Phase equilibria and diffusion coefficients in the Fe-Zn binary system

Zhu, Lilong; Honrao, Shreyas; Rijal, Biswas; Hennig, Richard G.; Manuel, Michele V.

doi:10.1016/j.matdes.2019.108437

Title: Phase equilibria and diffusion coefficients in the Fe-Zn binary system

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Abstract

Phase diagram and diffusion coefficients of the Fe-Zn binary system are required to predict and control the microstructure of galvanized zinc coatings and thus were systematically investigated in the temperature range from 700 to 1100 °C using nine novel Fe/Zn liquid-solid diffusion couples (LSDCs). The equilibrium compositions of the α and Γ phases of the Fe-Zn system were determined and agree well with the recently established Fe-Zn phase diagram. The extracted interdiffusion coefficients in α-Fe at temperatures between 700 and 1100 °C and in Γ at 750 and 700 °C using the forward-simulation analysis (FSA) extend the experimental interdiffusivity measurements to the whole solubility range of these two phases. Three impurity diffusion coefficients of Zn in paramagnetic α-Fe were also determined by the FSA and show good agreement with the literature data. The temperature dependence of the Zn impurity diffusion coefficients in both the paramagnetic and ferromagnetic α-Fe phases across the Curie temperature T_C was established by analyzing the reliable experimental results as well as by density functional theory (DFT) calculations. The newly measured phase equilibrium and diffusivity data provide reliable inputs for future thermodynamic and kinetic modeling of the Fe-Zn system.

Authors:

Zhu, Lilong; Honrao, Shreyas; Rijal, Biswas; Hennig, Richard G.;

Publication Date:: 2020-03-01

Research Org.:: Univ. of Florida, Gainesville, FL (United States)

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

OSTI Identifier:: 1579603

Alternate Identifier(s):: OSTI ID: 1799348

Grant/Contract Number:: EE0007742

Resource Type:: Published Article

Journal Name:: Materials & Design

Additional Journal Information:: Journal Name: Materials & Design Journal Volume: 188 Journal Issue: C; Journal ID: ISSN 0264-1275

Publisher:: Elsevier

Country of Publication:: United Kingdom

Language:: English

Subject:: 36 MATERIALS SCIENCE; Materials Science; Fe-Zn system; Coating; Fe/Zn LSDCs; Phase equilibria; Diffusion coefficients; DFT calculations

Citation Formats


                    Zhu, Lilong, Honrao, Shreyas, Rijal, Biswas, Hennig, Richard G., and Manuel, Michele V. Phase equilibria and diffusion coefficients in the Fe-Zn binary system.  United Kingdom: N. p., 2020. 
Web.  doi:10.1016/j.matdes.2019.108437.

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                    Zhu, Lilong, Honrao, Shreyas, Rijal, Biswas, Hennig, Richard G., & Manuel, Michele V. Phase equilibria and diffusion coefficients in the Fe-Zn binary system.  United Kingdom.  https://doi.org/10.1016/j.matdes.2019.108437

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                    Zhu, Lilong, Honrao, Shreyas, Rijal, Biswas, Hennig, Richard G., and Manuel, Michele V. Sun .  
"Phase equilibria and diffusion coefficients in the Fe-Zn binary system".  United Kingdom.  https://doi.org/10.1016/j.matdes.2019.108437.

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@article{osti_1579603,

  title        = {Phase equilibria and diffusion coefficients in the Fe-Zn binary system},

  author       = {Zhu, Lilong and Honrao, Shreyas and Rijal, Biswas and Hennig, Richard G. and Manuel, Michele V.},

  abstractNote = {Phase diagram and diffusion coefficients of the Fe-Zn binary system are required to predict and control the microstructure of galvanized zinc coatings and thus were systematically investigated in the temperature range from 700 to 1100 °C using nine novel Fe/Zn liquid-solid diffusion couples (LSDCs). The equilibrium compositions of the α and Γ phases of the Fe-Zn system were determined and agree well with the recently established Fe-Zn phase diagram. The extracted interdiffusion coefficients in α-Fe at temperatures between 700 and 1100 °C and in Γ at 750 and 700 °C using the forward-simulation analysis (FSA) extend the experimental interdiffusivity measurements to the whole solubility range of these two phases. Three impurity diffusion coefficients of Zn in paramagnetic α-Fe were also determined by the FSA and show good agreement with the literature data. The temperature dependence of the Zn impurity diffusion coefficients in both the paramagnetic and ferromagnetic α-Fe phases across the Curie temperature TC was established by analyzing the reliable experimental results as well as by density functional theory (DFT) calculations. The newly measured phase equilibrium and diffusivity data provide reliable inputs for future thermodynamic and kinetic modeling of the Fe-Zn system.},

  doi          = {10.1016/j.matdes.2019.108437},

  journal      = {Materials & Design},

  number       = C,

  volume       = 188,

  place        = {United Kingdom},

  year         = {2020},

  month        = {3}

}

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