Second‐order‐transition like characteristic contributes to strain temperature stability in (K, Na)NbO 3 ‐based materials
Abstract
Abstract High strain and good temperature stability are contradictory properties in (K, Na)NbO 3 (KNN)‐based materials. Herein, good temperature stability with high strain is obtained in a multiphase coexistent [ie, orthorhombic‐tetragonal (O‐T) and rhombohedral‐orthorhombic‐tetragonal (R‐O‐T)] KNN. A second‐order transition‐like characteristic should contribute to the temperature stability, in which an intrinsic lattice structure forms a bridge between them. The observed second‐order transition‐like characteristic is due to the reduced discrepancy among different lattice symmetries and a broadened temperature region for the phase transition. These integrated factors can slow the latent heat in a first‐order transition and extend it over a wide temperature region, thereby exhibiting second‐order transition‐like behavior. Correspondingly, the abrupt increase in strain near the phase transition temperature significantly slows. In addition, the appearance of pure tetragonal symmetry ( P 4 mm ) is deferred to a much higher temperature than T O‐T , in which the strain will inevitably decrease. As a result, good temperature stability with a high strain response can be realized in multiphase coexistent KNN materials, including d 33 *=448 pm/V, ‐27.5%≤fluctuation≤4.2% for O‐T, and d 33 *=446 pm/V, ‐17.5%≤fluctuation≤7.6% for R‐O‐T, over the whole temperature range 25 °C‐190 °C.
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1578136
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Journal of the American Ceramic Society
- Additional Journal Information:
- Journal Name: Journal of the American Ceramic Society Journal Volume: 103 Journal Issue: 4; Journal ID: ISSN 0002-7820
- Publisher:
- Wiley-Blackwell
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Liu, Gang, Yin, Jie, Zhao, Chunlin, Lv, Xiang, and Wu, Jiagang. Second‐order‐transition like characteristic contributes to strain temperature stability in (K, Na)NbO 3 ‐based materials. United States: N. p., 2019.
Web. doi:10.1111/jace.16927.
Liu, Gang, Yin, Jie, Zhao, Chunlin, Lv, Xiang, & Wu, Jiagang. Second‐order‐transition like characteristic contributes to strain temperature stability in (K, Na)NbO 3 ‐based materials. United States. https://doi.org/10.1111/jace.16927
Liu, Gang, Yin, Jie, Zhao, Chunlin, Lv, Xiang, and Wu, Jiagang. Wed .
"Second‐order‐transition like characteristic contributes to strain temperature stability in (K, Na)NbO 3 ‐based materials". United States. https://doi.org/10.1111/jace.16927.
@article{osti_1578136,
title = {Second‐order‐transition like characteristic contributes to strain temperature stability in (K, Na)NbO 3 ‐based materials},
author = {Liu, Gang and Yin, Jie and Zhao, Chunlin and Lv, Xiang and Wu, Jiagang},
abstractNote = {Abstract High strain and good temperature stability are contradictory properties in (K, Na)NbO 3 (KNN)‐based materials. Herein, good temperature stability with high strain is obtained in a multiphase coexistent [ie, orthorhombic‐tetragonal (O‐T) and rhombohedral‐orthorhombic‐tetragonal (R‐O‐T)] KNN. A second‐order transition‐like characteristic should contribute to the temperature stability, in which an intrinsic lattice structure forms a bridge between them. The observed second‐order transition‐like characteristic is due to the reduced discrepancy among different lattice symmetries and a broadened temperature region for the phase transition. These integrated factors can slow the latent heat in a first‐order transition and extend it over a wide temperature region, thereby exhibiting second‐order transition‐like behavior. Correspondingly, the abrupt increase in strain near the phase transition temperature significantly slows. In addition, the appearance of pure tetragonal symmetry ( P 4 mm ) is deferred to a much higher temperature than T O‐T , in which the strain will inevitably decrease. As a result, good temperature stability with a high strain response can be realized in multiphase coexistent KNN materials, including d 33 *=448 pm/V, ‐27.5%≤fluctuation≤4.2% for O‐T, and d 33 *=446 pm/V, ‐17.5%≤fluctuation≤7.6% for R‐O‐T, over the whole temperature range 25 °C‐190 °C.},
doi = {10.1111/jace.16927},
journal = {Journal of the American Ceramic Society},
number = 4,
volume = 103,
place = {United States},
year = {Wed Dec 11 00:00:00 EST 2019},
month = {Wed Dec 11 00:00:00 EST 2019}
}
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