Liquid cadmium cathode performance model based on the equilibrium behaviors of U and Pu in molten LiCl–KCl/Cd system at 500°C

Fredrickson, Guy L.; Yoo, Tae -Sic

doi:10.1016/j.jnucmat.2019.151883

Title: Liquid cadmium cathode performance model based on the equilibrium behaviors of U and Pu in molten LiCl–KCl/Cd system at 500°C

Journal Article · 06 November 2019 · Journal of Nuclear Materials

DOI: https://doi.org/10.1016/j.jnucmat.2019.151883 · OSTI ID:1578276

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Idaho National Lab. (INL), Idaho Falls, ID (United States)

The liquid cadmium cathode is a pyroprocessing technology used for the recovery of group actinide metals from the molten chloride salts that support uranium electrorefining. This article presents a model for the performance of a liquid cadmium cathode based on considerations of salt/alloy equilibrium thermodynamics, Cd-U-Pu phase diagram behaviors, and mass balance constraints. In conclusion, the model demonstrates how the salt/cadmium system responds as incremental additions of uranium are made to the liquid cadmium cathode.

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Research Organization:: Idaho National Laboratory (INL), Idaho Falls, ID (United States)

Sponsoring Organization:: USDOE Office of Nuclear Energy (NE)

Grant/Contract Number:: AC07-05ID14517

OSTI ID:: 1578276

Report Number(s):: INL/JOU--19-54973-Rev000

Journal Information:: Journal of Nuclear Materials, Journal Name: Journal of Nuclear Materials Journal Issue: C Vol. 528; ISSN 0022-3115

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Analysis and modeling of the equilibrium behaviors of U and Pu in molten LiCl-KCl/Cd system at 500 °C

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Fredrickson, Guy L.; Yoo, Tae-Sic

Experimental observations on electrorefining spent nuclear fuel in molten LiCl-KCl/liquid cadmium system.

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Johnson, T A; Laug, D V; Li, S X; +1 more

Experimental Investigations into U/TRU Recovery using a Liquid Cadmium Cathode and Salt Containing High Rare Earth Concentrations

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Li, Shelly X; Herrmann, Steven D; Simpson, Michael F

Related Subjects

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS
36 MATERIALS SCIENCE
Cadmium
Liquid Cadmium Cathode
Model
Phase Diagram
Plutonium
Thermodynamic
Uranium

Title: Liquid cadmium cathode performance model based on the equilibrium behaviors of U and Pu in molten LiCl–KCl/Cd system at 500°C

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