skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on October 14, 2020

Title: Anisotropically Electrochemical-Mechanical Evolution in Solid-State Batteries and Interfacial Tailored Strategy

Abstract

All-solid-state batteries have attracted attention owing to the potential high energy density and safety; however, little success has been made on practical applications of solid-state batteries, which is largely attributed to the solid–solid interface issues. A fundamental elucidation of electrode–electrolyte interface behaviors is of crucial significance but has proven difficult. The interfacial resistance and capacity fading issues in a solid-state battery were probed, revealing a heterogeneous phase transition evolution at solid–solid interfaces. The strain-induced interfacial change and the contact loss, as well as a dense metallic surface phase, deteriorate the electrochemical reaction in solid-state batteries. Furthermore, the in situ growth of electrolytes on secondary particles is proposed to fabricate robust solid–solid interface. Finally, our study enlightens new insights into the mechanism behind solid–solid interfacial reaction for optimizing advanced solid-state batteries.

Authors:
 [1];  [1];  [1];  [1];  [2];  [2];  [2];  [1];  [1]; ORCiD logo [1];  [3]
  1. Harbin Inst. of Technology (China). School of Chemistry and Chemical Engineering, MIIT Key Lab. of Critical Materials Technology for New Energy Conversion and Storage
  2. Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
  3. Univ. of Western Ontario, London, ON (Canada). Dept. of Mechanical and Materials Engineering
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1577426
Report Number(s):
BNL-212376-2019-JAAM
Journal ID: ISSN 1433-7851; ANIE
Grant/Contract Number:  
SC0012704
Resource Type:
Accepted Manuscript
Journal Name:
Angewandte Chemie (International Edition)
Additional Journal Information:
Journal Name: Angewandte Chemie (International Edition); Journal Volume: 58; Journal Issue: 51; Journal ID: ISSN 1433-7851
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; electrochemistry; interfaces; lithium; solid-state batteries; sulfide electrolyte

Citation Formats

Sun, Nan, Liu, Qingsong, Cao, Yi, Lou, Shuaifeng, Ge, Mingyuan, Xiao, Xianghui, Lee, Wah-Keat, Gao, Yunzhi, Yin, Geping, Wang, Jiajun, and Sun, Xueliang. Anisotropically Electrochemical-Mechanical Evolution in Solid-State Batteries and Interfacial Tailored Strategy. United States: N. p., 2019. Web. doi:10.1002/anie.201910993.
Sun, Nan, Liu, Qingsong, Cao, Yi, Lou, Shuaifeng, Ge, Mingyuan, Xiao, Xianghui, Lee, Wah-Keat, Gao, Yunzhi, Yin, Geping, Wang, Jiajun, & Sun, Xueliang. Anisotropically Electrochemical-Mechanical Evolution in Solid-State Batteries and Interfacial Tailored Strategy. United States. doi:10.1002/anie.201910993.
Sun, Nan, Liu, Qingsong, Cao, Yi, Lou, Shuaifeng, Ge, Mingyuan, Xiao, Xianghui, Lee, Wah-Keat, Gao, Yunzhi, Yin, Geping, Wang, Jiajun, and Sun, Xueliang. Mon . "Anisotropically Electrochemical-Mechanical Evolution in Solid-State Batteries and Interfacial Tailored Strategy". United States. doi:10.1002/anie.201910993.
@article{osti_1577426,
title = {Anisotropically Electrochemical-Mechanical Evolution in Solid-State Batteries and Interfacial Tailored Strategy},
author = {Sun, Nan and Liu, Qingsong and Cao, Yi and Lou, Shuaifeng and Ge, Mingyuan and Xiao, Xianghui and Lee, Wah-Keat and Gao, Yunzhi and Yin, Geping and Wang, Jiajun and Sun, Xueliang},
abstractNote = {All-solid-state batteries have attracted attention owing to the potential high energy density and safety; however, little success has been made on practical applications of solid-state batteries, which is largely attributed to the solid–solid interface issues. A fundamental elucidation of electrode–electrolyte interface behaviors is of crucial significance but has proven difficult. The interfacial resistance and capacity fading issues in a solid-state battery were probed, revealing a heterogeneous phase transition evolution at solid–solid interfaces. The strain-induced interfacial change and the contact loss, as well as a dense metallic surface phase, deteriorate the electrochemical reaction in solid-state batteries. Furthermore, the in situ growth of electrolytes on secondary particles is proposed to fabricate robust solid–solid interface. Finally, our study enlightens new insights into the mechanism behind solid–solid interfacial reaction for optimizing advanced solid-state batteries.},
doi = {10.1002/anie.201910993},
journal = {Angewandte Chemie (International Edition)},
number = 51,
volume = 58,
place = {United States},
year = {2019},
month = {10}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on October 14, 2020
Publisher's Version of Record

Save / Share:

Works referenced in this record:

The path towards sustainable energy
journal, December 2016

  • Chu, Steven; Cui, Yi; Liu, Nian
  • Nature Materials, Vol. 16, Issue 1
  • DOI: 10.1038/nmat4834

PGM‐Free Cathode Catalysts for PEM Fuel Cells: A Mini‐Review on Stability Challenges
journal, December 2018

  • Shao, Yuyan; Dodelet, Jean‐Pol; Wu, Gang
  • Advanced Materials, Vol. 31, Issue 31
  • DOI: 10.1002/adma.201807615

A review of graphene and graphene oxide sponge: material synthesis and applications to energy and the environment
journal, January 2014

  • Chabot, Victor; Higgins, Drew; Yu, Aiping
  • Energy & Environmental Science, Vol. 7, Issue 5
  • DOI: 10.1039/c3ee43385d

A Sulfur-Limonene-Based Electrode for Lithium-Sulfur Batteries: High-Performance by Self-Protection
journal, February 2018

  • Wu, Feixiang; Chen, Shuangqiang; Srot, Vesna
  • Advanced Materials, Vol. 30, Issue 13
  • DOI: 10.1002/adma.201706643

30 Years of Lithium-Ion Batteries
journal, June 2018


Compositional and orientational control in metal halide perovskites of reduced dimensionality
journal, September 2018

  • Quintero-Bermudez, Rafael; Gold-Parker, Aryeh; Proppe, Andrew H.
  • Nature Materials, Vol. 17, Issue 10
  • DOI: 10.1038/s41563-018-0154-x

Synchrotron X-ray Analytical Techniques for Studying Materials Electrochemistry in Rechargeable Batteries
journal, September 2017


Automotive Li-Ion Batteries: Current Status and Future Perspectives
journal, January 2019


Combining theory and experiment in lithium–sulfur batteries: Current progress and future perspectives
journal, January 2019


High-power all-solid-state batteries using sulfide superionic conductors
journal, March 2016


Promises, Challenges, and Recent Progress of Inorganic Solid-State Electrolytes for All-Solid-State Lithium Batteries
journal, February 2018


Recent advances in all-solid-state rechargeable lithium batteries
journal, March 2017


Lithium battery chemistries enabled by solid-state electrolytes
journal, February 2017


A lithium superionic conductor
journal, July 2011

  • Kamaya, Noriaki; Homma, Kenji; Yamakawa, Yuichiro
  • Nature Materials, Vol. 10, Issue 9, p. 682-686
  • DOI: 10.1038/nmat3066

Design Strategies, Practical Considerations, and New Solution Processes of Sulfide Solid Electrolytes for All-Solid-State Batteries
journal, April 2018

  • Park, Kern Ho; Bai, Qiang; Kim, Dong Hyeon
  • Advanced Energy Materials, Vol. 8, Issue 18
  • DOI: 10.1002/aenm.201800035

Interface Limited Lithium Transport in Solid-State Batteries
journal, December 2013

  • Santhanagopalan, Dhamodaran; Qian, Danna; McGilvray, Thomas
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 2
  • DOI: 10.1021/jz402467x

Anisotropic Lattice Strain and Mechanical Degradation of High- and Low-Nickel NCM Cathode Materials for Li-Ion Batteries
journal, February 2017

  • Kondrakov, Aleksandr O.; Schmidt, Alexander; Xu, Jin
  • The Journal of Physical Chemistry C, Vol. 121, Issue 6
  • DOI: 10.1021/acs.jpcc.6b12885

Chemo-mechanical expansion of lithium electrode materials – on the route to mechanically optimized all-solid-state batteries
journal, January 2018

  • Koerver, Raimund; Zhang, Wenbo; de Biasi, Lea
  • Energy & Environmental Science, Vol. 11, Issue 8
  • DOI: 10.1039/C8EE00907D

(Electro)chemical expansion during cycling: monitoring the pressure changes in operating solid-state lithium batteries
journal, January 2017

  • Zhang, Wenbo; Schröder, Daniel; Arlt, Tobias
  • Journal of Materials Chemistry A, Vol. 5, Issue 20
  • DOI: 10.1039/C7TA02730C

First principles study on electrochemical and chemical stability of solid electrolyte–electrode interfaces in all-solid-state Li-ion batteries
journal, January 2016

  • Zhu, Yizhou; He, Xingfeng; Mo, Yifei
  • Journal of Materials Chemistry A, Vol. 4, Issue 9
  • DOI: 10.1039/C5TA08574H

Interphase formation and degradation of charge transfer kinetics between a lithium metal anode and highly crystalline Li7P3S11 solid electrolyte
journal, March 2016


Solid State Enabled Reversible Four Electron Storage
journal, August 2012

  • Yersak, Thomas A.; Macpherson, H. Alex; Kim, Seul Cham
  • Advanced Energy Materials, Vol. 3, Issue 1
  • DOI: 10.1002/aenm.201200267

High-Energy All-Solid-State Lithium Batteries with Ultralong Cycle Life
journal, October 2016


In Situ Monitoring of Fast Li-Ion Conductor Li 7 P 3 S 11 Crystallization Inside a Hot-Press Setup
journal, August 2016


New, Highly Ion-Conductive Crystals Precipitated from Li2S-P2S5 Glasses
journal, April 2005

  • Mizuno, F.; Hayashi, A.; Tadanaga, K.
  • Advanced Materials, Vol. 17, Issue 7, p. 918-921
  • DOI: 10.1002/adma.200401286

Iron Pyrite/Titanium Dioxide Photoanode for Extended Near Infrared Light Harvesting in a Photoelectrochemical Cell
journal, February 2016

  • Wang, Di-Yan; Li, Cheng-Hung; Li, Shao-Sian
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep20397

Design, characterization, and performance of a hard x-ray transmission microscope at the National Synchrotron Light Source II 18-ID beamline
journal, May 2019

  • Coburn, David Scott; Nazaretski, Evgeny; Xu, Weihe
  • Review of Scientific Instruments, Vol. 90, Issue 5
  • DOI: 10.1063/1.5088124

One-minute nano-tomography using hard X-ray full-field transmission microscope
journal, August 2018

  • Ge, Mingyuan; Coburn, David Scott; Nazaretski, Evgeny
  • Applied Physics Letters, Vol. 113, Issue 8
  • DOI: 10.1063/1.5048378

In Situ Three-Dimensional Synchrotron X-Ray Nanotomography of the (De)lithiation Processes in Tin Anodes
journal, March 2014

  • Wang, Jiajun; Chen-Wiegart, Yu-chen Karen; Wang, Jun
  • Angewandte Chemie International Edition, Vol. 53, Issue 17
  • DOI: 10.1002/anie.201310402

Phase evolution for conversion reaction electrodes in lithium-ion batteries
journal, February 2014

  • Lin, Feng; Nordlund, Dennis; Weng, Tsu-Chien
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms4358