Mechanical mismatch-driven rippling in carbon-coated silicon sheets for stress-resilient battery anodes

Ryu, Jaegeon; Chen, Tianwu; Bok, Taesoo; Song, Gyujin; Ma, Jiyoung; Hwang, Chihyun; Luo, Langli; Song, Hyun -Kon; Cho, Jaephil; Wang, Chongmin; Zhang, Sulin; Park, Soojin

doi:10.1038/s41467-018-05398-9

Title: Mechanical mismatch-driven rippling in carbon-coated silicon sheets for stress-resilient battery anodes

Journal Article · 26 July 2018 · Nature Communications

DOI: https://doi.org/10.1038/s41467-018-05398-9 · OSTI ID:1578272

^[1];

^[2]; Bok, Taesoo ^[1]; Song, Gyujin ^[1]; Ma, Jiyoung ^[1]; Hwang, Chihyun ^[1];

^[3]; Song, Hyun -Kon ^[1]; Cho, Jaephil ^[1];

^[3]; Zhang, Sulin ^[2];

^[1]

Ulsan National Inst. of Science and Technology (UNIST), Ulsan (Republic of Korea)
Pennsylvania State Univ., University Park, PA (United States)
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

High gravimetric/volumetric capacity and low working potential make Si as one of the ideal candidate anode materials for lithium ion batteries. However, the large volume change of Si upon lithiation/delithiation poses a critical challenge for stable battery operations. Here, we introduce a novel designing concept, which takes advantage of such a deformation and ensures the structural stability of the material by developing a 2D Si nanosheet coated with a thin carbon layer (2DSi@C). Upon electrochemical cycling, this 2DSi@C exhibits unique deformation patterns, featuring accommodation of deformation in the thickness direction upon lithiation, while forming ripples upon delithiation, as consistently demonstrated by in-situ TEM observation and chemomechanical simulation. The ripple formation presents a unique mechanism for releasing the cycling induced stress, rendering the 2DSi@C chemomechanically much more stable and durable than the bare 2DSi counterparts. This work demonstrates a general principle as how to take the advantage of the large deformation materials for designing high capacity electrode.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Biological and Environmental Research (BER) (SC-23)

Grant/Contract Number:: AC05-76RL01830; AC02-05CH11231

OSTI ID:: 1578272

Report Number(s):: PNNL-SA--132988

Journal Information:: Nature Communications, Journal Name: Nature Communications Journal Issue: 1 Vol. 9; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

References (84)

Strain Anisotropies and Self-Limiting Capacities in Single-Crystalline 3D Silicon Microstructures: Models for High Energy Density Lithium-Ion Battery Anodes Goldman, Jason L.; Long, Brandon R.; Gewirth, Andrew A. Advanced Functional Materials, Vol. 21, Issue 13, p. 2412-2422 https://doi.org/10.1002/adfm.201002487	journal	April 2011
Reversible Storage of Lithium in Silver-Coated Three-Dimensional Macroporous Silicon Yu, Yan; Gu, Lin; Zhu, Changbao Advanced Materials, Vol. 22, Issue 20 https://doi.org/10.1002/adma.200903755	journal	May 2010
Silicon Thin Films as Anodes for High-Performance Lithium-Ion Batteries with Effective Stress Relaxation Yu, Cunjiang; Li, Xin; Ma, Teng Advanced Energy Materials, Vol. 2, Issue 1 https://doi.org/10.1002/aenm.201100634	journal	December 2011
Strong kinetics-stress coupling in lithiation of Si and Ge anodes Yang, Hui; Liang, Wentao; Guo, Xu Extreme Mechanics Letters, Vol. 2 https://doi.org/10.1016/j.eml.2014.11.008	journal	March 2015
Mechanics of electrochemically driven mechanical energy harvesting Chen, Tianwu; Yang, Hui; Li, Ju Extreme Mechanics Letters, Vol. 15 https://doi.org/10.1016/j.eml.2017.06.002	journal	September 2017
First principles study of Li–Si crystalline phases: Charge transfer, electronic structure, and lattice vibrations Chevrier, V. L.; Zwanziger, J. W.; Dahn, J. R. Journal of Alloys and Compounds, Vol. 496, Issue 1-2 https://doi.org/10.1016/j.jallcom.2010.01.142	journal	April 2010
Nonlinear analyses of wrinkles in a film bonded to a compliant substrate Huang, Z. Y.; Hong, W.; Suo, Z. Journal of the Mechanics and Physics of Solids, Vol. 53, Issue 9, p. 2101-2118 https://doi.org/10.1016/j.jmps.2005.03.007	journal	September 2005
A chemo-mechanical model of lithiation in silicon Yang, Hui; Fan, Feifei; Liang, Wentao Journal of the Mechanics and Physics of Solids, Vol. 70 https://doi.org/10.1016/j.jmps.2014.06.004	journal	October 2014
Stress-modulated driving force for lithiation reaction in hollow nano-anodes Jia, Zheng; Li, Teng Journal of Power Sources, Vol. 275 https://doi.org/10.1016/j.jpowsour.2014.11.081	journal	February 2015
Investigation on silicon alloying kinetics during lithiation by galvanostatic impedance spectroscopy Ko, Younghoon; Hwang, Chihyun; Song, Hyun-Kon Journal of Power Sources, Vol. 315 https://doi.org/10.1016/j.jpowsour.2016.03.008	journal	May 2016
Design of an ultra-durable silicon-based battery anode material with exceptional high-temperature cycling stability Park, Hyungmin; Choi, Sinho; Lee, Sung-Jun Nano Energy, Vol. 26 https://doi.org/10.1016/j.nanoen.2016.05.030	journal	August 2016
Two-Fold Anisotropy Governs Morphological Evolution and Stress Generation in Sodiated Black Phosphorus for Sodium Ion Batteries Chen, Tianwu; Zhao, Peng; Guo, Xu Nano Letters, Vol. 17, Issue 4 https://doi.org/10.1021/acs.nanolett.6b05033	journal	March 2017
Synthesis of Ultrathin Si Nanosheets from Natural Clays for Lithium-Ion Battery Anodes Ryu, Jaegeon; Hong, Dongki; Choi, Sinho ACS Nano, Vol. 10, Issue 2 https://doi.org/10.1021/acsnano.5b07977	journal	January 2016
Multiscale Hyperporous Silicon Flake Anodes for High Initial Coulombic Efficiency and Cycle Stability Ryu, Jaegeon; Hong, Dongki; Shin, Myoungsoo ACS Nano, Vol. 10, Issue 11 https://doi.org/10.1021/acsnano.6b06828	journal	November 2016
Anisotropic Swelling and Fracture of Silicon Nanowires during Lithiation Liu, Xiao Hua; Zheng, He; Zhong, Li Nano Letters, Vol. 11, Issue 8, p. 3312-3318 https://doi.org/10.1021/nl201684d	journal	August 2011
Anomalous Shape Changes of Silicon Nanopillars by Electrochemical Lithiation Lee, Seok Woo; McDowell, Matthew T.; Choi, Jang Wook Nano Letters, Vol. 11, Issue 7 https://doi.org/10.1021/nl201787r	journal	July 2011
A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Anodes Liu, Nian; Wu, Hui; McDowell, Matthew T. Nano Letters, Vol. 12, Issue 6 https://doi.org/10.1021/nl3014814	journal	May 2012
Kinetics of Initial Lithiation of Crystalline Silicon Electrodes of Lithium-Ion Batteries Pharr, Matt; Zhao, Kejie; Wang, Xinwei Nano Letters, Vol. 12, Issue 9 https://doi.org/10.1021/nl302841y	journal	January 2012
Bending-Induced Symmetry Breaking of Lithiation in Germanium Nanowires Gu, Meng; Yang, Hui; Perea, Daniel E. Nano Letters, Vol. 14, Issue 8 https://doi.org/10.1021/nl501680w	journal	July 2014
Superior Lithium Electroactive Mesoporous Si@Carbon Core−Shell Nanowires for Lithium Battery Anode Material Kim, Hyesun; Cho, Jaephil Nano Letters, Vol. 8, Issue 11, p. 3688-3691 https://doi.org/10.1021/nl801853x	journal	November 2008
Synthesis of Si Nanosheets by a Chemical Vapor Deposition Process and Their Blue Emissions Kim, Ungkil; Kim, Ilsoo; Park, Yonghee ACS Nano, Vol. 5, Issue 3 https://doi.org/10.1021/nn103385p	journal	February 2011
Size-Dependent Fracture of Silicon Nanoparticles During Lithiation Liu, Xiao Hua; Zhong, Li; Huang, Shan ACS Nano, Vol. 6, Issue 2 https://doi.org/10.1021/nn204476h	journal	January 2012
Tough Germanium Nanoparticles under Electrochemical Cycling Liang, Wentao; Yang, Hui; Fan, Feifei ACS Nano, Vol. 7, Issue 4 https://doi.org/10.1021/nn400330h	journal	March 2013
Self-healing chemistry enables the stable operation of silicon microparticle anodes for high-energy lithium-ion batteries Wang, Chao; Wu, Hui; Chen, Zheng Nature Chemistry, Vol. 5, Issue 12 https://doi.org/10.1038/nchem.1802	journal	November 2013
Inward lithium-ion breathing of hierarchically porous silicon anodes Xiao, Qiangfeng; Gu, Meng; Yang, Hui Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9844	journal	November 2015
Growth of conformal graphene cages on micrometre-sized silicon particles as stable battery anodes Li, Yuzhang; Yan, Kai; Lee, Hyun-Wook Nature Energy, Vol. 1, Issue 2 https://doi.org/10.1038/nenergy.2015.29	journal	January 2016
High-performance lithium battery anodes using silicon nanowires Chan, Candace K.; Peng, Hailin; Liu, Gao Nature Nanotechnology, Vol. 3, Issue 1, p. 31-35 https://doi.org/10.1038/nnano.2007.411	journal	December 2007
A pomegranate-inspired nanoscale design for large-volume-change lithium battery anodes Liu, Nian; Lu, Zhenda; Zhao, Jie Nature Nanotechnology, Vol. 9, Issue 3 https://doi.org/10.1038/nnano.2014.6	journal	February 2014
Fast-charging high-energy lithium-ion batteries via implantation of amorphous silicon nanolayer in edge-plane activated graphite anodes Kim, Namhyung; Chae, Sujong; Ma, Jiyoung Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00973-y	journal	October 2017
Scalable synthesis of silicon nanosheets from sand as an anode for Li-ion batteries Kim, Won-Sik; Hwa, Yoon; Shin, Jung-Hoo Nanoscale, Vol. 6, Issue 8 https://doi.org/10.1039/c3nr05354g	journal	January 2014
Nanotubular structured Si-based multicomponent anodes for high-performance lithium-ion batteries with controllable pore size via coaxial electro-spinning Ryu, Jaegeon; Choi, Sinho; Bok, Taesoo Nanoscale, Vol. 7, Issue 14 https://doi.org/10.1039/c5nr00224a	journal	January 2015
A Major Constituent of Brown Algae for Use in High-Capacity Li-Ion Batteries Kovalenko, I.; Zdyrko, B.; Magasinski, A. Science, Vol. 334, Issue 6052 https://doi.org/10.1126/science.1209150	journal	September 2011
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High Capacity, Reversible Silicon Thin-Film Anodes for Lithium-Ion Batteries Maranchi, J. P.; Hepp, A. F.; Kumta, P. N. Electrochemical and Solid-State Letters, Vol. 6, Issue 9 https://doi.org/10.1149/1.1596918	journal	January 2003
Concurrent Reaction and Plasticity during Initial Lithiation of Crystalline Silicon in Lithium-Ion Batteries Zhao, Kejie; Pharr, Matt; Wan, Qiang Journal of The Electrochemical Society, Vol. 159, Issue 3 https://doi.org/10.1149/2.020203jes	journal	January 2012
The Effect of Stress on Battery-Electrode Capacity Bucci, Giovanna; Swamy, Tushar; Bishop, Sean Journal of The Electrochemical Society, Vol. 164, Issue 4 https://doi.org/10.1149/2.0371704jes	journal	January 2017
Strain Anisotropies and Self-Limiting Capacities in Single-Crystalline 3D Silicon Microstructures: Models for High Energy Density Lithium-Ion Battery Anodes Goldman, Jason L.; Long, Brandon R.; Gewirth, Andrew A. Advanced Functional Materials, Vol. 21, Issue 13, p. 2412-2422 https://doi.org/10.1002/adfm.201002487	journal	April 2011
Reversible Storage of Lithium in Silver-Coated Three-Dimensional Macroporous Silicon Yu, Yan; Gu, Lin; Zhu, Changbao Advanced Materials, Vol. 22, Issue 20 https://doi.org/10.1002/adma.200903755	journal	May 2010
25th Anniversary Article: Understanding the Lithiation of Silicon and Other Alloying Anodes for Lithium-Ion Batteries McDowell, Matthew T.; Lee, Seok Woo; Nix, William D. Advanced Materials, Vol. 25, Issue 36 https://doi.org/10.1002/adma.201301795	journal	August 2013
Scalable Synthesis of 2D Si Nanosheets Lang, Jialiang; Ding, Bin; Zhang, Shuai Advanced Materials, Vol. 29, Issue 31 https://doi.org/10.1002/adma.201701777	journal	June 2017
Silicon Thin Films as Anodes for High-Performance Lithium-Ion Batteries with Effective Stress Relaxation Yu, Cunjiang; Li, Xin; Ma, Teng Advanced Energy Materials, Vol. 2, Issue 1 https://doi.org/10.1002/aenm.201100634	journal	December 2011
Characterization of carbon-coated silicon Dimov, Nikolay; Fukuda, Kenji; Umeno, Tatsuo Journal of Power Sources, Vol. 114, Issue 1 https://doi.org/10.1016/S0378-7753(02)00533-5	journal	February 2003
Strong kinetics-stress coupling in lithiation of Si and Ge anodes Yang, Hui; Liang, Wentao; Guo, Xu Extreme Mechanics Letters, Vol. 2 https://doi.org/10.1016/j.eml.2014.11.008	journal	March 2015
Mechanics of electrochemically driven mechanical energy harvesting Chen, Tianwu; Yang, Hui; Li, Ju Extreme Mechanics Letters, Vol. 15 https://doi.org/10.1016/j.eml.2017.06.002	journal	September 2017
First principles study of Li–Si crystalline phases: Charge transfer, electronic structure, and lattice vibrations Chevrier, V. L.; Zwanziger, J. W.; Dahn, J. R. Journal of Alloys and Compounds, Vol. 496, Issue 1-2 https://doi.org/10.1016/j.jallcom.2010.01.142	journal	April 2010
Nonlinear analyses of wrinkles in a film bonded to a compliant substrate Huang, Z. Y.; Hong, W.; Suo, Z. Journal of the Mechanics and Physics of Solids, Vol. 53, Issue 9, p. 2101-2118 https://doi.org/10.1016/j.jmps.2005.03.007	journal	September 2005
A chemo-mechanical model of lithiation in silicon Yang, Hui; Fan, Feifei; Liang, Wentao Journal of the Mechanics and Physics of Solids, Vol. 70 https://doi.org/10.1016/j.jmps.2014.06.004	journal	October 2014
Stress-modulated driving force for lithiation reaction in hollow nano-anodes Jia, Zheng; Li, Teng Journal of Power Sources, Vol. 275 https://doi.org/10.1016/j.jpowsour.2014.11.081	journal	February 2015
Investigation on silicon alloying kinetics during lithiation by galvanostatic impedance spectroscopy Ko, Younghoon; Hwang, Chihyun; Song, Hyun-Kon Journal of Power Sources, Vol. 315 https://doi.org/10.1016/j.jpowsour.2016.03.008	journal	May 2016
Design of an ultra-durable silicon-based battery anode material with exceptional high-temperature cycling stability Park, Hyungmin; Choi, Sinho; Lee, Sung-Jun Nano Energy, Vol. 26 https://doi.org/10.1016/j.nanoen.2016.05.030	journal	August 2016
Two-Fold Anisotropy Governs Morphological Evolution and Stress Generation in Sodiated Black Phosphorus for Sodium Ion Batteries Chen, Tianwu; Zhao, Peng; Guo, Xu Nano Letters, Vol. 17, Issue 4 https://doi.org/10.1021/acs.nanolett.6b05033	journal	March 2017
Synthesis of Ultrathin Si Nanosheets from Natural Clays for Lithium-Ion Battery Anodes Ryu, Jaegeon; Hong, Dongki; Choi, Sinho ACS Nano, Vol. 10, Issue 2 https://doi.org/10.1021/acsnano.5b07977	journal	January 2016
Multiscale Hyperporous Silicon Flake Anodes for High Initial Coulombic Efficiency and Cycle Stability Ryu, Jaegeon; Hong, Dongki; Shin, Myoungsoo ACS Nano, Vol. 10, Issue 11 https://doi.org/10.1021/acsnano.6b06828	journal	November 2016
Interconnected Silicon Hollow Nanospheres for Lithium-Ion Battery Anodes with Long Cycle Life Yao, Yan; McDowell, Matthew T.; Ryu, Ill Nano Letters, Vol. 11, Issue 7, p. 2949-2954 https://doi.org/10.1021/nl201470j	journal	July 2011
Anisotropic Swelling and Fracture of Silicon Nanowires during Lithiation Liu, Xiao Hua; Zheng, He; Zhong, Li Nano Letters, Vol. 11, Issue 8, p. 3312-3318 https://doi.org/10.1021/nl201684d	journal	August 2011
Anomalous Shape Changes of Silicon Nanopillars by Electrochemical Lithiation Lee, Seok Woo; McDowell, Matthew T.; Choi, Jang Wook Nano Letters, Vol. 11, Issue 7 https://doi.org/10.1021/nl201787r	journal	July 2011
Orientation-Dependent Interfacial Mobility Governs the Anisotropic Swelling in Lithiated Silicon Nanowires Yang, Hui; Huang, Shan; Huang, Xu Nano Letters, Vol. 12, Issue 4 https://doi.org/10.1021/nl204437t	journal	January 2012
A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Anodes Liu, Nian; Wu, Hui; McDowell, Matthew T. Nano Letters, Vol. 12, Issue 6 https://doi.org/10.1021/nl3014814	journal	May 2012
Kinetics of Initial Lithiation of Crystalline Silicon Electrodes of Lithium-Ion Batteries Pharr, Matt; Zhao, Kejie; Wang, Xinwei Nano Letters, Vol. 12, Issue 9 https://doi.org/10.1021/nl302841y	journal	January 2012
Bending-Induced Symmetry Breaking of Lithiation in Germanium Nanowires Gu, Meng; Yang, Hui; Perea, Daniel E. Nano Letters, Vol. 14, Issue 8 https://doi.org/10.1021/nl501680w	journal	July 2014
Superior Lithium Electroactive Mesoporous Si@Carbon Core−Shell Nanowires for Lithium Battery Anode Material Kim, Hyesun; Cho, Jaephil Nano Letters, Vol. 8, Issue 11, p. 3688-3691 https://doi.org/10.1021/nl801853x	journal	November 2008
Synthesis of Si Nanosheets by a Chemical Vapor Deposition Process and Their Blue Emissions Kim, Ungkil; Kim, Ilsoo; Park, Yonghee ACS Nano, Vol. 5, Issue 3 https://doi.org/10.1021/nn103385p	journal	February 2011
Size-Dependent Fracture of Silicon Nanoparticles During Lithiation Liu, Xiao Hua; Zhong, Li; Huang, Shan ACS Nano, Vol. 6, Issue 2 https://doi.org/10.1021/nn204476h	journal	January 2012
Tough Germanium Nanoparticles under Electrochemical Cycling Liang, Wentao; Yang, Hui; Fan, Feifei ACS Nano, Vol. 7, Issue 4 https://doi.org/10.1021/nn400330h	journal	March 2013
Self-healing chemistry enables the stable operation of silicon microparticle anodes for high-energy lithium-ion batteries Wang, Chao; Wu, Hui; Chen, Zheng Nature Chemistry, Vol. 5, Issue 12 https://doi.org/10.1038/nchem.1802	journal	November 2013
Silicon carbide-free graphene growth on silicon for lithium-ion battery with high volumetric energy density Son, In Hyuk; Hwan Park, Jong; Kwon, Soonchul Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8393	journal	June 2015
Inward lithium-ion breathing of hierarchically porous silicon anodes Xiao, Qiangfeng; Gu, Meng; Yang, Hui Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9844	journal	November 2015
Growth of conformal graphene cages on micrometre-sized silicon particles as stable battery anodes Li, Yuzhang; Yan, Kai; Lee, Hyun-Wook Nature Energy, Vol. 1, Issue 2 https://doi.org/10.1038/nenergy.2015.29	journal	January 2016
Scalable synthesis of silicon-nanolayer-embedded graphite for high-energy lithium-ion batteries Ko, Minseong; Chae, Sujong; Ma, Jiyoung Nature Energy, Vol. 1, Issue 9 https://doi.org/10.1038/nenergy.2016.113	journal	August 2016
High-performance lithium battery anodes using silicon nanowires Chan, Candace K.; Peng, Hailin; Liu, Gao Nature Nanotechnology, Vol. 3, Issue 1, p. 31-35 https://doi.org/10.1038/nnano.2007.411	journal	December 2007
A pomegranate-inspired nanoscale design for large-volume-change lithium battery anodes Liu, Nian; Lu, Zhenda; Zhao, Jie Nature Nanotechnology, Vol. 9, Issue 3 https://doi.org/10.1038/nnano.2014.6	journal	February 2014
Fast-charging high-energy lithium-ion batteries via implantation of amorphous silicon nanolayer in edge-plane activated graphite anodes Kim, Namhyung; Chae, Sujong; Ma, Jiyoung Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00973-y	journal	October 2017
Si nanotubes ALD coated with TiO ₂ , TiN or Al ₂ O ₃ as high performance lithium ion battery anodes Lotfabad, Elmira Memarzadeh; Kalisvaart, Peter; Kohandehghan, Alireza J. Mater. Chem. A, Vol. 2, Issue 8 https://doi.org/10.1039/C3TA14302C	journal	January 2014
High-performance silicon-based multicomponent battery anodes produced via synergistic coupling of multifunctional coating layers Lee, Jung-In; Ko, Younghoon; Shin, Myoungsoo Energy & Environmental Science, Vol. 8, Issue 7 https://doi.org/10.1039/C5EE01493J	journal	January 2015
Nanotubular structured Si-based multicomponent anodes for high-performance lithium-ion batteries with controllable pore size via coaxial electro-spinning Ryu, Jaegeon; Choi, Sinho; Bok, Taesoo Nanoscale, Vol. 7, Issue 14 https://doi.org/10.1039/C5NR00224A	journal	January 2015
Self-healing SEI enables full-cell cycling of a silicon-majority anode with a coulombic efficiency exceeding 99.9% Jin, Yang; Li, Sa; Kushima, Akihiro Energy & Environmental Science, Vol. 10, Issue 2 https://doi.org/10.1039/C6EE02685K	journal	January 2017
Scalable synthesis of silicon nanosheets from sand as an anode for Li-ion batteries Kim, Won-Sik; Hwa, Yoon; Shin, Jung-Hoo Nanoscale, Vol. 6, Issue 8 https://doi.org/10.1039/c3nr05354g	journal	January 2014
Fracture of crystalline silicon nanopillars during electrochemical lithium insertion Lee, S. W.; McDowell, M. T.; Berla, L. A. Proceedings of the National Academy of Sciences, Vol. 109, Issue 11 https://doi.org/10.1073/pnas.1201088109	journal	February 2012
A Major Constituent of Brown Algae for Use in High-Capacity Li-Ion Batteries Kovalenko, I.; Zdyrko, B.; Magasinski, A. Science, Vol. 334, Issue 6052 https://doi.org/10.1126/science.1209150	journal	September 2011
Highly elastic binders integrating polyrotaxanes for silicon microparticle anodes in lithium ion batteries Choi, Sunghun; Kwon, Tae-woo; Coskun, Ali Science, Vol. 357, Issue 6348 https://doi.org/10.1126/science.aal4373	journal	July 2017
High-performance lithium battery anodes using silicon nanowires Chan, Candace K.; Peng, Hailin; Liu, Gao Materials for Sustainable Energy: A Collection of Peer-Reviewed Research and Review Articles from Nature Publishing Group, p. 187-191 https://doi.org/10.1142/9789814317665_0026	book	October 2010
High Capacity, Reversible Silicon Thin-Film Anodes for Lithium-Ion Batteries Maranchi, J. P.; Hepp, A. F.; Kumta, P. N. Electrochemical and Solid-State Letters, Vol. 6, Issue 9 https://doi.org/10.1149/1.1596918	journal	January 2003
Concurrent Reaction and Plasticity during Initial Lithiation of Crystalline Silicon in Lithium-Ion Batteries Zhao, Kejie; Pharr, Matt; Wan, Qiang Journal of The Electrochemical Society, Vol. 159, Issue 3 https://doi.org/10.1149/2.020203jes	journal	January 2012
The Effect of Stress on Battery-Electrode Capacity Bucci, Giovanna; Swamy, Tushar; Bishop, Sean Journal of The Electrochemical Society, Vol. 164, Issue 4 https://doi.org/10.1149/2.0371704jes	journal	January 2017

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