Effect of Oxide Support on Catalytic Performance of FeNi–based Catalysts for CO2–assisted Oxidative Dehydrogenation of Ethane

Yan, Binhang; Yao, Siyu; Chen, Jingguang G.

doi:10.1002/cctc.201901585

Title: Effect of Oxide Support on Catalytic Performance of FeNi–based Catalysts for CO₂–assisted Oxidative Dehydrogenation of Ethane

Journal Article · 08 October 2019 · ChemCatChem

DOI: https://doi.org/10.1002/cctc.201901585 · OSTI ID:1579502

^[1]; Yao, Siyu ^[2];

^[3]

Tsinghua Univ., Beijing (China); Brookhaven National Lab. (BNL), Upton, NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States); Columbia Univ., New York, NY (United States)

Abstract CO ₂ ‐assisted oxidative dehydrogenation of ethane over Fe ₃ Ni ₁ catalysts supported on SiO ₂ , ZrO ₂ , and CeO ₂ , as well as CeO ₂ ‐supported Fe _3x Ni _x with different metal loadings (x=0.25, 0.5, 1, 2, 4), were investigated to illustrate the effects of the oxide support and the metal loading amount in tuning the catalytic activity and selectivity. The oxidation state and the dispersion of the Ni and Fe species on the supported catalysts were determined by using in‐situ X‐ray diffraction (XRD) and X‐ray absorption fine structure (XAFS) measurements. Among these FeNi‐based catalysts, Fe ₃ Ni ₁ /CeO ₂ exhibited the best catalytic activity and maximum ethylene yield for the oxidative dehydrogenation of ethane. Excessive loading amount of active metals changed the reaction selectivity from oxidative dehydrogenation to dry reforming. The high activity and selectivity for CO ₂ ‐assisted oxidative dehydrogenation of ethane over Fe ₃ Ni ₁ /CeO ₂ are likely due to the formation of Ni‐FeO _x /CeO _x interfacial sites, while the presence of Ni‐ZrO ₂ interfacial sites on Fe ₃ Ni ₁ /ZrO ₂ and NiFe‐CeO _x interfacial sites on Fe ₁₂ Ni ₄ /CeO ₂ likely tune the reaction selectivity toward dry reforming of ethane.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704; AC02‐06CH11357

OSTI ID:: 1579502

Alternate ID(s):: OSTI ID: 1593481

Report Number(s):: BNL-212412-2019-JAAM

Journal Information:: ChemCatChem, Vol. 12, Issue 2; ISSN 1867-3880

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 23 works

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Title: Effect of Oxide Support on Catalytic Performance of FeNi–based Catalysts for CO2–assisted Oxidative Dehydrogenation of Ethane

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Title: Effect of Oxide Support on Catalytic Performance of FeNi–based Catalysts for CO₂–assisted Oxidative Dehydrogenation of Ethane