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Title: Liquid cadmium cathode performance model based on the equilibrium behaviors of U and Pu in molten LiCl–KCl/Cd system at 500°C

Abstract

The liquid cadmium cathode is a pyroprocessing technology used for the recovery of group actinide metals from the molten chloride salts that support uranium electrorefining. This article presents a model for the performance of a liquid cadmium cathode based on considerations of salt/alloy equilibrium thermodynamics, Cd-U-Pu phase diagram behaviors, and mass balance constraints. In conclusion, the model demonstrates how the salt/cadmium system responds as incremental additions of uranium are made to the liquid cadmium cathode.

Authors:
ORCiD logo [1]; ORCiD logo [1]
  1. Idaho National Lab. (INL), Idaho Falls, ID (United States)
Publication Date:
Research Org.:
Idaho National Lab. (INL), Idaho Falls, ID (United States)
Sponsoring Org.:
USDOE Office of Nuclear Energy (NE)
OSTI Identifier:
1578276
Alternate Identifier(s):
OSTI ID: 1580291
Report Number(s):
INL/JOU-19-54973-Rev000
Journal ID: ISSN 0022-3115
Grant/Contract Number:  
AC07-05ID14517
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Nuclear Materials
Additional Journal Information:
Journal Volume: 528; Journal Issue: C; Journal ID: ISSN 0022-3115
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS; 36 MATERIALS SCIENCE; Liquid Cadmium Cathode; Uranium; Plutonium; Cadmium; Model; Thermodynamic; Phase Diagram

Citation Formats

Fredrickson, Guy L., and Yoo, Tae -Sic. Liquid cadmium cathode performance model based on the equilibrium behaviors of U and Pu in molten LiCl–KCl/Cd system at 500°C. United States: N. p., 2019. Web. doi:10.1016/j.jnucmat.2019.151883.
Fredrickson, Guy L., & Yoo, Tae -Sic. Liquid cadmium cathode performance model based on the equilibrium behaviors of U and Pu in molten LiCl–KCl/Cd system at 500°C. United States. doi:10.1016/j.jnucmat.2019.151883.
Fredrickson, Guy L., and Yoo, Tae -Sic. Wed . "Liquid cadmium cathode performance model based on the equilibrium behaviors of U and Pu in molten LiCl–KCl/Cd system at 500°C". United States. doi:10.1016/j.jnucmat.2019.151883.
@article{osti_1578276,
title = {Liquid cadmium cathode performance model based on the equilibrium behaviors of U and Pu in molten LiCl–KCl/Cd system at 500°C},
author = {Fredrickson, Guy L. and Yoo, Tae -Sic},
abstractNote = {The liquid cadmium cathode is a pyroprocessing technology used for the recovery of group actinide metals from the molten chloride salts that support uranium electrorefining. This article presents a model for the performance of a liquid cadmium cathode based on considerations of salt/alloy equilibrium thermodynamics, Cd-U-Pu phase diagram behaviors, and mass balance constraints. In conclusion, the model demonstrates how the salt/cadmium system responds as incremental additions of uranium are made to the liquid cadmium cathode.},
doi = {10.1016/j.jnucmat.2019.151883},
journal = {Journal of Nuclear Materials},
number = C,
volume = 528,
place = {United States},
year = {2019},
month = {11}
}

Journal Article:
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This content will become publicly available on November 6, 2020
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