skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on November 4, 2020

Title: Multi-stimuli responsive tetra-PPO 60 -PEO 20 ethylene diamine block copolymer enables pH, temperature, and solvent regulation of Au nanoparticle composite plasmonic response

Abstract

Dynamic plasmonic tuning of Au NP organization through pH and temperature mediated polymer architecture transformation from lamellar to bicontinuous cubic.

Authors:
 [1];  [1];  [2]; ORCiD logo [1]; ORCiD logo [1];  [1]; ORCiD logo [1]
  1. Los Alamos National Laboratory, Los Alamos, USA
  2. Argonne National Laboratory, Lemont, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1576846
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Polymer Chemistry
Additional Journal Information:
Journal Name: Polymer Chemistry Journal Volume: 10 Journal Issue: 47; Journal ID: ISSN 1759-9954
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Diouf, Sokhna I. Y., Williams, Darrick J., Seifert, Sönke, Londoño-Calderon, Alejandra, Pettes, Michael T., Sheehan, Christopher J., and Firestone, Millicent A. Multi-stimuli responsive tetra-PPO 60 -PEO 20 ethylene diamine block copolymer enables pH, temperature, and solvent regulation of Au nanoparticle composite plasmonic response. United Kingdom: N. p., 2019. Web. doi:10.1039/C9PY01098J.
Diouf, Sokhna I. Y., Williams, Darrick J., Seifert, Sönke, Londoño-Calderon, Alejandra, Pettes, Michael T., Sheehan, Christopher J., & Firestone, Millicent A. Multi-stimuli responsive tetra-PPO 60 -PEO 20 ethylene diamine block copolymer enables pH, temperature, and solvent regulation of Au nanoparticle composite plasmonic response. United Kingdom. doi:10.1039/C9PY01098J.
Diouf, Sokhna I. Y., Williams, Darrick J., Seifert, Sönke, Londoño-Calderon, Alejandra, Pettes, Michael T., Sheehan, Christopher J., and Firestone, Millicent A. Tue . "Multi-stimuli responsive tetra-PPO 60 -PEO 20 ethylene diamine block copolymer enables pH, temperature, and solvent regulation of Au nanoparticle composite plasmonic response". United Kingdom. doi:10.1039/C9PY01098J.
@article{osti_1576846,
title = {Multi-stimuli responsive tetra-PPO 60 -PEO 20 ethylene diamine block copolymer enables pH, temperature, and solvent regulation of Au nanoparticle composite plasmonic response},
author = {Diouf, Sokhna I. Y. and Williams, Darrick J. and Seifert, Sönke and Londoño-Calderon, Alejandra and Pettes, Michael T. and Sheehan, Christopher J. and Firestone, Millicent A.},
abstractNote = {Dynamic plasmonic tuning of Au NP organization through pH and temperature mediated polymer architecture transformation from lamellar to bicontinuous cubic.},
doi = {10.1039/C9PY01098J},
journal = {Polymer Chemistry},
number = 47,
volume = 10,
place = {United Kingdom},
year = {2019},
month = {12}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on November 4, 2020
Publisher's Version of Record

Save / Share:

Works referenced in this record:

50th Anniversary Perspective : Are Polymer Nanocomposites Practical for Applications?
journal, January 2017


CO 2 -Responsive Polymer Single-Chain Nanoparticles and Self-Assembly for Gas-Tunable Nanoreactors
journal, June 2017


Effect of Interfaces on the Melting of PEO Confined in Triblock PS- b -PEO- b -PS Copolymers
journal, August 2013

  • Beaudoin, E.; Phan, T. N. T.; Robinet, M.
  • Langmuir, Vol. 29, Issue 34
  • DOI: 10.1021/la401889h

Structure and Optical Properties of a Thermoresponsive Polymer-Grafted, Lipid-Based Complex Fluid
journal, August 1998

  • Firestone, Millicent A.; Thiyagarajan, P.; Tiede, David M.
  • Langmuir, Vol. 14, Issue 17
  • DOI: 10.1021/la9805995

Toward functional nanocomposites: taking the best of nanoparticles, polymers, and small molecules
journal, January 2013

  • Kao, Joseph; Thorkelsson, Kari; Bai, Peter
  • Chem. Soc. Rev., Vol. 42, Issue 7
  • DOI: 10.1039/C2CS35375J

Hierarchical Structure and Crystal Orientation in Poly(ethylene oxide)/Clay Nanocomposite Films
journal, March 2014

  • Chu, Che-Yi; Chen, Meng-Hsin; Wu, Mei-Lin
  • Langmuir, Vol. 30, Issue 10
  • DOI: 10.1021/la4042748

Detection of Two Glass Transitions on Triton X-100 under Confinement
journal, October 2013

  • Merino, Esther G.; Neves, Paulo D.; Fonseca, Isabel M.
  • The Journal of Physical Chemistry C, Vol. 117, Issue 41
  • DOI: 10.1021/jp404306a

Film Architecture in Biomolecular Assemblies. Effect of Linker on the Orientation of Genetically Engineered Surface-Bound Proteins
journal, January 1996

  • Firestone, Millicent A.; Shank, Mary L.; Sligar, Stephen G.
  • Journal of the American Chemical Society, Vol. 118, Issue 38
  • DOI: 10.1021/ja961046o

Crystallization and melting behavior of low molar weight PEO–PPO–PEO triblock copolymers
journal, November 2006


Nanoparticle Arrays Formed by Spatial Compartmentalization in a Complex Fluid
journal, March 2001

  • Firestone, Millicent A.; Williams, Dixy E.; Seifert, Sönke
  • Nano Letters, Vol. 1, Issue 3
  • DOI: 10.1021/nl0155025

Cascade synthesis of a gold nanoparticle–network polymer composite
journal, January 2016

  • Grubjesic, Simonida; Ringstrand, Bryan S.; Jungjohann, Katherine L.
  • Nanoscale, Vol. 8, Issue 5
  • DOI: 10.1039/C5NR06594A

Raman and Infrared Spectra of Complexes of Ethylenediamine with Zinc(II), Cadmium(II), and Mercury(II)
journal, May 1966


Crystallization behaviour of poly(ethylene oxide) under confinement in the electrospun nanofibers of polystyrene/poly(ethylene oxide) blends
journal, January 2016

  • Samanta, Pratick; V., Thangapandian; Singh, Sajan
  • Soft Matter, Vol. 12, Issue 23
  • DOI: 10.1039/C6SM00648E

Conductivity of ionic liquid-derived polymers with internal gold nanoparticle conduits
journal, January 2009

  • Lee, Sungwon; Cummins, Matthew D.; Willing, Gerold A.
  • Journal of Materials Chemistry, Vol. 19, Issue 43
  • DOI: 10.1039/b910059h

Electron-Transfer Dynamics of Photosynthetic Reaction Centers in Thermoresponsive Soft Materials
journal, December 2005

  • Laible, Philip D.; Kelley, Richard F.; Wasielewski, Michael R.
  • The Journal of Physical Chemistry B, Vol. 109, Issue 49
  • DOI: 10.1021/jp053884n


journal, January 2017

  • Seyhan, Merve; Kucharczyk, William; Yarar, U. Ecem
  • Nanotechnology, Science and Applications, Vol. Volume 10
  • DOI: 10.2147/NSA.S129468

Highly conductive ionic liquid based ternary polymer electrolytes obtained by in situ photopolymerisation
journal, October 2009


Silica Scaffold with Shifted “Plumber's Nightmare” Networks and their Interconversion into Diamond Networks
journal, July 2017

  • Mao, Wenting; Cao, Xin; Sheng, Qingqing
  • Angewandte Chemie International Edition, Vol. 56, Issue 36
  • DOI: 10.1002/anie.201704639

Photothermally and magnetically controlled reconfiguration of polymer composites for soft robotics
journal, August 2019

  • Liu, Jessica A. -C.; Gillen, Jonathan H.; Mishra, Sumeet R.
  • Science Advances, Vol. 5, Issue 8
  • DOI: 10.1126/sciadv.aaw2897

Structural Study of Four-Armed Amphiphilic Star-Block Copolymers: Pristine and End-Linked Tetronic T1307
journal, January 2016


Multi-length scale evaluation of the temperature-tunable mechanical properties of a lyotropic mesophase
journal, July 2012

  • Lee, Sungwon; Seifert, Sönke; Firestone, Millicent A.
  • Polymer Journal, Vol. 45, Issue 2
  • DOI: 10.1038/pj.2012.99

Nanoparticle self-assembly: from interactions in suspension to polymer nanocomposites
journal, January 2018

  • Genix, Anne-Caroline; Oberdisse, Julian
  • Soft Matter, Vol. 14, Issue 25
  • DOI: 10.1039/C8SM00430G

Curvature Forces in Membrane Lipid–Protein Interactions
journal, November 2012


Evaporation and decomposition of Triton X-100 under various gases and temperatures
journal, February 1989

  • Mitsuda, Kenro; Kimura, Hiroshi; Murahashi, Toshiaki
  • Journal of Materials Science, Vol. 24, Issue 2
  • DOI: 10.1007/BF01107420

Enhanced Retention of Encapsulated Ions in Cross-Linked Polymersomes
journal, March 2015

  • Wang, Guanglin; Hoornweg, Arentien; Wolterbeek, Hubert T.
  • The Journal of Physical Chemistry B, Vol. 119, Issue 11
  • DOI: 10.1021/jp5125316

Morphological Transformation of PS- b -PEO Diblock Copolymer by Selectively Dispersed Colloidal CdS Quantum Dots
journal, October 2003

  • Yeh, Siao-Wei; Wei, Kung-Hwa; Sun, Ya-Sen
  • Macromolecules, Vol. 36, Issue 21
  • DOI: 10.1021/ma034800g

pH and thermo-responsive tetronic micelles for the synthesis of gold nanoparticles: effect of physiochemical aspects of tetronics
journal, January 2014

  • Singh, Vijender; Khullar, Poonam; Dave, Pragnesh N.
  • Physical Chemistry Chemical Physics, Vol. 16, Issue 10
  • DOI: 10.1039/c3cp55079f

Nanoparticle-Hydrogel Composites: Concept, Design, and Applications of These Promising, Multi-Functional Materials
journal, January 2015

  • Thoniyot, Praveen; Tan, Mein Jin; Karim, Anis Abdul
  • Advanced Science, Vol. 2, Issue 1-2
  • DOI: 10.1002/advs.201400010

Poloxamine-based nanomaterials for drug delivery
journal, January 2010

  • Alvarez-Lorenzo, Carmen
  • Frontiers in Bioscience, Vol. E2, Issue 2
  • DOI: 10.2741/e102

Ethylenediamine at Air/Liquid and Air/Silica Interfaces:  Protonation Versus Hydrogen Bonding Investigated by Sum Frequency Generation Spectroscopy
journal, March 2006

  • Xu, Man; Liu, Dingfang; Allen, Heather C.
  • Environmental Science & Technology, Vol. 40, Issue 5
  • DOI: 10.1021/es051537l

Small-Angle X-ray Scattering Study of the Interaction of Poly(ethylene oxide)- b -Poly(propylene oxide)- b -Poly(ethylene oxide) Triblock Copolymers with Lipid Bilayers
journal, November 2003

  • Firestone, Millicent A.; Wolf, Amanda C.; Seifert, Sönke
  • Biomacromolecules, Vol. 4, Issue 6
  • DOI: 10.1021/bm034134r

Spatial regulation of synthetic and biological nanoparticles by DNA nanotechnology
journal, February 2015

  • Yang, Zhongqiang; Liu, Huajie; Liu, Dongsheng
  • NPG Asia Materials, Vol. 7, Issue 2
  • DOI: 10.1038/am.2015.2

Formation of Gold Nanoparticles Using Amine Reducing Agents
journal, June 2006

  • Newman, J. D. S.; Blanchard, G. J.
  • Langmuir, Vol. 22, Issue 13
  • DOI: 10.1021/la060045z

Directed Self-Assembly of Nanoparticles
journal, June 2010

  • Grzelczak, Marek; Vermant, Jan; Furst, Eric M.
  • ACS Nano, Vol. 4, Issue 7
  • DOI: 10.1021/nn100869j

Preparation of a self-supporting cell architecture mimic by water channel confined photocrosslinking within a lamellar structured hydrogel
journal, January 2011

  • Grubjesic, Simonida; Lee, Byeongdu; Seifert, Sönke
  • Soft Matter, Vol. 7, Issue 20
  • DOI: 10.1039/c1sm06364b

Spectroscopic and Theoretical Studies on Solid 1,2-Ethylenediamine Dihydrochloride Salt
journal, December 2004

  • Amado, Ana M.; Otero, Juan Carlos; Marques, M. Paula M.
  • ChemPhysChem, Vol. 5, Issue 12
  • DOI: 10.1002/cphc.200400350

Anisotropic ion transport in nanostructured solid polymer electrolytes
journal, January 2015

  • Cheng, Shan; Smith, Derrick M.; Pan, Qiwei
  • RSC Advances, Vol. 5, Issue 60
  • DOI: 10.1039/C5RA05240H

Electrochemical Activity of Glucose Oxidase on a Poly(ionic liquid)–Au Nanoparticle Composite
journal, May 2012

  • Lee, Sungwon; Ringstrand, Bryan S.; Stone, David A.
  • ACS Applied Materials & Interfaces, Vol. 4, Issue 5
  • DOI: 10.1021/am300629n

Infrared spectroscopic studies of detergent-solubilized uncoupling protein from brown-adipose-tissue mitochondria
journal, February 1990


Lipid Cubic Phases as Stable Nanochannel Network Structures for Protein Biochip Development:  X-ray Diffraction Study
journal, August 2003

  • Angelova, Angelina; Ollivon, Michel; Campitelli, Andrew
  • Langmuir, Vol. 19, Issue 17
  • DOI: 10.1021/la0345284

Density Functional Theory-Based Conformational Analysis of a Phospholipid Molecule (Dimyristoyl Phosphatidylcholine)
journal, October 2008

  • Krishnamurty, S.; Stefanov, M.; Mineva, T.
  • The Journal of Physical Chemistry B, Vol. 112, Issue 42
  • DOI: 10.1021/jp804934d

Monoolein: a magic lipid?
journal, January 2011

  • Kulkarni, Chandrashekhar V.; Wachter, Wolfgang; Iglesias-Salto, Guillermo
  • Phys. Chem. Chem. Phys., Vol. 13, Issue 8
  • DOI: 10.1039/C0CP01539C

Composite Polymer Colloids for SERS-Based Applications
journal, December 2017

  • Strozyk, Malte S.; Jimenez de Aberasturi, Dorleta; Liz-Marzán, Luis M.
  • The Chemical Record, Vol. 18, Issue 7-8
  • DOI: 10.1002/tcr.201700082

Self-Assembling Nanocomposite Tectons
journal, December 2016

  • Zhang, Jianyuan; Santos, Peter J.; Gabrys, Paul A.
  • Journal of the American Chemical Society, Vol. 138, Issue 50
  • DOI: 10.1021/jacs.6b11052

Thermally Reversible Aggregation of Gold Nanoparticles in Polymer Nanocomposites through Hydrogen Bonding
journal, October 2013

  • Heo, Kyuyoung; Miesch, Caroline; Emrick, Todd
  • Nano Letters, Vol. 13, Issue 11
  • DOI: 10.1021/nl402813q

Physicochemical characterization of solid dispersion systems of tadalafil with poloxamer 407
journal, December 2009


Interaction of poloxamine block copolymers with lipid membranes: Role of copolymer structure and membrane cholesterol content
journal, September 2015


Controlled Poly(ethylene glycol) Network Structures through Silsesquioxane Cross-Links Formed by Sol−Gel Reactions
journal, December 2010

  • Radi, Babak; Wellard, R. Mark; George, Graeme A.
  • Macromolecules, Vol. 43, Issue 23
  • DOI: 10.1021/ma101511p

Tunable plasmonic nanostructures from noble metal nanoparticles and stimuli-responsive polymers
journal, January 2012


Reversible Lifting of Surface Supported Lipid Bilayers with a Membrane-Spanning Nonionic Triblock Copolymer
journal, March 2017


Greater than the sum: Synergy and emergent properties in nanoparticle–polymer composites
journal, September 2015

  • Firestone, Millicent A.; Hayden, Steven C.; Huber, Dale L.
  • MRS Bulletin, Vol. 40, Issue 9
  • DOI: 10.1557/mrs.2015.202

CO 2 -switchable polymer-hybrid silver nanoparticles and their gas-tunable catalytic activity
journal, January 2017


Thermal degradation of electrical conductivity of polyacrylic acid doped polyaniline: effect of molecular weight of the dopants
journal, July 2003


Compartmentalization Technologies via Self-Assembly and Cross-Linking of Amphiphilic Random Block Copolymers in Water
journal, May 2017

  • Matsumoto, Mayuko; Terashima, Takaya; Matsumoto, Kazuma
  • Journal of the American Chemical Society, Vol. 139, Issue 21
  • DOI: 10.1021/jacs.7b03152

Simple Method for Tuning the Optical Properties of Thermoresponsive Plasmonic Nanogels
journal, May 2016