Effect of Oxide Support on Catalytic Performance of FeNi–based Catalysts for CO2–assisted Oxidative Dehydrogenation of Ethane
Abstract
Abstract CO 2 ‐assisted oxidative dehydrogenation of ethane over Fe 3 Ni 1 catalysts supported on SiO 2 , ZrO 2 , and CeO 2 , as well as CeO 2 ‐supported Fe 3x Ni x with different metal loadings (x=0.25, 0.5, 1, 2, 4), were investigated to illustrate the effects of the oxide support and the metal loading amount in tuning the catalytic activity and selectivity. The oxidation state and the dispersion of the Ni and Fe species on the supported catalysts were determined by using in‐situ X‐ray diffraction (XRD) and X‐ray absorption fine structure (XAFS) measurements. Among these FeNi‐based catalysts, Fe 3 Ni 1 /CeO 2 exhibited the best catalytic activity and maximum ethylene yield for the oxidative dehydrogenation of ethane. Excessive loading amount of active metals changed the reaction selectivity from oxidative dehydrogenation to dry reforming. The high activity and selectivity for CO 2 ‐assisted oxidative dehydrogenation of ethane over Fe 3 Ni 1 /CeO 2 are likely due to the formation of Ni‐FeO x /CeO x interfacial sites, while the presence of Ni‐ZrO 2 interfacial sites on Fe 3 Ni 1 /ZrO 2 and NiFe‐CeO x interfacial sites on Fe 12 Ni 4 /CeO 2 likelymore »
- Authors:
-
- Tsinghua Univ., Beijing (China); Brookhaven National Lab. (BNL), Upton, NY (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States); Columbia Univ., New York, NY (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1579502
- Alternate Identifier(s):
- OSTI ID: 1593481
- Report Number(s):
- BNL-212412-2019-JAAM
Journal ID: ISSN 1867-3880
- Grant/Contract Number:
- SC0012704; AC02‐06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemCatChem
- Additional Journal Information:
- Journal Volume: 12; Journal Issue: 2; Journal ID: ISSN 1867-3880
- Publisher:
- ChemPubSoc Europe
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; Heterogeneous catalysis; Support effect; Oxidative dehydrogenation; Dry reforming; Selectivity
Citation Formats
Yan, Binhang, Yao, Siyu, and Chen, Jingguang G. Effect of Oxide Support on Catalytic Performance of FeNi–based Catalysts for CO2–assisted Oxidative Dehydrogenation of Ethane. United States: N. p., 2019.
Web. doi:10.1002/cctc.201901585.
Yan, Binhang, Yao, Siyu, & Chen, Jingguang G. Effect of Oxide Support on Catalytic Performance of FeNi–based Catalysts for CO2–assisted Oxidative Dehydrogenation of Ethane. United States. https://doi.org/10.1002/cctc.201901585
Yan, Binhang, Yao, Siyu, and Chen, Jingguang G. Tue .
"Effect of Oxide Support on Catalytic Performance of FeNi–based Catalysts for CO2–assisted Oxidative Dehydrogenation of Ethane". United States. https://doi.org/10.1002/cctc.201901585. https://www.osti.gov/servlets/purl/1579502.
@article{osti_1579502,
title = {Effect of Oxide Support on Catalytic Performance of FeNi–based Catalysts for CO2–assisted Oxidative Dehydrogenation of Ethane},
author = {Yan, Binhang and Yao, Siyu and Chen, Jingguang G.},
abstractNote = {Abstract CO 2 ‐assisted oxidative dehydrogenation of ethane over Fe 3 Ni 1 catalysts supported on SiO 2 , ZrO 2 , and CeO 2 , as well as CeO 2 ‐supported Fe 3x Ni x with different metal loadings (x=0.25, 0.5, 1, 2, 4), were investigated to illustrate the effects of the oxide support and the metal loading amount in tuning the catalytic activity and selectivity. The oxidation state and the dispersion of the Ni and Fe species on the supported catalysts were determined by using in‐situ X‐ray diffraction (XRD) and X‐ray absorption fine structure (XAFS) measurements. Among these FeNi‐based catalysts, Fe 3 Ni 1 /CeO 2 exhibited the best catalytic activity and maximum ethylene yield for the oxidative dehydrogenation of ethane. Excessive loading amount of active metals changed the reaction selectivity from oxidative dehydrogenation to dry reforming. The high activity and selectivity for CO 2 ‐assisted oxidative dehydrogenation of ethane over Fe 3 Ni 1 /CeO 2 are likely due to the formation of Ni‐FeO x /CeO x interfacial sites, while the presence of Ni‐ZrO 2 interfacial sites on Fe 3 Ni 1 /ZrO 2 and NiFe‐CeO x interfacial sites on Fe 12 Ni 4 /CeO 2 likely tune the reaction selectivity toward dry reforming of ethane.},
doi = {10.1002/cctc.201901585},
journal = {ChemCatChem},
number = 2,
volume = 12,
place = {United States},
year = {Tue Oct 08 00:00:00 EDT 2019},
month = {Tue Oct 08 00:00:00 EDT 2019}
}
Web of Science
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