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Title: Nonmetallic metal toward a pressure-induced bad-metal state in two-dimensional Cu 3 LiRu 2 O 6

Abstract

The two-dimensional honeycomb layered nonmetallic metal Cu 3 LiRu 2 O 6 exhibits Pauli-like paramagnetic and Mott variable range hopping semiconduction behaviors, which can be significantly suppressed toward a bad-metal state by pressure up to 35 GPa.

Authors:
 [1];  [2];  [1];  [1];  [1]; ORCiD logo [3]; ORCiD logo [3];  [4];  [5];  [6];  [6];  [7]; ORCiD logo [7];  [8];  [2];  [8]; ORCiD logo [8]; ORCiD logo [1]
  1. Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, P. R. China
  2. Beijing National Laboratory for Condensed Matter Physics and Institute of Physics, Chinese Academy of Sciences, Beijing 100190, P. R. China
  3. Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, Piscataway, USA
  4. Department of Physics and Astronomy, Rutgers, The State University of New Jersey, Piscataway, USA
  5. Materials Measurement Science Division, Material Measurement Laboratory, National Institute of Standards and Technology, Gaithersburg, USA
  6. Department of Physics, New Jersey Institute of Technology, Newark, USA
  7. College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China
  8. Beijing National Laboratory for Condensed Matter Physics and Institute of Physics, Chinese Academy of Sciences, Beijing 100190, P. R. China, School of Physical Sciences
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1577379
Grant/Contract Number:  
SC0012704
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Name: ChemComm Journal Volume: 56 Journal Issue: 2; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Huang, Bin, Liu, Ziyi, Han, Yifeng, Zhao, Shuang, Wu, Meixia, Frank, Corey E., Greenblatt, Martha, Croft, Mark, Quackenbush, Nicholas F., Liu, Sizhan, Tyson, Trevor A., Zhang, Lei, Sun, Junliang, Shan, Pengfei, Dai, Jianhong, Yu, Xiaohui, Cheng, Jinguang, and Li, Man-Rong. Nonmetallic metal toward a pressure-induced bad-metal state in two-dimensional Cu 3 LiRu 2 O 6. United Kingdom: N. p., 2020. Web. doi:10.1039/C9CC06691H.
Huang, Bin, Liu, Ziyi, Han, Yifeng, Zhao, Shuang, Wu, Meixia, Frank, Corey E., Greenblatt, Martha, Croft, Mark, Quackenbush, Nicholas F., Liu, Sizhan, Tyson, Trevor A., Zhang, Lei, Sun, Junliang, Shan, Pengfei, Dai, Jianhong, Yu, Xiaohui, Cheng, Jinguang, & Li, Man-Rong. Nonmetallic metal toward a pressure-induced bad-metal state in two-dimensional Cu 3 LiRu 2 O 6. United Kingdom. doi:10.1039/C9CC06691H.
Huang, Bin, Liu, Ziyi, Han, Yifeng, Zhao, Shuang, Wu, Meixia, Frank, Corey E., Greenblatt, Martha, Croft, Mark, Quackenbush, Nicholas F., Liu, Sizhan, Tyson, Trevor A., Zhang, Lei, Sun, Junliang, Shan, Pengfei, Dai, Jianhong, Yu, Xiaohui, Cheng, Jinguang, and Li, Man-Rong. Wed . "Nonmetallic metal toward a pressure-induced bad-metal state in two-dimensional Cu 3 LiRu 2 O 6". United Kingdom. doi:10.1039/C9CC06691H.
@article{osti_1577379,
title = {Nonmetallic metal toward a pressure-induced bad-metal state in two-dimensional Cu 3 LiRu 2 O 6},
author = {Huang, Bin and Liu, Ziyi and Han, Yifeng and Zhao, Shuang and Wu, Meixia and Frank, Corey E. and Greenblatt, Martha and Croft, Mark and Quackenbush, Nicholas F. and Liu, Sizhan and Tyson, Trevor A. and Zhang, Lei and Sun, Junliang and Shan, Pengfei and Dai, Jianhong and Yu, Xiaohui and Cheng, Jinguang and Li, Man-Rong},
abstractNote = {The two-dimensional honeycomb layered nonmetallic metal Cu 3 LiRu 2 O 6 exhibits Pauli-like paramagnetic and Mott variable range hopping semiconduction behaviors, which can be significantly suppressed toward a bad-metal state by pressure up to 35 GPa.},
doi = {10.1039/C9CC06691H},
journal = {ChemComm},
number = 2,
volume = 56,
place = {United Kingdom},
year = {2020},
month = {1}
}

Journal Article:
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