemeth, Laszlo T.; Renz, Michael
  • Nature, Vol. 412, Issue 6845
  • DOI: 10.1038/35086546

New Nb and Ta–FAU zeolites—Direct synthesis, characterisation and surface properties
journal, December 2010

Experimental determination of the electronic band structure of SnO2
journal, March 1998

Lewis Acid Catalysis Confined in Zeolite Cages as a Strategy for Sustainable Heterogeneous Hydration of Epoxides
journal, April 2016

Activity of Ti-Beta Catalyst for the Selective Oxidation of Alkenes and Alkanes
journal, January 1994

Improved Postsynthesis Strategy to Sn-Beta Zeolites as Lewis Acid Catalysts for the Ring-Opening Hydration of Epoxides
journal, July 2014

  • Tang, Bo; Dai, Weili; Wu, Guangjun
  • ACS Catalysis, Vol. 4, Issue 8
  • DOI: 10.1021/cs500891s

What Do the Niobium Framework Sites Look Like in Redox Zeolites? A Combined Theoretical and Experimental Investigation
journal, January 2010

  • Tielens, Frederik; Shishido, Tetsuya; Dzwigaj, Stanislaw
  • The Journal of Physical Chemistry C, Vol. 114, Issue 7
  • DOI: 10.1021/jp910956j

The Effect of Water on the Adsorption of NO 2 in Na− and Ba−Y, FAU Zeolites:  A Combined FTIR and TPD Investigation
journal, March 2004

  • Szanyi, János; Kwak, Ja Hun; Peden, Charles H. F.
  • The Journal of Physical Chemistry B, Vol. 108, Issue 12
  • DOI: 10.1021/jp037472v

Tin-containing zeolites are highly active catalysts for the isomerization of glucose in water
journal, March 2010

  • Moliner, M.; Roman-Leshkov, Y.; Davis, M. E.
  • Proceedings of the National Academy of Sciences, Vol. 107, Issue 14, p. 6164-6168
  • DOI: 10.1073/pnas.1002358107

Synthesis of titanated chabazite with enhanced thermal stability by hydrothermal conversion of titanated faujasite
journal, October 2015

Synthesis of reaction‐adapted zeolites as methanol-to-olefins catalysts with mimics of reaction intermediates as organic structure‐directing agents
journal, July 2018

  • Li, Chengeng; Paris, Cecilia; Martínez-Triguero, Joaquín
  • Nature Catalysis, Vol. 1, Issue 7
  • DOI: 10.1038/s41929-018-0104-7

N-Doping of anodic TiO2 nanotubes using heat treatment in ammonia
journal, April 2006

Propylene oxide inhibits propylene epoxidation over Au/TS-1
journal, September 2018

Postsynthesis and Effective Baeyer–Villiger Oxidation Properties of Hierarchical FAU-type Stannosilicate
journal, October 2016

  • Zhu, Zhiguo; Xu, Hao; Jiang, Jingang
  • The Journal of Physical Chemistry C, Vol. 120, Issue 41
  • DOI: 10.1021/acs.jpcc.6b07947

Synthesis of Itaconic Acid Ester Analogues via Self-Aldol Condensation of Ethyl Pyruvate Catalyzed by Hafnium BEA Zeolites
journal, April 2016

Local Environment Fine Structure in the 29Si NMR Spectra of Faujasite Zeolites
journal, April 1995

  • Melchior, M. T.; Vaughan, D. E. W.; Pictroski, C. F.
  • The Journal of Physical Chemistry, Vol. 99, Issue 16
  • DOI: 10.1021/j100016a058

Periodic Trends in Highly Dispersed Groups IV and V Supported Metal Oxide Catalysts for Alkene Epoxidation with H 2 O 2
journal, August 2015

  • Thornburg, Nicholas E.; Thompson, Anthony B.; Notestein, Justin M.
  • ACS Catalysis, Vol. 5, Issue 9
  • DOI: 10.1021/acscatal.5b01105

The catalytic diversity of zeolites: confinement and solvation effects within voids of molecular dimensions
journal, January 2013

  • Gounder, Rajamani; Iglesia, Enrique
  • Chemical Communications, Vol. 49, Issue 34
  • DOI: 10.1039/c3cc40731d

A comparative IR characterization of acidic sites on HY zeolite by pyridine and CO probes with silica–alumina and γ-alumina references
journal, January 2010

  • Kondo, Junko N.; Nishitani, Ryoko; Yoda, Eisuke
  • Physical Chemistry Chemical Physics, Vol. 12, Issue 37
  • DOI: 10.1039/c0cp00203h

Large pore Ti-zeolites and mesoporous Ti-silicalites as catalysts for selective oxidation of organic sulfides
journal, January 1996

  • Corma, A.; Iglesias, M.; S�nchez, F.
  • Catalysis Letters, Vol. 39, Issue 3-4
  • DOI: 10.1007/BF00805575

Predicting the Activity of Single Isolated Lewis Acid Sites in Solid Catalysts
journal, September 2006

  • Boronat, Mercedes; Corma, Avelino; Renz, Michael
  • Chemistry - A European Journal, Vol. 12, Issue 27
  • DOI: 10.1002/chem.200600478

Grafted Ta–calixarenes: Tunable, selective catalysts for direct olefin epoxidation with aqueous hydrogen peroxide
journal, October 2010

Adsorption properties of Fe-containing dealuminated BEA zeolites as revealed by FTIR spectroscopy
journal, June 2010

  • Hadjiivanov, Konstantin; Ivanova, Elena; Kefirov, Radoslav
  • Microporous and Mesoporous Materials, Vol. 131, Issue 1-3
  • DOI: 10.1016/j.micromeso.2009.11.034