A switchable iron-based coordination polymer toward reversible acetonitrile electro-optical readout
Abstract
Efficient and low cost detection of harmful volatile organic compounds (VOCs) is a major health and environmental need in industrialized societies. For this, tailor-made porous coordination polymers are emerging as promising molecular sensing materials thanks to their responsivity to a wide variety of external stimuli and could be used to complement conventional sensors. Here, a non-porous crystalline 1D Fe(ii) coordination polymer acting as a porous acetonitrile host is presented. The desorption of interstitial acetonitrile is accompanied by magneto-structural transitions easily detectable in the optical and electronic properties of the material. This structural switch and therefore its (opto)electronic readout are reversible under exposure of the crystal to acetonitrile vapor. This simple and robust iron-based coordination polymer could be ideally suited for the construction of multifunctional sensor devices for volatile acetonitrile and potentially for other organic compounds.
- Authors:
-
[1];
[1];
[2];
[4];
[5];
[6];
[2]
- IMDEA Nanosciencia, Madrid (Spain)
- IMDEA Nanociencia; Madrid; Spain
- Consejo Superior de Investigaciones Cientificas (CSIC), Madrid (Spain). Instituto de Cerámica y Vidrio
- UCM-ADIF-CSIC, Las Rozas (Spain). Instituto de Magnetismo Aplicado
- Univ. Grenoble Alpes (France)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- OSTI Identifier:
- 1579336
- Grant/Contract Number:
- [AC02-05CH11231]
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemical Science
- Additional Journal Information:
- [ Journal Volume: 10; Journal Issue: 27]; Journal ID: ISSN 2041-6520
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Resines-Urien, Esther, Burzurí, Enrique, Fernandez-Bartolome, Estefania, García García-Tuñón, Miguel Ángel, de la Presa, Patricia, Poloni, Roberta, Teat, Simon J., and Costa, Jose Sanchez. A switchable iron-based coordination polymer toward reversible acetonitrile electro-optical readout. United States: N. p., 2019.
Web. doi:10.1039/c9sc02522g.
Resines-Urien, Esther, Burzurí, Enrique, Fernandez-Bartolome, Estefania, García García-Tuñón, Miguel Ángel, de la Presa, Patricia, Poloni, Roberta, Teat, Simon J., & Costa, Jose Sanchez. A switchable iron-based coordination polymer toward reversible acetonitrile electro-optical readout. United States. doi:10.1039/c9sc02522g.
Resines-Urien, Esther, Burzurí, Enrique, Fernandez-Bartolome, Estefania, García García-Tuñón, Miguel Ángel, de la Presa, Patricia, Poloni, Roberta, Teat, Simon J., and Costa, Jose Sanchez. Thu .
"A switchable iron-based coordination polymer toward reversible acetonitrile electro-optical readout". United States. doi:10.1039/c9sc02522g. https://www.osti.gov/servlets/purl/1579336.
@article{osti_1579336,
title = {A switchable iron-based coordination polymer toward reversible acetonitrile electro-optical readout},
author = {Resines-Urien, Esther and Burzurí, Enrique and Fernandez-Bartolome, Estefania and García García-Tuñón, Miguel Ángel and de la Presa, Patricia and Poloni, Roberta and Teat, Simon J. and Costa, Jose Sanchez},
abstractNote = {Efficient and low cost detection of harmful volatile organic compounds (VOCs) is a major health and environmental need in industrialized societies. For this, tailor-made porous coordination polymers are emerging as promising molecular sensing materials thanks to their responsivity to a wide variety of external stimuli and could be used to complement conventional sensors. Here, a non-porous crystalline 1D Fe(ii) coordination polymer acting as a porous acetonitrile host is presented. The desorption of interstitial acetonitrile is accompanied by magneto-structural transitions easily detectable in the optical and electronic properties of the material. This structural switch and therefore its (opto)electronic readout are reversible under exposure of the crystal to acetonitrile vapor. This simple and robust iron-based coordination polymer could be ideally suited for the construction of multifunctional sensor devices for volatile acetonitrile and potentially for other organic compounds.},
doi = {10.1039/c9sc02522g},
journal = {Chemical Science},
number = [27],
volume = [10],
place = {United States},
year = {2019},
month = {6}
}
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Works referencing / citing this record:
Biomimetic Microfingerprints for Anti-Counterfeiting Strategies
journal, February 2015
- Bae, Hyung Jong; Bae, Sangwook; Park, Cheolheon
- Advanced Materials, Vol. 27, Issue 12
Electrically Conductive Porous Metal-Organic Frameworks
journal, January 2016
- Sun, Lei; Campbell, Michael G.; Dincă, Mircea
- Angewandte Chemie International Edition, Vol. 55, Issue 11
Non-Porous Iron(II)-Based Sensor: Crystallographic Insights into a Cycle of Colorful Guest-Induced Topotactic Transformations
journal, October 2016
- Rodríguez-Jiménez, Santiago; Feltham, Humphrey L. C.; Brooker, Sally
- Angewandte Chemie International Edition, Vol. 55, Issue 48
Embedding 1D Conducting Channels into 3D Isoporous Polymer Films for High-Performance Humidity Sensing
journal, August 2018
- Shevate, Rahul; Haque, Md Azimul; Akhtar, Faheem Hassan
- Angewandte Chemie International Edition, Vol. 57, Issue 35
A Three-Dimensional Dynamic Supramolecular “Sticky Fingers” Organic Framework
journal, January 2019
- Fernandez-Bartolome, Estefania; Santos, José; Gamonal, Arturo
- Angewandte Chemie International Edition, Vol. 58, Issue 8
Electrical porous silicon sensor for detection of various organic molecules in liquid phase: Electrical porous silicon sensor
journal, February 2015
- Harraz, Farid A.; Ismail, Adel A.; Bouzid, Houcine
- physica status solidi (a), Vol. 212, Issue 8
Supramolecular structural transformations involving coordination polymers in the solid state
journal, July 2007
- Vittal, Jagadese J.
- Coordination Chemistry Reviews, Vol. 251, Issue 13-14
A 7-fold interpenetrated 3D porous coordination polymer (PCP) with nitrobenzene sensing properties
journal, May 2016
- Wang, Peng; Xu, Ji; Zhuo, Qi-Dong
- Inorganic Chemistry Communications, Vol. 67
Coordination polymers: Opportunities and challenges for monitoring volatile organic compounds
journal, June 2015
- Kumar, Pawan; Deep, Akash; Kim, Ki-Hyun
- Progress in Polymer Science, Vol. 45
A highly sensitive and durable electrical sensor for liquid ethanol using thermally-oxidized mesoporous silicon
journal, December 2016
- Harraz, Farid A.; Ismail, Adel A.; Al-Sayari, S. A.
- Superlattices and Microstructures, Vol. 100
Metal–Organic Framework Materials as Chemical Sensors
journal, September 2011
- Kreno, Lauren E.; Leong, Kirsty; Farha, Omar K.
- Chemical Reviews, Vol. 112, Issue 2, p. 1105-1125
Nitrile-Rich Coordination Polymer 1 ∞ {[Fe(CH 3 CN) 4 (pyrazine)](ClO 4 ) 2 } Exhibiting a HS ⇆ LS Transition
journal, December 2010
- Białońska, Agata; Bronisz, Robert; Darowska, Kamilla
- Inorganic Chemistry, Vol. 49, Issue 24
Three-Way Crystal-to-Crystal Reversible Transformation and Controlled Spin Switching by a Nonporous Molecular Material
journal, February 2014
- Costa, José Sánchez; Rodríguez-Jiménez, Santiago; Craig, Gavin A.
- Journal of the American Chemical Society, Vol. 136, Issue 10
Measuring and Reporting Electrical Conductivity in Metal–Organic Frameworks: Cd 2 (TTFTB) as a Case Study
journal, October 2016
- Sun, Lei; Park, Sarah S.; Sheberla, Dennis
- Journal of the American Chemical Society, Vol. 138, Issue 44
Validate personal air-pollution sensors
journal, July 2016
- Lewis, Alastair; Edwards, Peter
- Nature, Vol. 535, Issue 7610
Tuning the magneto-structural properties of non-porous coordination polymers by HCl chemisorption
journal, January 2012
- Coronado, Eugenio; Giménez-Marqués, Mónica; Espallargas, Guillermo Mínguez
- Nature Communications, Vol. 3, Issue 1
Conductive MOF electrodes for stable supercapacitors with high areal capacitance
journal, October 2016
- Sheberla, Dennis; Bachman, John C.; Elias, Joseph S.
- Nature Materials, Vol. 16, Issue 2
In situ growth of continuous thin metal–organic framework film for capacitive humidity sensing
journal, January 2011
- Liu, Jia; Sun, Fuxing; Zhang, Feng
- Journal of Materials Chemistry, Vol. 21, Issue 11
Unravelling the spin-state of solvated [Fe(bpp) 2 ] 2+ spin-crossover complexes: structure–function relationship
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Infrared Spectra of Acetonitrile and Acetonitrile‐ d 3
journal, December 1968
- Pace, E. L.; Noe, Lewis J.
- The Journal of Chemical Physics, Vol. 49, Issue 12
Porous, Crystalline, Covalent Organic Frameworks
journal, November 2005
- Côté, Adrien P.; Benin, Annabelle I.; Ockwig, Nathan W.
- Science, Vol. 310, Issue 5751, p. 1166-1170
The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013
- Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
- Science, Vol. 341, Issue 6149, p. 1230444-1230444