Nonmetallic metal toward a pressure-induced bad-metal state in two-dimensional Cu 3 LiRu 2 O 6

Huang, Bin; Liu, Ziyi; Han, Yifeng; Zhao, Shuang; Wu, Meixia; Frank, Corey E.; Greenblatt, Martha; Croft, Mark; Quackenbush, Nicholas F.; Liu, Sizhan; Tyson, Trevor A.; Zhang, Lei; Sun, Junliang; Shan, Pengfei; Dai, Jianhong; Yu, Xiaohui; Cheng, Jinguang; Li, Man-Rong

doi:10.1039/C9CC06691H

Title: Nonmetallic metal toward a pressure-induced bad-metal state in two-dimensional Cu ₃ LiRu ₂ O ₆

Journal Article · 31 December 2019 · ChemComm

DOI: https://doi.org/10.1039/C9CC06691H · OSTI ID:1577379

Huang, Bin ^[1]; Liu, Ziyi ^[2]; Han, Yifeng ^[1]; Zhao, Shuang ^[1]; Wu, Meixia ^[1];

^[3];

^[3]; Croft, Mark ^[4]; Quackenbush, Nicholas F. ^[5]; Liu, Sizhan ^[6]; Tyson, Trevor A. ^[6]; Zhang, Lei ^[7];

^[7]; Shan, Pengfei ^[8]; Dai, Jianhong ^[2]; Yu, Xiaohui ^[8];

^[8];

^[1]

Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, P. R. China
Beijing National Laboratory for Condensed Matter Physics and Institute of Physics, Chinese Academy of Sciences, Beijing 100190, P. R. China
Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, Piscataway, USA
Department of Physics and Astronomy, Rutgers, The State University of New Jersey, Piscataway, USA
Materials Measurement Science Division, Material Measurement Laboratory, National Institute of Standards and Technology, Gaithersburg, USA
Department of Physics, New Jersey Institute of Technology, Newark, USA
College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China
Beijing National Laboratory for Condensed Matter Physics and Institute of Physics, Chinese Academy of Sciences, Beijing 100190, P. R. China, School of Physical Sciences

The two-dimensional honeycomb layered nonmetallic metal Cu ₃ LiRu ₂ O ₆ exhibits Pauli-like paramagnetic and Mott variable range hopping semiconduction behaviors, which can be significantly suppressed toward a bad-metal state by pressure up to 35 GPa.

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Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704

OSTI ID:: 1577379

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 2 Vol. 56; ISSN CHCOFS; ISSN 1359-7345

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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Title: Nonmetallic metal toward a pressure-induced bad-metal state in two-dimensional Cu ₃ LiRu ₂ O ₆