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Title: Mechanistic insights into copper-catalyzed aerobic oxidative coupling of N–N bonds

Journal Article · · Chemical Science
DOI: https://doi.org/10.1039/C9SC04305E · OSTI ID:1579758
ORCiD logo [1]; ORCiD logo [1];  [1]; ORCiD logo [1]; ORCiD logo [1];  [2]; ORCiD logo [1]
  1. Department of Chemistry, University of Wisconsin–Madison, Madison, USA
  2. Small Molecule Design and Development, Lilly Research Laboratories, Eli Lilly and Company, Indianapolis, USA
+ Show Author Affiliations

Mechanistic studies provide valuable insights into Cu-catalyzed N–N coupling reactions relevant to energy conversion and pharmaceutical synthesis.

Research Organization:
Univ. of Wisconsin, Madison, WI (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
FG02-05ER15690
OSTI ID:
1579758
Journal Information:
Chemical Science, Journal Name: Chemical Science Journal Issue: 4 Vol. 11; ISSN 2041-6520; ISSN CSHCBM
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

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Effects of Electron-Deficient β-Diketiminate and Formazan Supporting Ligands on Copper(I)-Mediated Dioxygen Activation journal May 2009
Dioxygen Activation at a Single Copper Site:  Structure, Bonding, and Mechanism of Formation of 1:1 Cu−O 2 Adducts journal December 2004
A Direct Intramolecular C−H Amination Reaction Cocatalyzed by Copper(II) and Iron(III) as Part of an Efficient Route for the Synthesis of Pyrido[1,2- a ]benzimidazoles from N -Aryl-2-aminopyridines journal September 2010
Mechanism of Copper(I)/TEMPO-Catalyzed Aerobic Alcohol Oxidation journal January 2013
Rh III /Cu II -Cocatalyzed Synthesis of 1 H -Indazoles through C–H Amidation and N–N Bond Formation journal June 2013
Total Synthesis of Dixiamycin B by Electrochemical Oxidation journal April 2014
Copper(II) Anilides in sp 3 C-H Amination journal July 2014
Mechanistic Study of Copper-Catalyzed Aerobic Oxidative Coupling of Arylboronic Esters and Methanol: Insights into an Organometallic Oxidase Reaction journal April 2009
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Insights into the Mechanism of Anodic N–N Bond Formation by Dehydrogenative Coupling journal August 2017
Cu-Catalyzed Aerobic Oxidative N–N Coupling of Carbazoles and Diarylamines Including Selective Cross-Coupling journal June 2018
Cu-Catalyzed Aerobic Oxidative Cyclization of Guanidylpyridines and Derivatives journal December 2014
Natural Products Containing a Nitrogen–Nitrogen Bond journal March 2013
Copper-Catalyzed Oxidative Alkynylation of Diaryl Imines with Terminal Alkynes: A Facile Synthesis of Ynimines journal December 2011
Electrolysis of liquid ammonia for hydrogen generation journal January 2015
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Gold-Catalyzed Synthesis of Aromatic Azo Compounds from Anilines and Nitroaromatics journal December 2008
Recent Researches in Triazole Compounds as Medicinal Drugs journal January 2012

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