Visualizing Buried Local Carrier Diffusion in Halide Perovskite Crystals via Two-Photon Microscopy

Stavrakas, Camille; Delport, Géraud; Zhumekenov, Ayan A.; Anaya, Miguel; Chahbazian, Rosemonde; Bakr, Osman M.; Barnard, Edward S.; Stranks, Samuel D.

doi:10.1021/acsenergylett.9b02244

Title: Visualizing Buried Local Carrier Diffusion in Halide Perovskite Crystals via Two-Photon Microscopy

Authors:

Stavrakas, Camille ^[1]; Delport, Géraud ^[1];

^[2];

^[1]; Chahbazian, Rosemonde ^[1];

^[2]; Barnard, Edward S. ^[3];

^[4]

Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE, United Kingdom
Division of Physical Sciences and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Kingdom of Saudi Arabia
Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States
Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE, United Kingdom, Department of Chemical Engineering & Biotechnology, University of Cambridge, Philippa Fawcett Drive, Cambridge CB3 0AS, United Kingdom

Publication Date:: 2019-11-19

Research Org.:: Univ. of Cambridge (United Kingdom); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1579455

Alternate Identifier(s):: OSTI ID: 1582584; OSTI ID: 1756878

Grant/Contract Number:: AC02-05CH11231; UF150033; 841386; 756962; EP/R023980/1

Resource Type:: Published Article

Journal Name:: ACS Energy Letters

Additional Journal Information:: Journal Name: ACS Energy Letters Journal Volume: 5 Journal Issue: 1; Journal ID: ISSN 2380-8195

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; Transport properties; Crystal; Diffusion; Crystal structure; Electrical conductivity

Citation Formats


                    Stavrakas, Camille, Delport, Géraud, Zhumekenov, Ayan A., Anaya, Miguel, Chahbazian, Rosemonde, Bakr, Osman M., Barnard, Edward S., and Stranks, Samuel D. Visualizing Buried Local Carrier Diffusion in Halide Perovskite Crystals via Two-Photon Microscopy.  United States: N. p., 2019. 
Web.  doi:10.1021/acsenergylett.9b02244.

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                    Stavrakas, Camille, Delport, Géraud, Zhumekenov, Ayan A., Anaya, Miguel, Chahbazian, Rosemonde, Bakr, Osman M., Barnard, Edward S., & Stranks, Samuel D. Visualizing Buried Local Carrier Diffusion in Halide Perovskite Crystals via Two-Photon Microscopy.  United States.  https://doi.org/10.1021/acsenergylett.9b02244

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                    Stavrakas, Camille, Delport, Géraud, Zhumekenov, Ayan A., Anaya, Miguel, Chahbazian, Rosemonde, Bakr, Osman M., Barnard, Edward S., and Stranks, Samuel D. Tue .  
"Visualizing Buried Local Carrier Diffusion in Halide Perovskite Crystals via Two-Photon Microscopy".  United States.  https://doi.org/10.1021/acsenergylett.9b02244.

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@article{osti_1579455,

  title        = {Visualizing Buried Local Carrier Diffusion in Halide Perovskite Crystals via Two-Photon Microscopy},

  author       = {Stavrakas, Camille and Delport, Géraud and Zhumekenov, Ayan A. and Anaya, Miguel and Chahbazian, Rosemonde and Bakr, Osman M. and Barnard, Edward S. and Stranks, Samuel D.},

  abstractNote = {},

  doi          = {10.1021/acsenergylett.9b02244},

  journal      = {ACS Energy Letters},

  number       = 1,

  volume       = 5,

  place        = {United States},

  year         = {2019},

  month        = {11}

}

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Surface Charge Trapping in Organolead Halide Perovskites Explored by Single-Particle Photoluminescence Imaging
journal, July 2015

Measuring n and k at the Microscale in Single Crystals of CH ₃ NH ₃ PbBr ₃ Perovskite
journal, December 2015

High-quality bulk hybrid perovskite single crystals within minutes by inverse temperature crystallization
journal, July 2015

Visualizing Carrier Diffusion in Individual Single-Crystal Organolead Halide Perovskite Nanowires and Nanoplates
journal, September 2015

Contactless measurements of photocarrier transport properties in perovskite single crystals
journal, April 2019

Heterogeneity at multiple length scales in halide perovskite semiconductors
journal, July 2019

Double Charged Surface Layers in Lead Halide Perovskite Crystals
journal, February 2017

Two-Photon Absorption in Organometallic Bromide Perovskites
journal, July 2015

The recombination mechanisms leading to amplified spontaneous emission at the true-green wavelength in CH ₃ NH ₃ PbBr ₃ perovskites
journal, February 2015

Recombination Kinetics in Organic-Inorganic Perovskites: Excitons, Free Charge, and Subgap States
journal, September 2014

High-efficiency two-dimensional Ruddlesden–Popper perovskite solar cells
journal, July 2016

High-efficiency solution-processed perovskite solar cells with millimeter-scale grains
journal, January 2015

Lead-free organic–inorganic tin halide perovskites for photovoltaic applications
journal, January 2014

Probing buried recombination pathways in perovskite structures using 3D photoluminescence tomography
journal, January 2018

Hydrogen-like Wannier–Mott Excitons in Single Crystal of Methylammonium Lead Bromide Perovskite
journal, May 2016

Photo-induced halide redistribution in organic–inorganic perovskite films
journal, May 2016

Surface Restructuring of Hybrid Perovskite Crystals
journal, November 2016

Changes from Bulk to Surface Recombination Mechanisms between Pristine and Cycled Perovskite Solar Cells
journal, February 2017

Subdiffusive Exciton Transport in Quantum Dot Solids
journal, May 2014

Water photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysts
journal, September 2014

Impact of microstructure on local carrier lifetime in perovskite solar cells
journal, April 2015

Perovskite energy funnels for efficient light-emitting diodes
journal, June 2016

Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency
journal, January 2016

Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber
journal, October 2013

Impact of Reabsorption on the Emission Spectra and Recombination Dynamics of Hybrid Perovskite Single Crystals
journal, June 2017

Approaching Bulk Carrier Dynamics in Organo-Halide Perovskite Nanocrystalline Films by Surface Passivation
journal, March 2016

Room-Temperature Cavity Polaritons with 3D Hybrid Perovskite: Toward Large-Surface Polaritonic Devices
journal, June 2019

Efficient planar heterojunction perovskite solar cells by vapour deposition
journal, September 2013

Tracking Photoexcited Carriers in Hybrid Perovskite Semiconductors: Trap-Dominated Spatial Heterogeneity and Diffusion
journal, September 2017

Controlling the Cavity Structures of Two-Photon-Pumped Perovskite Microlasers
journal, March 2016

Comparison of Recombination Dynamics in CH ₃ NH ₃ PbBr ₃ and CH ₃ NH ₃ PbI ₃ Perovskite Films: Influence of Exciton Binding Energy
journal, November 2015

Impact of grain boundaries on efficiency and stability of organic-inorganic trihalide perovskites
journal, December 2017

Slow Diffusion and Long Lifetime in Metal Halide Perovskites for Photovoltaics
journal, September 2018

Determination of the exciton binding energy and effective masses for methylammonium and formamidinium lead tri-halide perovskite semiconductors
journal, January 2016

Contactless Visualization of Fast Charge Carrier Diffusion in Hybrid Halide Perovskite Thin Films
journal, January 2016