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Title: High-pressure melting curve of sulfur up to 65 GPa

Abstract

The melting curve of elemental sulfur was measured to pressures of 65 GPa in a laser-heated diamond-anvil cell using ex situ textural analyses combined with spectroradiometry and benchmarked with laser-power-temperature functions. Here, the melting curve reaches temperatures of ~ 1800 K by 65 GPa and is smooth in the range of 23–65 GPa with a Clapeyron slope of ~ 14 K / GPa at 23 GPa. This is consistent with melting of a single tetragonal sulfur structure in this range, which is confirmed by in situ x-ray diffraction. An updated equation of state for tetragonal sulfur is determined, and the high-pressure, high-temperature stability region of tetragonal sulfur is reassessed.

Authors:
ORCiD logo [1];  [2];  [3]; ORCiD logo [4]
  1. Yale Univ., New Haven, CT (United States)
  2. Argonne National Lab. (ANL), Argonne, IL (United States)
  3. American School of Dubai, Dubai (United Arab Emirates)
  4. Yale Univ., New Haven, CT (United States); Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Publication Date:
Research Org.:
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Argonne National Lab. (ANL), Argonne, IL (United States); George Washington Univ., Washington, DC (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA); National Aeronautic and Space Administration (NASA); National Science Foundation (NSF); Carnegie/DOE Alliance Center (CDAC); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Scientific User Facilities Division; USDOE National Nuclear Security Administration (NNSA) Office of Defense Programs (NA-10)
OSTI Identifier:
1579613
Alternate Identifier(s):
OSTI ID: 1557390; OSTI ID: 1562279; OSTI ID: 1581182
Report Number(s):
LLNL-JRNL-784817
Journal ID: ISSN 2469-9950; PRBMDO; 979248
Grant/Contract Number:  
AC52-07NA27344; AC02-06CH11357; NA0002006; SC0012704; NA0003858
Resource Type:
Accepted Manuscript
Journal Name:
Physical Review B
Additional Journal Information:
Journal Volume: 100; Journal Issue: 5; Journal ID: ISSN 2469-9950
Publisher:
American Physical Society (APS)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 58 GEOSCIENCES

Citation Formats

Arveson, Sarah M., Meng, Yue, Lee, June, and Lee, Kanani K. M. High-pressure melting curve of sulfur up to 65 GPa. United States: N. p., 2019. Web. doi:10.1103/PhysRevB.100.054106.
Arveson, Sarah M., Meng, Yue, Lee, June, & Lee, Kanani K. M. High-pressure melting curve of sulfur up to 65 GPa. United States. doi:10.1103/PhysRevB.100.054106.
Arveson, Sarah M., Meng, Yue, Lee, June, and Lee, Kanani K. M. Thu . "High-pressure melting curve of sulfur up to 65 GPa". United States. doi:10.1103/PhysRevB.100.054106.
@article{osti_1579613,
title = {High-pressure melting curve of sulfur up to 65 GPa},
author = {Arveson, Sarah M. and Meng, Yue and Lee, June and Lee, Kanani K. M.},
abstractNote = {The melting curve of elemental sulfur was measured to pressures of 65 GPa in a laser-heated diamond-anvil cell using ex situ textural analyses combined with spectroradiometry and benchmarked with laser-power-temperature functions. Here, the melting curve reaches temperatures of ~ 1800 K by 65 GPa and is smooth in the range of 23–65 GPa with a Clapeyron slope of ~ 14 K / GPa at 23 GPa. This is consistent with melting of a single tetragonal sulfur structure in this range, which is confirmed by in situ x-ray diffraction. An updated equation of state for tetragonal sulfur is determined, and the high-pressure, high-temperature stability region of tetragonal sulfur is reassessed.},
doi = {10.1103/PhysRevB.100.054106},
journal = {Physical Review B},
number = 5,
volume = 100,
place = {United States},
year = {2019},
month = {8}
}

Journal Article:
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Works referenced in this record:

The isotopic abundance and content of sulfur in meteorites
journal, May 1966


Nonmetal-metal transition in sulphur melt under high pressure
journal, April 1991


Pressure–temperature phase diagram of molten elements: selenium, sulfur and iodine
journal, April 1999


X-ray-diffraction study of sulfur to 32 GPa: Amorphization at 25 GPa
journal, July 1993


Pressure-induced structural phase transition in sulfur at 83 GPa
journal, September 1993


β-Po phase of sulfur at 162 GPa: X-ray diffraction study to 212 GPa
journal, November 1993


Incommensurate sulfur above 100 GPa
journal, January 2005


Crystal structure of sulfur and selenium at pressures up to 160 GPa
journal, March 2005


Alternating sequence of ring and chain structures in sulphur at high pressure and temperature
journal, June 2005

  • Crapanzano, Laura; Crichton, Wilson A.; Monaco, Giulio
  • Nature Materials, Vol. 4, Issue 7
  • DOI: 10.1038/nmat1417

Conducting linear chains of sulphur inside carbon nanotubes
journal, July 2013

  • Fujimori, Toshihiko; Morelos-Gómez, Aarón; Zhu, Zhen
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms3162

Spiral chain structure of high pressure selenium II and sulfur II from powder x-ray diffraction
journal, October 2004


Novel chain structures in group VI elements
journal, January 2005

  • Degtyareva, Olga; Gregoryanz, Eugene; Somayazulu, Maddury
  • Nature Materials, Vol. 4, Issue 2
  • DOI: 10.1038/nmat1294

Color of liquid sulfur
journal, April 1971

  • Meyer, Beat; Oommen, T. V.; Jensen, Dan
  • The Journal of Physical Chemistry, Vol. 75, Issue 7
  • DOI: 10.1021/j100677a012

Chain breakage in liquid sulfur at high pressures and high temperatures
journal, May 2014


Properties of Group VI B Elements Under Pressure. I. Melting Curves of S, Se, and Te
journal, February 1965


Properties of the Group VI B Elements Under Pressure. III. Phase-Diagram Studies of Various Forms of Sulfur
journal, January 1967


Melting curve of sulfur to 31 kilobars
journal, December 1969

  • Vezzoli, Gary C.; Dachille, Frank; Roy, Rustum
  • Inorganic Chemistry, Vol. 8, Issue 12
  • DOI: 10.1021/ic50082a023

High-pressure optical studies on sulfur to 121 GPa: Optical evidence for metallization
journal, November 1991


New developments in laser-heated diamond anvil cell with in situ synchrotron x-ray diffraction at High Pressure Collaborative Access Team
journal, July 2015

  • Meng, Yue; Hrubiak, Rostislav; Rod, Eric
  • Review of Scientific Instruments, Vol. 86, Issue 7
  • DOI: 10.1063/1.4926895

Mapping temperatures and temperature gradients during flash heating in a diamond-anvil cell
journal, July 2013

  • Du, Zhixue; Amulele, George; Robin Benedetti, Laura
  • Review of Scientific Instruments, Vol. 84, Issue 7
  • DOI: 10.1063/1.4813704

The influence of wavelength-dependent absorption and temperature gradients on temperature determination in laser-heated diamond-anvil cells
journal, January 2017

  • Deng, Jie; Du, Zhixue; Benedetti, Laura Robin
  • Journal of Applied Physics, Vol. 121, Issue 2
  • DOI: 10.1063/1.4973344

Using stepped anvils to make even insulation layers in laser-heated diamond-anvil cell samples
journal, September 2015

  • Du, Zhixue; Gu, Tingting; Dobrosavljevic, Vasilije
  • Review of Scientific Instruments, Vol. 86, Issue 9
  • DOI: 10.1063/1.4929667

Refinement of the structure of orthorhombic sulfur, α-S8
journal, December 1987

  • Rettig, S. J.; Trotter, J.
  • Acta Crystallographica Section C Crystal Structure Communications, Vol. 43, Issue 12
  • DOI: 10.1107/S0108270187088152

High-pressure Raman spectroscopy of diamond anvils to 250GPa: Method for pressure determination in the multimegabar pressure range
journal, October 2004

  • Akahama, Yuichi; Kawamura, Haruki
  • Journal of Applied Physics, Vol. 96, Issue 7
  • DOI: 10.1063/1.1778482

High-pressure–high-temperature equation of state of KCl and KBr
journal, June 2012


Toward an internally consistent pressure scale
journal, May 2007

  • Fei, Y.; Ricolleau, A.; Frank, M.
  • Proceedings of the National Academy of Sciences, Vol. 104, Issue 22
  • DOI: 10.1073/pnas.0609013104

High-pressure melting of MgO from (Mg,Fe)O solid solutions: High pressure melting of MgO
journal, November 2014

  • Du, Zhixue; Lee, Kanani K. M.
  • Geophysical Research Letters, Vol. 41, Issue 22
  • DOI: 10.1002/2014GL061954

The effect of pressure on the optical absorption edge of sulfur to 300 kbar
journal, December 1984

  • Peanasky, M. J.; Jurgensen, C. W.; Drickamer, H. G.
  • The Journal of Chemical Physics, Vol. 81, Issue 12
  • DOI: 10.1063/1.447556

Flash heating in the diamond cell: Melting curve of rhenium
journal, June 2012

  • Yang, Liuxiang; Karandikar, Amol; Boehler, Reinhard
  • Review of Scientific Instruments, Vol. 83, Issue 6
  • DOI: 10.1063/1.4730595

Crystallization of silicon dioxide and compositional evolution of the Earth’s core
journal, February 2017

  • Hirose, Kei; Morard, Guillaume; Sinmyo, Ryosuke
  • Nature, Vol. 543, Issue 7643
  • DOI: 10.1038/nature21367

Pulsed laser heating and temperature determination in a diamond anvil cell
journal, December 2005

  • Deemyad, S.; Sterer, E.; Barthel, C.
  • Review of Scientific Instruments, Vol. 76, Issue 12
  • DOI: 10.1063/1.2140493

Melting of Iron at Earth's Inner Core Boundary Based on Fast X-ray Diffraction
journal, April 2013


High-pressure differential thermal analysis measurements of the melting curve of lithium
journal, April 2010

  • Lazicki, Amy; Fei, Yingwei; Hemley, Russell J.
  • Solid State Communications, Vol. 150, Issue 13-14
  • DOI: 10.1016/j.ssc.2009.12.029

Solid phases of FeSi to 47 GPa and 2800 K: New data
journal, April 2014


Sulfur: A New High-Pressure Form
journal, May 1965


Structure of Pressure‐Induced Fibrous Sulfur
journal, July 1969

  • Lind, M. D.; Geller, S.
  • The Journal of Chemical Physics, Vol. 51, Issue 1
  • DOI: 10.1063/1.1671729

The Viscosity of Sulfur 1
journal, April 1943

  • Bacon, Raymond F.; Fanelli, Rocco
  • Journal of the American Chemical Society, Vol. 65, Issue 4
  • DOI: 10.1021/ja01244a043

Structure of Liquid Se under High Pressure*
journal, January 1988


A first-order liquid–liquid phase transition in phosphorus
journal, January 2000

  • Katayama, Yoshinori; Mizutani, Takeshi; Utsumi, Wataru
  • Nature, Vol. 403, Issue 6766
  • DOI: 10.1038/35003143

High-Pressure Melting Curve of Nitrogen and the Liquid-Liquid Phase Transition
journal, November 2007


Triple Point on the Melting Curve and Polymorphism of Nitrogen at High Pressure
journal, August 2008

  • Goncharov, Alexander F.; Crowhurst, Jonathan C.; Struzhkin, Viktor V.
  • Physical Review Letters, Vol. 101, Issue 9
  • DOI: 10.1103/PhysRevLett.101.095502

Melting and phase transitions of nitrogen under high pressures and temperatures
journal, June 2014

  • Tomasino, Dane; Jenei, Zsolt; Evans, William
  • The Journal of Chemical Physics, Vol. 140, Issue 24
  • DOI: 10.1063/1.4885724

Immiscible two-liquid regions in the Fe–O–S system at high pressure: Implications for planetary cores
journal, January 2007

  • Tsuno, Kyusei; Ohtani, Eiji; Terasaki, Hidenori
  • Physics of the Earth and Planetary Interiors, Vol. 160, Issue 1
  • DOI: 10.1016/j.pepi.2006.09.004

Closure of the Fe–S–Si liquid miscibility gap at high pressure
journal, October 2004