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Title: The effect of grain size on the hydration of BaZr 0.9 Y 0.1 O 3−δ proton conductor studied by ambient pressure X-ray photoelectron spectroscopy

Abstract

Three BaZr 0.9 Y 0.1 O 3−δ (BZY10) pellets were prepared using different sintering processes, resulting in samples with grain sizes between 0.3 to 5 microns. The OH concentration increases with grain size and with decreasing the analysis depth.

Authors:
 [1];  [2]; ORCiD logo [3];  [4]; ORCiD logo [2]
  1. Materials Science and Engineering, University of Maryland, College Park, USA, Chemistry and Biochemistry
  2. Department of Mechanical Engineering, Colorado School of Mines, Golden, USA
  3. Advanced Light Source, Lawrence Berkeley National Laboratories, Berkeley, USA
  4. Chemistry and Biochemistry, University of Maryland, College Park, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1576999
Grant/Contract Number:  
DESC000116; AC02-05CH11231
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Physical Chemistry Chemical Physics. PCCP (Print)
Additional Journal Information:
Journal Name: Physical Chemistry Chemical Physics. PCCP (Print) Journal Volume: 22 Journal Issue: 1; Journal ID: ISSN 1463-9076
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Jarry, Angelique, Jackson, Gregory S., Crumlin, Ethan J., Eichhorn, Bryan, and Ricote, Sandrine. The effect of grain size on the hydration of BaZr 0.9 Y 0.1 O 3−δ proton conductor studied by ambient pressure X-ray photoelectron spectroscopy. United Kingdom: N. p., 2020. Web. doi:10.1039/C9CP04335G.
Jarry, Angelique, Jackson, Gregory S., Crumlin, Ethan J., Eichhorn, Bryan, & Ricote, Sandrine. The effect of grain size on the hydration of BaZr 0.9 Y 0.1 O 3−δ proton conductor studied by ambient pressure X-ray photoelectron spectroscopy. United Kingdom. doi:10.1039/C9CP04335G.
Jarry, Angelique, Jackson, Gregory S., Crumlin, Ethan J., Eichhorn, Bryan, and Ricote, Sandrine. Wed . "The effect of grain size on the hydration of BaZr 0.9 Y 0.1 O 3−δ proton conductor studied by ambient pressure X-ray photoelectron spectroscopy". United Kingdom. doi:10.1039/C9CP04335G.
@article{osti_1576999,
title = {The effect of grain size on the hydration of BaZr 0.9 Y 0.1 O 3−δ proton conductor studied by ambient pressure X-ray photoelectron spectroscopy},
author = {Jarry, Angelique and Jackson, Gregory S. and Crumlin, Ethan J. and Eichhorn, Bryan and Ricote, Sandrine},
abstractNote = {Three BaZr 0.9 Y 0.1 O 3−δ (BZY10) pellets were prepared using different sintering processes, resulting in samples with grain sizes between 0.3 to 5 microns. The OH − concentration increases with grain size and with decreasing the analysis depth.},
doi = {10.1039/C9CP04335G},
journal = {Physical Chemistry Chemical Physics. PCCP (Print)},
number = 1,
volume = 22,
place = {United Kingdom},
year = {2020},
month = {1}
}

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