skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Redox, transmetalation, and stacking properties of tetrathiafulvalene-2,3,6,7-tetrathiolate bridged tin, nickel, and palladium compounds

Abstract

Capping TTFtt enables facile transmetalation in three different oxidation states.

Authors:
 [1];  [1];  [1];  [1]; ORCiD logo [1]; ORCiD logo [1]
  1. Department of Chemistry, The James Franck Institute, University of Chicago, Chicago, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1579429
Grant/Contract Number:  
AC02-06CH11357; SC0019215
Resource Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Xie, Jiaze, Boyn, Jan-Niklas, Filatov, Alexander S., McNeece, Andrew J., Mazziotti, David A., and Anderson, John S. Redox, transmetalation, and stacking properties of tetrathiafulvalene-2,3,6,7-tetrathiolate bridged tin, nickel, and palladium compounds. United Kingdom: N. p., 2020. Web. doi:10.1039/C9SC04381K.
Xie, Jiaze, Boyn, Jan-Niklas, Filatov, Alexander S., McNeece, Andrew J., Mazziotti, David A., & Anderson, John S. Redox, transmetalation, and stacking properties of tetrathiafulvalene-2,3,6,7-tetrathiolate bridged tin, nickel, and palladium compounds. United Kingdom. doi:10.1039/C9SC04381K.
Xie, Jiaze, Boyn, Jan-Niklas, Filatov, Alexander S., McNeece, Andrew J., Mazziotti, David A., and Anderson, John S. Wed . "Redox, transmetalation, and stacking properties of tetrathiafulvalene-2,3,6,7-tetrathiolate bridged tin, nickel, and palladium compounds". United Kingdom. doi:10.1039/C9SC04381K.
@article{osti_1579429,
title = {Redox, transmetalation, and stacking properties of tetrathiafulvalene-2,3,6,7-tetrathiolate bridged tin, nickel, and palladium compounds},
author = {Xie, Jiaze and Boyn, Jan-Niklas and Filatov, Alexander S. and McNeece, Andrew J. and Mazziotti, David A. and Anderson, John S.},
abstractNote = {Capping TTFtt enables facile transmetalation in three different oxidation states.},
doi = {10.1039/C9SC04381K},
journal = {Chemical Science},
number = ,
volume = ,
place = {United Kingdom},
year = {2020},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C9SC04381K

Save / Share:

Works referenced in this record:

exo-Methylene-BEDT-TTF and alkene-functionalised BEDT-TTF derivatives: synthesis and radical cation salts
journal, January 2015

  • Zecchini, Matteo; Lopez, Jordan R.; Allen, Scott W.
  • RSC Advances, Vol. 5, Issue 39
  • DOI: 10.1039/C5RA03921E

Solid-State Redox Switching of Magnetic Exchange and Electronic Conductivity in a Benzoquinoid-Bridged Mn II Chain Compound
journal, May 2016

  • Jeon, Ie-Rang; Sun, Lei; Negru, Bogdan
  • Journal of the American Chemical Society, Vol. 138, Issue 20
  • DOI: 10.1021/jacs.6b02485

Dithiolate and diselenolate tin complexes as ligands transfer reagent towards other metals
journal, June 1999


Structural Characteristics in a Stable Metallic ET Salt with Unusually High Oxidation State (ET: Bis(ethylenedithio)tetrathiafulvalene)
journal, March 2012

  • Minemawari, Hiromi; Jose, Judy Fe F.; Takahashi, Yukihiro
  • Bulletin of the Chemical Society of Japan, Vol. 85, Issue 3
  • DOI: 10.1246/bcsj.20110253

Redox Activities of Metal–Organic Frameworks Incorporating Rare-Earth Metal Chains and Tetrathiafulvalene Linkers
journal, February 2019


Active-space two-electron reduced-density-matrix method: Complete active-space calculations without diagonalization of the N-electron Hamiltonian
journal, October 2008

  • Gidofalvi, Gergely; Mazziotti, David A.
  • The Journal of Chemical Physics, Vol. 129, Issue 13
  • DOI: 10.1063/1.2983652

Single-component molecular conductor [Pt(dmdt) 2 ]—a three-dimensional ambient-pressure molecular Dirac electron system
journal, January 2019

  • Zhou, Biao; Ishibashi, Shoji; Ishii, Tatsuru
  • Chemical Communications, Vol. 55, Issue 23
  • DOI: 10.1039/C9CC00218A

Control of Electronic Structure and Conductivity in Two-Dimensional Metal–Semiquinoid Frameworks of Titanium, Vanadium, and Chromium
journal, February 2018

  • Ziebel, Michael E.; Darago, Lucy E.; Long, Jeffrey R.
  • Journal of the American Chemical Society, Vol. 140, Issue 8
  • DOI: 10.1021/jacs.7b13510

Superconductivity in a Copper(II)-Based Coordination Polymer with Perfect Kagome Structure
journal, December 2017

  • Huang, Xing; Zhang, Shuai; Liu, Liyao
  • Angewandte Chemie International Edition, Vol. 57, Issue 1
  • DOI: 10.1002/anie.201707568

Dinuclear Cp* Cobalt Complexes of the 1,2,4,5-Benzenetetrathiolate Bischelating Ligand
journal, February 2008

  • Nomura, Mitsushiro; Fourmigué, Marc
  • Inorganic Chemistry, Vol. 47, Issue 4
  • DOI: 10.1021/ic700778b

Large-Scale Semidefinite Programming for Many-Electron Quantum Mechanics
journal, February 2011


High Electrical Conductivity in Ni 3 (2,3,6,7,10,11-hexaiminotriphenylene) 2 , a Semiconducting Metal–Organic Graphene Analogue
journal, April 2014

  • Sheberla, Dennis; Sun, Lei; Blood-Forsythe, Martin A.
  • Journal of the American Chemical Society, Vol. 136, Issue 25
  • DOI: 10.1021/ja502765n

Photo- and Electronically Switchable Spin-Crossover Iron(II) Metal-Organic Frameworks Based on a Tetrathiafulvalene Ligand
journal, April 2017

  • Wang, Hai-Ying; Ge, Jing-Yuan; Hua, Carol
  • Angewandte Chemie International Edition, Vol. 56, Issue 20
  • DOI: 10.1002/anie.201611824

2D Conductive Iron-Quinoid Magnets Ordering up to T c = 105 K via Heterogenous Redox Chemistry
journal, March 2017

  • DeGayner, Jordan A.; Jeon, Ie-Rang; Sun, Lei
  • Journal of the American Chemical Society, Vol. 139, Issue 11
  • DOI: 10.1021/jacs.7b00705

Redox-switchable breathing behavior in tetrathiafulvalene-based metal–organic frameworks
journal, December 2017


Preparation and physical properties of highly conducting metal (M = Ni, Co, Cu) coordination polymers
journal, March 1993


Two-Electron Reduced Density Matrix as the Basic Variable in Many-Electron Quantum Chemistry and Physics
journal, August 2011


Synthesis, Structures, and Properties of 1,2,4,5-Benzenetetrathiolate Linked Group 10 Metal Complexes
journal, November 2009

  • Arumugam, Kuppuswamy; Shaw, Mohamed C.; Chandrasekaran, P.
  • Inorganic Chemistry, Vol. 48, Issue 22
  • DOI: 10.1021/ic901257s

Two dication salts of ET: preparation and crystal structures of ET [FeII(CN)4(CO)2]
journal, July 2004


Breathing-Dependent Redox Activity in a Tetrathiafulvalene-Based Metal–Organic Framework
journal, July 2018

  • Souto, Manuel; Romero, Jorge; Calbo, Joaquín
  • Journal of the American Chemical Society, Vol. 140, Issue 33
  • DOI: 10.1021/jacs.8b05890

Variational calculations of fermion second-order reduced density matrices by semidefinite programming algorithm
journal, May 2001

  • Nakata, Maho; Nakatsuji, Hiroshi; Ehara, Masahiro
  • The Journal of Chemical Physics, Vol. 114, Issue 19
  • DOI: 10.1063/1.1360199

Novel Topology in Semiconducting Tetrathiafulvalene Lanthanide Metal-Organic Frameworks
journal, August 2018


Redox-Controlled Selective Docking in a [2]Catenane Host
journal, February 2013

  • Barin, Gokhan; Frasconi, Marco; Dyar, Scott M.
  • Journal of the American Chemical Society, Vol. 135, Issue 7
  • DOI: 10.1021/ja3125004

A Three-Pole Supramolecular Switch
journal, April 1999

  • Ashton, Peter R.; Balzani, Vincenzo; Becher, Jan
  • Journal of the American Chemical Society, Vol. 121, Issue 16
  • DOI: 10.1021/ja984341c

Structures and properties of assembled oxidized metal complexes with C8H4S8 and related sulfur-rich dithiolate ligands
journal, March 2002


On the Oxidation of Octamethylenetetrathiafulvalene by CuBr 2 - Synthesis, Crystal Structure and Magnetic Properties of (OMTTF) 2 [Cu 4 Br 10 ]
journal, March 2009

  • Beck, Johannes; Bof de Oliveira, Adriano
  • Zeitschrift für anorganische und allgemeine Chemie, Vol. 635, Issue 3
  • DOI: 10.1002/zaac.200801306

Functional coordination polymers based on redox-active tetrathiafulvalene and its derivatives
journal, August 2017


Robust and conductive two-dimensional metal−organic frameworks with exceptionally high volumetric and areal capacitance
journal, January 2018


Self-association and columnar liquid crystalline phase of cationic alkyl-substituted-bipyridine benzenedithiolato gold(iii) complexes
journal, January 2013

  • Ogawa, Tomohiro; Sakamoto, Misaki; Honda, Hirotaka
  • Dalton Transactions, Vol. 42, Issue 45
  • DOI: 10.1039/c3dt51444g

Conductive Copper Benzenehexathiol Coordination Polymer as a Hydrogen Evolution Catalyst
journal, November 2017

  • Huang, Xing; Yao, Huiying; Cui, Yutao
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 46
  • DOI: 10.1021/acsami.7b14523

ET cation-radical salts with metal complex anions
journal, December 1988


Ligand non-innocence and strong correlation in manganese superoxide dismutase mimics
journal, January 2017

  • McIsaac, Alexandra R.; Mazziotti, David A.
  • Physical Chemistry Chemical Physics, Vol. 19, Issue 6
  • DOI: 10.1039/C6CP07563K

New Concepts in Tetrathiafulvalene Chemistry
journal, April 2001


Static and Dynamic Electron Correlation in the Ligand Noninnocent Oxidation of Nickel Dithiolates
journal, November 2017

  • Schlimgen, Anthony W.; Mazziotti, David A.
  • The Journal of Physical Chemistry A, Vol. 121, Issue 48
  • DOI: 10.1021/acs.jpca.7b09567

Variational Two-Particle Density Matrix Calculation for the Hubbard Model Below Half Filling Using Spin-Adapted Lifting Conditions
journal, May 2012


Harnessing Structural Dynamics in a 2D Manganese–Benzoquinoid Framework To Dramatically Accelerate Metal Transport in Diffusion-Limited Metal Exchange Reactions
journal, July 2018

  • Liu, Lujia; Li, Liang; DeGayner, Jordan A.
  • Journal of the American Chemical Society, Vol. 140, Issue 36
  • DOI: 10.1021/jacs.8b06774

Novel coordination complexes of tetrathiafulvalene derivatives
journal, March 1993


Coordination Chemistry of a π-Extended, Rigid and Redox-Active Tetrathiafulvalene-Fused Schiff-Base Ligand
journal, April 2008

  • Wu, Jin-Cai; Liu, Shi-Xia; Keene, Tony D.
  • Inorganic Chemistry, Vol. 47, Issue 8
  • DOI: 10.1021/ic800138x

Linking Molybdenum–Sulfur Clusters for Electrocatalytic Hydrogen Evolution
journal, September 2018

  • Ji, Zhe; Trickett, Christopher; Pei, Xiaokun
  • Journal of the American Chemical Society, Vol. 140, Issue 42
  • DOI: 10.1021/jacs.8b09807

Active-Space N -Representability Constraints for Variational Two-Particle Reduced Density Matrix Calculations
journal, November 2010


Synthesis, structures and properties of a new series of platinum–diimine–dithiolate complexes
journal, January 2007

  • Adams, Christopher J.; Fey, Natalie; Parfitt, Matthew
  • Dalton Transactions, Issue 39
  • DOI: 10.1039/b709252k

Redox bifunctionality in a Pt(ii) dithiolene complex of a tetrathiafulvalene diphosphine ligand
journal, January 2008

  • Shin, Kyong-Soon; Jung, YounJung; Lee, Su-Kyung
  • Dalton Transactions, Issue 43
  • DOI: 10.1039/b812797b

A Microporous and Naturally Nanostructured Thermoelectric Metal-Organic Framework with Ultralow Thermal Conductivity
journal, September 2017


Cu 3 (hexaiminotriphenylene) 2 : An Electrically Conductive 2D Metal-Organic Framework for Chemiresistive Sensing
journal, February 2015

  • Campbell, Michael G.; Sheberla, Dennis; Liu, Sophie F.
  • Angewandte Chemie International Edition, Vol. 54, Issue 14
  • DOI: 10.1002/anie.201411854

A Ferric Semiquinoid Single-Chain Magnet via Thermally-Switchable Metal–Ligand Electron Transfer
journal, May 2018

  • DeGayner, Jordan A.; Wang, Kunyu; Harris, T. David
  • Journal of the American Chemical Society, Vol. 140, Issue 21
  • DOI: 10.1021/jacs.8b03949

Realization of Quantum Chemistry without Wave Functions through First-Order Semidefinite Programming
journal, November 2004


Photoinduced Long-Lived Charge Separation in a Tetrathiafulvalene−Porphyrin−Fullerene Triad Detected by Time-Resolved Electron Paramagnetic Resonance
journal, August 2005

  • Di Valentin, Marilena; Bisol, Arianna; Agostini, Giancarlo
  • The Journal of Physical Chemistry B, Vol. 109, Issue 30
  • DOI: 10.1021/jp051345c

Interplay between Organic–Organometallic Electrophores within Bis(cyclopentadienyl)Molybdenum Dithiolene Tetrathiafulvalene Complexes
journal, April 2015


Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal–Organic Framework
journal, December 2015

  • Darago, Lucy E.; Aubrey, Michael L.; Yu, Chung Jui
  • Journal of the American Chemical Society, Vol. 137, Issue 50
  • DOI: 10.1021/jacs.5b10385

A two-dimensional π–d conjugated coordination polymer with extremely high electrical conductivity and ambipolar transport behaviour
journal, June 2015

  • Huang, Xing; Sheng, Peng; Tu, Zeyi
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8408

Synthesis and Reactivity of Trinuclear Gold(III) Dithiolate Complexes. X-ray Structure of [Au(C6F5)(S2C6H4)]3 and [Au(C6F5)(S2C6H4)(SC6H4SPPh3)]
journal, December 1995

  • Cerrada, Elena; Fernandez, Eduardo J.; Jones, Peter G.
  • Organometallics, Vol. 14, Issue 12
  • DOI: 10.1021/om00012a021

A BEDT-TTF Complex Including a Magnetic Anion, (BEDT-TTF) 3 (MnCl 4 ) 2
journal, February 1988

  • Mori, Takehiko; Inokuchi, Hiroo
  • Bulletin of the Chemical Society of Japan, Vol. 61, Issue 2
  • DOI: 10.1246/bcsj.61.591

Large-Scale Variational Two-Electron Reduced-Density-Matrix-Driven Complete Active Space Self-Consistent Field Methods
journal, April 2016

  • Fosso-Tande, Jacob; Nguyen, Truong-Son; Gidofalvi, Gergely
  • Journal of Chemical Theory and Computation, Vol. 12, Issue 5
  • DOI: 10.1021/acs.jctc.6b00190

Inkjet-printed flexible organic thin-film thermoelectric devices based on p- and n-type poly(metal 1,1,2,2-ethenetetrathiolate)s/polymer composites through ball-milling
journal, April 2014

  • Jiao, Fei; Di, Chong-an; Sun, Yimeng
  • Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 372, Issue 2013
  • DOI: 10.1098/rsta.2013.0008

Electrochemical oxygen reduction catalysed by Ni3(hexaiminotriphenylene)2
journal, March 2016

  • Miner, Elise M.; Fukushima, Tomohiro; Sheberla, Dennis
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms10942

Signature of Metallic Behavior in the Metal–Organic Frameworks M 3 (hexaiminobenzene) 2 (M = Ni, Cu)
journal, September 2017

  • Dou, Jin-Hu; Sun, Lei; Ge, Yicong
  • Journal of the American Chemical Society, Vol. 139, Issue 39
  • DOI: 10.1021/jacs.7b07234

A 2D Semiquinone Radical-Containing Microporous Magnet with Solvent-Induced Switching from T c = 26 to 80 K
journal, December 2015

  • Jeon, Ie-Rang; Negru, Bogdan; Van Duyne, Richard P.
  • Journal of the American Chemical Society, Vol. 137, Issue 50
  • DOI: 10.1021/jacs.5b10382

Flexible n-Type High-Performance Thermoelectric Thin Films of Poly(nickel-ethylenetetrathiolate) Prepared by an Electrochemical Method
journal, March 2016


Diverse π–π stacking motifs modulate electrical conductivity in tetrathiafulvalene-based metal–organic frameworks
journal, January 2019

  • Xie, Lilia S.; Alexandrov, Eugeny V.; Skorupskii, Grigorii
  • Chemical Science, Vol. 10, Issue 37
  • DOI: 10.1039/C9SC03348C

[Cu 3 (C 6 Se 6 )] n : The First Highly Conductive 2D π–d Conjugated Coordination Polymer Based on Benzenehexaselenolate
journal, March 2019


Building block ligands for new molecular conductors: homobimetallic tetrathiafulvalene tetrathiolates and metal diselenolenes and ditellurolenes
journal, January 1995

  • McCullough, Richard D.; Belot, John A.; Seth, Jyoti
  • Journal of Materials Chemistry, Vol. 5, Issue 10
  • DOI: 10.1039/jm9950501581

Redox Control and High Conductivity of Nickel Bis(dithiolene) Complex π-Nanosheet: A Potential Organic Two-Dimensional Topological Insulator
journal, October 2014

  • Kambe, Tetsuya; Sakamoto, Ryota; Kusamoto, Tetsuro
  • Journal of the American Chemical Society, Vol. 136, Issue 41
  • DOI: 10.1021/ja507619d

Bis(dithioline)-Based Metal–Organic Frameworks with Superior Electronic and Magnetic Properties: Spin Frustration to Spintronics and Gas Sensing
journal, December 2016

  • Chakravarty, Chandrima; Mandal, Bikash; Sarkar, Pranab
  • The Journal of Physical Chemistry C, Vol. 120, Issue 49
  • DOI: 10.1021/acs.jpcc.6b09416

A Single-component Molecular Conductor with Metal–Metal Bonding, [Pd(hfdt) 2 ] (hfdt: bis(trifluoromethyl)tetrathiafulvalenedithiolate)
journal, March 2016

  • Zhou, Biao; Ogura, Satomi; Liu, Qi Zhi
  • Chemistry Letters, Vol. 45, Issue 3
  • DOI: 10.1246/cl.151121

Multiple-Bridged Bis-Tetrathiafulvalenes:  New Synthetic Protocols and Spectroelectrochemical Investigations
journal, October 2000

  • Spanggaard, Holger; Prehn, Jesper; Nielsen, Mogens Brøndsted
  • Journal of the American Chemical Society, Vol. 122, Issue 39
  • DOI: 10.1021/ja000537c

S,C- and S,S-coupling via dithiolate transfer reactions from tin to nickel complexes
journal, January 2009

  • Cerrada, Elena; Moreno, Ana; Laguna, Mariano
  • Dalton Transactions, Issue 34
  • DOI: 10.1039/b902569c

Dication salt of bis(ethylenedithio)tetrathiafulvalene: preparation and crystal structure of BEDT-TTF(ClO4)2
journal, January 1993

  • Abboud, Khalil A.; Clevenger, Marvin B.; de Oliveira, Gl�nisson F.
  • Journal of the Chemical Society, Chemical Communications, Issue 20
  • DOI: 10.1039/c39930001560

Single-Component Molecular Conductor [Cu(dmdt) 2 ] with Three-Dimensionally Arranged Magnetic Moments Exhibiting a Coupled Electric and Magnetic Transition
journal, July 2012

  • Zhou, Biao; Idobata, Yuki; Kobayashi, Akiko
  • Journal of the American Chemical Society, Vol. 134, Issue 30
  • DOI: 10.1021/ja3044757

Strong Electron Correlation in Nitrogenase Cofactor, FeMoco
journal, May 2018

  • Montgomery, Jason M.; Mazziotti, David A.
  • The Journal of Physical Chemistry A, Vol. 122, Issue 22
  • DOI: 10.1021/acs.jpca.8b00941

Highly Conducting Neutral Coordination Polymer with Infinite Two-Dimensional Silver–Sulfur Networks
journal, September 2018

  • Huang, Xing; Li, Haisheng; Tu, Zeyi
  • Journal of the American Chemical Society, Vol. 140, Issue 45
  • DOI: 10.1021/jacs.8b07921

Toward New Electronic, Magnetic, and Optical Materials: Structure and Properties of the First Homobimetallic Tetrathiafulvalene Tetrathiolate Building Block
journal, October 1995

  • McCullough, Richard D.; Belot, John A.; Rheingold, Arnold L.
  • Journal of the American Chemical Society, Vol. 117, Issue 39
  • DOI: 10.1021/ja00144a019

Organic Thermoelectric Materials and Devices Based on p- and n-Type Poly(metal 1,1,2,2-ethenetetrathiolate)s
journal, January 2012


Multielectron-Transfer-based Rechargeable Energy Storage of Two-Dimensional Coordination Frameworks with Non-Innocent Ligands
journal, May 2018

  • Wada, Keisuke; Sakaushi, Ken; Sasaki, Sono
  • Angewandte Chemie International Edition, Vol. 57, Issue 29
  • DOI: 10.1002/anie.201802521

Molecular orbital theory of the properties of inorganic and organometallic compounds. 6. Extended basis sets for second-row transition metals
journal, September 1987

  • Dobbs, K. D.; Hehre, W. J.
  • Journal of Computational Chemistry, Vol. 8, Issue 6
  • DOI: 10.1002/jcc.540080615

Molecular orbital theory of the properties of inorganic and organometallic compounds 5. Extended basis sets for first-row transition metals
journal, September 1987

  • Dobbs, K. D.; Hehre, W. J.
  • Journal of Computational Chemistry, Vol. 8, Issue 6
  • DOI: 10.1002/jcc.540080614

Stabilizing Radical Cation and Dication of a Tetrathiafulvalene Derivative by a Weakly Coordinating Anion
journal, May 2014

  • Gao, Feng; Zhu, Fei-Fei; Wang, Xing-Yong
  • Inorganic Chemistry, Vol. 53, Issue 10
  • DOI: 10.1021/ic5006117

Recent progress on conducting organic charge-transfer salts
journal, January 1991


Gold and Nickel Extended Thiophenic-TTF Bisdithiolene Complexes
journal, February 2018


Self-consistent molecular orbital methods. 21. Small split-valence basis sets for first-row elements
journal, January 1980

  • Binkley, J. Stephen; Pople, John A.; Hehre, Warren J.
  • Journal of the American Chemical Society, Vol. 102, Issue 3
  • DOI: 10.1021/ja00523a008

Modular O 2 electroreduction activity in triphenylene-based metal–organic frameworks
journal, January 2018

  • Miner, Elise M.; Wang, Lu; Dincă, Mircea
  • Chemical Science, Vol. 9, Issue 29
  • DOI: 10.1039/C8SC02049C

Tunable Mixed-Valence Doping toward Record Electrical Conductivity in a Three-Dimensional Metal–Organic Framework
journal, May 2018

  • Xie, Lilia S.; Sun, Lei; Wan, Ruomeng
  • Journal of the American Chemical Society, Vol. 140, Issue 24
  • DOI: 10.1021/jacs.8b03604

A Radical-Radical and Metal–Metal Coupling Tetrathiafulvalene Derivative in which Organic Radicals Directly Coordinate to CuII Ions
journal, April 2006

  • Lu, Wen; Zhang, Yong; Dai, Jie
  • European Journal of Inorganic Chemistry, Vol. 2006, Issue 8
  • DOI: 10.1002/ejic.200500945

Mn 2 (2,5-disulfhydrylbenzene-1,4-dicarboxylate): A Microporous Metal–Organic Framework with Infinite (−Mn–S−) Chains and High Intrinsic Charge Mobility
journal, May 2013

  • Sun, Lei; Miyakai, Tomoyo; Seki, Shu
  • Journal of the American Chemical Society, Vol. 135, Issue 22
  • DOI: 10.1021/ja4037516

Stabilization of Hexaaminobenzene in a 2D Conductive Metal–Organic Framework for High Power Sodium Storage
journal, July 2018

  • Park, Jihye; Lee, Minah; Feng, Dawei
  • Journal of the American Chemical Society, Vol. 140, Issue 32
  • DOI: 10.1021/jacs.8b06020

Synthesis and Characterization of Monosubstituted TTF and Its Solvent Dependent Mono- and Dication Charge-Transfer Salts
journal, September 2009

  • Wang, Yu; Cui, Shuxin; Li, Bo
  • Crystal Growth & Design, Vol. 9, Issue 9
  • DOI: 10.1021/cg900635f

Reversible redox switching of magnetic order and electrical conductivity in a 2D manganese benzoquinoid framework
journal, January 2019

  • Liu, Lujia; DeGayner, Jordan A.; Sun, Lei
  • Chemical Science, Vol. 10, Issue 17
  • DOI: 10.1039/C9SC00606K

A Single-Component Molecular Superconductor
journal, May 2014

  • Cui, HengBo; Kobayashi, Hayao; Ishibashi, Shoji
  • Journal of the American Chemical Society, Vol. 136, Issue 21
  • DOI: 10.1021/ja503690m

Electronic Properties of π-Conjugated Nickel Bis(dithiolene) Network and Its Addition Reactivity with Ethylene
journal, July 2013

  • Tang, Qing; Zhou, Zhen
  • The Journal of Physical Chemistry C, Vol. 117, Issue 27
  • DOI: 10.1021/jp405055f

The Chemistry of TTFTT; 1: New Efficient Synthesis and Reactions of Tetrathiafulvalene-2,3,6,7-tetrathiolate (TTFTT): An Important Building Block in TTF-Syntheses
journal, January 1994

  • Svenstrup, Niels; Rasmussen, Karen Margrethe; Hansen, Thomas Kruse
  • Synthesis, Vol. 1994, Issue 08
  • DOI: 10.1055/s-1994-25580

Electroactive Ligands:  The First Metal Complexes of Tetrathiafulvenyl−Acetylacetonate
journal, November 2005

  • Massue, Julien; Bellec, Nathalie; Chopin, Stéphanie
  • Inorganic Chemistry, Vol. 44, Issue 24
  • DOI: 10.1021/ic051017r

Entangled Electrons Foil Synthesis of Elusive Low-Valent Vanadium Oxo Complex
journal, January 2016

  • Schlimgen, Anthony W.; Heaps, Charles W.; Mazziotti, David A.
  • The Journal of Physical Chemistry Letters, Vol. 7, Issue 4
  • DOI: 10.1021/acs.jpclett.5b02547

π-Conjugated Nickel Bis(dithiolene) Complex Nanosheet
journal, February 2013

  • Kambe, Tetsuya; Sakamoto, Ryota; Hoshiko, Ken
  • Journal of the American Chemical Society, Vol. 135, Issue 7
  • DOI: 10.1021/ja312380b

Tetrathiafulvalenes as building blocks in supramolecular chemistry II
journal, January 2000

  • Nielsen, Mogens Brøndsted; Lomholt, Christian; Becher, Jan
  • Chemical Society Reviews, Vol. 29, Issue 3
  • DOI: 10.1039/a803992e

Conductive MOF electrodes for stable supercapacitors with high areal capacitance
journal, October 2016

  • Sheberla, Dennis; Bachman, John C.; Elias, Joseph S.
  • Nature Materials, Vol. 16, Issue 2
  • DOI: 10.1038/nmat4766

Synthesis and properties of tetrathiafulvalene–metal bisdithiolene macromolecules
journal, January 1979

  • Rivera, Nilda Martinez; Engler, Edward M.; Schumaker, Robert R.
  • J. Chem. Soc., Chem. Commun., Issue 4
  • DOI: 10.1039/C39790000184

High-mobility band-like charge transport in a semiconducting two-dimensional metal–organic framework
journal, October 2018


High Charge Mobility in a Tetrathiafulvalene-Based Microporous Metal–Organic Framework
journal, July 2012

  • Narayan, Tarun C.; Miyakai, Tomoyo; Seki, Shu
  • Journal of the American Chemical Society, Vol. 134, Issue 31
  • DOI: 10.1021/ja3059827

Dimerization and stacking in transition-metal bisdithiolenes and tetrathiolates
journal, October 1985

  • Alvarez, Santiago; Vicente, Ramon; Hoffmann, Roald
  • Journal of the American Chemical Society, Vol. 107, Issue 22
  • DOI: 10.1021/ja00308a018

Diorganotin 1,3-dithiole-2-thione-4,5-dithiolate compounds, R2Sn(dmit): the crystal structure of MePhSn(dmit)
journal, June 1996

  • Doidge-Harrison, Solange M. S. V.; Irvine, John T. S.; Khan, Abdullah
  • Journal of Organometallic Chemistry, Vol. 516, Issue 1-2
  • DOI: 10.1016/0022-328X(96)06139-6

(ET) 3 (Br 3 ) 5 : A Metallic Conductor with an Unusually High Oxidation State of ET (ET = Bis(ethylenedithio)tetrathiafulvalene)
journal, January 2007

  • Minemawari, Hiromi; Naito, Toshio; Inabe, Tamotsu
  • Chemistry Letters, Vol. 36, Issue 1
  • DOI: 10.1246/cl.2007.74

Bis[tetrakis(methylsulfanyl)tetrathiafulvalenium] oxalate dichloride
journal, May 2005

  • Wang, Lei; Zhang, Jing-Ping; Zhang, Bin
  • Acta Crystallographica Section E Structure Reports Online, Vol. 61, Issue 6
  • DOI: 10.1107/S1600536805014121

Single-Component Molecular Metals with Extended-TTF Dithiolate Ligands
journal, November 2004

  • Kobayashi, Akiko; Fujiwara, Emiko; Kobayashi, Hayao
  • Chemical Reviews, Vol. 104, Issue 11
  • DOI: 10.1021/cr030656l

Charge Delocalization and Bulk Electronic Conductivity in the Mixed-Valence Metal–Organic Framework Fe(1,2,3-triazolate) 2 (BF 4 ) x
journal, June 2018

  • Park, Jesse G.; Aubrey, Michael L.; Oktawiec, Julia
  • Journal of the American Chemical Society, Vol. 140, Issue 27
  • DOI: 10.1021/jacs.8b03696

Do π-dimers of tetrathiafulvalene cation radicals really exist at room temperature?
journal, January 2001

  • Khodorkovsky, Vladimir; Shapiro, Lev; Krief, Pnina
  • Chem. Commun., Issue 24
  • DOI: 10.1039/B104934H

Metal–organic frameworks for energy storage: Batteries and supercapacitors
journal, January 2016


Redox-Active 1D Coordination Polymers of Iron–Sulfur Clusters
journal, February 2019

  • Horwitz, Noah E.; Xie, Jiaze; Filatov, Alexander S.
  • Journal of the American Chemical Society, Vol. 141, Issue 9
  • DOI: 10.1021/jacs.8b12339

Electrical conductive and magnetic properties of conjugated tetrathiolate nickel polymers
journal, June 1990

  • Yoshioka, Naoki; Nishide, Hiroyuki; Inagaki, Katsunari
  • Polymer Bulletin, Vol. 23, Issue 6
  • DOI: 10.1007/BF01033109

A LAXS (large angle x-ray scattering) and EXAFS (extended x-ray absorption fine structure) investigation of conductive amorphous nickel tetrathiolato polymers
journal, March 1988

  • Vogt, Thomas.; Faulmann, Christophe.; Soules, Regis.
  • Journal of the American Chemical Society, Vol. 110, Issue 6
  • DOI: 10.1021/ja00214a028

Large-Area, Free-Standing, Two-Dimensional Supramolecular Polymer Single-Layer Sheets for Highly Efficient Electrocatalytic Hydrogen Evolution
journal, August 2015

  • Dong, Renhao; Pfeffermann, Martin; Liang, Haiwei
  • Angewandte Chemie International Edition, Vol. 54, Issue 41
  • DOI: 10.1002/anie.201506048

Crystal and Electronic Structures of (BEDT-TTF)AuCl 2 AuCl 4
journal, December 1986


Self-consistent molecular-orbital methods. 22. Small split-valence basis sets for second-row elements
journal, May 1982

  • Gordon, Mark S.; Binkley, J. Stephen; Pople, John A.
  • Journal of the American Chemical Society, Vol. 104, Issue 10
  • DOI: 10.1021/ja00374a017

π-Conjugated Multidonor/Acceptor Arrays of Fullerene−Cobaltadithiolene−Tetrathiafulvalene: From Synthesis and Structure to Electronic Interactions
journal, September 2009

  • Matsuo, Yutaka; Maruyama, Masashi; Gayathri, S. Shankara
  • Journal of the American Chemical Society, Vol. 131, Issue 35
  • DOI: 10.1021/ja902312q

TTF[Ni(dmit)2]2: From single-crystals to thin layers, nanowires, and nanoparticles
journal, February 2016

  • Valade, Lydie; de Caro, Dominique; Faulmann, Christophe
  • Coordination Chemistry Reviews, Vol. 308
  • DOI: 10.1016/j.ccr.2015.05.014

High-Pressure (up to 10.7 GPa) Crystal Structure of Single-Component Molecular Metal [Au(tmdt) 2 ]
journal, May 2009

  • Okano, Yoshinori; Zhou, Biao; Tanaka, Hishashi
  • Journal of the American Chemical Society, Vol. 131, Issue 20
  • DOI: 10.1021/ja9010018

Graphene-like metal–organic frameworks: morphology control, optimization of thin film electrical conductivity and fast sensing applications
journal, January 2018

  • Hoppe, Bastian; Hindricks, Karen D. J.; Warwas, Dawid P.
  • CrystEngComm, Vol. 20, Issue 41
  • DOI: 10.1039/C8CE01264D

Two-Dimensional Metal–Organic Surfaces for Efficient Hydrogen Evolution from Water
journal, December 2014

  • Clough, Andrew J.; Yoo, Joseph W.; Mecklenburg, Matthew H.
  • Journal of the American Chemical Society, Vol. 137, Issue 1
  • DOI: 10.1021/ja5116937

Grand Challenges and Future Opportunities for Metal–Organic Frameworks
journal, June 2017

  • Hendon, Christopher H.; Rieth, Adam J.; Korzyński, Maciej D.
  • ACS Central Science, Vol. 3, Issue 6
  • DOI: 10.1021/acscentsci.7b00197

Coordination Programming of Two-Dimensional Metal Complex Frameworks
journal, March 2016


Prediction of a Two-Dimensional Organic Topological Insulator
journal, May 2013

  • Wang, Z. F.; Su, Ninghai; Liu, Feng
  • Nano Letters, Vol. 13, Issue 6, p. 2842-2845
  • DOI: 10.1021/nl401147u

Measuring and Reporting Electrical Conductivity in Metal–Organic Frameworks: Cd 2 (TTFTB) as a Case Study
journal, October 2016

  • Sun, Lei; Park, Sarah S.; Sheberla, Dennis
  • Journal of the American Chemical Society, Vol. 138, Issue 44
  • DOI: 10.1021/jacs.6b09345

Electrically Conductive Porous Metal-Organic Frameworks
journal, January 2016

  • Sun, Lei; Campbell, Michael G.; Dincă, Mircea
  • Angewandte Chemie International Edition, Vol. 55, Issue 11
  • DOI: 10.1002/anie.201506219