Investigating Electrode Flooding in a Flowing Electrolyte, Gas‐Fed Carbon Dioxide Electrolyzer
- Authors:
-
[1];
[1];
[2];
[1];
[1]
- Department of Chemical EngineeringMassachusetts Institute of Technology Cambridge MA 02139 USA
- Department of Chemical EngineeringMassachusetts Institute of Technology Cambridge MA 02139 USA, Membrane Materials and ProcessesDepartment of Chemical Engineering and ChemistryEindhoven University of Technology Het Kranenveld 14, P.O. Box 513, 5600 MB Eindhoven The Netherlands
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1579595
- Grant/Contract Number:
- SC0015173
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- ChemSusChem
- Additional Journal Information:
- Journal Name: ChemSusChem Journal Volume: 13 Journal Issue: 2; Journal ID: ISSN 1864-5631
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Leonard, McLain E., Clarke, Lauren E., Forner‐Cuenca, Antoni, Brown, Steven M., and Brushett, Fikile R. Investigating Electrode Flooding in a Flowing Electrolyte, Gas‐Fed Carbon Dioxide Electrolyzer. Germany: N. p., 2019.
Web. doi:10.1002/cssc.201902547.
Leonard, McLain E., Clarke, Lauren E., Forner‐Cuenca, Antoni, Brown, Steven M., & Brushett, Fikile R. Investigating Electrode Flooding in a Flowing Electrolyte, Gas‐Fed Carbon Dioxide Electrolyzer. Germany. doi:10.1002/cssc.201902547.
Leonard, McLain E., Clarke, Lauren E., Forner‐Cuenca, Antoni, Brown, Steven M., and Brushett, Fikile R. Fri .
"Investigating Electrode Flooding in a Flowing Electrolyte, Gas‐Fed Carbon Dioxide Electrolyzer". Germany. doi:10.1002/cssc.201902547.
@article{osti_1579595,
title = {Investigating Electrode Flooding in a Flowing Electrolyte, Gas‐Fed Carbon Dioxide Electrolyzer},
author = {Leonard, McLain E. and Clarke, Lauren E. and Forner‐Cuenca, Antoni and Brown, Steven M. and Brushett, Fikile R.},
abstractNote = {},
doi = {10.1002/cssc.201902547},
journal = {ChemSusChem},
number = 2,
volume = 13,
place = {Germany},
year = {2019},
month = {12}
}
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/cssc.201902547
DOI: 10.1002/cssc.201902547
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 9 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Simultaneous neutron imaging of six operating PEFCs: Experimental set-up and study of the MPL effect
journal, July 2012
- Oberholzer, P.; Boillat, P.; Siegrist, R.
- Electrochemistry Communications, Vol. 20
Capillary pressure and hydrophilic porosity in gas diffusion layers for polymer electrolyte fuel cells
journal, June 2006
- Gostick, Jeffrey T.; Fowler, Michael W.; Ioannidis, Marios A.
- Journal of Power Sources, Vol. 156, Issue 2
Analysis of Mass Flows and Membrane Cross-over in CO 2 Reduction at High Current Densities in an MEA-Type Electrolyzer
journal, October 2019
- Larrazábal, Gastón O.; Strøm-Hansen, Patrick; Heli, Jens P.
- ACS Applied Materials & Interfaces, Vol. 11, Issue 44
Characterization of the Intrinsic Water Wettability of Graphite Using Contact Angle Measurements: Effect of Defects on Static and Dynamic Contact Angles
journal, January 2017
- Kozbial, Andrew; Trouba, Charlie; Liu, Haitao
- Langmuir, Vol. 33, Issue 4
Efficient Electrochemical Flow System with Improved Anode for the Conversion of CO2 to CO
journal, January 2014
- Ma, S.; Luo, R.; Moniri, S.
- Journal of the Electrochemical Society, Vol. 161, Issue 10, p. F1124-F1131
Multilayer Electrolyzer Stack Converts Carbon Dioxide to Gas Products at High Pressure with High Efficiency
journal, June 2019
- Endrődi, B.; Kecsenovity, E.; Samu, A.
- ACS Energy Letters, Vol. 4, Issue 7
What would it take for renewably powered electrosynthesis to displace petrochemical processes?
journal, April 2019
- De Luna, Phil; Hahn, Christopher; Higgins, Drew
- Science, Vol. 364, Issue 6438
Electrochemical CO2 Reduction on Metal Electrodes
book, January 2008
- Hori, Y.; Vayenas, Constantinos G.; White, Ralph E.
- Modern Aspects of Electrochemistry, p. 89-189
Neutron imaging of fuel cells – Recent trends and future prospects
journal, October 2017
- Boillat, P.; Lehmann, E. H.; Trtik, P.
- Current Opinion in Electrochemistry, Vol. 5, Issue 1
CO 2 separation using bipolar membrane electrodialysis
journal, January 2011
- Eisaman, Matthew D.; Alvarado, Luis; Larner, Daniel
- Energy Environ. Sci., Vol. 4, Issue 4
Deconvolution of electrochemical double layer capacitance between fractions of active and total surface area of graphite felts
journal, January 2017
- Rabbow, Thomas J.; Whitehead, Adam H.
- Carbon, Vol. 111
Advanced Water Management in PEFCs: Diffusion Layers with Patterned Wettability: III. Operando Characterization with Neutron Imaging
journal, January 2016
- Forner-Cuenca, A.; Biesdorf, J.; Manzi-Orezzoli, V.
- Journal of The Electrochemical Society, Vol. 163, Issue 13
Surface Tension of Aqueous Solutions of Potassium Hydroxide
journal, December 1962
- Dunlap, Peggy M.; Faris, Sam R.
- Nature, Vol. 196, Issue 4861
Advanced Water Management in PEFCs: Diffusion Layers with Patterned Wettability: I. Synthetic Routes, Wettability Tuning and Thermal Stability
journal, January 2016
- Forner-Cuenca, Antoni; Manzi-Orezzoli, Victoria; Biesdorf, Johannes
- Journal of The Electrochemical Society, Vol. 163, Issue 8
Carbonate Dynamics and Opportunities With Low Temperature, Anion Exchange Membrane-Based Electrochemical Carbon Dioxide Separators
journal, May 2017
- Rigdon, William A.; Omasta, Travis J.; Lewis, Connor
- Journal of Electrochemical Energy Conversion and Storage, Vol. 14, Issue 2
Impact of Microporous Layer Pore Properties on Liquid Water Transport in PEM Fuel Cells: Carbon Black Type and Perforation
journal, January 2017
- Simon, Christoph; Kartouzian, Dena; Müller, David
- Journal of The Electrochemical Society, Vol. 164, Issue 14
Effect of carbon dioxide on the performance of Ni/PTFE and Ag/PTFE electrodes in an alkaline fuel cell
journal, June 1994
- Al-Saleh, M. A.; Gültekin, S.; Al-Zakri, A. S.
- Journal of Applied Electrochemistry, Vol. 24, Issue 6
Damage in porous media due to salt crystallization
journal, June 2010
- Shahidzadeh-Bonn, Noushine; Desarnaud, Julie; Bertrand, François
- Physical Review E, Vol. 81, Issue 6
Carbonate resilience of flowing electrolyte-based alkaline fuel cells
journal, February 2011
- Naughton, Matt S.; Brushett, Fikile R.; Kenis, Paul J. A.
- Journal of Power Sources, Vol. 196, Issue 4
Modeling and Experimental Validation of Electrochemical Reduction of CO 2 to CO in a Microfluidic Cell
journal, November 2014
- Wu, Kunna; Birgersson, Erik; Kim, Byoungsu
- Journal of The Electrochemical Society, Vol. 162, Issue 1
Water Transport Mechanisms in PEMFC Gas Diffusion Layers
journal, January 2010
- Owejan, Jon P.; Owejan, Jeanette E.; Gu, Wenbin
- Journal of The Electrochemical Society, Vol. 157, Issue 10
Water flow in the gas diffusion layer of PEM fuel cells
journal, September 2005
- Benziger, J.; Nehlsen, J.; Blackwell, D.
- Journal of Membrane Science, Vol. 261, Issue 1-2
Effects of composition of the micro porous layer and the substrate on performance in the electrochemical reduction of CO2 to CO
journal, April 2016
- Kim, Byoungsu; Hillman, Febrian; Ariyoshi, Miho
- Journal of Power Sources, Vol. 312
Insights into the Low Overpotential Electroreduction of CO 2 to CO on a Supported Gold Catalyst in an Alkaline Flow Electrolyzer
journal, November 2017
- Verma, Sumit; Hamasaki, Yuki; Kim, Chaerin
- ACS Energy Letters, Vol. 3, Issue 1
On the problem of ageing of carbon—air electrodes in alkaline electrolytes
journal, January 1980
- Rolla, A.; Sadkowski, A.; Wild, J.
- Journal of Power Sources, Vol. 5, Issue 2
Direct measurement of the capillary pressure characteristics of water–air–gas diffusion layer systems for PEM fuel cells
journal, October 2008
- Gostick, Jeff T.; Ioannidis, Marios A.; Fowler, Michael W.
- Electrochemistry Communications, Vol. 10, Issue 10
Investigating Evaporation in Gas Diffusion Layers for Fuel Cells with X-ray Computed Tomography
journal, December 2016
- Zenyuk, Iryna V.; Lamibrac, Adrien; Eller, Jens
- The Journal of Physical Chemistry C, Vol. 120, Issue 50
An alkaline polymer electrolyte CO 2 electrolyzer operated with pure water
journal, January 2019
- Yin, Zhenglei; Peng, Hanqing; Wei, Xing
- Energy & Environmental Science, Vol. 12, Issue 8
Progress toward Commercial Application of Electrochemical Carbon Dioxide Reduction
journal, November 2018
- Chen, Chi; Khosrowabadi Kotyk, Juliet F.; Sheehan, Stafford W.
- Chem, Vol. 4, Issue 11
Electrolysis of Gaseous CO 2 to CO in a Flow Cell with a Bipolar Membrane
journal, November 2017
- Salvatore, Danielle A.; Weekes, David M.; He, Jingfu
- ACS Energy Letters, Vol. 3, Issue 1
Ex-situ characterisation of gas diffusion layers for proton exchange membrane fuel cells
journal, November 2012
- El-kharouf, Ahmad; Mason, Thomas J.; Brett, Dan J. L.
- Journal of Power Sources, Vol. 218
Improving water management in fuel cells through microporous layer modifications: Fast operando tomographic imaging of liquid water
journal, September 2019
- Nagai, Yasutaka; Eller, Jens; Hatanaka, Tatsuya
- Journal of Power Sources, Vol. 435
Characterization of Liquid Water Saturation in Gas Diffusion Layers by X-Ray Tomographic Microscopy
journal, December 2015
- Lamibrac, A.; Roth, J.; Toulec, M.
- Journal of The Electrochemical Society, Vol. 163, Issue 3
On the role of the microporous layer in PEMFC operation
journal, March 2009
- Gostick, Jeff T.; Ioannidis, Marios A.; Fowler, Michael W.
- Electrochemistry Communications, Vol. 11, Issue 3
The effect of electrolyte composition on the electroreduction of CO 2 to CO on Ag based gas diffusion electrodes
journal, January 2016
- Verma, Sumit; Lu, Xun; Ma, Sichao
- Physical Chemistry Chemical Physics, Vol. 18, Issue 10
Introductory Guide to Assembling and Operating Gas Diffusion Electrodes for Electrochemical CO 2 Reduction
journal, February 2019
- Liu, Kai; Smith, Wilson A.; Burdyny, Thomas
- ACS Energy Letters, Vol. 4, Issue 3
Wettability of a Single Carbon Fiber
journal, September 2016
- Qiu, Si; Fuentes, Carlos A.; Zhang, Dongxing
- Langmuir, Vol. 32, Issue 38
Modeling gas-diffusion electrodes for CO 2 reduction
journal, January 2018
- Weng, Lien-Chun; Bell, Alexis T.; Weber, Adam Z.
- Physical Chemistry Chemical Physics, Vol. 20, Issue 25
Modeling Transport in Polymer-Electrolyte Fuel Cells
journal, October 2004
- Weber, Adam Z.; Newman, John
- Chemical Reviews, Vol. 104, Issue 10
Selective and Efficient Reduction of Carbon Dioxide to Carbon Monoxide on Oxide-Derived Nanostructured Silver Electrocatalysts
journal, July 2016
- Ma, Ming; Trześniewski, Bartek J.; Xie, Jie
- Angewandte Chemie, Vol. 128, Issue 33
Influence of dilute feed and pH on electrochemical reduction of CO2 to CO on Ag in a continuous flow electrolyzer
journal, June 2015
- Kim, Byoungsu; Ma, Sichao; Molly Jhong, Huei-Ru
- Electrochimica Acta, Vol. 166, p. 271-276
Effects of temperature and gas–liquid mass transfer on the operation of small electrochemical cells for the quantitative evaluation of CO 2 reduction electrocatalysts
journal, January 2016
- Lobaccaro, Peter; Singh, Meenesh R.; Clark, Ezra Lee
- Physical Chemistry Chemical Physics, Vol. 18, Issue 38
Electrochemical conversion of CO2 to formic acid utilizing Sustainion™ membranes
journal, July 2017
- Yang, Hongzhou; Kaczur, Jerry J.; Sajjad, Syed Dawar
- Journal of CO2 Utilization, Vol. 20
A Historical Perspective of Fuel Cell Technology in the 20th Century
journal, January 2002
- Perry, M. L.; Fuller, T. F.
- Journal of The Electrochemical Society, Vol. 149, Issue 7
4-acetamido-2,2,6,6-tetramethylpiperidine-1-oxyl as a model organic redox active compound for nonaqueous flow batteries
journal, September 2016
- Milshtein, Jarrod D.; Barton, John L.; Darling, Robert M.
- Journal of Power Sources, Vol. 327
Ab Initio Thermodynamic Study of the CO 2 Capture Properties of Potassium Carbonate Sesquihydrate, K 2 CO 3 ·1.5H 2 O
journal, June 2012
- Duan, Yuhua; Luebke, David R.; Pennline, Henry W.
- The Journal of Physical Chemistry C, Vol. 116, Issue 27
Discrete Salt Crystallization at the Surface of a Porous Medium
journal, February 2012
- Veran-Tissoires, S.; Marcoux, M.; Prat, M.
- Physical Review Letters, Vol. 108, Issue 5
Insights into the electrocatalytic reduction of CO 2 on metallic silver surfaces
journal, January 2014
- Hatsukade, Toru; Kuhl, Kendra P.; Cave, Etosha R.
- Phys. Chem. Chem. Phys., Vol. 16, Issue 27
A Process for Capturing CO2 from the Atmosphere
journal, August 2018
- Keith, David W.; Holmes, Geoffrey; St. Angelo, David
- Joule, Vol. 2, Issue 8
Degradation of some carbon-chain polymers by electrochemical reduction
journal, January 1985
- Shapoval, G. S.; Pud, A. A.; Zamotayev, P. V.
- Polymer Science U.S.S.R., Vol. 27, Issue 10
What Is the Contact Angle of Water on Graphene?
journal, January 2013
- Taherian, Fereshte; Marcon, Valentina; van der Vegt, Nico F. A.
- Langmuir, Vol. 29, Issue 5
Continuous-flow electroreduction of carbon dioxide
journal, September 2017
- Endrődi, B.; Bencsik, G.; Darvas, F.
- Progress in Energy and Combustion Science, Vol. 62
Electroreduction of carbon dioxide to formate at high current densities using tin and tin oxide gas diffusion electrodes
journal, July 2019
- Sen, Sujat; Brown, Steven M.; Leonard, McLain
- Journal of Applied Electrochemistry, Vol. 49, Issue 9
CO 2 electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface
journal, May 2018
- Dinh, Cao-Thang; Burdyny, Thomas; Kibria, Md Golam
- Science, Vol. 360, Issue 6390
Selective and Efficient Reduction of Carbon Dioxide to Carbon Monoxide on Oxide-Derived Nanostructured Silver Electrocatalysts
journal, July 2016
- Ma, Ming; Trześniewski, Bartek J.; Xie, Jie
- Angewandte Chemie International Edition, Vol. 55, Issue 33
Wettability and capillary behavior of fibrous gas diffusion media for polymer electrolyte membrane fuel cells
journal, October 2009
- Gostick, Jeff T.; Ioannidis, Marios A.; Fowler, Michael W.
- Journal of Power Sources, Vol. 194, Issue 1
The Effects of Catalyst Layer Deposition Methodology on Electrode Performance
journal, February 2013
- Jhong, Huei-Ru “Molly”; Brushett, Fikile R.; Kenis, Paul J. A.
- Advanced Energy Materials, Vol. 3, Issue 5
Influence of flow and pressure distribution inside a gas diffusion electrode on the performance of a flow-by CO2 electrolyzer
journal, December 2019
- De Mot, Bert; Hereijgers, Jonas; Duarte, Miguel
- Chemical Engineering Journal, Vol. 378
Surface Properties of PEMFC Gas Diffusion Layers
journal, January 2010
- Wood, David L.; Rulison, Christopher; Borup, Rodney L.
- Journal of The Electrochemical Society, Vol. 157, Issue 2
Towards membrane-electrode assembly systems for CO 2 reduction: a modeling study
journal, January 2019
- Weng, Lien-Chun; Bell, Alexis T.; Weber, Adam Z.
- Energy & Environmental Science, Vol. 12, Issue 6
CO 2 reduction on gas-diffusion electrodes and why catalytic performance must be assessed at commercially-relevant conditions
journal, January 2019
- Burdyny, Thomas; Smith, Wilson A.
- Energy & Environmental Science, Vol. 12, Issue 5
Double Layer Capacitance Measurements To Characterize the Water Intrusion into Porous Materials
journal, October 2016
- Sow, Pradeep Kumar; Lu, Zhaowei; Talebian, Hoda
- The Journal of Physical Chemistry C, Vol. 120, Issue 43
Combined high alkalinity and pressurization enable efficient CO 2 electroreduction to CO
journal, January 2018
- Gabardo, Christine M.; Seifitokaldani, Ali; Edwards, Jonathan P.
- Energy & Environmental Science, Vol. 11, Issue 9
High Rate Gas Phase CO[sub 2] Reduction to Ethylene and Methane Using Gas Diffusion Electrodes
journal, January 1990
- Cook, Ronald L.
- Journal of The Electrochemical Society, Vol. 137, Issue 2
Determination of the rate constants for the carbon dioxide to bicarbonate inter-conversion in pH-buffered seawater systems
journal, June 2006
- Schulz, K. G.; Riebesell, U.; Rost, B.
- Marine Chemistry, Vol. 100, Issue 1-2
Preparation of Air Electrodes and Long Run Tests
journal, January 1991
- Lamminen, Jaakko
- Journal of The Electrochemical Society, Vol. 138, Issue 4
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
journal, January 2012
- Kuhl, Kendra P.; Cave, Etosha R.; Abram, David N.
- Energy & Environmental Science, Vol. 5, Issue 5
Technical photosynthesis involving CO2 electrolysis and fermentation
journal, January 2018
- Haas, Thomas; Krause, Ralf; Weber, Rainer
- Nature Catalysis, Vol. 1, Issue 1
Advanced Water Management in PEFCs: Diffusion Layers with Patterned Wettability: II. Measurement of Capillary Pressure Characteristic with Neutron and Synchrotron Imaging
journal, January 2016
- Forner-Cuenca, A.; Biesdorf, J.; Lamibrac, A.
- Journal of The Electrochemical Society, Vol. 163, Issue 9
Capillary Hysteresis in Neutrally Wettable Fibrous Media: A Pore Network Study of a Fuel Cell Electrode
journal, December 2017
- Tranter, T. G.; Gostick, J. T.; Burns, A. D.
- Transport in Porous Media, Vol. 121, Issue 3
High Rate, Selective, and Stable Electroreduction of CO 2 to CO in Basic and Neutral Media
journal, October 2018
- Dinh, Cao-Thang; García de Arquer, F. Pelayo; Sinton, David
- ACS Energy Letters, Vol. 3, Issue 11
Liquid-Water Interactions with Gas-Diffusion-Layer Surfaces
journal, January 2014
- Santamaria, Anthony D.; Das, Prodip K.; MacDonald, James C.
- Journal of The Electrochemical Society, Vol. 161, Issue 12
Electrochemical CO2 reduction using alkaline membrane electrode assembly on various metal electrodes
journal, May 2019
- Lee, Jonghyeok; Lim, Jinkyu; Roh, Chi-Woo
- Journal of CO2 Utilization, Vol. 31
CO 2 Electrolysis to CO and O 2 at High Selectivity, Stability and Efficiency Using Sustainion Membranes
journal, January 2018
- Liu, Zengcai; Yang, Hongzhou; Kutz, Robert
- Journal of The Electrochemical Society, Vol. 165, Issue 15
Redox-Mediated Separation of Carbon Dioxide from Flue Gas
journal, October 2015
- Watkins, John D.; Siefert, Nicholas S.; Zhou, Xu
- Energy & Fuels, Vol. 29, Issue 11
The Solubility of Carbon Dioxide in Water at Low Pressure
journal, November 1991
- Carroll, John J.; Slupsky, John D.; Mather, Alan E.
- Journal of Physical and Chemical Reference Data, Vol. 20, Issue 6
One-step electrosynthesis of ethylene and ethanol from CO2 in an alkaline electrolyzer
journal, January 2016
- Ma, Sichao; Sadakiyo, Masaaki; Luo, Raymond
- Journal of Power Sources, Vol. 301