Advances and challenges in electrochemical CO 2 reduction processes: an engineering and design perspective looking beyond new catalyst materials

doi:10.1039/C9TA13298H

This content will become publicly available on December 12, 2020

Title: Advances and challenges in electrochemical CO ₂ reduction processes: an engineering and design perspective looking beyond new catalyst materials

Abstract

This review of design and operating conditions of electrochemical CO ₂ reduction covers electrolytes, electrodes, reactors, temperature, pressure, and pH effects.

Authors:

Garg, Sahil ^[1];

^[1];

^[2];

^[3]; Li, Liye ^[4]; Rudolph, Victor ^[1]; Wang, Guoxiong ^[1];

^[1]

School of Chemical Engineering, The University of Queensland, St Lucia 4072, Australia
Joint Center for Artificial Photosynthesis, Lawrence Berkeley National Laboratory, Berkeley, USA
School of Chemical Engineering, The University of Queensland, St Lucia 4072, Australia, Center for Future Materials
HBIS Group Technology Research Institute, Shijiazhuang, China

Publication Date:: 2020-01-01

Sponsoring Org.:: USDOE

OSTI Identifier:: 1579974

Grant/Contract Number:: SC0004993

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Journal of Materials Chemistry. A

Additional Journal Information:: Journal Name: Journal of Materials Chemistry. A; Journal ID: ISSN 2050-7488

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Garg, Sahil, Li, Mengran, Weber, Adam Z., Ge, Lei, Li, Liye, Rudolph, Victor, Wang, Guoxiong, and Rufford, Thomas E. Advances and challenges in electrochemical CO 2 reduction processes: an engineering and design perspective looking beyond new catalyst materials.  United Kingdom: N. p., 2020. 
        Web.  doi:10.1039/C9TA13298H.

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                    Garg, Sahil, Li, Mengran, Weber, Adam Z., Ge, Lei, Li, Liye, Rudolph, Victor, Wang, Guoxiong, & Rufford, Thomas E. Advances and challenges in electrochemical CO 2 reduction processes: an engineering and design perspective looking beyond new catalyst materials.  United Kingdom.  doi:10.1039/C9TA13298H.

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                    Garg, Sahil, Li, Mengran, Weber, Adam Z., Ge, Lei, Li, Liye, Rudolph, Victor, Wang, Guoxiong, and Rufford, Thomas E. Wed .  
        "Advances and challenges in electrochemical CO 2 reduction processes: an engineering and design perspective looking beyond new catalyst materials".  United Kingdom.  doi:10.1039/C9TA13298H.

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@article{osti_1579974,

  title        = {Advances and challenges in electrochemical CO 2 reduction processes: an engineering and design perspective looking beyond new catalyst materials},

  author       = {Garg, Sahil and Li, Mengran and Weber, Adam Z. and Ge, Lei and Li, Liye and Rudolph, Victor and Wang, Guoxiong and Rufford, Thomas E.},

  abstractNote = {This review of design and operating conditions of electrochemical CO 2 reduction covers electrolytes, electrodes, reactors, temperature, pressure, and pH effects.},

  doi          = {10.1039/C9TA13298H},

  journal      = {Journal of Materials Chemistry. A},

  number       = ,

  volume       = ,

  place        = {United Kingdom},

  year         = {2020},

  month        = {1}

}

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DOI: 10.1039/C9TA13298H

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Works referenced in this record:

Mesostructure-Induced Selectivity in CO ₂ Reduction Catalysis
journal, November 2015

Hall, Anthony Shoji; Yoon, Youngmin; Wuttig, Anna
Journal of the American Chemical Society, Vol. 137, Issue 47
DOI: 10.1021/jacs.5b08259

A review on the electrochemical reduction of CO2 in fuel cells, metal electrodes and molecular catalysts
journal, September 2014

Lim, Rern Jern; Xie, Mingshi; Sk, Mahasin Alam
Catalysis Today, Vol. 233
DOI: 10.1016/j.cattod.2013.11.037

Hydrophobic Gas-Diffusion Media for Polymer-Electrolyte Fuel Cells by Direct Fluorination
journal, January 2015

Van Nguyen, Trung; Ahosseini, Azita; Wang, Xuhai
Journal of The Electrochemical Society, Vol. 162, Issue 14
DOI: 10.1149/2.0411514jes

Ionic-liquid materials for the electrochemical challenges of the future
journal, July 2009

Armand, Michel; Endres, Frank; MacFarlane, Douglas R.
Nature Materials, Vol. 8, Issue 8, p. 621-629
DOI: 10.1038/nmat2448

Electrodeposition of tin on Nafion-bonded carbon black as an active catalyst layer for efficient electroreduction of CO2 to formic acid
journal, October 2017

Wang, Qinian; Wang, Xinqi; Wu, Chao
Scientific Reports, Vol. 7, Issue 1
DOI: 10.1038/s41598-017-14233-y

High-Yield Electrochemical Production of Formaldehyde from CO ₂ and Seawater
journal, November 2013

Nakata, Kazuya; Ozaki, Takuya; Terashima, Chiaki
Angewandte Chemie, Vol. 126, Issue 3
DOI: 10.1002/ange.201308657

Ultrathin Bismuth Nanosheets as a Highly Efficient CO ₂ Reduction Electrocatalyst
journal, January 2018

Su, Panpan; Xu, Wenbin; Qiu, Yanling
ChemSusChem, Vol. 11, Issue 5
DOI: 10.1002/cssc.201702229

Mass transport modelling for the electroreduction of CO ₂ on Cu nanowires
journal, December 2017

Raciti, David; Mao, Mark; Wang, Chao
Nanotechnology, Vol. 29, Issue 4
DOI: 10.1088/1361-6528/aa9bd7

High-Rate Electrochemical Reduction of Carbon Monoxide to Ethylene Using Cu-Nanoparticle-Based Gas Diffusion Electrodes
journal, March 2018

Han, Lihao; Zhou, Wu; Xiang, Chengxiang
ACS Energy Letters, Vol. 3, Issue 4
DOI: 10.1021/acsenergylett.8b00164

Electrochemical CO₂ Reduction on Metal Electrodes
book, January 2008

Hori, Y.; Vayenas, Constantinos G.; White, Ralph E.
Modern Aspects of Electrochemistry, p. 89-189
DOI: 10.1007/978-0-387-49489-0_3

Mechanism and kinetic characteristics of the electrochemical reduction of carbon dioxide in media of low proton availability
journal, August 1981

Amatore, Christian; Saveant, Jean Michel
Journal of the American Chemical Society, Vol. 103, Issue 17
DOI: 10.1021/ja00407a008

Manipulating the Hydrocarbon Selectivity of Copper Nanoparticles in CO ₂ Electroreduction by Process Conditions
journal, December 2014

Kas, Recep; Kortlever, Ruud; Yılmaz, Hasan
ChemElectroChem, Vol. 2, Issue 3
DOI: 10.1002/celc.201402373

High-Performance Electrocatalysis Using Metallic Cobalt Pyrite (CoS ₂ ) Micro- and Nanostructures
journal, June 2014

Faber, Matthew S.; Dziedzic, Rafal; Lukowski, Mark A.
Journal of the American Chemical Society, Vol. 136, Issue 28
DOI: 10.1021/ja504099w

CO2 electrochemical reduction via adsorbed halide anions
journal, January 2011

Ogura, Kotaro; Salazar-Villalpando, Maria D.
JOM, Vol. 63, Issue 1
DOI: 10.1007/s11837-011-0009-2

Conversion of carbon dioxide into methanol – a potential liquid fuel: Fundamental challenges and opportunities (a review)
journal, March 2014

Ganesh, Ibram
Renewable and Sustainable Energy Reviews, Vol. 31
DOI: 10.1016/j.rser.2013.11.045

Chlor-alkali electrolysis with oxygen depolarized cathodes: history, present status and future prospects
journal, May 2008

Moussallem, Imad; Jörissen, Jakob; Kunz, Ulrich
Journal of Applied Electrochemistry, Vol. 38, Issue 9
DOI: 10.1007/s10800-008-9556-9

Fundamentals and Challenges of Electrochemical CO2 Reduction Using Two-Dimensional Materials
journal, October 2017

Sun, Zhenyu; Ma, Tao; Tao, Hengcong
Chem, Vol. 3, Issue 4
DOI: 10.1016/j.chempr.2017.09.009

Electrolytic Reduction of Carbon Dioxide at Mercury Electrode in Aqueous Solution
journal, March 1982

Hori, Yoshio; Suzuki, Shin
Bulletin of the Chemical Society of Japan, Vol. 55, Issue 3
DOI: 10.1246/bcsj.55.660

Electrocatalytic Alloys for CO ₂ Reduction
journal, December 2017

He, Jingfu; Johnson, Noah J. J.; Huang, Aoxue
ChemSusChem, Vol. 11, Issue 1
DOI: 10.1002/cssc.201701825

Optimizing C–C Coupling on Oxide-Derived Copper Catalysts for Electrochemical CO ₂ Reduction
journal, June 2017

Lum, Yanwei; Yue, Binbin; Lobaccaro, Peter
The Journal of Physical Chemistry C, Vol. 121, Issue 26
DOI: 10.1021/acs.jpcc.7b03673

The solubility of methane in aqueous solutions of monoethanolamine, diethanolamine and triethanolamine
journal, October 1998

Carroll, John J.; Jou, Fang-Yuan; Mather, Alan E.
The Canadian Journal of Chemical Engineering, Vol. 76, Issue 5
DOI: 10.1002/cjce.5450760512

An electrochemical engineering assessment of the operational conditions and constraints for solar-driven water-splitting systems at near-neutral pH
journal, January 2015

Singh, Meenesh R.; Papadantonakis, Kimberly; Xiang, Chengxiang
Energy & Environmental Science, Vol. 8, Issue 9
DOI: 10.1039/C5EE01721A

Flow-Field Designs of Bipolar Plates in PEM Fuel Cells: Theory and Applications
journal, November 2012

Wang, J.; Wang, H.
Fuel Cells, Vol. 12, Issue 6
DOI: 10.1002/fuce.201200074

Tuning Sn-Catalysis for Electrochemical Reduction of CO ₂ to CO via the Core/Shell Cu/SnO ₂ Structure
journal, March 2017

Li, Qing; Fu, Jiaju; Zhu, Wenlei
Journal of the American Chemical Society, Vol. 139, Issue 12
DOI: 10.1021/jacs.7b00261

Production of Methane and Ethylene in Electrochemical Reduction of Carbon Dioxide at Copper Electrode in Aqueous Hydrogencarbonate Solution
journal, June 1986

Hori, Yoshio; Kikuchi, Katsuhei; Murata, Akira
Chemistry Letters, Vol. 15, Issue 6
DOI: 10.1246/cl.1986.897

Hydrogen production by alkaline water electrolysis
journal, January 2013

Santos, Diogo M. F.; Sequeira, César A. C.; Figueiredo, José L.
Química Nova, Vol. 36, Issue 8
DOI: 10.1590/S0100-40422013000800017

Defining a Materials Database for the Design of Copper Binary Alloy Catalysts for Electrochemical CO ₂ Conversion
journal, January 2018

Lee, Chan Woo; Yang, Ki Dong; Nam, Dae-Hyun
Advanced Materials, Vol. 30, Issue 42
DOI: 10.1002/adma.201704717

Understanding Selectivity for the Electrochemical Reduction of Carbon Dioxide to Formic Acid and Carbon Monoxide on Metal Electrodes
journal, June 2017

Feaster, Jeremy T.; Shi, Chuan; Cave, Etosha R.
ACS Catalysis, Vol. 7, Issue 7
DOI: 10.1021/acscatal.7b00687

Carbon dioxide reduction at low temperature on various metal electrodes
journal, March 1989

Azuma, Masashi; Hashimoto, Kazuhito; Hiramoto, Masahiro
Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 260, Issue 2, p. 441-445
DOI: 10.1016/0022-0728(89)87158-X

Controlling the selectivity of CO2 electroreduction on copper: The effect of the electrolyte concentration and the importance of the local pH
journal, February 2016

Varela, Ana Sofia; Kroschel, Matthias; Reier, Tobias
Catalysis Today, Vol. 260
DOI: 10.1016/j.cattod.2015.06.009

Electro-catalytic membrane reactors and the development of bipolar membrane technology
journal, September 2004

Balster, J.; Stamatialis, D. F.; Wessling, M.
Chemical Engineering and Processing: Process Intensification, Vol. 43, Issue 9
DOI: 10.1016/j.cep.2003.11.010

Efficient Reduction of CO ₂ to CO with High Current Density Using in Situ or ex Situ Prepared Bi-Based Materials
journal, May 2014

Medina-Ramos, Jonnathan; DiMeglio, John L.; Rosenthal, Joel
Journal of the American Chemical Society, Vol. 136, Issue 23
DOI: 10.1021/ja501923g

The Suitability of Monopolar and Bipolar Ion Exchange Membranes as Separators for Biological Fuel Cells
journal, March 2008

Harnisch, Falk; Schröder, Uwe; Scholz, Fritz
Environmental Science & Technology, Vol. 42, Issue 5
DOI: 10.1021/es702224a

Energy applications of ionic liquids
journal, January 2014

MacFarlane, Douglas R.; Tachikawa, Naoki; Forsyth, Maria
Energy Environ. Sci., Vol. 7, Issue 1
DOI: 10.1039/C3EE42099J

Improved CO ₂ Electroreduction Performance on Plasma-Activated Cu Catalysts via Electrolyte Design: Halide Effect
journal, July 2017

Gao, Dunfeng; Scholten, Fabian; Roldan Cuenya, Beatriz
ACS Catalysis, Vol. 7, Issue 8
DOI: 10.1021/acscatal.7b01416

Catalytic Electrochemical Reduction of CO2 in Ionic Liquid EMIMBF3Cl
journal, January 2011

Snuffin, Laura L.; Whaley, Louis W.; Yu, Lei
Journal of The Electrochemical Society, Vol. 158, Issue 9
DOI: 10.1149/1.3606487

Review of bipolar plates in PEM fuel cells: Flow-field designs
journal, March 2005

Li, Xianguo; Sabir, Imran
International Journal of Hydrogen Energy, Vol. 30, Issue 4, p. 359-371
DOI: 10.1016/j.ijhydene.2004.09.019

Membraneless laminar flow cell for electrocatalytic CO ₂ reduction with liquid product separation
journal, March 2017

Monroe, Morgan M.; Lobaccaro, Peter; Lum, Yanwei
Journal of Physics D: Applied Physics, Vol. 50, Issue 15
DOI: 10.1088/1361-6463/aa6359

Theoretical Insights into a CO Dimerization Mechanism in CO ₂ Electroreduction
journal, May 2015

Montoya, Joseph H.; Shi, Chuan; Chan, Karen
The Journal of Physical Chemistry Letters, Vol. 6, Issue 11
DOI: 10.1021/acs.jpclett.5b00722

Long-term activation of the copper cathode in the course of CO₂ reduction
journal, August 1994

Jermann, B.; Augustynski, J.
Electrochimica Acta, Vol. 39, Issue 11-12, p. 1891-1896
DOI: 10.1016/0013-4686(94)85181-6

Electrochemical reduction of carbon dioxide to ethylene: Mechanistic approach
journal, June 2013

Ogura, Kotaro
Journal of CO2 Utilization, Vol. 1
DOI: 10.1016/j.jcou.2013.03.003

Product Selectivity Affected by Cationic Species in Electrochemical Reduction of CO ₂ and CO at a Cu Electrode
journal, January 1991

Murata, Akira; Hori, Yoshio
Bulletin of the Chemical Society of Japan, Vol. 64, Issue 1
DOI: 10.1246/bcsj.64.123

High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts
journal, February 2015

Roberts, F. Sloan; Kuhl, Kendra P.; Nilsson, Anders
Angewandte Chemie International Edition, Vol. 54, Issue 17
DOI: 10.1002/anie.201412214

Cu2O-loaded gas diffusion electrodes for the continuous electrochemical reduction of CO2 to methanol
journal, November 2016

Albo, Jonathan; Irabien, Angel
Journal of Catalysis, Vol. 343
DOI: 10.1016/j.jcat.2015.11.014

Ionic liquids in the electrochemical valorisation of CO ₂
journal, January 2015

Alvarez-Guerra, Manuel; Albo, Jonathan; Alvarez-Guerra, Enrique
Energy & Environmental Science, Vol. 8, Issue 9
DOI: 10.1039/C5EE01486G

Identification of Possible Pathways for C–C Bond Formation during Electrochemical Reduction of CO ₂ : New Theoretical Insights from an Improved Electrochemical Model
journal, April 2016

Goodpaster, Jason D.; Bell, Alexis T.; Head-Gordon, Martin
The Journal of Physical Chemistry Letters, Vol. 7, Issue 8
DOI: 10.1021/acs.jpclett.6b00358

Design of Electrocatalysts and Electrochemical Cells for Carbon Dioxide Reduction Reactions
journal, March 2018

Yang, Wanfeng; Dastafkan, Kamran; Jia, Chen
Advanced Materials Technologies, Vol. 3, Issue 9
DOI: 10.1002/admt.201700377

Towards a better Sn: Efficient electrocatalytic reduction of CO 2 to formate by Sn/SnS 2 derived from SnS 2 nanosheets
journal, January 2017

Li, Fengwang; Chen, Lu; Xue, Mianqi
Nano Energy, Vol. 31
DOI: 10.1016/j.nanoen.2016.11.004

Effects of temperature and gas–liquid mass transfer on the operation of small electrochemical cells for the quantitative evaluation of CO ₂ reduction electrocatalysts
journal, January 2016

Lobaccaro, Peter; Singh, Meenesh R.; Clark, Ezra Lee
Physical Chemistry Chemical Physics, Vol. 18, Issue 38
DOI: 10.1039/C6CP05287H

Electrochemical reduction of CO2 to formate at high current density using gas diffusion electrodes
journal, August 2014

Kopljar, D.; Inan, A.; Vindayer, P.
Journal of Applied Electrochemistry, Vol. 44, Issue 10
DOI: 10.1007/s10800-014-0731-x

Influence of adsorption processes on the CO₂ electroreduction: An electrochemical mass spectrometry study
journal, August 2005

Dubé, P.; Brisard, G. M.
Journal of Electroanalytical Chemistry, Vol. 582, Issue 1-2, p. 230-240
DOI: 10.1016/j.jelechem.2005.04.016

On the performance of membraneless laminar flow-based fuel cells
journal, June 2010

Jayashree, Ranga S.; Yoon, Seong Kee; Brushett, Fikile R.
Journal of Power Sources, Vol. 195, Issue 11
DOI: 10.1016/j.jpowsour.2009.12.029

Ionic Liquid-Mediated Selective Conversion of CO₂ to CO at Low Overpotentials
journal, September 2011

Rosen, B. A.; Salehi-Khojin, A.; Thorson, M. R.
Science, Vol. 334, Issue 6056, p. 643-644
DOI: 10.1126/science.1209786

Selective ethylene formation by pulse-mode electrochemical reduction of carbon dioxide using copper and copper-oxide electrodes
journal, July 2006

Yano, Jun; Morita, Toshiro; Shimano, Koji
Journal of Solid State Electrochemistry, Vol. 11, Issue 4, p. 554-557
DOI: 10.1007/s10008-006-0181-4

Insights into the electrocatalytic reduction of CO ₂ on metallic silver surfaces
journal, January 2014

Hatsukade, Toru; Kuhl, Kendra P.; Cave, Etosha R.
Phys. Chem. Chem. Phys., Vol. 16, Issue 27
DOI: 10.1039/C4CP00692E

A broad parameter range for selective methane production with bicarbonate solution in electrochemical CO ₂ reduction
journal, January 2017

Hashiba, Hiroshi; Sato, Hiroki K.; Yotsuhashi, Satoshi
Sustainable Energy & Fuels, Vol. 1, Issue 8
DOI: 10.1039/C7SE00352H

Electrochemical conversion of CO2 to HCOOH at tin cathode in a pressurized undivided filter-press cell
journal, July 2018

Proietto, Federica; Schiavo, Benedetto; Galia, Alessandro
Electrochimica Acta, Vol. 277
DOI: 10.1016/j.electacta.2018.04.159

High Efficiency Electrochemical Reduction of Carbon Dioxide under High Pressure on a Gas Diffusion Electrode Containing Pt Catalysts
journal, January 1995

Hara, Kohjiro
Journal of The Electrochemical Society, Vol. 142, Issue 4
DOI: 10.1149/1.2044182

Tuning Catalytic Selectivity at the Mesoscale via Interparticle Interactions
journal, January 2016

Mistry, Hemma; Behafarid, Farzad; Reske, Rulle
ACS Catalysis, Vol. 6, Issue 2
DOI: 10.1021/acscatal.5b02202

Selective Electrochemical Reduction of Carbon Dioxide to Ethylene and Ethanol on Copper(I) Oxide Catalysts
journal, March 2015

Ren, Dan; Deng, Yilin; Handoko, Albertus Denny
ACS Catalysis, Vol. 5, Issue 5
DOI: 10.1021/cs502128q

Homogeneously Catalyzed Electroreduction of Carbon Dioxide—Methods, Mechanisms, and Catalysts
journal, January 2018

Francke, Robert; Schille, Benjamin; Roemelt, Michael
Chemical Reviews, Vol. 118, Issue 9
DOI: 10.1021/acs.chemrev.7b00459

Enhanced Electrochemical Methanation of Carbon Dioxide with a Dispersible Nanoscale Copper Catalyst
journal, September 2014

Manthiram, Karthish; Beberwyck, Brandon J.; Alivisatos, A. Paul
Journal of the American Chemical Society, Vol. 136, Issue 38
DOI: 10.1021/ja5065284

Investigation of Formic Acid Separation from Aqueous Solution by Reactive Extraction: Effects of Extractant and Diluent
journal, April 2010

Şahin, Selin; Bayazit, Şahika Sena; Bilgin, Mehmet
Journal of Chemical & Engineering Data, Vol. 55, Issue 4
DOI: 10.1021/je9006635

Methanol to Olefins (MTO): From Fundamentals to Commercialization
journal, February 2015

Tian, Peng; Wei, Yingxu; Ye, Mao
ACS Catalysis, Vol. 5, Issue 3
DOI: 10.1021/acscatal.5b00007

Effects of electrolyte, catalyst, and membrane composition and operating conditions on the performance of solar-driven electrochemical reduction of carbon dioxide
journal, January 2015

Singh, Meenesh R.; Clark, Ezra L.; Bell, Alexis T.
Physical Chemistry Chemical Physics, Vol. 17, Issue 29
DOI: 10.1039/C5CP03283K

A review on microstructure reconstruction of PEM fuel cells porous electrodes for pore scale simulation
journal, November 2016

Shojaeefard, M. H.; Molaeimanesh, G. R.; Nazemian, M.
International Journal of Hydrogen Energy, Vol. 41, Issue 44
DOI: 10.1016/j.ijhydene.2016.08.179

Impurity Ion Complexation Enhances Carbon Dioxide Reduction Catalysis
journal, June 2015

Wuttig, Anna; Surendranath, Yogesh
ACS Catalysis, Vol. 5, Issue 7
DOI: 10.1021/acscatal.5b00808

Continuous electroreduction of CO ₂ to formate using Sn gas diffusion electrodes
journal, July 2014

Del Castillo, Andrés; Alvarez-Guerra, Manuel; Irabien, Angel
AIChE Journal, Vol. 60, Issue 10
DOI: 10.1002/aic.14544

A review of the gas diffusion layer in proton exchange membrane fuel cells: Durability and degradation
journal, October 2015

Park, Jaeman; Oh, Hwanyeong; Ha, Taehun
Applied Energy, Vol. 155
DOI: 10.1016/j.apenergy.2015.06.068

Roles of ion pairing on electroreduction of carbon dioxide based on imidazolium-based salts
journal, March 2015

Niu, Dongfang; Wang, Haiyang; Li, Huicheng
Electrochimica Acta, Vol. 158
DOI: 10.1016/j.electacta.2015.01.096

Carbon Dioxide and Water Electrolysis Using New Alkaline Stable Anion Membranes
journal, July 2018

Kaczur, Jerry J.; Yang, Hongzhou; Liu, Zengcai
Frontiers in Chemistry, Vol. 6
DOI: 10.3389/fchem.2018.00263

High Rate Gas Phase CO[sub 2] Reduction to Ethylene and Methane Using Gas Diffusion Electrodes
journal, January 1990

Cook, Ronald L.
Journal of The Electrochemical Society, Vol. 137, Issue 2
DOI: 10.1149/1.2086515

Reduction of CO₂ and CO to methane on Cu foil electrodes
journal, April 1988

Kim, J. J.; Summers, D. P.; Frese, K. W.
Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 245, Issue 1-2, p. 223-244
DOI: 10.1016/0022-0728(88)80071-8

Use of Bipolar Membranes for Maintaining Steady-State pH Gradients in Membrane-Supported, Solar-Driven Water Splitting
journal, September 2014

McDonald, Michael B.; Ardo, Shane; Lewis, Nathan S.
ChemSusChem, Vol. 7, Issue 11
DOI: 10.1002/cssc.201402288

New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
journal, January 2012

Kuhl, Kendra P.; Cave, Etosha R.; Abram, David N.
Energy & Environmental Science, Vol. 5, Issue 5
DOI: 10.1039/c2ee21234j

Highly selective electrocatalytic reduction of carbon dioxide to carbon monoxide on silver electrode with aqueous ionic liquids
journal, September 2014

Zhou, Feng; Liu, Shimin; Yang, Benqun
Electrochemistry Communications, Vol. 46
DOI: 10.1016/j.elecom.2014.06.023

Selectivity of ion exchange membranes: A review
journal, June 2018

Luo, Tao; Abdu, Said; Wessling, Matthias
Journal of Membrane Science, Vol. 555
DOI: 10.1016/j.memsci.2018.03.051

A new mechanism for the selectivity to C1 and C2 species in the electrochemical reduction of carbon dioxide on copper electrodes
journal, January 2011

Schouten, K. J. P.; Kwon, Y.; van der Ham, C. J. M.
Chemical Science, Vol. 2, Issue 10
DOI: 10.1039/c1sc00277e

Recent advances in the nanoengineering of electrocatalysts for CO ₂ reduction
journal, January 2018

Li, Fengwang; MacFarlane, Douglas R.; Zhang, Jie
Nanoscale, Vol. 10, Issue 14
DOI: 10.1039/C7NR09620H

Electrocatalytic Production of C3-C4 Compounds by Conversion of CO ₂ on a Chloride-Induced Bi-Phasic Cu ₂ O-Cu Catalyst
journal, October 2015

Lee, Seunghwa; Kim, Dahee; Lee, Jaeyoung
Angewandte Chemie, Vol. 127, Issue 49
DOI: 10.1002/ange.201505730

Electrochemical Reduction of Carbon Dioxide to Formic Acid in Ionic Liquid [Emim][N(CN)2]/Water System
journal, September 2017

Zhang, Xiangjing; Zhao, Ying; Hu, Shuozhen
Electrochimica Acta, Vol. 247
DOI: 10.1016/j.electacta.2017.06.112

A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
journal, January 2014

Qiao, Jinli; Liu, Yuyu; Hong, Feng
Chem. Soc. Rev., Vol. 43, Issue 2
DOI: 10.1039/C3CS60323G

Tuning the Catalytic Activity and Selectivity of Cu for CO ₂ Electroreduction in the Presence of Halides
journal, February 2016

Varela, Ana Sofia; Ju, Wen; Reier, Tobias
ACS Catalysis, Vol. 6, Issue 4
DOI: 10.1021/acscatal.5b02550

Porous tin-based film deposited on copper foil for electrochemical reduction of carbon dioxide to formate
journal, January 2016

Lv, Weixin; Zhou, Jing; Kong, Fenying
International Journal of Hydrogen Energy, Vol. 41, Issue 3
DOI: 10.1016/j.ijhydene.2015.11.100

Use of gas-diffusion electrodes for high-rate electrochemical reduction of carbon dioxide. I. Reduction at lead, indium- and tin-impregnated electrodes
journal, November 1987

Mahmood, M. N.; Masheder, D.; Harty, C. J.
Journal of Applied Electrochemistry, Vol. 17, Issue 6
DOI: 10.1007/BF01023599

Metal–Organic Frameworks for Electrocatalytic Reduction of Carbon Dioxide
journal, October 2015

Kornienko, Nikolay; Zhao, Yingbo; Kley, Christopher S.
Journal of the American Chemical Society, Vol. 137, Issue 44
DOI: 10.1021/jacs.5b08212

The Alkaline Stability of Anion Exchange Membrane for Fuel Cell Applications: The Effects of Alkaline Media
journal, June 2018

Sun, Zhe; Pan, Ji; Guo, Jiangna
Advanced Science, Vol. 5, Issue 8
DOI: 10.1002/advs.201800065

Selective Conversion of CO ₂ to CO with High Efficiency Using an Inexpensive Bismuth-Based Electrocatalyst
journal, June 2013

DiMeglio, John L.; Rosenthal, Joel
Journal of the American Chemical Society, Vol. 135, Issue 24
DOI: 10.1021/ja4033549

CO ₂ Conversion to Formic Acid in a Three Compartment Cell with Sustainion™ Membranes
journal, July 2017

Yang, Hongzhou; Kaczur, Jerry J.; Sajjad, Syed D.
ECS Transactions, Vol. 77, Issue 11
DOI: 10.1149/07711.1425ecst

Selective Formation of Formic Acid, Oxalic Acid, and Carbon Monoxide by Electrochemical Reduction of Carbon Dioxide
journal, July 1987

Ikeda, Shoichiro; Takagi, Takehiko; Ito, Kaname
Bulletin of the Chemical Society of Japan, Vol. 60, Issue 7, p. 2517-2522
DOI: 10.1246/bcsj.60.2517

Pulsed Electroreduction of CO[sub 2] on Copper Electrodes-II
journal, January 1994

Nogami, Gyoichi
Journal of The Electrochemical Society, Vol. 141, Issue 5
DOI: 10.1149/1.2054886

Efficient Electrochemical Reduction of CO ₂ to HCOOH over Sub-2 nm SnO ₂ Quantum Wires with Exposed Grain Boundaries
journal, May 2019

Liu, Subiao; Xiao, Jing; Lu, Xue Feng
Angewandte Chemie International Edition, Vol. 58, Issue 25
DOI: 10.1002/anie.201903613

CO-CO coupling on Cu facets: Coverage, strain and field effects
journal, December 2016

Sandberg, Robert B.; Montoya, Joseph H.; Chan, Karen
Surface Science, Vol. 654
DOI: 10.1016/j.susc.2016.08.006

Mathematical Modeling of CO[sub 2] Reduction to CO in Aqueous Electrolytes
journal, January 2010

Delacourt, Charles; Ridgway, Paul L.; Newman, John
Journal of The Electrochemical Society, Vol. 157, Issue 12
DOI: 10.1149/1.3502532

Solubility of CO ₂ , CH ₄ , C ₂ H ₆ , C ₂ H ₄ , O ₂ , and N ₂ in 1-Hexyl-3-methylpyridinium Bis(trifluoromethylsulfonyl)imide: Comparison to Other Ionic Liquids
journal, November 2007

Anderson, Jessica L.; Dixon, JaNeille K.; Brennecke, Joan F.
Accounts of Chemical Research, Vol. 40, Issue 11
DOI: 10.1021/ar7001649

Electrochemical Reduction of CO[sub 2] on a Cu Electrode under High Pressure
journal, January 1994

Hara, Kohjiro
Journal of The Electrochemical Society, Vol. 141, Issue 8
DOI: 10.1149/1.2055067

Comparative study of solvent properties for carbon dioxide absorption
journal, January 2010

Aschenbrenner, Ortrud; Styring, Peter
Energy & Environmental Science, Vol. 3, Issue 8
DOI: 10.1039/c002915g

Electrocatalytic process of CO selectivity in electrochemical reduction of CO₂ at metal electrodes in aqueous media
journal, August 1994

Hori, Yoshio; Wakebe, Hidetoshi; Tsukamoto, Toshio
Electrochimica Acta, Vol. 39, Issue 11-12, p. 1833-1839
DOI: 10.1016/0013-4686(94)85172-7

Principles and implementations of electrolysis systems for water splitting
journal, January 2016

Xiang, Chengxiang; Papadantonakis, Kimberly M.; Lewis, Nathan S.
Materials Horizons, Vol. 3, Issue 3
DOI: 10.1039/C6MH00016A

Purification strategies and purity visualization techniques for single-walled carbon nanotubes
journal, January 2006

Park, Tae-Jin; Banerjee, Sarbajit; Hemraj-Benny, Tirandai
J. Mater. Chem., Vol. 16, Issue 2
DOI: 10.1039/B510858F

Solubility of CO2 in aqueous solutions of NaCl, KCl, CaCl2 and their mixed salts at different temperatures and pressures
journal, March 2011

Liu, Yuanhui; Hou, Minqiang; Yang, Guanying
The Journal of Supercritical Fluids, Vol. 56, Issue 2
DOI: 10.1016/j.supflu.2010.12.003

Prism-Shaped Cu Nanocatalysts for Electrochemical CO ₂ Reduction to Ethylene
journal, December 2017

Jeon, Hyo Sang; Kunze, Sebastian; Scholten, Fabian
ACS Catalysis, Vol. 8, Issue 1
DOI: 10.1021/acscatal.7b02959

Selective electrochemical reduction of CO₂ to ethylene at a three-phase interface on copper(I) halide-confined Cu-mesh electrodes in acidic solutions of potassium halides
journal, April 2004

Yano, H.; Tanaka, T.; Nakayama, M.
Journal of Electroanalytical Chemistry, Vol. 565, Issue 2, p. 287-293
DOI: 10.1016/j.jelechem.2003.10.021

Electrochemical reduction of CO2 in methanol at −30°C
journal, July 1995

Mizuno, Takayuki; Naitoh, Akira; Ohta, Kiyohisa
Journal of Electroanalytical Chemistry, Vol. 391, Issue 1-2
DOI: 10.1016/0022-0728(95)03936-B

Assessing the Utility of Bipolar Membranes for use in Photoelectrochemical Water-Splitting Cells
journal, September 2014

Vargas-Barbosa, Nella M.; Geise, Geoffrey M.; Hickner, Michael A.
ChemSusChem, Vol. 7, Issue 11
DOI: 10.1002/cssc.201402535

A Critical Review of Modeling Transport Phenomena in Polymer-Electrolyte Fuel Cells
journal, January 2014

Weber, Adam Z.; Borup, Rodney L.; Darling, Robert M.
Journal of The Electrochemical Society, Vol. 161, Issue 12
DOI: 10.1149/2.0751412jes

Catholyte-Free Electrocatalytic CO ₂ Reduction to Formate
journal, May 2018

Lee, Wonhee; Kim, Young Eun; Youn, Min Hye
Angewandte Chemie, Vol. 130, Issue 23
DOI: 10.1002/ange.201803501

Rapid prototyping of electrolyzer flow field plates
journal, January 2016

Hudkins, Jesse R.; Wheeler, Danika G.; Peña, Bruno
Energy & Environmental Science, Vol. 9, Issue 11
DOI: 10.1039/C6EE01997H

Stable and selective electrochemical reduction of carbon dioxide to ethylene on copper mesocrystals
journal, January 2015

Chen, Chung Shou; Handoko, Albertus D.; Wan, Jane Hui
Catalysis Science & Technology, Vol. 5, Issue 1
DOI: 10.1039/C4CY00906A

Enhanced formation of >C1 Products in Electroreduction of CO ₂ by Adding a CO ₂ Adsorption Component to a Gas-Diffusion Layer-Type Catalytic Electrode
journal, October 2017

Marepally, Bhanu Chandra; Ampelli, Claudio; Genovese, Chiara
ChemSusChem, Vol. 10, Issue 22
DOI: 10.1002/cssc.201701506

Efficient Electrochemical CO ₂ Conversion Powered by Renewable Energy
journal, July 2015

Kauffman, Douglas R.; Thakkar, Jay; Siva, Rajan
ACS Applied Materials & Interfaces, Vol. 7, Issue 28
DOI: 10.1021/acsami.5b04393

Potential Dependencies of the Products on Electrochemical Reduction of Carbon Dioxide at a Copper Electrode
journal, February 1989

Noda, Hidetomo; Ikeda, Shoichiro; Oda, Yoshiyuki
Chemistry Letters, Vol. 18, Issue 2
DOI: 10.1246/cl.1989.289

Bio-inspired hydrophobicity promotes CO2 reduction on a Cu surface
journal, August 2019

Wakerley, David; Lamaison, Sarah; Ozanam, François
Nature Materials, Vol. 18, Issue 11
DOI: 10.1038/s41563-019-0445-x

Mechanistic Insights into the Selective Electroreduction of Carbon Dioxide to Ethylene on Cu ₂ O-Derived Copper Catalysts
journal, September 2016

Handoko, Albertus D.; Ong, Cheng Wai; Huang, Yun
The Journal of Physical Chemistry C, Vol. 120, Issue 36
DOI: 10.1021/acs.jpcc.6b07128

Solubility of carbon dioxide in aqueous solution of monoethanolamine or 2-amino-2-methyl-1-propanol: Experimental measurements and modelling
journal, January 2012

Tong, Danlu; Trusler, J. P. Martin; Maitland, Geoffrey C.
International Journal of Greenhouse Gas Control, Vol. 6
DOI: 10.1016/j.ijggc.2011.11.005

Selective Electrochemical Production of Formate from Carbon Dioxide with Bismuth-Based Catalysts in an Aqueous Electrolyte
journal, January 2018

Lee, Chan Woo; Hong, Jung Sug; Yang, Ki Dong
ACS Catalysis, Vol. 8, Issue 2
DOI: 10.1021/acscatal.7b03242

Electrolysis of Gaseous CO ₂ to CO in a Flow Cell with a Bipolar Membrane
journal, November 2017

Salvatore, Danielle A.; Weekes, David M.; He, Jingfu
ACS Energy Letters, Vol. 3, Issue 1
DOI: 10.1021/acsenergylett.7b01017

Opportunities and challenges for a sustainable energy future
journal, August 2012

Chu, Steven; Majumdar, Arun
Nature, Vol. 488, Issue 7411, p. 294-303
DOI: 10.1038/nature11475

New Method for Prediction of Binary Gas-Phase Diffusion Coefficients
journal, May 1966

Fuller, Edward N.; Schettler, Paul D.; Giddings, J. Calvin.
Industrial & Engineering Chemistry, Vol. 58, Issue 5
DOI: 10.1021/ie50677a007

Electrochemical Reduction of Carbon Dioxide to Formic Acid
journal, May 2014

Lu, Xu; Leung, Dennis Y. C.; Wang, Huizhi
ChemElectroChem, Vol. 1, Issue 5
DOI: 10.1002/celc.201300206

Mechanistic insights into electrochemical reduction of CO ₂ over Ag using density functional theory and transport models
journal, October 2017

Singh, Meenesh R.; Goodpaster, Jason D.; Weber, Adam Z.
Proceedings of the National Academy of Sciences, Vol. 114, Issue 42
DOI: 10.1073/pnas.1713164114

Amine Scrubbing for CO2 Capture
journal, September 2009

Rochelle, G. T.
Science, Vol. 325, Issue 5948
DOI: 10.1126/science.1176731

Effect of pressure on the electrochemical reduction of CO2 on Group VIII metal electrodes
journal, June 1991

Nakagawa, Shinji; Kudo, Akihiko; Azuma, Masashi
Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 308, Issue 1-2
DOI: 10.1016/0022-0728(91)85080-9

Ionic Liquids for CO ₂ Capture and Emission Reduction
journal, December 2010

Brennecke, Joan F.; Gurkan, Burcu E.
The Journal of Physical Chemistry Letters, Vol. 1, Issue 24
DOI: 10.1021/jz1014828

Design of an Electrochemical Cell Making Syngas (CO + H₂) from CO₂ and H₂O Reduction at Room Temperature
journal, January 2008

Delacourt, Charles; Ridgway, Paul L.; Kerr, John B.
Journal of The Electrochemical Society, Vol. 155, Issue 1, p. B42-B49
DOI: 10.1149/1.2801871

Gas diffusion layer modifications and treatments for improving the performance of proton exchange membrane fuel cells and electrolysers: A review
journal, November 2017

Omrani, Reza; Shabani, Bahman
International Journal of Hydrogen Energy, Vol. 42, Issue 47
DOI: 10.1016/j.ijhydene.2017.09.132

Metal ion cycling of Cu foil for selective C–C coupling in electrochemical CO2 reduction
journal, January 2018

Jiang, Kun; Sandberg, Robert B.; Akey, Austin J.
Nature Catalysis, Vol. 1, Issue 2
DOI: 10.1038/s41929-017-0009-x

The Importance of Cannizzaro-Type Reactions during Electrocatalytic Reduction of Carbon Dioxide
journal, January 2017

Birdja, Yuvraj Y.; Koper, Marc T. M.
Journal of the American Chemical Society, Vol. 139, Issue 5
DOI: 10.1021/jacs.6b12008

Effect of Alkyl Chain Length of Imidazolium Cation on the Electroreduction of CO2 to CO on Ag Electrode in Acetonitrile
journal, January 2017

Wang, Qianqian; Chen, Chengzhen; Zhong, Juhua
Australian Journal of Chemistry, Vol. 70, Issue 3
DOI: 10.1071/CH16138

Bench-scale electrochemical system for generation of CO and syn-gas
journal, March 2011

Dufek, Eric J.; Lister, Tedd E.; McIlwain, Michael E.
Journal of Applied Electrochemistry, Vol. 41, Issue 6
DOI: 10.1007/s10800-011-0271-6

Electrochemical promotion of catalysis over Pd nanoparticles for CO ₂ reduction
journal, January 2017

Cai, Fan; Gao, Dunfeng; Zhou, Hu
Chemical Science, Vol. 8, Issue 4
DOI: 10.1039/C6SC04966D

A review of the aqueous electrochemical reduction of CO₂ to hydrocarbons at copper
journal, August 2006

Gattrell, M.; Gupta, N.; Co, A.
Journal of Electroanalytical Chemistry, Vol. 594, Issue 1, p. 1-19
DOI: 10.1016/j.jelechem.2006.05.013

Carbon Capture and Utilization Update
journal, March 2017

Al-Mamoori, Ahmed; Krishnamurthy, Anirudh; Rownaghi, Ali A.
Energy Technology, Vol. 5, Issue 6
DOI: 10.1002/ente.201600747

Impurities in graphenes and carbon nanotubes and their influence on the redox properties
journal, January 2012

Pumera, Martin; Ambrosi, Adriano; Chng, Elaine Lay Khim
Chemical Science, Vol. 3, Issue 12
DOI: 10.1039/c2sc21374e

Electrochemical CO ₂ Reduction: Recent Advances and Current Trends
journal, September 2014

Jones, John-Paul; Prakash, G. K. Surya; Olah, George A.
Israel Journal of Chemistry, Vol. 54, Issue 10
DOI: 10.1002/ijch.201400081

Carbon Dioxide Reduction to Alcohols using Perovskite-Type Electrocatalysts
journal, January 1993

Schwartz, Michael
Journal of The Electrochemical Society, Vol. 140, Issue 3
DOI: 10.1149/1.2056131

Electrochemical Reduction of High Pressure CO[sub 2] on Ni Electrodes
journal, January 1993

Kudo, Akihiko
Journal of The Electrochemical Society, Vol. 140, Issue 6
DOI: 10.1149/1.2221599

Electrochemical conversion of CO2 to formic acid utilizing Sustainion™ membranes
journal, July 2017

Yang, Hongzhou; Kaczur, Jerry J.; Sajjad, Syed Dawar
Journal of CO2 Utilization, Vol. 20
DOI: 10.1016/j.jcou.2017.04.011

The mechanism of hydrogen evolution at copper cathodes in aqueous solutions
journal, January 1952

Bockris, J. O'M.; Pentland, N.
Transactions of the Faraday Society, Vol. 48
DOI: 10.1039/tf9524800833

Models proposed to explain the electrical conductivity of mixtures made of conductive and insulating materials
journal, January 1993

Lux, F.
Journal of Materials Science, Vol. 28, Issue 2
DOI: 10.1007/BF00357799

Electroreduction of carbon monoxide to methane and ethylene at a copper electrode in aqueous solutions at ambient temperature and pressure
journal, August 1987

Hori, Yoshio; Murata, Akira; Takahashi, Ryutaro
Journal of the American Chemical Society, Vol. 109, Issue 16
DOI: 10.1021/ja00250a044

Inhibited proton transfer enhances Au-catalyzed CO ₂ -to-fuels selectivity
journal, July 2016

Wuttig, Anna; Yaguchi, Momo; Motobayashi, Kenta
Proceedings of the National Academy of Sciences, Vol. 113, Issue 32
DOI: 10.1073/pnas.1602984113

Low-dimensional catalysts for hydrogen evolution and CO2 reduction
journal, January 2018

Voiry, Damien; Shin, Hyeon Suk; Loh, Kian Ping
Nature Reviews Chemistry, Vol. 2, Issue 1
DOI: 10.1038/s41570-017-0105

Electric Field Effects in Electrochemical CO ₂ Reduction
journal, September 2016

Chen, Leanne D.; Urushihara, Makoto; Chan, Karen
ACS Catalysis, Vol. 6, Issue 10
DOI: 10.1021/acscatal.6b02299

Structure- and Potential-Dependent Cation Effects on CO Reduction at Copper Single-Crystal Electrodes
journal, November 2017

Pérez-Gallent, Elena; Marcandalli, Giulia; Figueiredo, Marta Costa
Journal of the American Chemical Society, Vol. 139, Issue 45
DOI: 10.1021/jacs.7b10142

Electrocatalytic reduction of carbon dioxide on indium coated gas diffusion electrodes—Comparison with indium foil
journal, July 2016

Bitar, Ziad; Fecant, Antoine; Trela-Baudot, Emmanuelle
Applied Catalysis B: Environmental, Vol. 189
DOI: 10.1016/j.apcatb.2016.02.041

Upscaling and continuous operation of electrochemical CO2 to CO conversion in aqueous solutions on silver gas diffusion electrodes
journal, March 2018

Jeanty, Philippe; Scherer, Christian; Magori, Erhard
Journal of CO2 Utilization, Vol. 24
DOI: 10.1016/j.jcou.2018.01.011

Operation of a Pressurized System for Continuous Reduction of CO ₂
journal, January 2012

Dufek, Eric J.; Lister, Tedd E.; Stone, Simon G.
Journal of The Electrochemical Society, Vol. 159, Issue 9
DOI: 10.1149/2.011209jes

Selective and Efficient Reduction of Carbon Dioxide to Carbon Monoxide on Oxide-Derived Nanostructured Silver Electrocatalysts
journal, July 2016

Ma, Ming; Trześniewski, Bartek J.; Xie, Jie
Angewandte Chemie International Edition, Vol. 55, Issue 33
DOI: 10.1002/anie.201604654

Electrochemical CO2 reduction on a glassy carbon electrode under high pressure
journal, January 1997

Hara, K.; Kudo, A.; Sakata, T.
Journal of Electroanalytical Chemistry, Vol. 421, Issue 1-2
DOI: 10.1016/S0022-0728(96)01028-5

Enhanced electrocatalytic CO2 reduction via field-induced reagent concentration
journal, August 2016

Liu, Min; Pang, Yuanjie; Zhang, Bo
Nature, Vol. 537, Issue 7620
DOI: 10.1038/nature19060

Sustainion Imidazolium-Functionalized Polymers for Carbon Dioxide Electrolysis
journal, March 2017

Kutz, Robert B.; Chen, Qingmei; Yang, Hongzhou
Energy Technology, Vol. 5, Issue 6
DOI: 10.1002/ente.201600636

Surface-Morphology-Dependent Electrolyte Effects on Gold-Catalyzed Electrochemical CO ₂ Reduction
journal, October 2017

Kim, Haeri; Park, Hyun Seo; Hwang, Yun Jeong
The Journal of Physical Chemistry C, Vol. 121, Issue 41
DOI: 10.1021/acs.jpcc.7b06286

Reaction Mechanisms for the Electrochemical Reduction of CO ₂ to CO and Formate on the Cu(100) Surface at 298 K from Quantum Mechanics Free Energy Calculations with Explicit Water
journal, October 2016

Cheng, Tao; Xiao, Hai; Goddard, William A.
Journal of the American Chemical Society, Vol. 138, Issue 42
DOI: 10.1021/jacs.6b08534

Silver-coated ion exchange membrane electrode applied to electrochemical reduction of carbon dioxide
journal, August 2003

Hori, Y.; Ito, H.; Okano, K.
Electrochimica Acta, Vol. 48, Issue 18
DOI: 10.1016/S0013-4686(03)00311-6

CO ₂ reduction on gas-diffusion electrodes and why catalytic performance must be assessed at commercially-relevant conditions
journal, January 2019

Burdyny, Thomas; Smith, Wilson A.
Energy & Environmental Science, Vol. 12, Issue 5
DOI: 10.1039/C8EE03134G

Electrolytic CO ₂ Reduction in a Flow Cell
journal, March 2018

Weekes, David M.; Salvatore, Danielle A.; Reyes, Angelica
Accounts of Chemical Research, Vol. 51, Issue 4
DOI: 10.1021/acs.accounts.8b00010

CO 2 utilization: Developments in conversion processes
journal, March 2017

Alper, Erdogan; Yuksel Orhan, Ozge
Petroleum, Vol. 3, Issue 1
DOI: 10.1016/j.petlm.2016.11.003

CO ₂ Electroreduction with Enhanced Ethylene and Ethanol Selectivity by Nanostructuring Polycrystalline Copper
journal, April 2016

Kwon, Youngkook; Lum, Yanwei; Clark, Ezra L.
ChemElectroChem, Vol. 3, Issue 6
DOI: 10.1002/celc.201600068

Review on microstructure modelling of a gas diffusion layer for proton exchange membrane fuel cells
journal, September 2017

Fadzillah, D. M.; Rosli, M. I.; Talib, M. Z. M.
Renewable and Sustainable Energy Reviews, Vol. 77
DOI: 10.1016/j.rser.2016.11.235

Polymer Electrolyte Membrane Fuel Cell (PEMFC) Flow Field Plate: Design, Materials and Characterisation
journal, May 2010

Hamilton, P. J.; Pollet, B. G.
Fuel Cells, Vol. 10, Issue 4
DOI: 10.1002/fuce.201000033

Prospects of CO₂ Utilization via Direct Heterogeneous Electrochemical Reduction
journal, December 2010

Whipple, Devin T.; Kenis, Paul J. A.
The Journal of Physical Chemistry Letters, Vol. 1, Issue 24, p. 3451-3458
DOI: 10.1021/jz1012627

Catalytic Conversion of Methane and Ethylene to Propylene
journal, January 1998

Lunsford, Jack H.; Qiu, Ping; Rosynek, Michael P.
The Journal of Physical Chemistry B, Vol. 102, Issue 1
DOI: 10.1021/jp9723628

Electrochemical Reduction of Carbon Dioxide on Various Metal Electrodes in Low-Temperature Aqueous KHCO₃ Media
journal, January 1990

Azuma, Masashi; Hashimoto, Kazuhito; Hiramoto, Masahiro
Journal of The Electrochemical Society, Vol. 137, Issue 6, p. 1772-1778
DOI: 10.1149/1.2086796

Solubility of CO ₂ in Aqueous Solutions of KCl and in Aqueous Solutions of K ₂ CO ₃
journal, May 2007

Pérez-Salado Kamps, Álvaro; Meyer, Eckehard; Rumpf, Bernd
Journal of Chemical & Engineering Data, Vol. 52, Issue 3
DOI: 10.1021/je060430q

Communication—Electrochemical Characterization of Commercial Bipolar Membranes under Electrolyte Conditions Relevant to Solar Fuels Technologies
journal, December 2015

Reiter, Ronald S.; White, William; Ardo, Shane
Journal of The Electrochemical Society, Vol. 163, Issue 4
DOI: 10.1149/2.0201604jes

Electrochemical Reduction of Carbon Dioxide at a Platinum Electrode in Acetonitrile-Water Mixtures
journal, January 2000

Tomita, Y.; Teruya, S.; Koga, O.
Journal of The Electrochemical Society, Vol. 147, Issue 11
DOI: 10.1149/1.1394035

Electrode reduction kinetics of carbon dioxide in aqueous solution
journal, October 1972

Ryu, J.; Andersen, T. N.; Eyring, H.
The Journal of Physical Chemistry, Vol. 76, Issue 22
DOI: 10.1021/j100666a029

Efficient Reduction of CO ₂ into Formic Acid on a Lead or Tin Electrode using an Ionic Liquid Catholyte Mixture
journal, June 2016

Zhu, Qinggong; Ma, Jun; Kang, Xinchen
Angewandte Chemie International Edition, Vol. 55, Issue 31
DOI: 10.1002/anie.201601974

Evaluation of CO2 solubility in potential aqueous amine-based solvents at low CO2 partial pressure
journal, January 2011

Singh, Prachi; Brilman, D. W. F. (Wim); Groeneveld, Michiel J.
International Journal of Greenhouse Gas Control, Vol. 5, Issue 1
DOI: 10.1016/j.ijggc.2010.06.009

Electrochemical reduction of carbon dioxide to ethylene with high Faradaic efficiency at a Cu electrode in CsOH/methanol
journal, September 1999

Kaneco, Satoshi; Iiba, Kenji; Hiei, Nobu-hide
Electrochimica Acta, Vol. 44, Issue 26, p. 4701-4706
DOI: 10.1016/S0013-4686(99)00262-5

Recent progress in alkaline water electrolysis for hydrogen production and applications
journal, June 2010

Zeng, Kai; Zhang, Dongke
Progress in Energy and Combustion Science, Vol. 36, Issue 3
DOI: 10.1016/j.pecs.2009.11.002

Tuning of CO ₂ Reduction Selectivity on Metal Electrocatalysts
journal, September 2017

Wang, Yuhang; Liu, Junlang; Wang, Yifei
Small, Vol. 13, Issue 43
DOI: 10.1002/smll.201701809

A comparative technoeconomic analysis of pathways for commercial electrochemical CO ₂ reduction to liquid products
journal, January 2018

Spurgeon, Joshua M.; Kumar, Bijandra
Energy & Environmental Science, Vol. 11, Issue 6
DOI: 10.1039/C8EE00097B

Influence of Electrolytes and Membranes on Cell Operation for Syn-Gas Production
journal, January 2012

Dufek, Eric J.; Lister, Tedd E.; McIlwain, Michael E.
Electrochemical and Solid-State Letters, Vol. 15, Issue 4
DOI: 10.1149/2.010204esl

Studies on the faradaic efficiency for electrochemical reduction of carbon dioxide to formate on tin electrode
journal, May 2014

Lv, Weixin; Zhang, Rui; Gao, Pengran
Journal of Power Sources, Vol. 253
DOI: 10.1016/j.jpowsour.2013.12.063

Amino acid modified copper electrodes for the enhanced selective electroreduction of carbon dioxide towards hydrocarbons
journal, January 2016

Xie, Ming Shi; Xia, Bao Yu; Li, Yawei
Energy & Environmental Science, Vol. 9, Issue 5
DOI: 10.1039/C5EE03694A

High pressure CO2 absorption studies on imidazolium-based ionic liquids: Experimental and simulation approaches
journal, August 2013

Karadas, Ferdi; Köz, Banu; Jacquemin, Johan
Fluid Phase Equilibria, Vol. 351
DOI: 10.1016/j.fluid.2012.10.022

Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide
journal, March 2016

Zhu, Dong Dong; Liu, Jin Long; Qiao, Shi Zhang
Advanced Materials, Vol. 28, Issue 18
DOI: 10.1002/adma.201504766

Transferring Electrochemical CO ₂ Reduction from Semi-Batch into Continuous Operation Mode Using Gas Diffusion Electrodes
journal, October 2016

Kopljar, Dennis; Wagner, Norbert; Klemm, Elias
Chemical Engineering & Technology, Vol. 39, Issue 11
DOI: 10.1002/ceat.201600198

Effects of mass transfer on the electrocatalytic CO 2 reduction on Cu
journal, June 2017

Lim, C. F. C.; Harrington, D. A.; Marshall, A. T.
Electrochimica Acta, Vol. 238
DOI: 10.1016/j.electacta.2017.04.017

Developments in electrode design: structure, decoration and applications of electrodes for electrochemical technology: Developments in electrode design
journal, July 2018

Walsh, Frank C.; Arenas, Luis F.; Ponce de León, Carlos
Journal of Chemical Technology & Biotechnology, Vol. 93, Issue 11
DOI: 10.1002/jctb.5706

The influence of pH on the reduction of CO and ${CO}_{2}$ to hydrocarbons on copper electrodes
journal, March 2014

Schouten, Klaas Jan P.; Pérez Gallent, Elena; Koper, Marc T. M.
Journal of Electroanalytical Chemistry, Vol. 716
DOI: 10.1016/j.jelechem.2013.08.033

Change in the product selectivity for the electrochemical CO2 reduction by adsorption of sulfide ion on metal electrodes
journal, August 1997

Hara, K.; Tsuneto, A.; Kudo, A.
Journal of Electroanalytical Chemistry, Vol. 434, Issue 1-2
DOI: 10.1016/S0022-0728(97)00045-4

Status and perspectives of CO2 conversion into fuels and chemicals by catalytic, photocatalytic and electrocatalytic processes
journal, January 2013

Kondratenko, Evgenii V.; Mul, Guido; Baltrusaitis, Jonas
Energy & Environmental Science, Vol. 6, Issue 11
DOI: 10.1039/c3ee41272e

Solubilities of carbon dioxide in the aqueous potassium carbonate and potassium carbonatepoly(ethylene glycol) solutions
journal, June 1997

Park, Sung-Bum; Shim, Choon-Sik; Lee, Huen
Fluid Phase Equilibria, Vol. 134, Issue 1-2
DOI: 10.1016/S0378-3812(97)00052-6

Electrochemical reduction of CO₂ over Sn-Nafion^® coated electrode for a fuel-cell-like device
journal, February 2013

Prakash, G. K. Surya; Viva, Federico A.; Olah, George A.
Journal of Power Sources, Vol. 223, p. 68-73
DOI: 10.1016/j.jpowsour.2012.09.036

Electrocatalytic Formation of CH[sub 4] from CO[sub 2] on a Pt Gas Diffusion Electrode
journal, January 1997

Hara, Kohjiro
Journal of The Electrochemical Society, Vol. 144, Issue 2
DOI: 10.1149/1.1837445

Ultrastable atomic copper nanosheets for selective electrochemical reduction of carbon dioxide
journal, September 2017

Dai, Lei; Qin, Qing; Wang, Pei
Science Advances, Vol. 3, Issue 9
DOI: 10.1126/sciadv.1701069

Understanding cation effects in electrochemical CO ₂ reduction
journal, January 2019

Ringe, Stefan; Clark, Ezra L.; Resasco, Joaquin
Energy & Environmental Science, Vol. 12, Issue 10
DOI: 10.1039/C9EE01341E

Effects of composition of the micro porous layer and the substrate on performance in the electrochemical reduction of CO2 to CO
journal, April 2016

Kim, Byoungsu; Hillman, Febrian; Ariyoshi, Miho
Journal of Power Sources, Vol. 312
DOI: 10.1016/j.jpowsour.2016.02.043

Controllable Hydrocarbon Formation from the Electrochemical Reduction of CO ₂ over Cu Nanowire Arrays
journal, April 2016

Ma, Ming; Djanashvili, Kristina; Smith, Wilson A.
Angewandte Chemie International Edition, Vol. 55, Issue 23
DOI: 10.1002/anie.201601282

Raman spectro-electrochemistry. I. In situ raman spectroscopic studies of the electrochemical reduction of CO2 at lead-impregnated PTFE-bonded carbon gas diffusion electrodes
journal, September 1987

Masheder, D.; Williams, K. P. J.
Journal of Raman Spectroscopy, Vol. 18, Issue 6
DOI: 10.1002/jrs.1250180603

Cathodic degradation mechanisms of pure Sn electrocatalyst in a nitrogen atmosphere
journal, November 2011

Chiacchiarelli, L. M.; Zhai, Y.; Frankel, G. S.
Journal of Applied Electrochemistry, Vol. 42, Issue 1
DOI: 10.1007/s10800-011-0367-z

A Gross-Margin Model for Defining Technoeconomic Benchmarks in the Electroreduction of CO ₂
journal, June 2016

Verma, Sumit; Kim, Byoungsu; Jhong, Huei-Ru “Molly”
ChemSusChem, Vol. 9, Issue 15
DOI: 10.1002/cssc.201600394

Promoter Effects of Alkali Metal Cations on the Electrochemical Reduction of Carbon Dioxide
journal, August 2017

Resasco, Joaquin; Chen, Leanne D.; Clark, Ezra
Journal of the American Chemical Society, Vol. 139, Issue 32
DOI: 10.1021/jacs.7b06765

Recent Technological Progress in CO ₂ Electroreduction to Fuels and Energy Carriers in Aqueous Environments
journal, February 2015

Bevilacqua, Manuela; Filippi, Jonathan; Miller, Hamish A.
Energy Technology, Vol. 3, Issue 3
DOI: 10.1002/ente.201402166

The electrochemical reduction of CO₂ to CH₄ and C₂H₄ at Cu/Nafion electrodes (solid polymer electrolyte structures)
journal, January 1988

Dewulf, David W.; Bard, Allen J.
Catalysis Letters, Vol. 1, Issue 1-3, p. 73-79
DOI: 10.1007/BF00765357

“Deactivation of copper electrode” in electrochemical reduction of CO2
journal, September 2005

Hori, Y.; Konishi, H.; Futamura, T.
Electrochimica Acta, Vol. 50, Issue 27
DOI: 10.1016/j.electacta.2005.03.015

Electrochemical Reduction of CO ₂ into Multicarbon Alcohols on Activated Cu Mesh Catalysts: An Identical Location (IL) Study
journal, October 2017

Rahaman, Motiar; Dutta, Abhijit; Zanetti, Alberto
ACS Catalysis, Vol. 7, Issue 11
DOI: 10.1021/acscatal.7b02234

In Situ Spectroscopic Examination of a Low Overpotential Pathway for Carbon Dioxide Conversion to Carbon Monoxide
journal, July 2012

Rosen, Brian A.; Haan, John L.; Mukherjee, Prabuddha
The Journal of Physical Chemistry C, Vol. 116, Issue 29, p. 15307-15312
DOI: 10.1021/jp210542v

Universal dependence of hydrogen oxidation and evolution reaction activity of platinum-group metals on pH and hydrogen binding energy
journal, March 2016

Zheng, Jie; Sheng, Wenchao; Zhuang, Zhongbin
Science Advances, Vol. 2, Issue 3
DOI: 10.1126/sciadv.1501602

The Electro-Reduction of Carbon Dioxide in a Continuous Reactor
journal, October 2005

Li, Hui; Oloman, Colin
Journal of Applied Electrochemistry, Vol. 35, Issue 10
DOI: 10.1007/s10800-005-7173-4

Chemical Recycling of Carbon Dioxide to Methanol and Dimethyl Ether: From Greenhouse Gas to Renewable, Environmentally Carbon Neutral Fuels and Synthetic Hydrocarbons
journal, January 2009

Olah, George A.; Goeppert, Alain; Prakash, G. K. Surya
The Journal of Organic Chemistry, Vol. 74, Issue 2, p. 487-498
DOI: 10.1021/jo801260f

Water Enhancement of CO₂ Conversion on Silver in 1-Ethyl-3-Methylimidazolium Tetrafluoroborate
journal, November 2012

Rosen, B. A.; Zhu, W.; Kaul, G.
Journal of the Electrochemical Society, Vol. 160, Issue 2, p. H138-H141
DOI: 10.1149/2.004303jes

The Technical and Energetic Challenges of Separating (Photo)Electrochemical Carbon Dioxide Reduction Products
journal, March 2018

Greenblatt, Jeffery B.; Miller, Daniel J.; Ager, Joel W.
Joule, Vol. 2, Issue 3
DOI: 10.1016/j.joule.2018.01.014

Carbon Foam Decorated with Silver Nanoparticles for Electrochemical CO ₂ Conversion
journal, January 2017

Ma, Sichao; Liu, Jianfeng; Sasaki, Kazunari
Energy Technology, Vol. 5, Issue 6
DOI: 10.1002/ente.201600576

Microfluidic Reactor for the Electrochemical Reduction of Carbon Dioxide: The Effect of pH
journal, January 2010

Whipple, Devin T.; Finke, Eryn C.; Kenis, Paul J. A.
Electrochemical and Solid-State Letters, Vol. 13, Issue 9
DOI: 10.1149/1.3456590

Solubility of Ethylene in Water.
journal, July 1960

Davis, J. E.; McKetta, J. J.
Journal of Chemical & Engineering Data, Vol. 5, Issue 3
DOI: 10.1021/je60007a039

Electrochemical conversion of CO2 to useful chemicals: current status, remaining challenges, and future opportunities
journal, May 2013

Jhong, Huei-Ru “Molly”; Ma, Sichao; Kenis, Paul JA
Current Opinion in Chemical Engineering, Vol. 2, Issue 2
DOI: 10.1016/j.coche.2013.03.005

Preparation of a Pb loaded gas diffusion electrode and its application to CO2 electroreduction
journal, September 2012

Li, Ang; Wang, Hua; Han, Jinyu
Frontiers of Chemical Science and Engineering, Vol. 6, Issue 4
DOI: 10.1007/s11705-012-1216-2

Prospective scenarios on energy efficiency and CO2 emissions in the European Iron & Steel industry
journal, June 2013

Pardo, Nicolás; Moya, José Antonio
Energy, Vol. 54
DOI: 10.1016/j.energy.2013.03.015

Switching the Reaction Course of Electrochemical CO ₂ Reduction with Ionic Liquids
journal, May 2014

Sun, Liyuan; Ramesha, Ganganahalli K.; Kamat, Prashant V.
Langmuir, Vol. 30, Issue 21
DOI: 10.1021/la5009076

Reduced Graphene Oxide Bipolar Membranes for Integrated Solar Water Splitting in Optimal pH
journal, July 2015

McDonald, Michael B.; Bruce, Jared P.; McEleney, Kevin
ChemSusChem, Vol. 8, Issue 16
DOI: 10.1002/cssc.201500538

High-rate electroreduction of carbon monoxide to multi-carbon products
journal, August 2018

Jouny, Matthew; Luc, Wesley; Jiao, Feng
Nature Catalysis, Vol. 1, Issue 10
DOI: 10.1038/s41929-018-0133-2

Mechanism of CO ₂ Reduction at Copper Surfaces: Pathways to C ₂ Products
journal, January 2018

Garza, Alejandro J.; Bell, Alexis T.; Head-Gordon, Martin
ACS Catalysis, Vol. 8, Issue 2
DOI: 10.1021/acscatal.7b03477

Electrochemical Reduction of CO at a Copper Electrode
journal, September 1997

Hori, Yoshio; Takahashi, Ryutaro; Yoshinami, Yuzuru
The Journal of Physical Chemistry B, Vol. 101, Issue 36
DOI: 10.1021/jp970284i

Two Pathways for the Formation of Ethylene in CO Reduction on Single-Crystal Copper Electrodes
journal, June 2012

Schouten, Klaas Jan P.; Qin, Zisheng; Pérez Gallent, Elena
Journal of the American Chemical Society, Vol. 134, Issue 24
DOI: 10.1021/ja302668n

Enhanced performance of gas diffusion electrode for electrochemical reduction of carbon dioxide to formate by adding polytetrafluoroethylene into catalyst layer
journal, April 2015

Wang, Qinian; Dong, Heng; Yu, Han
Journal of Power Sources, Vol. 279
DOI: 10.1016/j.jpowsour.2014.12.118

Investigations on the effects of ethanol–methanol–gasoline blends in a spark-ignition engine: Performance and emissions analysis
journal, December 2015

Elfasakhany, Ashraf
Engineering Science and Technology, an International Journal, Vol. 18, Issue 4
DOI: 10.1016/j.jestch.2015.05.003

Electrochemical conversion of carbon dioxide to methane in aqueous NaHCO₃ solution at less than 273 K
journal, November 2002

Kaneco, Satoshi; Hiei, Nobu-hide; Xing, Yue
Electrochimica Acta, Vol. 48, Issue 1, p. 51-55
DOI: 10.1016/S0013-4686(02)00550-9

Electrochemical reduction of carbon dioxide under high pressure on various electrodes in an aqueous electrolyte
journal, July 1995

Hara, Kohjiro; Kudo, Akihiko; Sakata, Tadayoshi
Journal of Electroanalytical Chemistry, Vol. 391, Issue 1-2, p. 141-147
DOI: 10.1016/0022-0728(95)03935-A

Influence of cation adsorption on the kinetics of electrode processes
journal, January 1959

Frumkin, A. N.
Transactions of the Faraday Society, Vol. 55
DOI: 10.1039/tf9595500156

Improving the hydrogen oxidation reaction rate by promotion of hydroxyl adsorption
journal, February 2013

Strmcnik, Dusan; Uchimura, Masanobu; Wang, Chao
Nature Chemistry, Vol. 5, Issue 4
DOI: 10.1038/nchem.1574

Low-energy formate production from CO ₂ electroreduction using electrodeposited tin on GDE
journal, January 2016

Irtem, E.; Andreu, T.; Parra, A.
Journal of Materials Chemistry A, Vol. 4, Issue 35
DOI: 10.1039/C6TA04432H

Reinforcing fabrics as the mechanical support of ion exchange membranes
journal, September 2017

Stránská, Eliška; Neděla, David
Journal of Industrial Textiles, Vol. 48, Issue 2
DOI: 10.1177/1528083717732075

3D Porous Carbonaceous Electrodes for Electrocatalytic Applications
journal, January 2018

Lai, Jianping; Nsabimana, Anaclet; Luque, Rafael
Joule, Vol. 2, Issue 1
DOI: 10.1016/j.joule.2017.10.005

Production of methanol from CO2 electroreduction at Cu2O and Cu2O/ZnO-based electrodes in aqueous solution
journal, October 2015

Albo, Jonathan; Sáez, Alfonso; Solla-Gullón, Jose
Applied Catalysis B: Environmental, Vol. 176-177
DOI: 10.1016/j.apcatb.2015.04.055

Electrochemical CO ₂ reduction on Au surfaces: mechanistic aspects regarding the formation of major and minor products
journal, January 2017

Cave, Etosha R.; Montoya, Joseph H.; Kuhl, Kendra P.
Physical Chemistry Chemical Physics, Vol. 19, Issue 24
DOI: 10.1039/C7CP02855E

Continuous-flow electroreduction of carbon dioxide
journal, September 2017

Endrődi, B.; Bencsik, G.; Darvas, F.
Progress in Energy and Combustion Science, Vol. 62
DOI: 10.1016/j.pecs.2017.05.005

Electroreduction of carbon dioxide
journal, July 1985

Vassiliev, Yu. B.; Bagotsky, V. S.; Osetrova, N. V.
Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 189, Issue 2, p. 271-294
DOI: 10.1016/0368-1874(85)80073-3

Examination of Near-Electrode Concentration Gradients and Kinetic Impacts on the Electrochemical Reduction of CO ₂ using Surface-Enhanced Infrared Spectroscopy
journal, April 2018

Dunwell, Marco; Yang, Xuan; Setzler, Brian P.
ACS Catalysis, Vol. 8, Issue 5
DOI: 10.1021/acscatal.8b01032

The Effects of Catalyst Layer Deposition Methodology on Electrode Performance
journal, February 2013

Jhong, Huei-Ru “Molly”; Brushett, Fikile R.; Kenis, Paul J. A.
Advanced Energy Materials, Vol. 3, Issue 5
DOI: 10.1002/aenm.201200759

Solubility of Carbon Dioxide in Aqueous Solutions of Monoethanolamine in the Low and High Gas Loading Regions
journal, March 2013

Wagner, Michael; von Harbou, Inga; Kim, Jaeik
Journal of Chemical & Engineering Data, Vol. 58, Issue 4
DOI: 10.1021/je301030z

Effect of Cations on the Electrochemical Conversion of CO₂ to CO
journal, November 2012

Thorson, M. R.; Siil, K. I.; Kenis, P. J. A.
Journal of the Electrochemical Society, Vol. 160, Issue 1, p. F69-F74
DOI: 10.1149/2.052301jes

Competition between Hydrogen Evolution and Carbon Dioxide Reduction on Copper Electrodes in Mildly Acidic Media
journal, May 2017

Ooka, Hideshi; Figueiredo, Marta C.; Koper, Marc T. M.
Langmuir, Vol. 33, Issue 37
DOI: 10.1021/acs.langmuir.7b00696

Gas-Diffusion Electrodes for Carbon Dioxide Reduction: A New Paradigm
journal, December 2018

Higgins, Drew; Hahn, Christopher; Xiang, Chengxiang
ACS Energy Letters, Vol. 4, Issue 1
DOI: 10.1021/acsenergylett.8b02035

Effects of Electrolyte Buffer Capacity on Surface Reactant Species and the Reaction Rate of CO ₂ in Electrochemical CO ₂ Reduction
journal, February 2018

Hashiba, Hiroshi; Weng, Lien-Chun; Chen, Yikai
The Journal of Physical Chemistry C, Vol. 122, Issue 7
DOI: 10.1021/acs.jpcc.7b11316

Bipolar Membrane-Assisted Solar Water Splitting in Optimal pH
journal, April 2016

Luo, Jingshan; Vermaas, David A.; Bi, Dongqin
Advanced Energy Materials, Vol. 6, Issue 13
DOI: 10.1002/aenm.201600100

Technical photosynthesis involving CO2 electrolysis and fermentation
journal, January 2018

Haas, Thomas; Krause, Ralf; Weber, Rainer
Nature Catalysis, Vol. 1, Issue 1
DOI: 10.1038/s41929-017-0005-1

CO₂ Capture by a Task-Specific Ionic Liquid
journal, February 2002

Bates, Eleanor D.; Mayton, Rebecca D.; Ntai, Ioanna
Journal of the American Chemical Society, Vol. 124, Issue 6, p. 926-927
DOI: 10.1021/ja017593d

Tuning the electrocatalytic properties of a Cu electrode with organic additives containing amine group for CO ₂ reduction
journal, January 2019

Qiu, Yanling; Zhong, Hexiang; Xu, Wenbin
Journal of Materials Chemistry A, Vol. 7, Issue 10
DOI: 10.1039/C9TA00039A

Effects of Temperature and Carbon Dioxide on Anion Exchange Membrane Conductivity
journal, January 2011

Grew, Kyle N.; Ren, Xiaoming; Chu, Deryn
Electrochemical and Solid-State Letters, Vol. 14, Issue 12
DOI: 10.1149/2.011112esl

Differential Electrochemical Mass Spectrometer Cell Design for Online Quantification of Products Produced during Electrochemical Reduction of CO ₂
journal, July 2015

Clark, Ezra L.; Singh, Meenesh R.; Kwon, Youngkook
Analytical Chemistry, Vol. 87, Issue 15
DOI: 10.1021/acs.analchem.5b02080

A review of gas diffusion layer in PEM fuel cells: Materials and designs
journal, April 2012

Park, Sehkyu; Lee, Jong-Won; Popov, Branko N.
International Journal of Hydrogen Energy, Vol. 37, Issue 7
DOI: 10.1016/j.ijhydene.2011.12.148

Theoretical Considerations on the Electroreduction of CO to C ₂ Species on Cu(100) Electrodes
journal, June 2013

Calle-Vallejo, Federico; Koper, Marc T. M.
Angewandte Chemie International Edition, Vol. 52, Issue 28
DOI: 10.1002/anie.201301470

The solubility of CO ₂ in a 30 mass percent monoethanolamine solution
journal, February 1995

Jou, Fang-Yuan; Mather, Alan E.; Otto, Frederick D.
The Canadian Journal of Chemical Engineering, Vol. 73, Issue 1
DOI: 10.1002/cjce.5450730116

CO₂ attraction by specifically adsorbed anions and subsequent accelerated electrochemical reduction
journal, December 2010

Ogura, Kotaro; Ferrell, Jack R.; Cugini, Anthony V.
Electrochimica Acta, Vol. 56, Issue 1, p. 381-386
DOI: 10.1016/j.electacta.2010.08.065

The effective surface pH during reactions at the solid–liquid interface
journal, June 2011

Katsounaros, Ioannis; Meier, Josef C.; Klemm, Sebastian O.
Electrochemistry Communications, Vol. 13, Issue 6
DOI: 10.1016/j.elecom.2011.03.032

Alkali cation specific adsorption onto fcc(111) transition metal electrodes
journal, January 2014

Mills, J. N.; McCrum, I. T.; Janik, M. J.
Phys. Chem. Chem. Phys., Vol. 16, Issue 27
DOI: 10.1039/C4CP00760C

Facet Dependence of CO ₂ Reduction Paths on Cu Electrodes
journal, December 2015

Luo, Wenjia; Nie, Xiaowa; Janik, Michael J.
ACS Catalysis, Vol. 6, Issue 1
DOI: 10.1021/acscatal.5b01967

Hydrolysis of Electrolyte Cations Enhances the Electrochemical Reduction of CO ₂ over Ag and Cu
journal, September 2016

Singh, Meenesh R.; Kwon, Youngkook; Lum, Yanwei
Journal of the American Chemical Society, Vol. 138, Issue 39
DOI: 10.1021/jacs.6b07612

Electrochemical Carbon Monoxide Reduction on Polycrystalline Copper: Effects of Potential, Pressure, and pH on Selectivity toward Multicarbon and Oxygenated Products
journal, July 2018

Wang, Lei; Nitopi, Stephanie A.; Bertheussen, Erlend
ACS Catalysis, Vol. 8, Issue 8
DOI: 10.1021/acscatal.8b01200

Gas diffusion layer for proton exchange membrane fuel cells—A review
journal, October 2009

Cindrella, L.; Kannan, A. M.; Lin, J. F.
Journal of Power Sources, Vol. 194, Issue 1
DOI: 10.1016/j.jpowsour.2009.04.005

The role of non-covalent interactions in electrocatalytic fuel-cell reactions on platinum
journal, August 2009

Strmcnik, D.; Kodama, K.; van der Vliet, D.
Nature Chemistry, Vol. 1, Issue 6
DOI: 10.1038/nchem.330

Standard Electrode Potentials for the Reduction of CO ₂ to CO in Acetonitrile–Water Mixtures Determined Using a Generalized Method for Proton-Coupled Electron-Transfer Reactions
journal, August 2017

Matsubara, Yasuo
ACS Energy Letters, Vol. 2, Issue 8
DOI: 10.1021/acsenergylett.7b00548

Low cost hydrogen production by anion exchange membrane electrolysis: A review
journal, January 2018

Vincent, Immanuel; Bessarabov, Dmitri
Renewable and Sustainable Energy Reviews, Vol. 81
DOI: 10.1016/j.rser.2017.05.258

What Should We Make with CO2 and How Can We Make It?
journal, May 2018

Bushuyev, Oleksandr S.; De Luna, Phil; Dinh, Cao Thang
Joule, Vol. 2, Issue 5
DOI: 10.1016/j.joule.2017.09.003

Carbon black vs. black carbon and other airborne materials containing elemental carbon: Physical and chemical distinctions
journal, October 2013

Long, Christopher M.; Nascarella, Marc A.; Valberg, Peter A.
Environmental Pollution, Vol. 181
DOI: 10.1016/j.envpol.2013.06.009

Efficient electrochemical conversion of CO2 to CO, C2H4 and CH4 at a three-phase interface on a Cu net electrode in acidic solution
journal, February 2002

Yano, H.; Shirai, F.; Nakayama, M.
Journal of Electroanalytical Chemistry, Vol. 519, Issue 1-2
DOI: 10.1016/S0022-0728(01)00729-X

Ionic Liquids at Electrified Interfaces
journal, March 2014

Fedorov, Maxim V.; Kornyshev, Alexei A.
Chemical Reviews, Vol. 114, Issue 5
DOI: 10.1021/cr400374x

Electroreduction of CO2 on polycrystalline copper: Effect of temperature on product selectivity
journal, June 2017

Ahn, Steven T.; Abu-Baker, Ismael; Palmore, G. Tayhas R.
Catalysis Today, Vol. 288
DOI: 10.1016/j.cattod.2016.09.028

A selective and efficient electrocatalyst for carbon dioxide reduction
journal, January 2014

Lu, Qi; Rosen, Jonathan; Zhou, Yang
Nature Communications, Vol. 5, Issue 1
DOI: 10.1038/ncomms4242

Influence of cathode gas diffusion media on the performance of the PEMFCs
journal, May 2004

Prasanna, M.; Ha, H. Y.; Cho, E. A.
Journal of Power Sources, Vol. 131, Issue 1-2
DOI: 10.1016/j.jpowsour.2004.01.030

Electrochemical reduction of high pressure carbon dioxide on Fe electrodes at large current density
journal, April 1995

Hara, Kohjiro; Kudo, Akihiko; Sakata, Tadayoshi
Journal of Electroanalytical Chemistry, Vol. 386, Issue 1-2
DOI: 10.1016/0022-0728(95)03917-6

Sn nanoparticles on gas diffusion electrodes: Synthesis, characterization and use for continuous CO 2 electroreduction to formate
journal, March 2017

Del Castillo, A.; Alvarez-Guerra, M.; Solla-Gullón, J.
Journal of CO2 Utilization, Vol. 18
DOI: 10.1016/j.jcou.2017.01.021

Coupled CO2 recovery from the atmosphere and water electrolysis: Feasibility of a new process for hydrogen storage
journal, August 1995

Stucki, S.
International Journal of Hydrogen Energy, Vol. 20, Issue 8
DOI: 10.1016/0360-3199(95)00007-Z

A review of the synthesis and characterization of anion exchange membranes
journal, May 2018

Hagesteijn, Kimberly F. L.; Jiang, Shanxue; Ladewig, Bradley P.
Journal of Materials Science, Vol. 53, Issue 16
DOI: 10.1007/s10853-018-2409-y

Catalysis of the electrochemical reduction of carbon dioxide
journal, January 2013

Costentin, Cyrille; Robert, Marc; Savéant, Jean-Michel
Chem. Soc. Rev., Vol. 42, Issue 6
DOI: 10.1039/C2CS35360A

Poisoning and Activation of the Gold Cathode during Electroreduction of CO[sub 2]
journal, January 1994

Kedzierzawski, P.
Journal of The Electrochemical Society, Vol. 141, Issue 5
DOI: 10.1149/1.2054936

Selective Formation of C2 Compounds from Electrochemical Reduction of CO ₂ at a Series of Copper Single Crystal Electrodes
journal, January 2002

Hori, Yoshio; Takahashi, Ichiro; Koga, Osamu
The Journal of Physical Chemistry B, Vol. 106, Issue 1
DOI: 10.1021/jp013478d

Effects of Anion Identity and Concentration on Electrochemical Reduction of CO ₂
journal, February 2018

Resasco, Joaquin; Lum, Yanwei; Clark, Ezra
ChemElectroChem, Vol. 5, Issue 7
DOI: 10.1002/celc.201701316

Controlling the Product Syngas H ₂ :CO Ratio through Pulsed-Bias Electrochemical Reduction of CO ₂ on Copper
journal, June 2016

Kumar, Bijandra; Brian, Joseph P.; Atla, Veerendra
ACS Catalysis, Vol. 6, Issue 7
DOI: 10.1021/acscatal.6b00857

Chlor-syngas: Coupling of Electrochemical Technologies for Production of Commodity Chemicals
journal, January 2013

Lister, Tedd E.; Dufek, Eric J.
Energy & Fuels, Vol. 27, Issue 8
DOI: 10.1021/ef302033j

Pulse-mode electrochemical reduction of carbon dioxide using copper and copper oxide electrodes for selective ethylene formation
journal, July 2008

Yano, J.; Yamasaki, S.
Journal of Applied Electrochemistry, Vol. 38, Issue 12
DOI: 10.1007/s10800-008-9622-3

Anion-exchange membranes in electrochemical energy systems
journal, January 2014

Varcoe, John R.; Atanassov, Plamen; Dekel, Dario R.
Energy & Environmental Science, Vol. 7, Issue 10, p. 3135-3191
DOI: 10.1039/C4EE01303D

Nanoparticle Silver Catalysts That Show Enhanced Activity for Carbon Dioxide Electrolysis
journal, January 2013

Salehi-Khojin, Amin; Jhong, Huei-Ru Molly; Rosen, Brian A.
The Journal of Physical Chemistry C, Vol. 117, Issue 4
DOI: 10.1021/jp310509z

Enhanced formation of ethylene and alcohols at ambient temperature and pressure in electrochemical reduction of carbon dioxide at a copper electrode
journal, January 1988

Hori, Yoshio; Murata, Akira; Takahashi, Ryutaro
Journal of the Chemical Society, Chemical Communications, Issue 1
DOI: 10.1039/C39880000017

Influence of interfacial surface conduction on the DC electrical conductivity of particle reinforced composites
journal, May 1998

Lipton, Robert
Proceedings of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences, Vol. 454, Issue 1973
DOI: 10.1098/rspa.1998.0212

Recent Progress in the Theoretical Investigation of Electrocatalytic Reduction of CO ₂
journal, April 2018

Tian, Ziqi; Priest, Chad; Chen, Liang
Advanced Theory and Simulations, Vol. 1, Issue 5
DOI: 10.1002/adts.201800004

Bicarbonate Is Not a General Acid in Au-Catalyzed CO ₂ Electroreduction
journal, November 2017

Wuttig, Anna; Yoon, Youngmin; Ryu, Jaeyune
Journal of the American Chemical Society, Vol. 139, Issue 47
DOI: 10.1021/jacs.7b08345

Acceleration of the reduction of carbon dioxide in the presence of multivalent cations
journal, September 2012

Schizodimou, Agoritsa; Kyriacou, Georgios
Electrochimica Acta, Vol. 78
DOI: 10.1016/j.electacta.2012.05.118

A practical method for measuring the true hydroxide conductivity of anion exchange membranes
journal, March 2018

Ziv, Noga; Dekel, Dario R.
Electrochemistry Communications, Vol. 88
DOI: 10.1016/j.elecom.2018.01.021

Electrochemical reduction of CO2 at metal-porphyrin supported gas diffusion electrodes under high pressure CO2
journal, June 1999

Sonoyama, Noriyuki; Kirii, Masakazu; Sakata, Tadayoshi
Electrochemistry Communications, Vol. 1, Issue 6
DOI: 10.1016/S1388-2481(99)00041-7

The effect of electrolyte composition on the electroreduction of CO ₂ to CO on Ag based gas diffusion electrodes
journal, January 2016

Verma, Sumit; Lu, Xun; Ma, Sichao
Physical Chemistry Chemical Physics, Vol. 18, Issue 10
DOI: 10.1039/C5CP05665A

The influence of electrolyte identity upon the electro-reduction of CO2
journal, September 2014

Setterfield-Price, Briony M.; Dryfe, Robert A. W.
Journal of Electroanalytical Chemistry, Vol. 730
DOI: 10.1016/j.jelechem.2014.07.009

New Insights into Perfluorinated Sulfonic-Acid Ionomers
journal, January 2017

Kusoglu, Ahmet; Weber, Adam Z.
Chemical Reviews, Vol. 117, Issue 3
DOI: 10.1021/acs.chemrev.6b00159

Standards and Protocols for Data Acquisition and Reporting for Studies of the Electrochemical Reduction of Carbon Dioxide
journal, May 2018

Clark, Ezra L.; Resasco, Joaquin; Landers, Alan
ACS Catalysis, Vol. 8, Issue 7
DOI: 10.1021/acscatal.8b01340

Modeling gas-diffusion electrodes for CO ₂ reduction
journal, January 2018

Weng, Lien-Chun; Bell, Alexis T.; Weber, Adam Z.
Physical Chemistry Chemical Physics, Vol. 20, Issue 25
DOI: 10.1039/C8CP01319E

Development of rolling tin gas diffusion electrode for carbon dioxide electrochemical reduction to produce formate in aqueous electrolyte
journal, December 2014

Wang, Qinian; Dong, Heng; Yu, Hongbing
Journal of Power Sources, Vol. 271
DOI: 10.1016/j.jpowsour.2014.08.017

Electrochemical reduction of high pressure CO₂ at Pb, Hg and In electrodes in an aqueous KHCO₃ solution
journal, September 1995

Todoroki, Makoto; Hara, Kohjiro; Kudo, Akihiko
Journal of Electroanalytical Chemistry, Vol. 394, Issue 1-2, p. 199-203
DOI: 10.1016/0022-0728(95)04010-L

Effect of Temperature on Electrochemical Reduction of High-Pressure CO ₂ with In, Sn, and Pb Electrodes
journal, September 1995

Mizuno, Takayuki; Ohta, Kiyohisa; Sasaki, Akira
Energy Sources, Vol. 17, Issue 5
DOI: 10.1080/00908319508946098

Development of an Electrochemical Process for the Simultaneous Treatment of Wastewater and the Conversion of Carbon Dioxide to Higher Value Products
journal, October 2016

Sabatino, Simona; Galia, Alessandro; Saracco, Guido
ChemElectroChem, Vol. 4, Issue 1
DOI: 10.1002/celc.201600475

Calculations of Product Selectivity in Electrochemical CO ₂ Reduction
journal, April 2018

Hussain, Javed; Jónsson, Hannes; Skúlason, Egill
ACS Catalysis, Vol. 8, Issue 6
DOI: 10.1021/acscatal.7b03308

Electrochemical reduction of high pressure CO2 at a Cu electrode in cold methanol
journal, June 2006

Kaneco, Satoshi; Iiba, Kenji; Katsumata, Hideyuki
Electrochimica Acta, Vol. 51, Issue 23
DOI: 10.1016/j.electacta.2006.01.032

Ionic liquids for energy, materials, and medicine
journal, January 2014

Smiglak, M.; Pringle, J. M.; Lu, X.
Chem. Commun., Vol. 50, Issue 66
DOI: 10.1039/C4CC02021A

Conversion of carbon dioxide into formate using a continuous electrochemical reduction process in a lead cathode
journal, October 2012

Alvarez-Guerra, Manuel; Quintanilla, Sheila; Irabien, Angel
Chemical Engineering Journal, Vol. 207-208
DOI: 10.1016/j.cej.2012.06.099

Highly Dense Cu Nanowires for Low-Overpotential CO₂ Reduction
journal, September 2015

Raciti, David; Livi, Kenneth J.; Wang, Chao
Nano Letters, Vol. 15, Issue 10, p. 6829-6835
DOI: 10.1021/acs.nanolett.5b03298

Carbon dioxide reduction with homogenous early transition metal complexes: Opportunities and challenges for developing CO 2 catalysis
journal, April 2017

Grice, Kyle A.
Coordination Chemistry Reviews, Vol. 336
DOI: 10.1016/j.ccr.2017.01.007

Fabrication of a novel tin gas diffusion electrode for electrochemical reduction of carbon dioxide to formic acid
journal, January 2014

Wang, Qinian; Dong, Heng; Yu, Hongbing
RSC Adv., Vol. 4, Issue 104
DOI: 10.1039/C4RA10775F

Kinetic studies of the electrolytic reduction of carbon dioxide on the mercury electrode
journal, December 1969

Paik, W.; Andersen, T. N.; Eyring, H.
Electrochimica Acta, Vol. 14, Issue 12
DOI: 10.1016/0013-4686(69)87019-2

Robust carbon dioxide reduction on molybdenum disulphide edges
journal, July 2014

Asadi, Mohammad; Kumar, Bijandra; Behranginia, Amirhossein
Nature Communications, Vol. 5, Issue 1
DOI: 10.1038/ncomms5470

Electrochemical reduction of CO₂ to hydrocarbons to store renewable electrical energy and upgrade biogas
journal, April 2007

Gattrell, M.; Gupta, N.; Co, A.
Energy Conversion and Management, Vol. 48, Issue 4, p. 1255-1265
DOI: 10.1016/j.enconman.2006.09.019

New Insights Into the Role of Imidazolium-Based Promoters for the Electroreduction of CO ₂ on a Silver Electrode
journal, June 2016

Lau, Genevieve P. S.; Schreier, Marcel; Vasilyev, Dmitry
Journal of the American Chemical Society, Vol. 138, Issue 25
DOI: 10.1021/jacs.6b03366

CO ₂ electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface
journal, May 2018

Dinh, Cao-Thang; Burdyny, Thomas; Kibria, Md Golam
Science, Vol. 360, Issue 6390
DOI: 10.1126/science.aas9100

Calculation for the cathode surface concentrations in the electrochemical reduction of CO2 in KHCO3 solutions
journal, October 2005

Gupta, N.; Gattrell, M.; MacDougall, B.
Journal of Applied Electrochemistry, Vol. 36, Issue 2
DOI: 10.1007/s10800-005-9058-y

CO2 recycling for hydrogen storage and transportation —Electrochemical CO2 removal and fixation
journal, June 1995

Bandi, Andreas; Specht, Michael; Weimer, Thomas
Energy Conversion and Management, Vol. 36, Issue 6-9
DOI: 10.1016/0196-8904(95)00148-7

Large Current Density CO ₂ Reduction under High Pressure Using Gas Diffusion Electrodes
journal, March 1997

Hara, Kohjiro; Sakata, Tadayoshi
Bulletin of the Chemical Society of Japan, Vol. 70, Issue 3
DOI: 10.1246/bcsj.70.571

Effects of Microporous Layers in Polymer Electrolyte Fuel Cells
journal, January 2005

Weber, Adam Z.; Newman, John
Journal of The Electrochemical Society, Vol. 152, Issue 4
DOI: 10.1149/1.1861194

Towards membrane-electrode assembly systems for CO ₂ reduction: a modeling study
journal, January 2019

Weng, Lien-Chun; Bell, Alexis T.; Weber, Adam Z.
Energy & Environmental Science, Vol. 12, Issue 6
DOI: 10.1039/C9EE00909D

Viscosity of liquid water in the range −8 °C to 150 °C
journal, July 1978

Kestin, Joseph; Sokolov, Mordechai; Wakeham, William A.
Journal of Physical and Chemical Reference Data, Vol. 7, Issue 3
DOI: 10.1063/1.555581

Electrolysis of CO ₂ to Syngas in Bipolar Membrane-Based Electrochemical Cells
journal, November 2016

Li, Yuguang C.; Zhou, Dekai; Yan, Zhifei
ACS Energy Letters, Vol. 1, Issue 6
DOI: 10.1021/acsenergylett.6b00475

Electrocatalytic and homogeneous approaches to conversion of CO ₂ to liquid fuels
journal, January 2009

Benson, Eric E.; Kubiak, Clifford P.; Sathrum, Aaron J.
Chem. Soc. Rev., Vol. 38, Issue 1
DOI: 10.1039/B804323J

Economics of carbon dioxide capture and utilization—a supply and demand perspective
journal, May 2016

Naims, Henriette
Environmental Science and Pollution Research, Vol. 23, Issue 22
DOI: 10.1007/s11356-016-6810-2

High Pressure Electrochemical Reduction of CO ₂ to Formic Acid/Formate: A Comparison between Bipolar Membranes and Cation Exchange Membranes
journal, January 2019

Ramdin, Mahinder; Morrison, Andrew R. T.; de Groen, Mariette
Industrial & Engineering Chemistry Research, Vol. 58, Issue 5
DOI: 10.1021/acs.iecr.8b04944

The Electrochemical Reduction of Carbon Dioxide to Formate/Formic Acid: Engineering and Economic Feasibility
journal, September 2011

Agarwal, Arun S.; Zhai, Yumei; Hill, Davion
ChemSusChem, Vol. 4, Issue 9
DOI: 10.1002/cssc.201100220

Salt concentration dependence of ionic conductivity in ion exchange membranes
journal, February 2018

Kamcev, Jovan; Sujanani, Rahul; Jang, Eui-Soung
Journal of Membrane Science, Vol. 547
DOI: 10.1016/j.memsci.2017.10.024

Voltammetric study of CO2 reduction at Cu electrodes under different KHCO3 concentrations, temperatures and CO2 pressures
journal, October 2001

De Jesús-Cardona, Héctor; del Moral, Cynthia; Cabrera, Carlos R.
Journal of Electroanalytical Chemistry, Vol. 513, Issue 1
DOI: 10.1016/S0022-0728(01)00598-8

Tailoring gas-phase CO ₂ electroreduction selectivity to hydrocarbons at Cu nanoparticles
journal, November 2017

Merino-Garcia, I.; Albo, J.; Irabien, A.
Nanotechnology, Vol. 29, Issue 1
DOI: 10.1088/1361-6528/aa994e

pH effects on the electrochemical reduction of CO(2) towards C2 products on stepped copper
journal, January 2019

Liu, Xinyan; Schlexer, Philomena; Xiao, Jianping
Nature Communications, Vol. 10, Issue 1
DOI: 10.1038/s41467-018-07970-9

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Title: Advances and challenges in electrochemical CO 2 reduction processes: an engineering and design perspective looking beyond new catalyst materials

Abstract

Citation Formats

Mesostructure-Induced Selectivity in CO 2 Reduction Catalysis journal, November 2015

A review on the electrochemical reduction of CO2 in fuel cells, metal electrodes and molecular catalysts journal, September 2014

Hydrophobic Gas-Diffusion Media for Polymer-Electrolyte Fuel Cells by Direct Fluorination journal, January 2015

Ionic-liquid materials for the electrochemical challenges of the future journal, July 2009

Electrodeposition of tin on Nafion-bonded carbon black as an active catalyst layer for efficient electroreduction of CO2 to formic acid journal, October 2017

High-Yield Electrochemical Production of Formaldehyde from CO 2 and Seawater journal, November 2013

Ultrathin Bismuth Nanosheets as a Highly Efficient CO 2 Reduction Electrocatalyst journal, January 2018

Mass transport modelling for the electroreduction of CO 2 on Cu nanowires journal, December 2017

High-Rate Electrochemical Reduction of Carbon Monoxide to Ethylene Using Cu-Nanoparticle-Based Gas Diffusion Electrodes journal, March 2018

Electrochemical CO2 Reduction on Metal Electrodes book, January 2008

Mechanism and kinetic characteristics of the electrochemical reduction of carbon dioxide in media of low proton availability journal, August 1981

Manipulating the Hydrocarbon Selectivity of Copper Nanoparticles in CO 2 Electroreduction by Process Conditions journal, December 2014

High-Performance Electrocatalysis Using Metallic Cobalt Pyrite (CoS 2 ) Micro- and Nanostructures journal, June 2014

CO2 electrochemical reduction via adsorbed halide anions journal, January 2011

Conversion of carbon dioxide into methanol – a potential liquid fuel: Fundamental challenges and opportunities (a review) journal, March 2014

Chlor-alkali electrolysis with oxygen depolarized cathodes: history, present status and future prospects journal, May 2008

Fundamentals and Challenges of Electrochemical CO2 Reduction Using Two-Dimensional Materials journal, October 2017

Electrolytic Reduction of Carbon Dioxide at Mercury Electrode in Aqueous Solution journal, March 1982

Electrocatalytic Alloys for CO 2 Reduction journal, December 2017

Optimizing C–C Coupling on Oxide-Derived Copper Catalysts for Electrochemical CO 2 Reduction journal, June 2017

The solubility of methane in aqueous solutions of monoethanolamine, diethanolamine and triethanolamine journal, October 1998

An electrochemical engineering assessment of the operational conditions and constraints for solar-driven water-splitting systems at near-neutral pH journal, January 2015

Flow-Field Designs of Bipolar Plates in PEM Fuel Cells: Theory and Applications journal, November 2012

Tuning Sn-Catalysis for Electrochemical Reduction of CO 2 to CO via the Core/Shell Cu/SnO 2 Structure journal, March 2017

Production of Methane and Ethylene in Electrochemical Reduction of Carbon Dioxide at Copper Electrode in Aqueous Hydrogencarbonate Solution journal, June 1986

Hydrogen production by alkaline water electrolysis journal, January 2013

Defining a Materials Database for the Design of Copper Binary Alloy Catalysts for Electrochemical CO 2 Conversion journal, January 2018

Understanding Selectivity for the Electrochemical Reduction of Carbon Dioxide to Formic Acid and Carbon Monoxide on Metal Electrodes journal, June 2017

Carbon dioxide reduction at low temperature on various metal electrodes journal, March 1989

Controlling the selectivity of CO2 electroreduction on copper: The effect of the electrolyte concentration and the importance of the local pH journal, February 2016

Electro-catalytic membrane reactors and the development of bipolar membrane technology journal, September 2004

Efficient Reduction of CO 2 to CO with High Current Density Using in Situ or ex Situ Prepared Bi-Based Materials journal, May 2014

The Suitability of Monopolar and Bipolar Ion Exchange Membranes as Separators for Biological Fuel Cells journal, March 2008

Energy applications of ionic liquids journal, January 2014

Improved CO 2 Electroreduction Performance on Plasma-Activated Cu Catalysts via Electrolyte Design: Halide Effect journal, July 2017

Catalytic Electrochemical Reduction of CO2 in Ionic Liquid EMIMBF3Cl journal, January 2011

Review of bipolar plates in PEM fuel cells: Flow-field designs journal, March 2005

Membraneless laminar flow cell for electrocatalytic CO 2 reduction with liquid product separation journal, March 2017

Theoretical Insights into a CO Dimerization Mechanism in CO 2 Electroreduction journal, May 2015

Long-term activation of the copper cathode in the course of CO2 reduction journal, August 1994

Electrochemical reduction of carbon dioxide to ethylene: Mechanistic approach journal, June 2013

Product Selectivity Affected by Cationic Species in Electrochemical Reduction of CO 2 and CO at a Cu Electrode journal, January 1991

High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts journal, February 2015

Cu2O-loaded gas diffusion electrodes for the continuous electrochemical reduction of CO2 to methanol journal, November 2016

Ionic liquids in the electrochemical valorisation of CO 2 journal, January 2015

Identification of Possible Pathways for C–C Bond Formation during Electrochemical Reduction of CO 2 : New Theoretical Insights from an Improved Electrochemical Model journal, April 2016

Design of Electrocatalysts and Electrochemical Cells for Carbon Dioxide Reduction Reactions journal, March 2018

Towards a better Sn: Efficient electrocatalytic reduction of CO 2 to formate by Sn/SnS 2 derived from SnS 2 nanosheets journal, January 2017

Effects of temperature and gas–liquid mass transfer on the operation of small electrochemical cells for the quantitative evaluation of CO 2 reduction electrocatalysts journal, January 2016

Electrochemical reduction of CO2 to formate at high current density using gas diffusion electrodes journal, August 2014

Influence of adsorption processes on the CO2 electroreduction: An electrochemical mass spectrometry study journal, August 2005

On the performance of membraneless laminar flow-based fuel cells journal, June 2010

Ionic Liquid-Mediated Selective Conversion of CO2 to CO at Low Overpotentials journal, September 2011

Selective ethylene formation by pulse-mode electrochemical reduction of carbon dioxide using copper and copper-oxide electrodes journal, July 2006

Insights into the electrocatalytic reduction of CO 2 on metallic silver surfaces journal, January 2014

A broad parameter range for selective methane production with bicarbonate solution in electrochemical CO 2 reduction journal, January 2017

Electrochemical conversion of CO2 to HCOOH at tin cathode in a pressurized undivided filter-press cell journal, July 2018

High Efficiency Electrochemical Reduction of Carbon Dioxide under High Pressure on a Gas Diffusion Electrode Containing Pt Catalysts journal, January 1995

Tuning Catalytic Selectivity at the Mesoscale via Interparticle Interactions journal, January 2016

Selective Electrochemical Reduction of Carbon Dioxide to Ethylene and Ethanol on Copper(I) Oxide Catalysts journal, March 2015

Homogeneously Catalyzed Electroreduction of Carbon Dioxide—Methods, Mechanisms, and Catalysts journal, January 2018

Enhanced Electrochemical Methanation of Carbon Dioxide with a Dispersible Nanoscale Copper Catalyst journal, September 2014

Investigation of Formic Acid Separation from Aqueous Solution by Reactive Extraction: Effects of Extractant and Diluent journal, April 2010

Methanol to Olefins (MTO): From Fundamentals to Commercialization journal, February 2015

Effects of electrolyte, catalyst, and membrane composition and operating conditions on the performance of solar-driven electrochemical reduction of carbon dioxide journal, January 2015

A review on microstructure reconstruction of PEM fuel cells porous electrodes for pore scale simulation journal, November 2016

Impurity Ion Complexation Enhances Carbon Dioxide Reduction Catalysis journal, June 2015

Continuous electroreduction of CO 2 to formate using Sn gas diffusion electrodes journal, July 2014

A review of the gas diffusion layer in proton exchange membrane fuel cells: Durability and degradation journal, October 2015

Roles of ion pairing on electroreduction of carbon dioxide based on imidazolium-based salts journal, March 2015

Carbon Dioxide and Water Electrolysis Using New Alkaline Stable Anion Membranes journal, July 2018

High Rate Gas Phase CO[sub 2] Reduction to Ethylene and Methane Using Gas Diffusion Electrodes journal, January 1990

Reduction of CO2 and CO to methane on Cu foil electrodes journal, April 1988

Use of Bipolar Membranes for Maintaining Steady-State pH Gradients in Membrane-Supported, Solar-Driven Water Splitting journal, September 2014

New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces journal, January 2012

Highly selective electrocatalytic reduction of carbon dioxide to carbon monoxide on silver electrode with aqueous ionic liquids journal, September 2014

Title: Advances and challenges in electrochemical CO ₂ reduction processes: an engineering and design perspective looking beyond new catalyst materials

Mesostructure-Induced Selectivity in CO ₂ Reduction Catalysis
journal, November 2015

A review on the electrochemical reduction of CO2 in fuel cells, metal electrodes and molecular catalysts
journal, September 2014

Hydrophobic Gas-Diffusion Media for Polymer-Electrolyte Fuel Cells by Direct Fluorination
journal, January 2015

Ionic-liquid materials for the electrochemical challenges of the future
journal, July 2009

Electrodeposition of tin on Nafion-bonded carbon black as an active catalyst layer for efficient electroreduction of CO2 to formic acid
journal, October 2017

High-Yield Electrochemical Production of Formaldehyde from CO ₂ and Seawater
journal, November 2013

Ultrathin Bismuth Nanosheets as a Highly Efficient CO ₂ Reduction Electrocatalyst
journal, January 2018

Mass transport modelling for the electroreduction of CO ₂ on Cu nanowires
journal, December 2017

High-Rate Electrochemical Reduction of Carbon Monoxide to Ethylene Using Cu-Nanoparticle-Based Gas Diffusion Electrodes
journal, March 2018

Electrochemical CO₂ Reduction on Metal Electrodes
book, January 2008

Mechanism and kinetic characteristics of the electrochemical reduction of carbon dioxide in media of low proton availability
journal, August 1981

Manipulating the Hydrocarbon Selectivity of Copper Nanoparticles in CO ₂ Electroreduction by Process Conditions
journal, December 2014

High-Performance Electrocatalysis Using Metallic Cobalt Pyrite (CoS ₂ ) Micro- and Nanostructures
journal, June 2014

CO2 electrochemical reduction via adsorbed halide anions
journal, January 2011

Conversion of carbon dioxide into methanol – a potential liquid fuel: Fundamental challenges and opportunities (a review)
journal, March 2014

Chlor-alkali electrolysis with oxygen depolarized cathodes: history, present status and future prospects
journal, May 2008

Fundamentals and Challenges of Electrochemical CO2 Reduction Using Two-Dimensional Materials
journal, October 2017

Electrolytic Reduction of Carbon Dioxide at Mercury Electrode in Aqueous Solution
journal, March 1982

Electrocatalytic Alloys for CO ₂ Reduction
journal, December 2017

Optimizing C–C Coupling on Oxide-Derived Copper Catalysts for Electrochemical CO ₂ Reduction
journal, June 2017

The solubility of methane in aqueous solutions of monoethanolamine, diethanolamine and triethanolamine
journal, October 1998

An electrochemical engineering assessment of the operational conditions and constraints for solar-driven water-splitting systems at near-neutral pH
journal, January 2015

Flow-Field Designs of Bipolar Plates in PEM Fuel Cells: Theory and Applications
journal, November 2012

Tuning Sn-Catalysis for Electrochemical Reduction of CO ₂ to CO via the Core/Shell Cu/SnO ₂ Structure
journal, March 2017

Production of Methane and Ethylene in Electrochemical Reduction of Carbon Dioxide at Copper Electrode in Aqueous Hydrogencarbonate Solution
journal, June 1986

Hydrogen production by alkaline water electrolysis
journal, January 2013

Defining a Materials Database for the Design of Copper Binary Alloy Catalysts for Electrochemical CO ₂ Conversion
journal, January 2018

Understanding Selectivity for the Electrochemical Reduction of Carbon Dioxide to Formic Acid and Carbon Monoxide on Metal Electrodes
journal, June 2017

Carbon dioxide reduction at low temperature on various metal electrodes
journal, March 1989

Controlling the selectivity of CO2 electroreduction on copper: The effect of the electrolyte concentration and the importance of the local pH
journal, February 2016

Electro-catalytic membrane reactors and the development of bipolar membrane technology
journal, September 2004

Efficient Reduction of CO ₂ to CO with High Current Density Using in Situ or ex Situ Prepared Bi-Based Materials
journal, May 2014

The Suitability of Monopolar and Bipolar Ion Exchange Membranes as Separators for Biological Fuel Cells
journal, March 2008

Energy applications of ionic liquids
journal, January 2014

Improved CO ₂ Electroreduction Performance on Plasma-Activated Cu Catalysts via Electrolyte Design: Halide Effect
journal, July 2017

Catalytic Electrochemical Reduction of CO2 in Ionic Liquid EMIMBF3Cl
journal, January 2011

Review of bipolar plates in PEM fuel cells: Flow-field designs
journal, March 2005

Membraneless laminar flow cell for electrocatalytic CO ₂ reduction with liquid product separation
journal, March 2017

Theoretical Insights into a CO Dimerization Mechanism in CO ₂ Electroreduction
journal, May 2015

Long-term activation of the copper cathode in the course of CO₂ reduction
journal, August 1994

Electrochemical reduction of carbon dioxide to ethylene: Mechanistic approach
journal, June 2013

Product Selectivity Affected by Cationic Species in Electrochemical Reduction of CO ₂ and CO at a Cu Electrode
journal, January 1991

High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts
journal, February 2015

Cu2O-loaded gas diffusion electrodes for the continuous electrochemical reduction of CO2 to methanol
journal, November 2016

Ionic liquids in the electrochemical valorisation of CO ₂
journal, January 2015

Identification of Possible Pathways for C–C Bond Formation during Electrochemical Reduction of CO ₂ : New Theoretical Insights from an Improved Electrochemical Model
journal, April 2016

Design of Electrocatalysts and Electrochemical Cells for Carbon Dioxide Reduction Reactions
journal, March 2018

Towards a better Sn: Efficient electrocatalytic reduction of CO 2 to formate by Sn/SnS 2 derived from SnS 2 nanosheets
journal, January 2017

Effects of temperature and gas–liquid mass transfer on the operation of small electrochemical cells for the quantitative evaluation of CO ₂ reduction electrocatalysts
journal, January 2016

Electrochemical reduction of CO2 to formate at high current density using gas diffusion electrodes
journal, August 2014

Influence of adsorption processes on the CO₂ electroreduction: An electrochemical mass spectrometry study
journal, August 2005

On the performance of membraneless laminar flow-based fuel cells
journal, June 2010

Ionic Liquid-Mediated Selective Conversion of CO₂ to CO at Low Overpotentials
journal, September 2011

Selective ethylene formation by pulse-mode electrochemical reduction of carbon dioxide using copper and copper-oxide electrodes
journal, July 2006

Insights into the electrocatalytic reduction of CO ₂ on metallic silver surfaces
journal, January 2014

A broad parameter range for selective methane production with bicarbonate solution in electrochemical CO ₂ reduction
journal, January 2017

Electrochemical conversion of CO2 to HCOOH at tin cathode in a pressurized undivided filter-press cell
journal, July 2018

High Efficiency Electrochemical Reduction of Carbon Dioxide under High Pressure on a Gas Diffusion Electrode Containing Pt Catalysts
journal, January 1995

Tuning Catalytic Selectivity at the Mesoscale via Interparticle Interactions
journal, January 2016

Selective Electrochemical Reduction of Carbon Dioxide to Ethylene and Ethanol on Copper(I) Oxide Catalysts
journal, March 2015

Homogeneously Catalyzed Electroreduction of Carbon Dioxide—Methods, Mechanisms, and Catalysts
journal, January 2018

Enhanced Electrochemical Methanation of Carbon Dioxide with a Dispersible Nanoscale Copper Catalyst
journal, September 2014

Investigation of Formic Acid Separation from Aqueous Solution by Reactive Extraction: Effects of Extractant and Diluent
journal, April 2010

Methanol to Olefins (MTO): From Fundamentals to Commercialization
journal, February 2015

Effects of electrolyte, catalyst, and membrane composition and operating conditions on the performance of solar-driven electrochemical reduction of carbon dioxide
journal, January 2015

A review on microstructure reconstruction of PEM fuel cells porous electrodes for pore scale simulation
journal, November 2016

Impurity Ion Complexation Enhances Carbon Dioxide Reduction Catalysis
journal, June 2015

Continuous electroreduction of CO ₂ to formate using Sn gas diffusion electrodes
journal, July 2014

A review of the gas diffusion layer in proton exchange membrane fuel cells: Durability and degradation
journal, October 2015

Roles of ion pairing on electroreduction of carbon dioxide based on imidazolium-based salts
journal, March 2015

Carbon Dioxide and Water Electrolysis Using New Alkaline Stable Anion Membranes
journal, July 2018

High Rate Gas Phase CO[sub 2] Reduction to Ethylene and Methane Using Gas Diffusion Electrodes
journal, January 1990

Reduction of CO₂ and CO to methane on Cu foil electrodes
journal, April 1988

Use of Bipolar Membranes for Maintaining Steady-State pH Gradients in Membrane-Supported, Solar-Driven Water Splitting
journal, September 2014

New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
journal, January 2012

Highly selective electrocatalytic reduction of carbon dioxide to carbon monoxide on silver electrode with aqueous ionic liquids
journal, September 2014

Selectivity of ion exchange membranes: A review
journal, June 2018

A new mechanism for the selectivity to C1 and C2 species in the electrochemical reduction of carbon dioxide on copper electrodes
journal, January 2011

Recent advances in the nanoengineering of electrocatalysts for CO ₂ reduction
journal, January 2018