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Title: Synthesis, characterization and C–H amination reactivity of nickel iminyl complexes

Abstract

Nickel-supported nitrenoids exhibit iminyl character, as determined by multi-edge XAS and TDDFT analysis, demonstrate efficacy for C–H activation and nitrene transfer chemistry.

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [1]
  1. Department of Chemistry and Chemical Biology, Harvard University, Cambridge, USA
  2. Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, New York 14853, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1579760
Grant/Contract Number:  
AC02-76SF00515
Resource Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Dong, Yuyang, Lukens, James T., Clarke, Ryan M., Zheng, Shao-Liang, Lancaster, Kyle M., and Betley, Theodore A. Synthesis, characterization and C–H amination reactivity of nickel iminyl complexes. United Kingdom: N. p., 2020. Web. doi:10.1039/C9SC04879K.
Dong, Yuyang, Lukens, James T., Clarke, Ryan M., Zheng, Shao-Liang, Lancaster, Kyle M., & Betley, Theodore A. Synthesis, characterization and C–H amination reactivity of nickel iminyl complexes. United Kingdom. doi:10.1039/C9SC04879K.
Dong, Yuyang, Lukens, James T., Clarke, Ryan M., Zheng, Shao-Liang, Lancaster, Kyle M., and Betley, Theodore A. Wed . "Synthesis, characterization and C–H amination reactivity of nickel iminyl complexes". United Kingdom. doi:10.1039/C9SC04879K.
@article{osti_1579760,
title = {Synthesis, characterization and C–H amination reactivity of nickel iminyl complexes},
author = {Dong, Yuyang and Lukens, James T. and Clarke, Ryan M. and Zheng, Shao-Liang and Lancaster, Kyle M. and Betley, Theodore A.},
abstractNote = {Nickel-supported nitrenoids exhibit iminyl character, as determined by multi-edge XAS and TDDFT analysis, demonstrate efficacy for C–H activation and nitrene transfer chemistry.},
doi = {10.1039/C9SC04879K},
journal = {Chemical Science},
number = ,
volume = ,
place = {United Kingdom},
year = {2020},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C9SC04879K

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