skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on December 2, 2020

Title: A highly active and Cr-resistant infiltrated cathode for practical solid oxide fuel cells

Abstract

An SCT conformally coated LSCF–GDC cathode shows significantly improved ORR activity with a strong Cr-tolerance.

Authors:
ORCiD logo [1]; ORCiD logo [2];  [2];  [2]; ORCiD logo [2]
  1. Department of Mechanical Engineering, University of South Carolina, Columbia, USA, Department of Materials Science and Engineering
  2. Department of Materials Science and Engineering, Northwestern University, Evanston, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Fossil Energy (FE)
OSTI Identifier:
1577384
Grant/Contract Number:  
FE-0031671
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Name: Journal of Materials Chemistry. A Journal Volume: 8 Journal Issue: 1; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Yang, Tianrang, Wen, Yeting, Wu, Tao, Xu, Nansheng, and Huang, Kevin. A highly active and Cr-resistant infiltrated cathode for practical solid oxide fuel cells. United Kingdom: N. p., 2020. Web. doi:10.1039/C9TA11657E.
Yang, Tianrang, Wen, Yeting, Wu, Tao, Xu, Nansheng, & Huang, Kevin. A highly active and Cr-resistant infiltrated cathode for practical solid oxide fuel cells. United Kingdom. doi:10.1039/C9TA11657E.
Yang, Tianrang, Wen, Yeting, Wu, Tao, Xu, Nansheng, and Huang, Kevin. Wed . "A highly active and Cr-resistant infiltrated cathode for practical solid oxide fuel cells". United Kingdom. doi:10.1039/C9TA11657E.
@article{osti_1577384,
title = {A highly active and Cr-resistant infiltrated cathode for practical solid oxide fuel cells},
author = {Yang, Tianrang and Wen, Yeting and Wu, Tao and Xu, Nansheng and Huang, Kevin},
abstractNote = {An SCT conformally coated LSCF–GDC cathode shows significantly improved ORR activity with a strong Cr-tolerance.},
doi = {10.1039/C9TA11657E},
journal = {Journal of Materials Chemistry. A},
number = 1,
volume = 8,
place = {United Kingdom},
year = {2020},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on December 2, 2020
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Enhanced Electrochemical Activity and Chromium Tolerance of the Nucleation-Agent-Free La2Ni0.9Fe0.1O4+δ Cathode by Gd0.1Ce0.9O1.95 Incorporation
journal, March 2018


Surface strontium enrichment on highly active perovskites for oxygen electrocatalysis in solid oxide fuel cells
journal, January 2012

  • Crumlin, Ethan J.; Mutoro, Eva; Liu, Zhi
  • Energy & Environmental Science, Vol. 5, Issue 3
  • DOI: 10.1039/c2ee03397f

Lowering the Temperature of Solid Oxide Fuel Cells
journal, November 2011


Solid oxide fuel cell cathodes prepared by infiltration of LaNi0.6Fe0.4O3 and La0.91Sr0.09Ni0.6Fe0.4O3 in porous yttria-stabilized zirconia
journal, September 2009


Chromium Deposition and Poisoning at Ba0.5Sr0.5Co0.8Fe0.2O3−δ Cathode of Solid Oxide Fuel Cells
journal, January 2011

  • Kim, Yu−Mi; Chen, Xinbing; Jiang, San Ping
  • Electrochemical and Solid-State Letters, Vol. 14, Issue 4
  • DOI: 10.1149/1.3549169

Investigation of surface Sr segregation in model thin film solid oxidefuel cell perovskite electrodes
journal, January 2012

  • Jung, WooChul; Tuller, Harry L.
  • Energy Environ. Sci., Vol. 5, Issue 1
  • DOI: 10.1039/C1EE02762J

Synergistic effects of temperature and polarization on Cr poisoning of La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3−δ solid oxide fuel cell cathodes
journal, January 2019

  • Ni, Na; Wang, Cheng Cheng; Jiang, San Ping
  • Journal of Materials Chemistry A, Vol. 7, Issue 15
  • DOI: 10.1039/C9TA01275C

A perspective on low-temperature solid oxide fuel cells
journal, January 2016

  • Gao, Zhan; Mogni, Liliana V.; Miller, Elizabeth C.
  • Energy & Environmental Science, Vol. 9, Issue 5
  • DOI: 10.1039/C5EE03858H

Low-temperature SOFCs based on Gd0.1Ce0.9O1.95 fabricated by dry pressing
journal, December 2001


Recent Advances in the Understanding of the Evolution of Surfaces and Interfaces in Solid Oxide Cells
journal, June 2019


Chromium poisoning and degradation at Gd0.2Ce0.8O2-impregnated LaNi0.6Fe0.4O3−δ cathode for solid oxide fuel cell
journal, October 2012


Mitigating Cr Contamination by Hot Air Filtering in Solid Oxide Fuel Cells
journal, January 2011

  • Schuler, J. Andreas; Schuler, Albert J.; Penner, Dirk
  • Electrochemical and Solid-State Letters, Vol. 14, Issue 12, p. B132-B134
  • DOI: 10.1149/2.002112esl

Stabilizing Nanostructured Solid Oxide Fuel Cell Cathode with Atomic Layer Deposition
journal, August 2013

  • Gong, Yunhui; Palacio, Diego; Song, Xueyan
  • Nano Letters, Vol. 13, Issue 9
  • DOI: 10.1021/nl402138w

Ta-Doped SrCoO 3−δ as a promising bifunctional oxygen electrode for reversible solid oxide fuel cells: a focused study on stability
journal, January 2017

  • Wang, Jie; Yang, Tianrang; Lei, Libin
  • Journal of Materials Chemistry A, Vol. 5, Issue 19
  • DOI: 10.1039/C7TA02003A

3D core–shell architecture from infiltration and beneficial reactive sintering as highly efficient and thermally stable oxygen reduction electrode
journal, January 2014

  • Chen, Dengjie; Yang, Guangming; Ciucci, Francesco
  • J. Mater. Chem. A, Vol. 2, Issue 5
  • DOI: 10.1039/C3TA13253F

Cation Size Mismatch and Charge Interactions Drive Dopant Segregation at the Surfaces of Manganite Perovskites
journal, May 2013

  • Lee, Wonyoung; Han, Jeong Woo; Chen, Yan
  • Journal of the American Chemical Society, Vol. 135, Issue 21
  • DOI: 10.1021/ja3125349

Mechanism of La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3 cathode degradation
journal, July 2012

  • Oh, Dongjo; Gostovic, Danijel; Wachsman, Eric D.
  • Journal of Materials Research, Vol. 27, Issue 15
  • DOI: 10.1557/jmr.2012.222

Improving La0.6Sr0.4Co0.2Fe0.8O3−δ cathode performance by infiltration of a Sm0.5Sr0.5CoO3−δ coating
journal, October 2009


Oxidation energies of transition metal oxides within the GGA + U framework
journal, May 2006


Strontium Manganese Oxide Getter for Capturing Airborne Cr and S Contaminants in High-Temperature Electrochemical Systems
journal, June 2019

  • Hong, Junsung; Aphale, Ashish N.; Heo, Su Jeong
  • ACS Applied Materials & Interfaces, Vol. 11, Issue 38
  • DOI: 10.1021/acsami.9b09677

Systematic x-ray photoelectron spectroscopic study of La1?xSrx-based perovskite-type oxides
journal, January 2002

  • van der Heide, P. A. W.
  • Surface and Interface Analysis, Vol. 33, Issue 5
  • DOI: 10.1002/sia.1227

Physicochemical compatibility of CGO fluorite, LSM and LSCF perovskite electrode materials with La2Mo2O9 fast oxide-ion conductor
journal, October 2005


Trends in Stability of Perovskite Oxides
journal, September 2010

  • Calle-Vallejo, Federico; Martínez, José I.; García-Lastra, Juan M.
  • Angewandte Chemie International Edition, Vol. 49, Issue 42
  • DOI: 10.1002/anie.201002301

Synthesis and Stability of Sr x Ni y O z Chromium Getter for Solid Oxide Fuel Cells
journal, January 2018

  • Aphale, Ashish; Uddin, Md Aman; Hu, Boxun
  • Journal of The Electrochemical Society, Vol. 165, Issue 9
  • DOI: 10.1149/2.0811809jes

La(Ni,Fe)O3 as a cathode material with high tolerance to chromium poisoning for solid oxide fuel cells
journal, June 2007


Highly chromium contaminant tolerant BaO infiltrated La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3−δ cathodes for solid oxide fuel cells
journal, January 2015

  • Chen, Kongfa; Ai, Na; O'Donnell, Kane M.
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 7
  • DOI: 10.1039/C4CP04172K