A switchable iron-based coordination polymer toward reversible acetonitrile electro-optical readout
Abstract
Efficient and low cost detection of harmful volatile organic compounds (VOCs) is a major health and environmental need in industrialized societies. For this, tailor-made porous coordination polymers are emerging as promising molecular sensing materials thanks to their responsivity to a wide variety of external stimuli and could be used to complement conventional sensors. Here, a non-porous crystalline 1D Fe(ii) coordination polymer acting as a porous acetonitrile host is presented. The desorption of interstitial acetonitrile is accompanied by magneto-structural transitions easily detectable in the optical and electronic properties of the material. This structural switch and therefore its (opto)electronic readout are reversible under exposure of the crystal to acetonitrile vapor. This simple and robust iron-based coordination polymer could be ideally suited for the construction of multifunctional sensor devices for volatile acetonitrile and potentially for other organic compounds.
- Authors:
-
[1];
[1];
[2];
[4];
[5];
[6];
[2]
- IMDEA Nanosciencia, Madrid (Spain)
- IMDEA Nanociencia; Madrid; Spain
- Consejo Superior de Investigaciones Cientificas (CSIC), Madrid (Spain). Instituto de Cerámica y Vidrio
- UCM-ADIF-CSIC, Las Rozas (Spain). Instituto de Magnetismo Aplicado
- Univ. Grenoble Alpes (France)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1579336
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemical Science
- Additional Journal Information:
- Journal Volume: 10; Journal Issue: 27; Journal ID: ISSN 2041-6520
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Resines-Urien, Esther, Burzurí, Enrique, Fernandez-Bartolome, Estefania, García García-Tuñón, Miguel Ángel, de la Presa, Patricia, Poloni, Roberta, Teat, Simon J., and Costa, Jose Sanchez. A switchable iron-based coordination polymer toward reversible acetonitrile electro-optical readout. United States: N. p., 2019.
Web. doi:10.1039/c9sc02522g.
Resines-Urien, Esther, Burzurí, Enrique, Fernandez-Bartolome, Estefania, García García-Tuñón, Miguel Ángel, de la Presa, Patricia, Poloni, Roberta, Teat, Simon J., & Costa, Jose Sanchez. A switchable iron-based coordination polymer toward reversible acetonitrile electro-optical readout. United States. https://doi.org/10.1039/c9sc02522g
Resines-Urien, Esther, Burzurí, Enrique, Fernandez-Bartolome, Estefania, García García-Tuñón, Miguel Ángel, de la Presa, Patricia, Poloni, Roberta, Teat, Simon J., and Costa, Jose Sanchez. Thu .
"A switchable iron-based coordination polymer toward reversible acetonitrile electro-optical readout". United States. https://doi.org/10.1039/c9sc02522g. https://www.osti.gov/servlets/purl/1579336.
@article{osti_1579336,
title = {A switchable iron-based coordination polymer toward reversible acetonitrile electro-optical readout},
author = {Resines-Urien, Esther and Burzurí, Enrique and Fernandez-Bartolome, Estefania and García García-Tuñón, Miguel Ángel and de la Presa, Patricia and Poloni, Roberta and Teat, Simon J. and Costa, Jose Sanchez},
abstractNote = {Efficient and low cost detection of harmful volatile organic compounds (VOCs) is a major health and environmental need in industrialized societies. For this, tailor-made porous coordination polymers are emerging as promising molecular sensing materials thanks to their responsivity to a wide variety of external stimuli and could be used to complement conventional sensors. Here, a non-porous crystalline 1D Fe(ii) coordination polymer acting as a porous acetonitrile host is presented. The desorption of interstitial acetonitrile is accompanied by magneto-structural transitions easily detectable in the optical and electronic properties of the material. This structural switch and therefore its (opto)electronic readout are reversible under exposure of the crystal to acetonitrile vapor. This simple and robust iron-based coordination polymer could be ideally suited for the construction of multifunctional sensor devices for volatile acetonitrile and potentially for other organic compounds.},
doi = {10.1039/c9sc02522g},
journal = {Chemical Science},
number = 27,
volume = 10,
place = {United States},
year = {2019},
month = {6}
}
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Works referencing / citing this record:
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