DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Changes in Ni-NiO equilibrium due to LaFeO3 and the effect on dry reforming of CH4

ORCiD logo; ; ; ORCiD logo
Publication Date:
Sponsoring Org.:
OSTI Identifier:
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Catalysis
Additional Journal Information:
Journal Name: Journal of Catalysis Journal Volume: 381 Journal Issue: C; Journal ID: ISSN 0021-9517
Country of Publication:
United States

Citation Formats

Mao, Xinyu, Foucher, Alexandre C., Stach, Eric A., and Gorte, Raymond J. Changes in Ni-NiO equilibrium due to LaFeO3 and the effect on dry reforming of CH4. United States: N. p., 2020. Web. doi:10.1016/j.jcat.2019.11.040.
Mao, Xinyu, Foucher, Alexandre C., Stach, Eric A., & Gorte, Raymond J. Changes in Ni-NiO equilibrium due to LaFeO3 and the effect on dry reforming of CH4. United States.
Mao, Xinyu, Foucher, Alexandre C., Stach, Eric A., and Gorte, Raymond J. Wed . "Changes in Ni-NiO equilibrium due to LaFeO3 and the effect on dry reforming of CH4". United States.
title = {Changes in Ni-NiO equilibrium due to LaFeO3 and the effect on dry reforming of CH4},
author = {Mao, Xinyu and Foucher, Alexandre C. and Stach, Eric A. and Gorte, Raymond J.},
abstractNote = {},
doi = {10.1016/j.jcat.2019.11.040},
journal = {Journal of Catalysis},
number = C,
volume = 381,
place = {United States},
year = {2020},
month = {1}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 2 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Dry reforming of methane has no future for hydrogen production: Comparison with steam reforming at high pressure in standard and membrane reactors
journal, July 2012

New Atomic-Scale Insight into Self-Regeneration of Pt-CaTiO 3 Catalysts: Incipient Redox-Induced Structures Revealed by a Small-Angle Tilting STEM Technique
journal, August 2017

  • Zhang, Shuyi; Katz, Michael B.; Dai, Sheng
  • The Journal of Physical Chemistry C, Vol. 121, Issue 32
  • DOI: 10.1021/acs.jpcc.7b05200

Additive effect of noble metals on NiO-MgO solid solution in oxidative steam reforming of methane under atmospheric and pressurized conditions
journal, January 2006

Oxidation enthalpies for reduction of ceria surfaces
journal, June 2007

Polarization-Induced Hysteresis in CuCo-Doped Rare Earth Vanadates SOFC Anodes
journal, January 2012

  • Adijanto, Lawrence; Padmanabhan, Venu Balaji; Gorte, Raymond J.
  • Journal of The Electrochemical Society, Vol. 159, Issue 11
  • DOI: 10.1149/2.042211jes

Approaches for Understanding and Controlling Interfacial Effects in Oxide-Supported Metal Catalysts
journal, July 2018

Trends in electrode development for next generation solid oxide fuel cells
journal, January 2016

  • Kan, Wang Hay; Samson, Alfred Junio; Thangadurai, Venkataraman
  • Journal of Materials Chemistry A, Vol. 4, Issue 46
  • DOI: 10.1039/C6TA06757C

New Opportunity for in Situ Exsolution of Metallic Nanoparticles on Perovskite Parent
journal, July 2016

Strong metal-support interactions: Occurrence among the binary oxides of groups IIA?VB
journal, October 1978

Inverse NiAl 2 O 4 on LaAlO 3 –Al 2 O 3 : Unique Catalytic Structure for Stable CO 2 Reforming of Methane
journal, April 2013

  • Kathiraser, Yasotha; Thitsartarn, Warintorn; Sutthiumporn, Kesada
  • The Journal of Physical Chemistry C, Vol. 117, Issue 16
  • DOI: 10.1021/jp401855x

Coke-resistant Ni@SiO2 catalyst for dry reforming of methane
journal, October 2015

Facet-Dependent in Situ Growth of Nanoparticles in Epitaxial Thin Films: The Role of Interfacial Energy
journal, April 2019

  • Kim, Kun Joong; Han, Hyeon; Defferriere, Thomas
  • Journal of the American Chemical Society, Vol. 141, Issue 18
  • DOI: 10.1021/jacs.9b02283

Dynamical Observation and Detailed Description of Catalysts under Strong Metal–Support Interaction
journal, June 2016

Super-dry reforming of methane intensifies CO2 utilization via Le Chateliers principle
journal, October 2016

Improved Coking Resistance of “Intelligent” Ni Catalysts Prepared by Atomic Layer Deposition
journal, July 2018

Carbon dioxide reforming of methane to synthesis gas over Ni/La2O3 catalysts
journal, April 1996

Smart Pd Catalyst with Improved Thermal Stability Supported on High-Surface-Area LaFeO 3 Prepared by Atomic Layer Deposition
journal, January 2018

  • Onn, Tzia Ming; Monai, Matteo; Dai, Sheng
  • Journal of the American Chemical Society, Vol. 140, Issue 14
  • DOI: 10.1021/jacs.7b12900

Oxidation-induced degradation and performance fluctuation of solid oxide fuel cell Ni anodes under simulated high fuel utilization conditions
journal, April 2019

A thermodynamic study of the redox properties of supported Co particles
journal, April 2011

  • Bakhmutsky, Kevin; Wieder, Noah L.; Baldassare, Thomas
  • Applied Catalysis A: General, Vol. 397, Issue 1-2
  • DOI: 10.1016/j.apcata.2011.03.013

Evidence and Model for Strain-Driven Release of Metal Nanocatalysts from Perovskites during Exsolution
journal, December 2015

  • Oh, Tae-Sik; Rahani, Ehsan K.; Neagu, Dragos
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 24
  • DOI: 10.1021/acs.jpclett.5b02292

Structural Reversibility and Nickel Particle stability in Lanthanum Iron Nickel Perovskite-Type Catalysts
journal, May 2017

  • Steiger, Patrick; Delmelle, Renaud; Foppiano, Debora
  • ChemSusChem, Vol. 10, Issue 11
  • DOI: 10.1002/cssc.201700358

In Situ Observation of Rh-CaTiO 3 Catalysts during Reduction and Oxidation Treatments by Transmission Electron Microscopy
journal, January 2017

Search for a Self-Regenerating Perovskite Catalyst Using ab Initio Thermodynamics Calculations
journal, January 2013

  • Yanagisawa, Susumu; Uozumi, Akifumi; Hamada, Ikutaro
  • The Journal of Physical Chemistry C, Vol. 117, Issue 3
  • DOI: 10.1021/jp305392x

Steam Reforming and Graphite Formation on Ni Catalysts
journal, July 2002

  • Bengaard, H. S.; Nørskov, J. K.; Sehested, J.
  • Journal of Catalysis, Vol. 209, Issue 2
  • DOI: 10.1006/jcat.2002.3579

Stability of Nanocrystals:  Thermodynamic Analysis of Oxidation and Re-reduction of Cobalt in Water/Hydrogen Mixtures
journal, March 2005

  • van Steen, Eric; Claeys, Michael; Dry, Mark E.
  • The Journal of Physical Chemistry B, Vol. 109, Issue 8
  • DOI: 10.1021/jp045136o

Self-Regenerating Rh- and Pt-Based Perovskite Catalysts for Automotive-Emissions Control
journal, September 2006

  • Tanaka, Hirohisa; Taniguchi, Masashi; Uenishi, Mari
  • Angewandte Chemie International Edition, Vol. 45, Issue 36
  • DOI: 10.1002/anie.200503938

CO2 dry-reforming of methane over La0.8Sr0.2Ni0.8M0.2O3 perovskite (M = Bi, Co, Cr, Cu, Fe): Roles of lattice oxygen on C–H activation and carbon suppression
journal, August 2012

Evidence for Entropy Effects in the Reduction of Ceria−Zirconia Solutions
journal, October 2006

  • Shah, Parag R.; Kim, Taeyoon; Zhou, Gong
  • Chemistry of Materials, Vol. 18, Issue 22
  • DOI: 10.1021/cm061374f

Cooperation of Ni and CaO at Interface for CO 2 Reforming of CH 4 : A Combined Theoretical and Experimental Study
journal, September 2019

Self-regeneration of a Pd-perovskite catalyst for automotive emissions control
journal, July 2002

Nano-socketed nickel particles with enhanced coking resistance grown in situ by redox exsolution
journal, September 2015

  • Neagu, Dragos; Oh, Tae-Sik; Miller, David N.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms9120

Highly stable barium zirconate supported nickel oxide catalyst for dry reforming of methane: From powders toward shaped catalysts
journal, June 2018

“Intelligent” Pt Catalysts Studied on High-Surface-Area CaTiO 3 Films
journal, June 2019