skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on December 5, 2020

Title: Chromophore amphiphile–polyelectrolyte hybrid hydrogels for photocatalytic hydrogen production

Abstract

Incorporating supramolecular assemblies of chromophore amphiphiles into covalent hydrogels creates a reusable, robust host for photocatalysis.

Authors:
ORCiD logo [1]; ORCiD logo [2];  [2];  [2];  [3];  [2];  [2];  [2]; ORCiD logo [4]; ORCiD logo [5]; ORCiD logo [1]
  1. Simpson Querrey Institute, Northwestern University, Chicago, USA, Department of Materials Science and Engineering
  2. Department of Materials Science and Engineering, Evanston, USA
  3. Department of Chemistry, Northwestern University, Evanston, USA
  4. Simpson Querrey Institute, Northwestern University, Chicago, USA, Department of Chemistry
  5. Department of Materials Science and Engineering, Evanston, USA, Department of Chemistry, Northwestern University
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1577206
Grant/Contract Number:  
SC0000989
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Name: Journal of Materials Chemistry. A Journal Volume: 8 Journal Issue: 1; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Sai, Hiroaki, Erbas, Aykut, Dannenhoffer, Adam, Huang, Dongxu, Weingarten, Adam, Siismets, Erica, Jang, Kyujin, Qu, Karen, Palmer, Liam C., Olvera de la Cruz, Monica, and Stupp, Samuel I. Chromophore amphiphile–polyelectrolyte hybrid hydrogels for photocatalytic hydrogen production. United Kingdom: N. p., 2020. Web. doi:10.1039/C9TA08974H.
Sai, Hiroaki, Erbas, Aykut, Dannenhoffer, Adam, Huang, Dongxu, Weingarten, Adam, Siismets, Erica, Jang, Kyujin, Qu, Karen, Palmer, Liam C., Olvera de la Cruz, Monica, & Stupp, Samuel I. Chromophore amphiphile–polyelectrolyte hybrid hydrogels for photocatalytic hydrogen production. United Kingdom. doi:10.1039/C9TA08974H.
Sai, Hiroaki, Erbas, Aykut, Dannenhoffer, Adam, Huang, Dongxu, Weingarten, Adam, Siismets, Erica, Jang, Kyujin, Qu, Karen, Palmer, Liam C., Olvera de la Cruz, Monica, and Stupp, Samuel I. Wed . "Chromophore amphiphile–polyelectrolyte hybrid hydrogels for photocatalytic hydrogen production". United Kingdom. doi:10.1039/C9TA08974H.
@article{osti_1577206,
title = {Chromophore amphiphile–polyelectrolyte hybrid hydrogels for photocatalytic hydrogen production},
author = {Sai, Hiroaki and Erbas, Aykut and Dannenhoffer, Adam and Huang, Dongxu and Weingarten, Adam and Siismets, Erica and Jang, Kyujin and Qu, Karen and Palmer, Liam C. and Olvera de la Cruz, Monica and Stupp, Samuel I.},
abstractNote = {Incorporating supramolecular assemblies of chromophore amphiphiles into covalent hydrogels creates a reusable, robust host for photocatalysis.},
doi = {10.1039/C9TA08974H},
journal = {Journal of Materials Chemistry. A},
number = 1,
volume = 8,
place = {United Kingdom},
year = {2020},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on December 5, 2020
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Charge migration in supramolecular stacks of peripherally substituted porphyrins
journal, October 1991

  • Schouten, Pieter G.; Warman, John M.; de Haas, Matthijs P.
  • Nature, Vol. 353, Issue 6346
  • DOI: 10.1038/353736a0

Photoinduced electron transfer in supramolecular systems for artificial photosynthesis
journal, May 1992

  • Wasielewski, Michael R.
  • Chemical Reviews, Vol. 92, Issue 3, p. 435-461
  • DOI: 10.1021/cr00011a005

New Benchmark for Water Photooxidation by Nanostructured α-Fe 2 O 3 Films
journal, December 2006

  • Kay, Andreas; Cesar, Ilkay; Grätzel, Michael
  • Journal of the American Chemical Society, Vol. 128, Issue 49
  • DOI: 10.1021/ja064380l

Controlled Self-Assembly of Photofunctional Supramolecular Nanotubes
journal, December 2017


Energy and environment policy case for a global project on artificial photosynthesis
journal, January 2013

  • Faunce, Thomas A.; Lubitz, Wolfgang; Rutherford, A. W. (Bill)
  • Energy & Environmental Science, Vol. 6, Issue 3
  • DOI: 10.1039/c3ee00063j

Fast Parallel Algorithms for Short-Range Molecular Dynamics
journal, March 1995


Molecular Materials by Self-Assembly of Porphyrins, Phthalocyanines, and Perylenes
journal, May 2006

  • Elemans, J. A. A. W.; van Hameren, R.; Nolte, R. J. M.
  • Advanced Materials, Vol. 18, Issue 10
  • DOI: 10.1002/adma.200502498

Extended-Charge-Transfer Excitons in Crystalline Supramolecular Photocatalytic Scaffolds
journal, September 2016

  • Hestand, Nicholas J.; Kazantsev, Roman V.; Weingarten, Adam S.
  • Journal of the American Chemical Society, Vol. 138, Issue 36
  • DOI: 10.1021/jacs.6b05673

Function of the Two Cytochrome Components in Chloroplasts: A Working Hypothesis
journal, April 1960


Three-dimensional structure of cyanobacterial photosystem I at 2.5 Å resolution
journal, June 2001

  • Jordan, Patrick; Fromme, Petra; Witt, Horst Tobias
  • Nature, Vol. 411, Issue 6840
  • DOI: 10.1038/35082000

Self-Healing Materials Formed by Cross-Linked Polyrotaxanes with Reversible Bonds
journal, November 2016


Energy landscapes and functions of supramolecular systems
journal, January 2016

  • Tantakitti, Faifan; Boekhoven, Job; Wang, Xin
  • Nature Materials, Vol. 15, Issue 4
  • DOI: 10.1038/nmat4538

Visualization of Membrane Rafts Using a Perylene Monoimide Derivative and Fluorescence Lifetime Imaging
journal, October 2007


A metal-free polymeric photocatalyst for hydrogen production from water under visible light
journal, November 2008

  • Wang, Xinchen; Maeda, Kazuhiko; Thomas, Arne
  • Nature Materials, Vol. 8, Issue 1
  • DOI: 10.1038/nmat2317

In Situ Formation of an Oxygen-Evolving Catalyst in Neutral Water Containing Phosphate and Co2+
journal, August 2008


Elastic Modulus and Equilibrium Swelling of Polyelectrolyte Gels
journal, January 1996

  • Rubinstein, Michael; Colby, Ralph H.; Dobrynin, Andrey V.
  • Macromolecules, Vol. 29, Issue 1
  • DOI: 10.1021/ma9511917

Tunable Organic Photocatalysts for Visible-Light-Driven Hydrogen Evolution
journal, February 2015

  • Sprick, Reiner Sebastian; Jiang, Jia-Xing; Bonillo, Baltasar
  • Journal of the American Chemical Society, Vol. 137, Issue 9
  • DOI: 10.1021/ja511552k

Supported molybdenum–sulfur cluster compounds as precursors for HDS catalysts
journal, May 2001


Soft Photocatalysis: Organic Polymers for Solar Fuel Production
journal, July 2016


Swelling Equilibria and Volume Phase Transition in Hydrogels with Strongly Dissociating Electrolytes
journal, May 1994


Architecture of the Photosynthetic Oxygen-Evolving Center
journal, March 2004


Quantification of photosystem I and II in different parts of the thylakoid membrane from spinach
journal, January 2004

  • Danielsson, Ravi; Albertsson, Per-Åke; Mamedov, Fikret
  • Biochimica et Biophysica Acta (BBA) - Bioenergetics, Vol. 1608, Issue 1
  • DOI: 10.1016/j.bbabio.2003.10.005

Liquid crystalline perylene-3,4-dicarboximide derivatives with high thermal and photochemical stability
journal, January 1998

  • Müller, Gert R. J.; Meiners, Christian; Enkelmann, Volker
  • Journal of Materials Chemistry, Vol. 8, Issue 1
  • DOI: 10.1039/a705910h

Versatile Photocatalytic Systems for H 2 Generation in Water Based on an Efficient DuBois-Type Nickel Catalyst
journal, December 2013

  • Gross, Manuela A.; Reynal, Anna; Durrant, James R.
  • Journal of the American Chemical Society, Vol. 136, Issue 1
  • DOI: 10.1021/ja410592d

Self-Assembled PDINH Supramolecular System for Photocatalysis under Visible Light
journal, June 2016


Self-assembling hydrogel scaffolds for photocatalytic hydrogen production
journal, October 2014

  • Weingarten, Adam S.; Kazantsev, Roman V.; Palmer, Liam C.
  • Nature Chemistry, Vol. 6, Issue 11
  • DOI: 10.1038/nchem.2075

Functional Supramolecular Porphyrin–Dendrimer Assemblies for Light Harvesting and Photocatalysis
journal, April 2017


Molecular Control of Internal Crystallization and Photocatalytic Function in Supramolecular Nanostructures
journal, July 2018


Building an appropriate active-site motif into a hydrogen-evolution catalyst with thiomolybdate [Mo3S13]2− clusters
journal, January 2014

  • Kibsgaard, Jakob; Jaramillo, Thomas F.; Besenbacher, Flemming
  • Nature Chemistry, Vol. 6, Issue 3
  • DOI: 10.1038/nchem.1853

Chromophore Dipole Directs Morphology and Photocatalytic Hydrogen Generation
journal, April 2018

  • Weingarten, Adam S.; Dannenhoffer, Adam J.; Kazantsev, Roman V.
  • Journal of the American Chemical Society, Vol. 140, Issue 15
  • DOI: 10.1021/jacs.7b12641

Swelling Equilibria of Hydrogels with Sulfonate Groups in Water and in Aqueous Salt Solutions
journal, May 1995


Supramolecular Linear Heterojunction Composed of Graphite-Like Semiconducting Nanotubular Segments
journal, October 2011


Molecular Packing of Amphiphilic Nanosheets Resolved by X-ray Scattering
journal, January 2017

  • Harutyunyan, Boris; Dannenhoffer, Adam; Kewalramani, Sumit
  • The Journal of Physical Chemistry C, Vol. 121, Issue 2
  • DOI: 10.1021/acs.jpcc.6b11391

Linking Molybdenum–Sulfur Clusters for Electrocatalytic Hydrogen Evolution
journal, September 2018

  • Ji, Zhe; Trickett, Christopher; Pei, Xiaokun
  • Journal of the American Chemical Society, Vol. 140, Issue 42
  • DOI: 10.1021/jacs.8b09807

Robust Photogeneration of H2 in Water Using Semiconductor Nanocrystals and a Nickel Catalyst
journal, November 2012


Brownian Dynamics Simulation Study of Self-Diffusion of a Charged Particle in Swollen Counter-Charged Hydrogel Modeled as Cubic Lattice
journal, January 2002

  • Miyata, Tatsuhiko; Endo, Akira; Ohmori, Takao
  • JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, Vol. 35, Issue 7
  • DOI: 10.1252/jcej.35.640

Self-healing and thermoreversible rubber from supramolecular assembly
journal, February 2008

  • Cordier, Philippe; Tournilhac, François; Soulié-Ziakovic, Corinne
  • Nature, Vol. 451, Issue 7181, p. 977-980
  • DOI: 10.1038/nature06669

Ionic Conductivity in Polyelectrolyte Hydrogels
journal, November 2016


Energy Conversion in Polyelectrolyte Hydrogels
journal, July 2015


Visualizing the dynamic structure of the plant photosynthetic membrane
journal, November 2015


Artificial photosynthesis for solar fuels
journal, January 2012


Pathway complexity in supramolecular polymerization
journal, January 2012

  • Korevaar, Peter A.; George, Subi J.; Markvoort, Albert J.
  • Nature, Vol. 481, Issue 7382
  • DOI: 10.1038/nature10720

Supramolecular Packing Controls H 2 Photocatalysis in Chromophore Amphiphile Hydrogels
journal, November 2015

  • Weingarten, Adam S.; Kazantsev, Roman V.; Palmer, Liam C.
  • Journal of the American Chemical Society, Vol. 137, Issue 48
  • DOI: 10.1021/jacs.5b10027

Crystal-Phase Transitions and Photocatalysis in Supramolecular Scaffolds
journal, April 2017

  • Kazantsev, Roman V.; Dannenhoffer, Adam J.; Weingarten, Adam S.
  • Journal of the American Chemical Society, Vol. 139, Issue 17
  • DOI: 10.1021/jacs.6b13156

Conjugated Polymer Hydrogel Photocatalysts with Expandable Photoactive Sites in Water
journal, April 2019


Long-range energy transport in single supramolecular nanofibres at room temperature
journal, July 2015

  • Haedler, Andreas T.; Kreger, Klaus; Issac, Abey
  • Nature, Vol. 523, Issue 7559
  • DOI: 10.1038/nature14570

Equilibrium swelling properties of polyampholytic hydrogels
journal, June 1996

  • English, Anthony E.; Mafé, Salvador; Manzanares, José A.
  • The Journal of Chemical Physics, Vol. 104, Issue 21
  • DOI: 10.1063/1.471560

Impact of charge switching stimuli on supramolecular perylene monoimide assemblies
journal, January 2019

  • Dannenhoffer, Adam; Sai, Hiroaki; Huang, Dongxu
  • Chemical Science, Vol. 10, Issue 22
  • DOI: 10.1039/C8SC05595E

Hydrogen evolution catalysis by molybdenum sulfides (MoS x ): are thiomolybdate clusters like [Mo 3 S 13 ] 2− suitable active site models?
journal, January 2018

  • Grutza, Marie-Luise; Rajagopal, Ashwene; Streb, Carsten
  • Sustainable Energy & Fuels, Vol. 2, Issue 9
  • DOI: 10.1039/C8SE00155C