Advances and challenges in electrochemical CO 2 reduction processes: an engineering and design perspective looking beyond new catalyst materials

Garg, Sahil; Li, Mengran; Weber, Adam Z.; Ge, Lei; Li, Liye; Rudolph, Victor; Wang, Guoxiong; Rufford, Thomas E.

doi:10.1039/C9TA13298H

Title: Advances and challenges in electrochemical CO ₂ reduction processes: an engineering and design perspective looking beyond new catalyst materials

Abstract

This review of design and operating conditions of electrochemical CO ₂ reduction covers electrolytes, electrodes, reactors, temperature, pressure, and pH effects.

Authors:

Garg, Sahil ^[1];

^[1];

^[2];

^[3]; Li, Liye ^[4]; Rudolph, Victor ^[1]; Wang, Guoxiong ^[1];

^[1]

School of Chemical Engineering, The University of Queensland, St Lucia 4072, Australia
Joint Center for Artificial Photosynthesis, Lawrence Berkeley National Laboratory, Berkeley, USA
School of Chemical Engineering, The University of Queensland, St Lucia 4072, Australia, Center for Future Materials
HBIS Group Technology Research Institute, Shijiazhuang, China

Publication Date:: 2020-01-28

Sponsoring Org.:: USDOE

OSTI Identifier:: 1579974

Grant/Contract Number:: SC0004993

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Journal of Materials Chemistry. A

Additional Journal Information:: Journal Name: Journal of Materials Chemistry. A Journal Volume: 8 Journal Issue: 4; Journal ID: ISSN 2050-7488

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Garg, Sahil, Li, Mengran, Weber, Adam Z., Ge, Lei, Li, Liye, Rudolph, Victor, Wang, Guoxiong, and Rufford, Thomas E. Advances and challenges in electrochemical CO 2 reduction processes: an engineering and design perspective looking beyond new catalyst materials.  United Kingdom: N. p., 2020. 
Web.  doi:10.1039/C9TA13298H.

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                    Garg, Sahil, Li, Mengran, Weber, Adam Z., Ge, Lei, Li, Liye, Rudolph, Victor, Wang, Guoxiong, & Rufford, Thomas E. Advances and challenges in electrochemical CO 2 reduction processes: an engineering and design perspective looking beyond new catalyst materials.  United Kingdom.  https://doi.org/10.1039/C9TA13298H

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                    Garg, Sahil, Li, Mengran, Weber, Adam Z., Ge, Lei, Li, Liye, Rudolph, Victor, Wang, Guoxiong, and Rufford, Thomas E. Tue .  
"Advances and challenges in electrochemical CO 2 reduction processes: an engineering and design perspective looking beyond new catalyst materials".  United Kingdom.  https://doi.org/10.1039/C9TA13298H.

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@article{osti_1579974,

  title        = {Advances and challenges in electrochemical CO 2 reduction processes: an engineering and design perspective looking beyond new catalyst materials},

  author       = {Garg, Sahil and Li, Mengran and Weber, Adam Z. and Ge, Lei and Li, Liye and Rudolph, Victor and Wang, Guoxiong and Rufford, Thomas E.},

  abstractNote = {This review of design and operating conditions of electrochemical CO 2 reduction covers electrolytes, electrodes, reactors, temperature, pressure, and pH effects.},

  doi          = {10.1039/C9TA13298H},

  journal      = {Journal of Materials Chemistry. A},

  number       = 4,

  volume       = 8,

  place        = {United Kingdom},

  year         = {2020},

  month        = {1}

}

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Title: Advances and challenges in electrochemical CO 2 reduction processes: an engineering and design perspective looking beyond new catalyst materials

Abstract

Citation Formats

Mesostructure-Induced Selectivity in CO 2 Reduction Catalysis journal, November 2015

A review on the electrochemical reduction of CO2 in fuel cells, metal electrodes and molecular catalysts journal, September 2014

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Ionic-liquid materials for the electrochemical challenges of the future journal, July 2009

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Mass transport modelling for the electroreduction of CO 2 on Cu nanowires journal, December 2017

High-Rate Electrochemical Reduction of Carbon Monoxide to Ethylene Using Cu-Nanoparticle-Based Gas Diffusion Electrodes journal, March 2018

Electrochemical CO2 Reduction on Metal Electrodes book, January 2008

Mechanism and kinetic characteristics of the electrochemical reduction of carbon dioxide in media of low proton availability journal, August 1981

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Electrolytic Reduction of Carbon Dioxide at Mercury Electrode in Aqueous Solution journal, March 1982

Electrocatalytic Alloys for CO 2 Reduction journal, December 2017

Optimizing C–C Coupling on Oxide-Derived Copper Catalysts for Electrochemical CO 2 Reduction journal, June 2017

The solubility of methane in aqueous solutions of monoethanolamine, diethanolamine and triethanolamine journal, October 1998

An electrochemical engineering assessment of the operational conditions and constraints for solar-driven water-splitting systems at near-neutral pH journal, January 2015

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Production of Methane and Ethylene in Electrochemical Reduction of Carbon Dioxide at Copper Electrode in Aqueous Hydrogencarbonate Solution journal, June 1986

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Defining a Materials Database for the Design of Copper Binary Alloy Catalysts for Electrochemical CO 2 Conversion journal, January 2018

Understanding Selectivity for the Electrochemical Reduction of Carbon Dioxide to Formic Acid and Carbon Monoxide on Metal Electrodes journal, June 2017

Carbon dioxide reduction at low temperature on various metal electrodes journal, March 1989

Controlling the selectivity of CO2 electroreduction on copper: The effect of the electrolyte concentration and the importance of the local pH journal, February 2016

Electro-catalytic membrane reactors and the development of bipolar membrane technology journal, September 2004

Efficient Reduction of CO 2 to CO with High Current Density Using in Situ or ex Situ Prepared Bi-Based Materials journal, May 2014

The Suitability of Monopolar and Bipolar Ion Exchange Membranes as Separators for Biological Fuel Cells journal, March 2008

Energy applications of ionic liquids journal, January 2014

Improved CO 2 Electroreduction Performance on Plasma-Activated Cu Catalysts via Electrolyte Design: Halide Effect journal, July 2017

Catalytic Electrochemical Reduction of CO2 in Ionic Liquid EMIMBF3Cl journal, January 2011

Review of bipolar plates in PEM fuel cells: Flow-field designs journal, March 2005

Membraneless laminar flow cell for electrocatalytic CO 2 reduction with liquid product separation journal, March 2017

Theoretical Insights into a CO Dimerization Mechanism in CO 2 Electroreduction journal, May 2015

Long-term activation of the copper cathode in the course of CO2 reduction journal, August 1994

Electrochemical reduction of carbon dioxide to ethylene: Mechanistic approach journal, June 2013

Product Selectivity Affected by Cationic Species in Electrochemical Reduction of CO 2 and CO at a Cu Electrode journal, January 1991

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Cu2O-loaded gas diffusion electrodes for the continuous electrochemical reduction of CO2 to methanol journal, November 2016

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Electrochemical reduction of CO2 to formate at high current density using gas diffusion electrodes journal, August 2014

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Insights into the electrocatalytic reduction of CO 2 on metallic silver surfaces journal, January 2014

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High Efficiency Electrochemical Reduction of Carbon Dioxide under High Pressure on a Gas Diffusion Electrode Containing Pt Catalysts journal, January 1995

Tuning Catalytic Selectivity at the Mesoscale via Interparticle Interactions journal, January 2016

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Impurity Ion Complexation Enhances Carbon Dioxide Reduction Catalysis journal, June 2015

Continuous electroreduction of CO 2 to formate using Sn gas diffusion electrodes journal, July 2014

A review of the gas diffusion layer in proton exchange membrane fuel cells: Durability and degradation journal, October 2015

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Carbon Dioxide and Water Electrolysis Using New Alkaline Stable Anion Membranes journal, July 2018

High Rate Gas Phase CO[sub 2] Reduction to Ethylene and Methane Using Gas Diffusion Electrodes journal, January 1990

Reduction of CO2 and CO to methane on Cu foil electrodes journal, April 1988

Use of Bipolar Membranes for Maintaining Steady-State pH Gradients in Membrane-Supported, Solar-Driven Water Splitting journal, September 2014

New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces journal, January 2012

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Selectivity of ion exchange membranes: A review journal, June 2018

Title: Advances and challenges in electrochemical CO ₂ reduction processes: an engineering and design perspective looking beyond new catalyst materials

Mesostructure-Induced Selectivity in CO ₂ Reduction Catalysis
journal, November 2015

A review on the electrochemical reduction of CO2 in fuel cells, metal electrodes and molecular catalysts
journal, September 2014

Hydrophobic Gas-Diffusion Media for Polymer-Electrolyte Fuel Cells by Direct Fluorination
journal, January 2015

Ionic-liquid materials for the electrochemical challenges of the future
journal, July 2009

Electrodeposition of tin on Nafion-bonded carbon black as an active catalyst layer for efficient electroreduction of CO2 to formic acid
journal, October 2017

High-Yield Electrochemical Production of Formaldehyde from CO ₂ and Seawater
journal, November 2013

Ultrathin Bismuth Nanosheets as a Highly Efficient CO ₂ Reduction Electrocatalyst
journal, January 2018

Mass transport modelling for the electroreduction of CO ₂ on Cu nanowires
journal, December 2017

High-Rate Electrochemical Reduction of Carbon Monoxide to Ethylene Using Cu-Nanoparticle-Based Gas Diffusion Electrodes
journal, March 2018

Electrochemical CO₂ Reduction on Metal Electrodes
book, January 2008

Mechanism and kinetic characteristics of the electrochemical reduction of carbon dioxide in media of low proton availability
journal, August 1981

Manipulating the Hydrocarbon Selectivity of Copper Nanoparticles in CO ₂ Electroreduction by Process Conditions
journal, December 2014

High-Performance Electrocatalysis Using Metallic Cobalt Pyrite (CoS ₂ ) Micro- and Nanostructures
journal, June 2014

CO2 electrochemical reduction via adsorbed halide anions
journal, January 2011

Conversion of carbon dioxide into methanol – a potential liquid fuel: Fundamental challenges and opportunities (a review)
journal, March 2014

Chlor-alkali electrolysis with oxygen depolarized cathodes: history, present status and future prospects
journal, May 2008

Fundamentals and Challenges of Electrochemical CO2 Reduction Using Two-Dimensional Materials
journal, October 2017

Electrolytic Reduction of Carbon Dioxide at Mercury Electrode in Aqueous Solution
journal, March 1982

Electrocatalytic Alloys for CO ₂ Reduction
journal, December 2017

Optimizing C–C Coupling on Oxide-Derived Copper Catalysts for Electrochemical CO ₂ Reduction
journal, June 2017

The solubility of methane in aqueous solutions of monoethanolamine, diethanolamine and triethanolamine
journal, October 1998

An electrochemical engineering assessment of the operational conditions and constraints for solar-driven water-splitting systems at near-neutral pH
journal, January 2015

Flow-Field Designs of Bipolar Plates in PEM Fuel Cells: Theory and Applications
journal, November 2012

Tuning Sn-Catalysis for Electrochemical Reduction of CO ₂ to CO via the Core/Shell Cu/SnO ₂ Structure
journal, March 2017

Production of Methane and Ethylene in Electrochemical Reduction of Carbon Dioxide at Copper Electrode in Aqueous Hydrogencarbonate Solution
journal, June 1986

Hydrogen production by alkaline water electrolysis
journal, January 2013

Defining a Materials Database for the Design of Copper Binary Alloy Catalysts for Electrochemical CO ₂ Conversion
journal, January 2018

Understanding Selectivity for the Electrochemical Reduction of Carbon Dioxide to Formic Acid and Carbon Monoxide on Metal Electrodes
journal, June 2017

Carbon dioxide reduction at low temperature on various metal electrodes
journal, March 1989

Controlling the selectivity of CO2 electroreduction on copper: The effect of the electrolyte concentration and the importance of the local pH
journal, February 2016

Electro-catalytic membrane reactors and the development of bipolar membrane technology
journal, September 2004

Efficient Reduction of CO ₂ to CO with High Current Density Using in Situ or ex Situ Prepared Bi-Based Materials
journal, May 2014

The Suitability of Monopolar and Bipolar Ion Exchange Membranes as Separators for Biological Fuel Cells
journal, March 2008

Energy applications of ionic liquids
journal, January 2014

Improved CO ₂ Electroreduction Performance on Plasma-Activated Cu Catalysts via Electrolyte Design: Halide Effect
journal, July 2017

Catalytic Electrochemical Reduction of CO2 in Ionic Liquid EMIMBF3Cl
journal, January 2011

Review of bipolar plates in PEM fuel cells: Flow-field designs
journal, March 2005

Membraneless laminar flow cell for electrocatalytic CO ₂ reduction with liquid product separation
journal, March 2017

Theoretical Insights into a CO Dimerization Mechanism in CO ₂ Electroreduction
journal, May 2015

Long-term activation of the copper cathode in the course of CO₂ reduction
journal, August 1994

Electrochemical reduction of carbon dioxide to ethylene: Mechanistic approach
journal, June 2013

Product Selectivity Affected by Cationic Species in Electrochemical Reduction of CO ₂ and CO at a Cu Electrode
journal, January 1991

High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts
journal, February 2015

Cu2O-loaded gas diffusion electrodes for the continuous electrochemical reduction of CO2 to methanol
journal, November 2016

Ionic liquids in the electrochemical valorisation of CO ₂
journal, January 2015

Identification of Possible Pathways for C–C Bond Formation during Electrochemical Reduction of CO ₂ : New Theoretical Insights from an Improved Electrochemical Model
journal, April 2016

Design of Electrocatalysts and Electrochemical Cells for Carbon Dioxide Reduction Reactions
journal, March 2018

Towards a better Sn: Efficient electrocatalytic reduction of CO 2 to formate by Sn/SnS 2 derived from SnS 2 nanosheets
journal, January 2017

Effects of temperature and gas–liquid mass transfer on the operation of small electrochemical cells for the quantitative evaluation of CO ₂ reduction electrocatalysts
journal, January 2016

Electrochemical reduction of CO2 to formate at high current density using gas diffusion electrodes
journal, August 2014

Influence of adsorption processes on the CO₂ electroreduction: An electrochemical mass spectrometry study
journal, August 2005

On the performance of membraneless laminar flow-based fuel cells
journal, June 2010

Ionic Liquid-Mediated Selective Conversion of CO₂ to CO at Low Overpotentials
journal, September 2011

Selective ethylene formation by pulse-mode electrochemical reduction of carbon dioxide using copper and copper-oxide electrodes
journal, July 2006

Insights into the electrocatalytic reduction of CO ₂ on metallic silver surfaces
journal, January 2014

A broad parameter range for selective methane production with bicarbonate solution in electrochemical CO ₂ reduction
journal, January 2017

Electrochemical conversion of CO2 to HCOOH at tin cathode in a pressurized undivided filter-press cell
journal, July 2018

High Efficiency Electrochemical Reduction of Carbon Dioxide under High Pressure on a Gas Diffusion Electrode Containing Pt Catalysts
journal, January 1995

Tuning Catalytic Selectivity at the Mesoscale via Interparticle Interactions
journal, January 2016

Selective Electrochemical Reduction of Carbon Dioxide to Ethylene and Ethanol on Copper(I) Oxide Catalysts
journal, March 2015

Homogeneously Catalyzed Electroreduction of Carbon Dioxide—Methods, Mechanisms, and Catalysts
journal, January 2018

Enhanced Electrochemical Methanation of Carbon Dioxide with a Dispersible Nanoscale Copper Catalyst
journal, September 2014

Investigation of Formic Acid Separation from Aqueous Solution by Reactive Extraction: Effects of Extractant and Diluent
journal, April 2010

Methanol to Olefins (MTO): From Fundamentals to Commercialization
journal, February 2015

Effects of electrolyte, catalyst, and membrane composition and operating conditions on the performance of solar-driven electrochemical reduction of carbon dioxide
journal, January 2015

A review on microstructure reconstruction of PEM fuel cells porous electrodes for pore scale simulation
journal, November 2016

Impurity Ion Complexation Enhances Carbon Dioxide Reduction Catalysis
journal, June 2015

Continuous electroreduction of CO ₂ to formate using Sn gas diffusion electrodes
journal, July 2014

A review of the gas diffusion layer in proton exchange membrane fuel cells: Durability and degradation
journal, October 2015

Roles of ion pairing on electroreduction of carbon dioxide based on imidazolium-based salts
journal, March 2015

Carbon Dioxide and Water Electrolysis Using New Alkaline Stable Anion Membranes
journal, July 2018

High Rate Gas Phase CO[sub 2] Reduction to Ethylene and Methane Using Gas Diffusion Electrodes
journal, January 1990

Reduction of CO₂ and CO to methane on Cu foil electrodes
journal, April 1988

Use of Bipolar Membranes for Maintaining Steady-State pH Gradients in Membrane-Supported, Solar-Driven Water Splitting
journal, September 2014

New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
journal, January 2012

Highly selective electrocatalytic reduction of carbon dioxide to carbon monoxide on silver electrode with aqueous ionic liquids
journal, September 2014

Selectivity of ion exchange membranes: A review
journal, June 2018

A new mechanism for the selectivity to C1 and C2 species in the electrochemical reduction of carbon dioxide on copper electrodes
journal, January 2011

Recent advances in the nanoengineering of electrocatalysts for CO ₂ reduction
journal, January 2018