Blue Light Emitting Defective Nanocrystals Composed of Earth‐Abundant Elements

doi:10.1002/ange.201911436

Title: Blue Light Emitting Defective Nanocrystals Composed of Earth‐Abundant Elements

Authors:

^[1];

^[2];

^[1];

^[2];

^[1]

Department of ChemistryMassachusetts Institute of Technology 77 Massachusetts Avenue Cambridge MA 02139 USA
Department of Materials Science and EngineeringMassachusetts Institute of Technology 77 Massachusetts Avenue Cambridge MA 02139 USA

Publication Date:: 2019-12-03

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1577004

Grant/Contract Number:: FG02-07ER46454; AC02-05CH11231

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Angewandte Chemie

Additional Journal Information:: Journal Name: Angewandte Chemie Journal Volume: 132 Journal Issue: 2; Journal ID: ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Hansen, Eric C., Liu, Yun, Utzat, Hendrik, Bertram, Sophie N., Grossman, Jeffrey C., and Bawendi, Moungi G. Blue Light Emitting Defective Nanocrystals Composed of Earth‐Abundant Elements.  Germany: N. p., 2019. 
        Web.  doi:10.1002/ange.201911436.

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                    Hansen, Eric C., Liu, Yun, Utzat, Hendrik, Bertram, Sophie N., Grossman, Jeffrey C., & Bawendi, Moungi G. Blue Light Emitting Defective Nanocrystals Composed of Earth‐Abundant Elements.  Germany.  doi:10.1002/ange.201911436.

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                    Hansen, Eric C., Liu, Yun, Utzat, Hendrik, Bertram, Sophie N., Grossman, Jeffrey C., and Bawendi, Moungi G. Tue .  
        "Blue Light Emitting Defective Nanocrystals Composed of Earth‐Abundant Elements".  Germany.  doi:10.1002/ange.201911436.

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@article{osti_1577004,

  title        = {Blue Light Emitting Defective Nanocrystals Composed of Earth‐Abundant Elements},

  author       = {Hansen, Eric C. and Liu, Yun and Utzat, Hendrik and Bertram, Sophie N. and Grossman, Jeffrey C. and Bawendi, Moungi G.},

  abstractNote = {},

  doi          = {10.1002/ange.201911436},

  journal      = {Angewandte Chemie},

  number       = 2,

  volume       = 132,

  place        = {Germany},

  year         = {2019},

  month        = {12}

}

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DOI: 10.1002/ange.201911436

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Title: Blue Light Emitting Defective Nanocrystals Composed of Earth‐Abundant Elements

Citation Formats

Ternary I−III−VI Quantum Dots Luminescent in the Red to Near-Infrared journal, July 2008

Generalized Gradient Approximation Made Simple journal, October 1996

Spectro-electrochemical Probing of Intrinsic and Extrinsic Processes in Exciton Recombination in I–III–VI 2 Nanocrystals journal, June 2017

Efficient White-Light-Emitting Diodes Fabricated from Highly Fluorescent Copper Indium Sulfide Core/Shell Quantum Dots journal, May 2012

Zinc Thiolate Enables Bright Cu‐Deficient Cu‐In‐S/ZnS Quantum Dots journal, April 2019

Single-Particle Photoluminescence Spectra, Blinking, and Delayed Luminescence of Colloidal CuInS 2 Nanocrystals journal, July 2016

Highly efficient large-area colourless luminescent solar concentrators using heavy-metal-free colloidal quantum dots journal, August 2015

Electrostatic interactions between charged defects in supercells journal, December 2010

Excitonic pathway to photoinduced magnetism in colloidal nanocrystals with nonmagnetic dopants journal, December 2017

Fully Ab Initio Finite-Size Corrections for Charged-Defect Supercell Calculations journal, January 2009

From ultrasoft pseudopotentials to the projector augmented-wave method journal, January 1999

Solid-state infrared-to-visible upconversion sensitized by colloidal nanocrystals journal, November 2015

Defect physics of CuGaS 2 journal, May 2010

Luminescent Colloidal Semiconductor Nanocrystals Containing Copper: Synthesis, Photophysics, and Applications journal, May 2016

Photoluminescence Studies in CuAlS 2 :Zn journal, October 1993

Efficient Synthesis of Highly Luminescent Copper Indium Sulfide-Based Core/Shell Nanocrystals with Surprisingly Long-Lived Emission journal, February 2011

Colloidal quantum-dot light-emitting diodes with metal-oxide charge transport layers journal, March 2008

Light Emission Mechanisms in CuInS 2 Quantum Dots Evaluated by Spectral Electrochemistry journal, September 2017

Defect physics of the CuInSe 2 chalcopyrite semiconductor journal, April 1998

Formation of High-Quality I−III−VI Semiconductor Nanocrystals by Tuning Relative Reactivity of Cationic Precursors journal, April 2009

Chemistry of defect induced photoluminescence in chalcopyrites: The case of CuAlS2 journal, January 2011

Computational Studies of the Electronic Structures of Copper-Doped CdSe Nanocrystals: Oxidation States, Jahn–Teller Distortions, Vibronic Bandshapes, and Singlet–Triplet Splittings journal, January 2016

Synthesis and Photoluminescence of Cd 1- x Mn x S ( x ≤ 5) Nanocrystals journal, July 1998

Visible photoluminescence of Zn‐doped CuAlS 2 journal, August 1992

Valence-Band Electronic Structures of Cu + -Doped ZnS, Alloyed Cu–In–Zn–S, and Ternary CuInS 2 Nanocrystals: A Unified Description of Photoluminescence across Compositions journal, July 2018

First-principles study of CuAlS 2 for p-type transparent conductive materials journal, September 2010

The nitrogen-vacancy colour centre in diamond journal, July 2013

Doped Nanocrystals journal, March 2008

Optical Transparency Enabled by Anomalous Stokes Shift in Visible Light-Emitting CuAlS 2 -Based Quantum Dots journal, July 2018

Triplet Sensitization by “Self-Trapped” Excitons of Nontoxic CuInS 2 Nanocrystals for Efficient Photon Upconversion journal, August 2019

Zur Kenntnis des Aluminiumsulfids: α-Al2S3 und Al2S3(tetr.) / On Aluminium Sulfide: α-Al2S3 and Al2S3 (tetr.) journal, May 1981

Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set journal, July 1996

High-Performance CuInS 2 Quantum Dot Laminated Glass Luminescent Solar Concentrators for Windows journal, January 2018

Bright CuInS 2 /CdS nanocrystal phosphors for high-gain full-spectrum luminescent solar concentrators journal, January 2015

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set journal, October 1996

Synthesis of CuInS 2 , CuInSe 2 , and Cu(In x Ga 1- x )Se 2 (CIGS) Nanocrystal “Inks” for Printable Photovoltaics journal, December 2008

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Analysis of Optical Losses in High-Efficiency CuInS 2 -Based Nanocrystal Luminescent Solar Concentrators: Balancing Absorption versus Scattering journal, February 2017

Thermodynamics and kinetics of the copper vacancy in CuInSe2, CuGaSe2, CuInS2, and CuGaS2 from screened-exchange hybrid density functional theory journal, July 2010

Nanocrystalline Chalcopyrite Materials (CuInS 2 and CuInSe 2 ) via Low-Temperature Pyrolysis of Molecular Single-Source Precursors journal, August 2003

Magneto-Optical Properties of CuInS 2 Nanocrystals journal, November 2014

Improved performance and stability in quantum dot solar cells through band alignment engineering journal, May 2014

Quality Factor of Luminescent Solar Concentrators and Practical Concentration Limits Attainable with Semiconductor Quantum Dots journal, May 2016

Next-generation in vivo optical imaging with short-wave infrared quantum dots journal, April 2017

Rationale for mixing exact exchange with density functional approximations journal, December 1996

Thick-Shell CuInS 2 /ZnS Quantum Dots with Suppressed “Blinking” and Narrow Single-Particle Emission Line Widths journal, February 2017

Efficient Photosynthesis of Organics from Aqueous Bicarbonate Ions by Quantum Dots Using Visible Light journal, June 2018

Two Distinct Transitions in Cu x InS 2 Quantum Dots. Bandgap versus Sub-Bandgap Excitations in Copper-Deficient Structures journal, April 2016

Singlet–Triplet Splittings in the Luminescent Excited States of Colloidal Cu + :CdSe, Cu + :InP, and CuInS 2 Nanocrystals: Charge-Transfer Configurations and Self-Trapped Excitons journal, September 2015

Optical properties of Mn-doped CdS nanocrystals journal, February 1996

Ternary I−III−VI Quantum Dots Luminescent in the Red to Near-Infrared
journal, July 2008

Generalized Gradient Approximation Made Simple
journal, October 1996

Spectro-electrochemical Probing of Intrinsic and Extrinsic Processes in Exciton Recombination in I–III–VI ₂ Nanocrystals
journal, June 2017

Efficient White-Light-Emitting Diodes Fabricated from Highly Fluorescent Copper Indium Sulfide Core/Shell Quantum Dots
journal, May 2012

Zinc Thiolate Enables Bright Cu‐Deficient Cu‐In‐S/ZnS Quantum Dots
journal, April 2019

Single-Particle Photoluminescence Spectra, Blinking, and Delayed Luminescence of Colloidal CuInS ₂ Nanocrystals
journal, July 2016

Highly efficient large-area colourless luminescent solar concentrators using heavy-metal-free colloidal quantum dots
journal, August 2015

Electrostatic interactions between charged defects in supercells
journal, December 2010

Excitonic pathway to photoinduced magnetism in colloidal nanocrystals with nonmagnetic dopants
journal, December 2017

Fully Ab Initio Finite-Size Corrections for Charged-Defect Supercell Calculations
journal, January 2009

From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999

Solid-state infrared-to-visible upconversion sensitized by colloidal nanocrystals
journal, November 2015

Defect physics of ${CuGaS}_{2}$
journal, May 2010

Luminescent Colloidal Semiconductor Nanocrystals Containing Copper: Synthesis, Photophysics, and Applications
journal, May 2016

Photoluminescence Studies in CuAlS ₂ :Zn
journal, October 1993

Efficient Synthesis of Highly Luminescent Copper Indium Sulfide-Based Core/Shell Nanocrystals with Surprisingly Long-Lived Emission
journal, February 2011

Colloidal quantum-dot light-emitting diodes with metal-oxide charge transport layers
journal, March 2008

Light Emission Mechanisms in CuInS ₂ Quantum Dots Evaluated by Spectral Electrochemistry
journal, September 2017

Defect physics of the ${CuInSe}_{2}$ chalcopyrite semiconductor
journal, April 1998

Formation of High-Quality I−III−VI Semiconductor Nanocrystals by Tuning Relative Reactivity of Cationic Precursors
journal, April 2009

Chemistry of defect induced photoluminescence in chalcopyrites: The case of CuAlS2
journal, January 2011

Computational Studies of the Electronic Structures of Copper-Doped CdSe Nanocrystals: Oxidation States, Jahn–Teller Distortions, Vibronic Bandshapes, and Singlet–Triplet Splittings
journal, January 2016

Synthesis and Photoluminescence of Cd _1- _x Mn _x S ( x ≤ 5) Nanocrystals
journal, July 1998

Visible photoluminescence of Zn‐doped CuAlS ₂
journal, August 1992

Valence-Band Electronic Structures of Cu ⁺ -Doped ZnS, Alloyed Cu–In–Zn–S, and Ternary CuInS ₂ Nanocrystals: A Unified Description of Photoluminescence across Compositions
journal, July 2018

First-principles study of CuAlS ₂ for p-type transparent conductive materials
journal, September 2010

The nitrogen-vacancy colour centre in diamond
journal, July 2013

Doped Nanocrystals
journal, March 2008

Optical Transparency Enabled by Anomalous Stokes Shift in Visible Light-Emitting CuAlS ₂ -Based Quantum Dots
journal, July 2018

Triplet Sensitization by “Self-Trapped” Excitons of Nontoxic CuInS ₂ Nanocrystals for Efficient Photon Upconversion
journal, August 2019

Zur Kenntnis des Aluminiumsulfids: α-Al2S3 und Al2S3(tetr.) / On Aluminium Sulfide: α-Al2S3 and Al2S3 (tetr.)
journal, May 1981

Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996

High-Performance CuInS ₂ Quantum Dot Laminated Glass Luminescent Solar Concentrators for Windows
journal, January 2018

Bright CuInS ₂ /CdS nanocrystal phosphors for high-gain full-spectrum luminescent solar concentrators
journal, January 2015

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996

Synthesis of CuInS ₂ , CuInSe ₂ , and Cu(In _x Ga _{1- x} )Se ₂ (CIGS) Nanocrystal “Inks” for Printable Photovoltaics
journal, December 2008

A Novel Route for the Preparation of CuSe and CuInSe₂ Nanoparticles
journal, December 1999

High-Quality CuInS ₂ /ZnS Quantum Dots for In vitro and In vivo Bioimaging
journal, July 2012

Analysis of Optical Losses in High-Efficiency CuInS ₂ -Based Nanocrystal Luminescent Solar Concentrators: Balancing Absorption versus Scattering
journal, February 2017

Thermodynamics and kinetics of the copper vacancy in CuInSe2, CuGaSe2, CuInS2, and CuGaS2 from screened-exchange hybrid density functional theory
journal, July 2010

Nanocrystalline Chalcopyrite Materials (CuInS ₂ and CuInSe ₂ ) via Low-Temperature Pyrolysis of Molecular Single-Source Precursors
journal, August 2003

Magneto-Optical Properties of CuInS ₂ Nanocrystals
journal, November 2014

Improved performance and stability in quantum dot solar cells through band alignment engineering
journal, May 2014

Quality Factor of Luminescent Solar Concentrators and Practical Concentration Limits Attainable with Semiconductor Quantum Dots
journal, May 2016

Next-generation in vivo optical imaging with short-wave infrared quantum dots
journal, April 2017

Rationale for mixing exact exchange with density functional approximations
journal, December 1996

Thick-Shell CuInS ₂ /ZnS Quantum Dots with Suppressed “Blinking” and Narrow Single-Particle Emission Line Widths
journal, February 2017

Efficient Photosynthesis of Organics from Aqueous Bicarbonate Ions by Quantum Dots Using Visible Light
journal, June 2018

Two Distinct Transitions in Cu _x InS ₂ Quantum Dots. Bandgap versus Sub-Bandgap Excitations in Copper-Deficient Structures
journal, April 2016

Singlet–Triplet Splittings in the Luminescent Excited States of Colloidal Cu ⁺ :CdSe, Cu ⁺ :InP, and CuInS ₂ Nanocrystals: Charge-Transfer Configurations and Self-Trapped Excitons
journal, September 2015

Optical properties of Mn-doped CdS nanocrystals
journal, February 1996