Anisotropically Electrochemical-Mechanical Evolution in Solid-State Batteries and Interfacial Tailored Strategy

Sun, Nan; Liu, Qingsong; Cao, Yi; Lou, Shuaifeng; Ge, Mingyuan; Xiao, Xianghui; Lee, Wah-Keat; Gao, Yunzhi; Yin, Geping; Wang, Jiajun; Sun, Xueliang

doi:10.1002/anie.201910993

Title: Anisotropically Electrochemical-Mechanical Evolution in Solid-State Batteries and Interfacial Tailored Strategy

Journal Article · 13 October 2019 · Angewandte Chemie (International Edition)

DOI: https://doi.org/10.1002/anie.201910993 · OSTI ID:1577426

Sun, Nan ^[1]; Liu, Qingsong ^[1]; Cao, Yi ^[1]; Lou, Shuaifeng ^[1]; Ge, Mingyuan ^[2]; Xiao, Xianghui ^[2]; Lee, Wah-Keat ^[2]; Gao, Yunzhi ^[1]; Yin, Geping ^[1];

^[1]; Sun, Xueliang ^[3]

Harbin Inst. of Technology (China). School of Chemistry and Chemical Engineering, MIIT Key Lab. of Critical Materials Technology for New Energy Conversion and Storage
Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
Univ. of Western Ontario, London, ON (Canada). Dept. of Mechanical and Materials Engineering

All-solid-state batteries have attracted attention owing to the potential high energy density and safety; however, little success has been made on practical applications of solid-state batteries, which is largely attributed to the solid–solid interface issues. A fundamental elucidation of electrode–electrolyte interface behaviors is of crucial significance but has proven difficult. The interfacial resistance and capacity fading issues in a solid-state battery were probed, revealing a heterogeneous phase transition evolution at solid–solid interfaces. The strain-induced interfacial change and the contact loss, as well as a dense metallic surface phase, deteriorate the electrochemical reaction in solid-state batteries. Furthermore, the in situ growth of electrolytes on secondary particles is proposed to fabricate robust solid–solid interface. Finally, our study enlightens new insights into the mechanism behind solid–solid interfacial reaction for optimizing advanced solid-state batteries.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0012704

OSTI ID:: 1577426

Report Number(s):: BNL--212376-2019-JAAM

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 51 Vol. 58; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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