Mechanical mismatch-driven rippling in carbon-coated silicon sheets for stress-resilient battery anodes
Abstract
High gravimetric/volumetric capacity and low working potential make Si as one of the ideal candidate anode materials for lithium ion batteries. However, the large volume change of Si upon lithiation/delithiation poses a critical challenge for stable battery operations. Here, we introduce a novel designing concept, which takes advantage of such a deformation and ensures the structural stability of the material by developing a 2D Si nanosheet coated with a thin carbon layer (2DSi@C). Upon electrochemical cycling, this 2DSi@C exhibits unique deformation patterns, featuring accommodation of deformation in the thickness direction upon lithiation, while forming ripples upon delithiation, as consistently demonstrated by in-situ TEM observation and chemomechanical simulation. The ripple formation presents a unique mechanism for releasing the cycling induced stress, rendering the 2DSi@C chemomechanically much more stable and durable than the bare 2DSi counterparts. This work demonstrates a general principle as how to take the advantage of the large deformation materials for designing high capacity electrode.
- Authors:
-
[1];
[2];
[3];
[3];
[1]
- Ulsan National Inst. of Science and Technology (UNIST), Ulsan (Republic of Korea)
- Pennsylvania State Univ., University Park, PA (United States)
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Publication Date:
- Research Org.:
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Biological and Environmental Research (BER)
- OSTI Identifier:
- 1578272
- Report Number(s):
- PNNL-SA-132988
Journal ID: ISSN 2041-1723
- Grant/Contract Number:
- AC05-76RL01830; AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 1; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Ryu, Jaegeon, Chen, Tianwu, Bok, Taesoo, Song, Gyujin, Ma, Jiyoung, Hwang, Chihyun, Luo, Langli, Song, Hyun -Kon, Cho, Jaephil, Wang, Chongmin, Zhang, Sulin, and Park, Soojin. Mechanical mismatch-driven rippling in carbon-coated silicon sheets for stress-resilient battery anodes. United States: N. p., 2018.
Web. doi:10.1038/s41467-018-05398-9.
Ryu, Jaegeon, Chen, Tianwu, Bok, Taesoo, Song, Gyujin, Ma, Jiyoung, Hwang, Chihyun, Luo, Langli, Song, Hyun -Kon, Cho, Jaephil, Wang, Chongmin, Zhang, Sulin, & Park, Soojin. Mechanical mismatch-driven rippling in carbon-coated silicon sheets for stress-resilient battery anodes. United States. doi:https://doi.org/10.1038/s41467-018-05398-9
Ryu, Jaegeon, Chen, Tianwu, Bok, Taesoo, Song, Gyujin, Ma, Jiyoung, Hwang, Chihyun, Luo, Langli, Song, Hyun -Kon, Cho, Jaephil, Wang, Chongmin, Zhang, Sulin, and Park, Soojin. Thu .
"Mechanical mismatch-driven rippling in carbon-coated silicon sheets for stress-resilient battery anodes". United States. doi:https://doi.org/10.1038/s41467-018-05398-9. https://www.osti.gov/servlets/purl/1578272.
@article{osti_1578272,
title = {Mechanical mismatch-driven rippling in carbon-coated silicon sheets for stress-resilient battery anodes},
author = {Ryu, Jaegeon and Chen, Tianwu and Bok, Taesoo and Song, Gyujin and Ma, Jiyoung and Hwang, Chihyun and Luo, Langli and Song, Hyun -Kon and Cho, Jaephil and Wang, Chongmin and Zhang, Sulin and Park, Soojin},
abstractNote = {High gravimetric/volumetric capacity and low working potential make Si as one of the ideal candidate anode materials for lithium ion batteries. However, the large volume change of Si upon lithiation/delithiation poses a critical challenge for stable battery operations. Here, we introduce a novel designing concept, which takes advantage of such a deformation and ensures the structural stability of the material by developing a 2D Si nanosheet coated with a thin carbon layer (2DSi@C). Upon electrochemical cycling, this 2DSi@C exhibits unique deformation patterns, featuring accommodation of deformation in the thickness direction upon lithiation, while forming ripples upon delithiation, as consistently demonstrated by in-situ TEM observation and chemomechanical simulation. The ripple formation presents a unique mechanism for releasing the cycling induced stress, rendering the 2DSi@C chemomechanically much more stable and durable than the bare 2DSi counterparts. This work demonstrates a general principle as how to take the advantage of the large deformation materials for designing high capacity electrode.},
doi = {10.1038/s41467-018-05398-9},
journal = {Nature Communications},
number = 1,
volume = 9,
place = {United States},
year = {2018},
month = {7}
}
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