Flexibility in Metal–Organic Frameworks: A fundamental understanding

Elsaidi, Sameh K.; Mohamed, Mona H.; Banerjee, Debasis; Thallapally, Praveen K.

doi:10.1016/j.ccr.2017.11.022

Title: Flexibility in Metal–Organic Frameworks: A fundamental understanding

Journal Article · 01 March 2018 · Coordination Chemistry Reviews

DOI: https://doi.org/10.1016/j.ccr.2017.11.022 · OSTI ID:1576843

Elsaidi, Sameh K.; Mohamed, Mona H.; Banerjee, Debasis; Thallapally, Praveen K.

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Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI ID:: 1576843

Journal Information:: Coordination Chemistry Reviews, Journal Name: Coordination Chemistry Reviews Journal Issue: C Vol. 358; ISSN 0010-8545

Publisher:: ElsevierCopyright Statement

Country of Publication:: Netherlands

Language:: English

References (190)

Polymeric Layers Catenated by Ribbons of Rings in a Three-Dimensional Self-Assembled Architecture: A Nanoporous Network with Spongelike Behavior Carlucci, Lucia; Ciani, Gianfranco; Moret, Massimo Angewandte Chemie International Edition, Vol. 39, Issue 8 https://doi.org/10.1002/(SICI)1521-3773(20000417)39:8<1506::AID-ANIE1506>3.0.CO;2-U	journal	April 2000
A Pillared-Layer Coordination Polymer Network Displaying Hysteretic Sorption: [Cu2(pzdc)2(dpyg)]n (pzdc= Pyrazine-2,3-dicarboxylate; dpyg=1,2-Di(4-pyridyl)glycol) Kitaura, Ryo; Fujimoto, Kentaro; Noro, Shin-ichiro Angewandte Chemie, Vol. 114, Issue 1 https://doi.org/10.1002/1521-3757(20020104)114:1<141::AID-ANGE141>3.0.CO;2-D	journal	January 2002
Novel Flexible Frameworks of Porous Cobalt(II) Coordination Polymers That Show Selective Guest Adsorption Based on the Switching of Hydrogen-Bond Pairs of Amide Groups Uemura, Kazuhiro; Kitagawa, Susumu; Kondo, Mitsuru Chemistry - A European Journal, Vol. 8, Issue 16 https://doi.org/10.1002/1521-3765(20020816)8:16<3586::AID-CHEM3586>3.0.CO;2-K	journal	August 2002
A Pillared-Layer Coordination Polymer Network Displaying Hysteretic Sorption: [Cu2(pzdc)2(dpyg)]n (pzdc= Pyrazine-2,3-dicarboxylate; dpyg=1,2-Di(4-pyridyl)glycol) Kitaura, Ryo; Fujimoto, Kentaro; Noro, Shin-ichiro Angewandte Chemie International Edition, Vol. 41, Issue 1 https://doi.org/10.1002/1521-3773(20020104)41:1<133::AID-ANIE133>3.0.CO;2-R	journal	January 2002
A Breathing Hybrid Organic–Inorganic Solid with Very Large Pores and High Magnetic Characteristics Barthelet, Karin; Marrot, Jérôme; Riou, Didier Angewandte Chemie International Edition, Vol. 41, Issue 2 https://doi.org/10.1002/1521-3773(20020118)41:2<281::AID-ANIE281>3.0.CO;2-Y	journal	January 2002
A Springlike 3D-Coordination Network That Shrinks or Swells in a Crystal-to-Crystal Manner upon Guest Removal or Readsorption Biradha, Kumar; Fujita, Makoto Angewandte Chemie International Edition, Vol. 41, Issue 18 https://doi.org/10.1002/1521-3773(20020916)41:18<3392::AID-ANIE3392>3.0.CO;2-V	journal	September 2002
Massive Anisotropic Thermal Expansion and Thermo-Responsive Breathing in Metal-Organic Frameworks Modulated by Linker Functionalization Henke, Sebastian; Schneemann, Andreas; Fischer, Roland A. Advanced Functional Materials, Vol. 23, Issue 48 https://doi.org/10.1002/adfm.201301256	journal	July 2013
Three-Dimensional Framework with Channeling Cavities for Small Molecules:{[M2(4, 4′-bpy)3(NO3)4]·xH2O}n(M Co, Ni, Zn) Kondo, Mitsuru; Yoshitomi, Tomomichi; Matsuzaka, Hiroyuki Angewandte Chemie International Edition in English, Vol. 36, Issue 16 https://doi.org/10.1002/anie.199717251	journal	September 1997
Functional Porous Coordination Polymers Kitagawa, Susumu; Kitaura, Ryo; Noro, Shin-ichiro Angewandte Chemie International Edition, Vol. 43, Issue 18, p. 2334-2375 https://doi.org/10.1002/anie.200300610	journal	April 2004
Porous Coordination-Polymer Crystals with Gated Channels Specific for Supercritical Gases Kitaura, Ryo; Seki, Kenji; Akiyama, George Angewandte Chemie International Edition, Vol. 42, Issue 4 https://doi.org/10.1002/anie.200390130	journal	January 2003
A Route to the Synthesis of Trivalent Transition-Metal Porous Carboxylates with Trimeric Secondary Building Units Serre, Christian; Millange, Franck; Surblé, Suzy Angewandte Chemie International Edition, Vol. 43, Issue 46 https://doi.org/10.1002/anie.200454250	journal	September 2004
A Hybrid Solid with Giant Pores Prepared by a Combination of Targeted Chemistry, Simulation, and Powder Diffraction Férey, Gérard; Serre, Christian; Mellot-Draznieks, Caroline Angewandte Chemie International Edition, Vol. 43, Issue 46 https://doi.org/10.1002/anie.200460592	journal	August 2004
Rigid and Flexible: A Highly Porous Metal–Organic Framework with Unusual Guest-Dependent Dynamic Behavior Dybtsev, Danil N.; Chun, Hyungphil; Kim, Kimoon Angewandte Chemie International Edition, Vol. 43, Issue 38, p. 5033-5036 https://doi.org/10.1002/anie.200460712	journal	September 2004
Crystal Engineering: A Holistic View Desiraju, Gautam R. Angewandte Chemie International Edition, Vol. 46, Issue 44 https://doi.org/10.1002/anie.200700534	journal	November 2007
Two-Step Adsorption/Desorption on a Jungle-Gym-Type Porous Coordination Polymer Uemura, Kazuhiro; Yamasaki, Yukari; Komagawa, Yuki Angewandte Chemie International Edition, Vol. 46, Issue 35 https://doi.org/10.1002/anie.200702390	journal	September 2007
Crystallographic Observation of Dynamic Gas Adsorption Sites and Thermal Expansion in a Breathable Fluorous Metal-Organic Framework Yang, Chi; Wang, Xiaoping; Omary, Mohammad A. Angewandte Chemie International Edition, Vol. 48, Issue 14 https://doi.org/10.1002/anie.200804739	journal	March 2009
The Effect of Pressure on ZIF-8: Increasing Pore Size with Pressure and the Formation of a High-Pressure Phase at 1.47 GPa Moggach, Stephen A.; Bennett, Thomas D.; Cheetham, Anthony K. Angewandte Chemie International Edition, Vol. 48, Issue 38 https://doi.org/10.1002/anie.200902643	journal	September 2009
BioMOFs: Metal-Organic Frameworks for Biological and Medical Applications McKinlay, Alistair C.; Morris, Russell E.; Horcajada, Patricia Angewandte Chemie International Edition, Vol. 49, Issue 36, p. 6260-6266 https://doi.org/10.1002/anie.201000048	journal	July 2010
Dynamics of Benzene Rings in MIL-53(Cr) and MIL-47(V) Frameworks Studied by 2H NMR Spectroscopy Kolokolov, Daniil I.; Jobic, Hervé; Stepanov, Alexander G. Angewandte Chemie International Edition, Vol. 49, Issue 28 https://doi.org/10.1002/anie.201001238	journal	May 2010
A Catenated Strut in a Catenated Metal-Organic Framework Li, Qiaowei; Sue, Chi-Hau; Basu, Subhadeep Angewandte Chemie International Edition, Vol. 49, Issue 38, p. 6751-6755 https://doi.org/10.1002/anie.201003221	journal	August 2010
Post-Synthetic Modification of Porphyrin-Encapsulating Metal-Organic Materials by Cooperative Addition of Inorganic Salts to Enhance CO ₂ / CH ₄ Selectivity Zhang, Zhenjie; Gao, Wen-Yang; Wojtas, Lukasz Angewandte Chemie International Edition, Vol. 51, Issue 37 https://doi.org/10.1002/anie.201203594	journal	August 2012
Dynamic Photo-Switching in Metal-Organic Frameworks as a Route to Low-Energy Carbon Dioxide Capture and Release Lyndon, Richelle; Konstas, Kristina; Ladewig, Bradley P. Angewandte Chemie International Edition, Vol. 52, Issue 13 https://doi.org/10.1002/anie.201206359	journal	February 2013
Pressure-Induced Bond Rearrangement and Reversible Phase Transformation in a Metal-Organic Framework Spencer, Elinor C.; Kiran, Mangalampalli S. R. N.; Li, Wei Angewandte Chemie International Edition, Vol. 53, Issue 22 https://doi.org/10.1002/anie.201310276	journal	April 2014
Extreme Flexibility in a Zeolitic Imidazolate Framework: Porous to Dense Phase Transition in Desolvated ZIF-4 Wharmby, Michael T.; Henke, Sebastian; Bennett, Thomas D. Angewandte Chemie International Edition, Vol. 54, Issue 22 https://doi.org/10.1002/anie.201410167	journal	April 2015
A Rationale for the Large Breathing of the Porous Aluminum Terephthalate (MIL-53) Upon Hydration Loiseau, Thierry; Serre, Christian; Huguenard, Clarisse Chemistry - A European Journal, Vol. 10, Issue 6 https://doi.org/10.1002/chem.200305413	journal	March 2004
Structures and H2 Adsorption Properties of Porous Scandium Metal-Organic Frameworks Ibarra, Ilich A.; Lin, Xiang; Yang, Sihai Chemistry - A European Journal, Vol. 16, Issue 46 https://doi.org/10.1002/chem.201000926	journal	October 2010
Highly Selective CO2 Capture by a Flexible Microporous Metal-Organic Framework (MMOF) Material Wu, Haohan; Reali, Randall S.; Smith, David A. Chemistry - A European Journal, Vol. 16, Issue 47 https://doi.org/10.1002/chem.201002683	journal	November 2010
Direct Structural Identification of Gas Induced Gate-Opening Coupled with Commensurate Adsorption in a Microporous Metal-Organic Framework Banerjee, Debasis; Wang, Hao; Plonka, Anna M. Chemistry - A European Journal, Vol. 22, Issue 33 https://doi.org/10.1002/chem.201601784	journal	July 2016
Insights into the Temperature-Dependent “Breathing” of a Flexible Fluorinated Metal-Organic Framework Fernandez, Carlos A.; Thallapally, Praveen K.; McGrail, B. Peter ChemPhysChem, Vol. 13, Issue 14 https://doi.org/10.1002/cphc.201200243	journal	July 2012
Design, synthesis and structural diversity in coordination polymers Abourahma, Heba; McManus, Gregory J.; Moulton, Brian Macromolecular Symposia, Vol. 196, Issue 1 https://doi.org/10.1002/masy.200390162	journal	July 2003
Designing Heterogeneous Catalysts by Incorporating Enzyme-Like Functionalities into MOFs Lillerud, Karl Petter; Olsbye, Unni; Tilset, Mats Topics in Catalysis, Vol. 53, Issue 13-14 https://doi.org/10.1007/s11244-010-9518-4	journal	May 2010
Inorganic crystal engineering using self-assembly of tailored building-blocks Blake, Alexander J.; Champness, Neil R.; Hubberstey, Peter Coordination Chemistry Reviews, Vol. 183, Issue 1 https://doi.org/10.1016/S0010-8545(98)00173-8	journal	March 1999
Synthesis, morphology control, and properties of porous metal–organic coordination polymers Huang, L. Microporous and Mesoporous Materials, Vol. 58, Issue 2 https://doi.org/10.1016/S1387-1811(02)00609-1	journal	March 2003
Approaches for synthesizing breathing MOFs by exploiting dimensional rigidity Murdock, Christopher R.; Hughes, Brianna C.; Lu, Zheng Coordination Chemistry Reviews, Vol. 258-259 https://doi.org/10.1016/j.ccr.2013.09.006	journal	January 2014
Origins of Negative Gas Adsorption Evans, Jack D.; Bocquet, Lydéric; Coudert, François-Xavier Chem, Vol. 1, Issue 6 https://doi.org/10.1016/j.chempr.2016.11.004	journal	December 2016
Hydrothermal synthesis and crystal structure of a new three-dimensional aluminum-organic framework MIL-69 with 2,6-naphthalenedicarboxylate (ndc), Al(OH)(ndc)·H2O Loiseau, Thierry; Mellot-Draznieks, Caroline; Muguerra, Hervé Comptes Rendus Chimie, Vol. 8, Issue 3-4 https://doi.org/10.1016/j.crci.2004.10.011	journal	March 2005
MOFs as catalysts: Activity, reusability and shape-selectivity of a Pd-containing MOF Llabrés i Xamena, Françesc X.; Abad, Alberto; Corma, Avelino Journal of Catalysis, Vol. 250, Issue 2, p. 294-298 https://doi.org/10.1016/j.jcat.2007.06.004	journal	September 2007
Flexibility in metal-organic framework materials: Impact on sorption properties Fletcher, Ashleigh J.; Thomas, K. Mark; Rosseinsky, Matthew J. Journal of Solid State Chemistry, Vol. 178, Issue 8 https://doi.org/10.1016/j.jssc.2005.05.019	journal	August 2005
Flexible microporous coordination polymers Uemura, Kazuhiro; Matsuda, Ryotaro; Kitagawa, Susumu Journal of Solid State Chemistry, Vol. 178, Issue 8 https://doi.org/10.1016/j.jssc.2005.05.036	journal	August 2005
Ethene/ethane separation by the MOF membrane ZIF-8: Molecular correlation of permeation, adsorption, diffusion Bux, Helge; Chmelik, Christian; Krishna, Rajamani Journal of Membrane Science, Vol. 369, Issue 1-2 https://doi.org/10.1016/j.memsci.2010.12.001	journal	March 2011
Structural transformation and high pressure methane adsorption of Co2(1,4-bdc)2dabco Wang, Hepeng; Getzschmann, Jürgen; Senkovska, Irena Microporous and Mesoporous Materials, Vol. 116, Issue 1-3 https://doi.org/10.1016/j.micromeso.2008.05.037	journal	December 2008
Ethene/ethane mixture diffusion in the MOF sieve ZIF-8 studied by MAS PFG NMR diffusometry Chmelik, Christian; Freude, Dieter; Bux, Helge Microporous and Mesoporous Materials, Vol. 147, Issue 1 https://doi.org/10.1016/j.micromeso.2011.06.009	journal	January 2012
Modeling flexibility in metal–organic frameworks: Comparison between Density-Functional Tight-Binding and Universal Force Field approaches for bonded interactions Garberoglio, Giovanni; Taioli, Simone Microporous and Mesoporous Materials, Vol. 163 https://doi.org/10.1016/j.micromeso.2012.07.026	journal	November 2012
Selective detection of olefins using a luminescent silver-functionalized metal organic framework, RPM3 Marti, Anne M.; Nijem, Nour; Chabal, Yves J. Microporous and Mesoporous Materials, Vol. 174 https://doi.org/10.1016/j.micromeso.2013.02.044	journal	July 2013
Framework mobility in the metal–organic framework crystal IRMOF-3: Evidence for aromatic ring and amine rotation Morris, William; Taylor, R. E.; Dybowski, C. Journal of Molecular Structure, Vol. 1004, Issue 1-3, p. 94-101 https://doi.org/10.1016/j.molstruc.2011.07.037	journal	October 2011
Responsive Metal–Organic Frameworks and Framework Materials: Under Pressure, Taking the Heat, in the Spotlight, with Friends Coudert, François-Xavier Chemistry of Materials, Vol. 27, Issue 6 https://doi.org/10.1021/acs.chemmater.5b00046	journal	February 2015
A Highly Stable Nanotubular MOF Rotator for Selective Adsorption of Benzene and Separation of Xylene Isomers Huang, Wei; Jiang, Jun; Wu, Dayu Inorganic Chemistry, Vol. 54, Issue 22 https://doi.org/10.1021/acs.inorgchem.5b01581	journal	October 2015
A Flexible Metal–Organic Framework: Guest Molecules Controlled Dynamic Gas Adsorption Yue, Yanfeng; Rabone, Jeremy A.; Liu, Hongjun The Journal of Physical Chemistry C, Vol. 119, Issue 17 https://doi.org/10.1021/acs.jpcc.5b02359	journal	April 2015
Metal-Cation-Independent Dynamics of Phenylene Ring in Microporous MOFs: A ² H Solid-State NMR Study Khudozhitkov, Alexander E.; Kolokolov, Daniil I.; Stepanov, Alexander G. The Journal of Physical Chemistry C, Vol. 119, Issue 50 https://doi.org/10.1021/acs.jpcc.5b09435	journal	December 2015
Gas-Induced Expansion and Contraction of a Fluorinated Metal−Organic Framework Fernandez, Carlos A.; Thallapally, Praveen K.; Motkuri, Radha Kishan Crystal Growth & Design, Vol. 10, Issue 3, p. 1037-1039 https://doi.org/10.1021/cg9014948	journal	March 2010
High CO ₂ and H ₂ Uptake in an Anionic Porous Framework with Amino-Decorated Polyhedral Cages Zhai, Quan-Guo; Lin, Qipu; Wu, Tao Chemistry of Materials, Vol. 24, Issue 14 https://doi.org/10.1021/cm301322b	journal	July 2012
Hysteretic Gas and Vapor Sorption in Flexible Interpenetrated Lanthanide-Based Metal–Organic Frameworks with Coordinated Molecular Gating via Reversible Single-Crystal-to-Single-Crystal Transformation for Enhanced Selectivity Wang, Chao; Li, Liangjun; Bell, Jon G. Chemistry of Materials, Vol. 27, Issue 5 https://doi.org/10.1021/cm503533r	journal	February 2015
Metal–Organic Frameworks in Biomedicine Horcajada, Patricia; Gref, Ruxandra; Baati, Tarek Chemical Reviews, Vol. 112, Issue 2, p. 1232-1268 https://doi.org/10.1021/cr200256v	journal	September 2011
Hydrogen Storage in Metal–Organic Frameworks Suh, Myunghyun Paik; Park, Hye Jeong; Prasad, Thazhe Kootteri Chemical Reviews, Vol. 112, Issue 2, p. 782-835 https://doi.org/10.1021/cr200274s	journal	September 2011
Synthesis of Metal-Organic Frameworks (MOFs): Routes to Various MOF Topologies, Morphologies, and Composites Stock, Norbert; Biswas, Shyam Chemical Reviews, Vol. 112, Issue 2 https://doi.org/10.1021/cr200304e	journal	September 2011
Carbon Dioxide Capture in Metal–Organic Frameworks Sumida, Kenji; Rogow, David L.; Mason, Jarad A. Chemical Reviews, Vol. 112, Issue 2, p. 724-781 https://doi.org/10.1021/cr2003272	journal	September 2011
Metal-Organic Frameworks Based on Trigonal Prismatic Building Blocks and the New “acs” Topology Sudik, Andrea C.; Côté, Adrien P.; Yaghi, Omar M. Inorganic Chemistry, Vol. 44, Issue 9, p. 2998-3000 https://doi.org/10.1021/ic050064g	journal	May 2005
In Situ Observation of Gating Phenomena in the Flexible Porous Coordination Polymer Zn ₂ (BPnDC) ₂ (bpy) (SNU-9) in a Combined Diffraction and Gas Adsorption Experiment Bon, Volodymyr; Senkovska, Irena; Wallacher, Dirk Inorganic Chemistry, Vol. 53, Issue 3 https://doi.org/10.1021/ic4024844	journal	January 2014
ℝPM3: A Multifunctional Microporous MOF with Recyclable Framework and High H ₂ Binding Energy ^† Lan, Anjian; Li, Kunhao; Wu, Haohan Inorganic Chemistry, Vol. 48, Issue 15 https://doi.org/10.1021/ic9002115	journal	August 2009
A molecular shuttle Anelli, Pier Lucio; Spencer, Neil; Stoddart, J. Fraser Journal of the American Chemical Society, Vol. 113, Issue 13 https://doi.org/10.1021/ja00013a096	journal	June 1991
Adsorption Dynamics of Gases and Vapors on the Nanoporous Metal Organic Framework Material Ni ₂ (4,4‘-Bipyridine) ₃ (NO ₃ ) ₄ : Guest Modification of Host Sorption Behavior Fletcher, Ashleigh J.; Cussen, Edmund J.; Prior, Timothy J. Journal of the American Chemical Society, Vol. 123, Issue 41 https://doi.org/10.1021/ja0109895	journal	October 2001
Flexible Sorption and Transformation Behavior in a Microporous Metal-Organic Framework Cussen, Edmund J.; Claridge, John B.; Rosseinsky, Matthew J. Journal of the American Chemical Society, Vol. 124, Issue 32 https://doi.org/10.1021/ja0262737	journal	August 2002
Very Large Breathing Effect in the First Nanoporous Chromium(III)-Based Solids MIL-53 or Cr^III(OH)·{O₂C−C₆H₄−CO₂}·{HO₂C−C₆H₄−CO₂H}_x·H₂O_y Serre, Christian; Millange, Franck; Thouvenot, Christelle Journal of the American Chemical Society, Vol. 124, Issue 45, p. 13519-13526 https://doi.org/10.1021/ja0276974	journal	November 2002
Different Adsorption Behaviors of Methane and Carbon Dioxide in the Isotypic Nanoporous Metal Terephthalates MIL-53 and MIL-47 Bourrelly, Sandrine; Llewellyn, Philip L.; Serre, Christian Journal of the American Chemical Society, Vol. 127, Issue 39 https://doi.org/10.1021/ja054668v	journal	October 2005
Very Large Swelling in Hybrid Frameworks: A Combined Computational and Powder Diffraction Study Mellot-Draznieks, Caroline; Serre, Christian; Surblé, Suzy Journal of the American Chemical Society, Vol. 127, Issue 46 https://doi.org/10.1021/ja054900x	journal	November 2005
In(OH)BDC·0.75BDCH ₂ (BDC = Benzenedicarboxylate), a Hybrid Inorganic−Organic Vernier Structure Anokhina, Ekaterina V.; Vougo-Zanda, Marie; Wang, Xiqu Journal of the American Chemical Society, Vol. 127, Issue 43 https://doi.org/10.1021/ja055757a	journal	November 2005
The Modular Synthesis of Functional Porous Coordination Networks Kawano, Masaki; Kawamichi, Takehide; Haneda, Tsuyoshi Journal of the American Chemical Society, Vol. 129, Issue 50, p. 15418-15419 https://doi.org/10.1021/ja0752540	journal	December 2007
Amphidynamic Character of Crystalline MOF-5: Rotational Dynamics of Terephthalate Phenylenes in a Free-Volume, Sterically Unhindered Environment Gould, Stephanie L.; Tranchemontagne, David; Yaghi, Omar M. Journal of the American Chemical Society, Vol. 130, Issue 11, p. 3246-3247 https://doi.org/10.1021/ja077122c	journal	March 2008
Supermolecular Building Blocks (SBBs) and Crystal Design: 12-Connected Open Frameworks Based on a Molecular Cubohemioctahedron Cairns, Amy J.; Perman, Jason A.; Wojtas, Lukasz Journal of the American Chemical Society, Vol. 130, Issue 5 https://doi.org/10.1021/ja078060t	journal	February 2008
Ethane/Ethene Separation Turned on Its Head: Selective Ethane Adsorption on the Metal−Organic Framework ZIF-7 through a Gate-Opening Mechanism Gücüyener, Canan; van den Bergh, Johan; Gascon, Jorge Journal of the American Chemical Society, Vol. 132, Issue 50 https://doi.org/10.1021/ja1089765	journal	December 2010
Soft Secondary Building Unit: Dynamic Bond Rearrangement on Multinuclear Core of Porous Coordination Polymers in Gas Media Seo, Joobeom; Bonneau, Charlotte; Matsuda, Ryotaro Journal of the American Chemical Society, Vol. 133, Issue 23 https://doi.org/10.1021/ja201484s	journal	June 2011
Opening the Gate: Framework Flexibility in ZIF-8 Explored by Experiments and Simulations Fairen-Jimenez, D.; Moggach, S. A.; Wharmby, M. T. Journal of the American Chemical Society, Vol. 133, Issue 23 https://doi.org/10.1021/ja202154j	journal	June 2011
“Nanoscale Lattice Fence” in a Metal–Organic Framework: Interplay between Hinged Topology and Highly Anisotropic Thermal Response DeVries, Lucas D.; Barron, Paul M.; Hurley, Evan P. Journal of the American Chemical Society, Vol. 133, Issue 38 https://doi.org/10.1021/ja2032822	journal	September 2011
Porous Coordination Polymer Hybrid Device with Quartz Oscillator: Effect of Crystal Size on Sorption Kinetics Uehara, Hiromitsu; Diring, Stéphane; Furukawa, Shuhei Journal of the American Chemical Society, Vol. 133, Issue 31 https://doi.org/10.1021/ja205082p	journal	August 2011
How Linker’s Modification Controls Swelling Properties of Highly Flexible Iron(III) Dicarboxylates MIL-88 Horcajada, Patricia; Salles, Fabrice; Wuttke, Stefan Journal of the American Chemical Society, Vol. 133, Issue 44 https://doi.org/10.1021/ja206936e	journal	November 2011
Reversible Alteration of CO ₂ Adsorption upon Photochemical or Thermal Treatment in a Metal–Organic Framework Park, Jinhee; Yuan, Daqiang; Pham, Khanh T. Journal of the American Chemical Society, Vol. 134, Issue 1 https://doi.org/10.1021/ja209197f	journal	December 2011
Single-Walled Polytetrazolate Metal–Organic Channels with High Density of Open Nitrogen-Donor Sites and Gas Uptake Lin, Qipu; Wu, Tao; Zheng, Shou-Tian Journal of the American Chemical Society, Vol. 134, Issue 2 https://doi.org/10.1021/ja2092882	journal	December 2011
Guest-to-Host Transmission of Structural Changes for Stimuli-Responsive Adsorption Property Yanai, Nobuhiro; Uemura, Takashi; Inoue, Masafumi Journal of the American Chemical Society, Vol. 134, Issue 10 https://doi.org/10.1021/ja2115713	journal	March 2012
Designing Higher Surface Area Metal–Organic Frameworks: Are Triple Bonds Better Than Phenyls? Farha, Omar K.; Wilmer, Christopher E.; Eryazici, Ibrahim Journal of the American Chemical Society, Vol. 134, Issue 24 https://doi.org/10.1021/ja302623w	journal	June 2012
Directing the Breathing Behavior of Pillared-Layered Metal–Organic Frameworks via a Systematic Library of Functionalized Linkers Bearing Flexible Substituents Henke, Sebastian; Schneemann, Andreas; Wütscher, Annika Journal of the American Chemical Society, Vol. 134, Issue 22 https://doi.org/10.1021/ja302991b	journal	May 2012
Metal–Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit? Farha, Omar K.; Eryazici, Ibrahim; Jeong, Nak Cheon Journal of the American Chemical Society, Vol. 134, Issue 36, p. 15016-15021 https://doi.org/10.1021/ja3055639	journal	August 2012
Tuning the Gate Opening Pressure of Metal–Organic Frameworks (MOFs) for the Selective Separation of Hydrocarbons Nijem, Nour; Wu, Haohan; Canepa, Pieremanuele Journal of the American Chemical Society, Vol. 134, Issue 37 https://doi.org/10.1021/ja305754f	journal	September 2012
Dimensionality Transformation through Paddlewheel Reconfiguration in a Flexible and Porous Zn-Based Metal–Organic Framework Stylianou, Kyriakos C.; Rabone, Jeremy; Chong, Samantha Y. Journal of the American Chemical Society, Vol. 134, Issue 50 https://doi.org/10.1021/ja308995t	journal	December 2012
MOFs Under Pressure: The Reversible Compression of a Single Crystal Gagnon, Kevin J.; Beavers, Christine M.; Clearfield, Abraham Journal of the American Chemical Society, Vol. 135, Issue 4 https://doi.org/10.1021/ja311613p	journal	January 2013
Tunable Anisotropic Thermal Expansion of a Porous Zinc(II) Metal–Organic Framework Grobler, Ilne; Smith, Vincent J.; Bhatt, Prashant M. Journal of the American Chemical Society, Vol. 135, Issue 17 https://doi.org/10.1021/ja401671p	journal	April 2013
Superprotonic Conductivity in a Highly Oriented Crystalline Metal–Organic Framework Nanofilm Xu, Gang; Otsubo, Kazuya; Yamada, Teppei Journal of the American Chemical Society, Vol. 135, Issue 20 https://doi.org/10.1021/ja402727d	journal	May 2013
Crystal Engineering: From Molecule to Crystal Desiraju, Gautam R. Journal of the American Chemical Society, Vol. 135, Issue 27 https://doi.org/10.1021/ja403264c	journal	June 2013
A Porous Metal–Organic Framework with Dynamic Pyrimidine Groups Exhibiting Record High Methane Storage Working Capacity Li, Bin; Wen, Hui-Min; Wang, Hailong Journal of the American Chemical Society, Vol. 136, Issue 17 https://doi.org/10.1021/ja501810r	journal	April 2014
Remarkable Pressure Responses of Metal–Organic Frameworks: Proton Transfer and Linker Coiling in Zinc Alkyl Gates Ortiz, Aurélie U.; Boutin, Anne; Gagnon, Kevin J. Journal of the American Chemical Society, Vol. 136, Issue 32 https://doi.org/10.1021/ja5060059	journal	July 2014
Supermolecular Building Blocks (SBBs) for the Design and Synthesis of Highly Porous Metal-Organic Frameworks Nouar, Farid; Eubank, Jarrod F.; Bousquet, Till Journal of the American Chemical Society, Vol. 130, Issue 6 https://doi.org/10.1021/ja710123s	journal	February 2008
Flexible Porous Metal-Organic Frameworks for a Controlled Drug Delivery Horcajada, Patricia; Serre, Christian; Maurin, Guillaume Journal of the American Chemical Society, Vol. 130, Issue 21 https://doi.org/10.1021/ja710973k	journal	May 2008
Homochiral Crystallization of Microporous Framework Materials from Achiral Precursors by Chiral Catalysis Zhang, Jian; Chen, Shumei; Wu, Tao Journal of the American Chemical Society, Vol. 130, Issue 39 https://doi.org/10.1021/ja805272j	journal	October 2008
Flexible (Breathing) Interpenetrated Metal−Organic Frameworks for CO ₂ Separation Applications Thallapally, Praveen K.; Tian, Jian; Radha Kishan, Motkuri Journal of the American Chemical Society, Vol. 130, Issue 50 https://doi.org/10.1021/ja806391k	journal	December 2008
Control of Pore Size and Functionality in Isoreticular Zeolitic Imidazolate Frameworks and their Carbon Dioxide Selective Capture Properties Banerjee, Rahul; Furukawa, Hiroyasu; Britt, David Journal of the American Chemical Society, Vol. 131, Issue 11, p. 3875-3877 https://doi.org/10.1021/ja809459e	journal	March 2009
A Porous Coordination Copolymer with over 5000 m ² /g BET Surface Area Koh, Kyoungmoo; Wong-Foy, Antek G.; Matzger, Adam J. Journal of the American Chemical Society, Vol. 131, Issue 12 https://doi.org/10.1021/ja809985t	journal	April 2009
Prediction of Breathing and Gate-Opening Transitions Upon Binary Mixture Adsorption in Metal−Organic Frameworks Coudert, François-Xavier; Mellot-Draznieks, Caroline; Fuchs, Alain H. Journal of the American Chemical Society, Vol. 131, Issue 32 https://doi.org/10.1021/ja904123f	journal	August 2009
A Pillared-Layer Coordination Polymer with a Rotatable Pillar Acting as a Molecular Gate for Guest Molecules Seo, Joobeom; Matsuda, Ryotaro; Sakamoto, Hirotoshi Journal of the American Chemical Society, Vol. 131, Issue 35 https://doi.org/10.1021/ja904363b	journal	September 2009
Functionalization in Flexible Porous Solids: Effects on the Pore Opening and the Host−Guest Interactions Devic, Thomas; Horcajada, Patricia; Serre, Christian Journal of the American Chemical Society, Vol. 132, Issue 3 https://doi.org/10.1021/ja9092715	journal	January 2010
Establishing Microporosity in Open Metal−Organic Frameworks: Gas Sorption Isotherms for Zn(BDC) (BDC = 1,4-Benzenedicarboxylate) Li, Hailian; Eddaoudi, Mohamed; Groy, Thomas L. Journal of the American Chemical Society, Vol. 120, Issue 33, p. 8571-8572 https://doi.org/10.1021/ja981669x	journal	August 1998
Mechanically Interlocked Linkers inside Metal–Organic Frameworks: Effect of Ring Size on Rotational Dynamics Vukotic, V. Nicholas; O’Keefe, Christopher A.; Zhu, Kelong Journal of the American Chemical Society, Vol. 137, Issue 30 https://doi.org/10.1021/jacs.5b04674	journal	July 2015
Control of Molecular Rotor Rotational Frequencies in Porous Coordination Polymers Using a Solid-Solution Approach Inukai, Munehiro; Fukushima, Tomohiro; Hijikata, Yuh Journal of the American Chemical Society, Vol. 137, Issue 38 https://doi.org/10.1021/jacs.5b05413	journal	September 2015
Tuning the Adsorption-Induced Phase Change in the Flexible Metal–Organic Framework Co(bdp) Taylor, Mercedes K.; Runčevski, Tomče; Oktawiec, Julia Journal of the American Chemical Society, Vol. 138, Issue 45 https://doi.org/10.1021/jacs.6b09155	journal	November 2016
The Influence of Intrinsic Framework Flexibility on Adsorption in Nanoporous Materials Witman, Matthew; Ling, Sanliang; Jawahery, Sudi Journal of the American Chemical Society, Vol. 139, Issue 15 https://doi.org/10.1021/jacs.7b01688	journal	April 2017
Syntheses and Characterization of Microporous Coordination Polymers with Open Frameworks Seki, K.; Mori, W. The Journal of Physical Chemistry B, Vol. 106, Issue 6, p. 1380-1385 https://doi.org/10.1021/jp0130416	journal	February 2002
Grand Canonical Monte Carlo Simulation of Low-Pressure Methane Adsorption in Nanoporous Framework Materials for Sensing Applications Zeitler, Todd R.; Allendorf, Mark D.; Greathouse, Jeffery A. The Journal of Physical Chemistry C, Vol. 116, Issue 5, p. 3492-3502 https://doi.org/10.1021/jp208596e	journal	January 2012
Adsorption-Induced Structural Transition of ZIF-8: A Combined Experimental and Simulation Study Tanaka, Hideki; Ohsaki, Shuji; Hiraide, Shotaro The Journal of Physical Chemistry C, Vol. 118, Issue 16 https://doi.org/10.1021/jp500931g	journal	April 2014
Utilizing the Gate-Opening Mechanism in ZIF-7 for Adsorption Discrimination between N ₂ O and CO ₂ Chen, De-Li; Wang, Ningwei; Wang, Fang-Fang The Journal of Physical Chemistry C, Vol. 118, Issue 31 https://doi.org/10.1021/jp5056733	journal	July 2014
Crystal-Size-Dependent Structural Transitions in Nanoporous Crystals: Adsorption-Induced Transitions in ZIF-8 Zhang, Chen; Gee, Jason A.; Sholl, David S. The Journal of Physical Chemistry C, Vol. 118, Issue 35 https://doi.org/10.1021/jp5081466	journal	August 2014
O ₂ Adsorption on ZIF-8: Temperature Dependence of the Gate-Opening Transition Russell, Brice; Villaroel, Jhonny; Sapag, Karim The Journal of Physical Chemistry C, Vol. 118, Issue 49 https://doi.org/10.1021/jp508382v	journal	November 2014
Molecular Dynamics Simulations on Gate Opening in ZIF-8: Identification of Factors for Ethane and Propane Separation Zheng, Bin; Pan, Yichang; Lai, Zhiping Langmuir, Vol. 29, Issue 28 https://doi.org/10.1021/la401015m	journal	June 2013
A chemically and electrochemically switchable molecular shuttle Bissell, Richard A.; Córdova, Emilio; Kaifer, Angel E. Nature, Vol. 369, Issue 6476 https://doi.org/10.1038/369133a0	journal	May 1994
Spontaneous assembly of a hinged coordination network Gardner, Geoffrey B.; Venkataraman, D.; Moore, Jeffrey S. Nature, Vol. 374, Issue 6525 https://doi.org/10.1038/374792a0	journal	April 1995
Design and synthesis of an exceptionally stable and highly porous metal-organic framework Li, Hailian; Eddaoudi, Mohamed; M., O'Keeffe Nature, Vol. 402, Issue 6759, p. 276-279 https://doi.org/10.1038/46248	journal	November 1999
Methane storage in flexible metal–organic frameworks with intrinsic thermal management Mason, Jarad A.; Oktawiec, Julia; Taylor, Mercedes K. Nature, Vol. 527, Issue 7578 https://doi.org/10.1038/nature15732	journal	October 2015
A pressure-amplifying framework material with negative gas adsorption transitions Krause, Simon; Bon, Volodymyr; Senkovska, Irena Nature, Vol. 532, Issue 7599 https://doi.org/10.1038/nature17430	journal	April 2016
Metal–organic frameworks with dynamic interlocked components Vukotic, V. Nicholas; Harris, Kristopher J.; Zhu, Kelong Nature Chemistry, Vol. 4, Issue 6 https://doi.org/10.1038/nchem.1354	journal	May 2012
Capturing snapshots of post-synthetic metallation chemistry in metal–organic frameworks Bloch, Witold M.; Burgun, Alexandre; Coghlan, Campbell J. Nature Chemistry, Vol. 6, Issue 10 https://doi.org/10.1038/nchem.2045	journal	September 2014
A molecular shuttle that operates inside a metal–organic framework Zhu, Kelong; O'Keefe, Christopher A.; Vukotic, V. Nicholas Nature Chemistry, Vol. 7, Issue 6 https://doi.org/10.1038/nchem.2258	journal	May 2015
Shuttling in the solid state Olson, Mark A. Nature Chemistry, Vol. 7, Issue 6 https://doi.org/10.1038/nchem.2268	journal	May 2015
Crystalline coordination framework endowed with dynamic gate-opening behaviour by being downsized to a thin film Sakaida, Shun; Otsubo, Kazuya; Sakata, Osami Nature Chemistry, Vol. 8, Issue 4 https://doi.org/10.1038/nchem.2469	journal	March 2016
Soft porous crystals Horike, Satoshi; Shimomura, Satoru; Kitagawa, Susumu Nature Chemistry, Vol. 1, Issue 9, p. 695-704 https://doi.org/10.1038/nchem.444	journal	November 2009
Robust dynamics Deng, Hexiang; Olson, Mark A.; Stoddart, J. Fraser Nature Chemistry, Vol. 2, Issue 6, p. 439-443 https://doi.org/10.1038/nchem.654	journal	May 2010
Selective sorption of oxygen and nitric oxide by an electron-donating flexible porous coordination polymer Shimomura, Satoru; Higuchi, Masakazu; Matsuda, Ryotaro Nature Chemistry, Vol. 2, Issue 8 https://doi.org/10.1038/nchem.684	journal	June 2010
De novo synthesis of a metal–organic framework material featuring ultrahigh surface area and gas storage capacities Farha, Omar K.; Özgür Yazaydın, A.; Eryazici, Ibrahim Nature Chemistry, Vol. 2, Issue 11, p. 944-948 https://doi.org/10.1038/nchem.834	journal	September 2010
A flexible interpenetrating coordination framework with a bimodal porous functionality Maji, Tapas Kumar; Matsuda, Ryotaro; Kitagawa, Susumu Nature Materials, Vol. 6, Issue 2 https://doi.org/10.1038/nmat1827	journal	January 2007
Gas-induced transformation and expansion of a non-porous organic solid Thallapally, Praveen K.; Peter McGrail, B.; Dalgarno, Scott J. Nature Materials, Vol. 7, Issue 2 https://doi.org/10.1038/nmat2097	journal	January 2008
A nanoporous molecular magnet with reversible solvent-induced mechanical and magnetic properties Maspoch, Daniel; Ruiz-Molina, Daniel; Wurst, Klaus Nature Materials, Vol. 2, Issue 3 https://doi.org/10.1038/nmat834	journal	February 2003
A selective magnetic sponge Férey, Gérard Nature Materials, Vol. 2, Issue 3 https://doi.org/10.1038/nmat837	journal	March 2003
V ^III (OH){O ₂ C–C ₆ H ₄ –CO ₂ }.(HO ₂ C–C ₆ H ₄ –CO ₂ H)x(DMF) _y (H ₂ O)z (or MIL-68), a new vanadocarboxylate with a large pore hybrid topology : reticular synthesis with infinite inorganic building blocks? Barthelet, K.; Marrot, J.; Férey, G. Chem. Commun., Issue 5 https://doi.org/10.1039/B312589K	journal	January 2004
Pore surface engineering of microporous coordination polymers Kitagawa, Susumu; Noro, Shin-ichiro; Nakamura, Takayoshi Chem. Commun., Issue 7, p. 701-707 https://doi.org/10.1039/B511728C	journal	January 2006
A new isoreticular class of metal-organic-frameworks with the MIL-88 topology Surblé, Suzy; Serre, Christian; Mellot-Draznieks, Caroline Chemical Communications, Vol. 0, Issue 3, p. 284-286 https://doi.org/10.1039/B512169H	journal	January 2006
A scandium coordination polymer constructed from trimeric octahedral building blocks and 2,5-dihydroxyterephthalate Dietzel, Pascal D. C.; Blom, Richard; Fjellvåg, Helmer Dalton Trans., Issue 17 https://doi.org/10.1039/B516365J	journal	January 2006
Flexible metal–organic supramolecular isomers for gas separation Radha Kishan, Motkuri; Tian, Jian; Thallapally, Praveen K. Chem. Commun., Vol. 46, Issue 4 https://doi.org/10.1039/B913910A	journal	January 2010
Gas storage in porous metal–organic frameworks for clean energy applications Ma, Shengqian; Zhou, Hong-Cai Chem. Commun., Vol. 46, Issue 1 https://doi.org/10.1039/B916295J	journal	January 2010
Guest-induced gate-opening of a zeolite imidazolate framework Aguado, Sonia; Bergeret, Gérard; Titus, Marc Pera New J. Chem., Vol. 35, Issue 3 https://doi.org/10.1039/C0NJ00836B	journal	January 2011
Electrical conductive coordination polymers Givaja, Gonzalo; Amo-Ochoa, Pilar; Gómez-García, Carlos J. Chem. Soc. Rev., Vol. 41, Issue 1 https://doi.org/10.1039/C1CS15092H	journal	January 2012
Great expectations: can artificial molecular machines deliver on their promise? Coskun, Ali; Banaszak, Michal; Astumian, R. Dean Chem. Soc. Rev., Vol. 41, Issue 1 https://doi.org/10.1039/C1CS15262A	journal	January 2012
A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO ₂ adsorption Mowat, John P. S.; Seymour, Valerie R.; Griffin, John M. Dalton Trans., Vol. 41, Issue 14 https://doi.org/10.1039/C1DT11729G	journal	January 2012
MOFs for CO ₂ capture and separation from flue gas mixtures: the effect of multifunctional sites on their adsorption capacity and selectivity Zhang, Zhijuan; Zhao, Yonggang; Gong, Qihan Chem. Commun., Vol. 49, Issue 7 https://doi.org/10.1039/C2CC35561B	journal	January 2013
Direct visualisation of carbon dioxide adsorption in gate-opening zeolitic imidazolate framework ZIF-7 Zhao, Pu; Lampronti, Giulio I.; Lloyd, Gareth O. J. Mater. Chem. A, Vol. 2, Issue 3 https://doi.org/10.1039/C3TA13981F	journal	January 2014
Flexible metal–organic frameworks Schneemann, A.; Bon, V.; Schwedler, I. Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C4CS00101J	journal	January 2014
Separation of polar compounds using a flexible metal–organic framework Motkuri, Radha Kishan; Thallapally, Praveen K.; Annapureddy, Harsha V. R. Chemical Communications, Vol. 51, Issue 40 https://doi.org/10.1039/C5CC00113G	journal	January 2015
Photoswitchable metal organic frameworks: turn on the lights and close the windows Castellanos, S.; Kapteijn, F.; Gascon, J. CrystEngComm, Vol. 18, Issue 22 https://doi.org/10.1039/C5CE02543E	journal	January 2016
Flexible MOFs under stress: pressure and temperature Clearfield, Abraham Dalton Transactions, Vol. 45, Issue 10 https://doi.org/10.1039/C5DT03228H	journal	January 2016
Tuning the flexibility in MOFs by SBU functionalization Bon, Volodymyr; Kavoosi, Negar; Senkovska, Irena Dalton Transactions, Vol. 45, Issue 10 https://doi.org/10.1039/C5DT03504J	journal	January 2016
Properties and emerging applications of mechanically interlocked ligands Lewis, James E. M.; Galli, Marzia; Goldup, Stephen M. Chemical Communications, Vol. 53, Issue 2 https://doi.org/10.1039/C6CC07377H	journal	January 2017
Particle size effects in the kinetic trapping of a structurally-locked form of a flexible MOF Linder-Patton, Oliver M.; Bloch, Witold M.; Coghlan, Campbell J. CrystEngComm, Vol. 18, Issue 22 https://doi.org/10.1039/C6CE00082G	journal	January 2016
Flexibility and disorder in metal–organic frameworks Bennett, Thomas D.; H. Fuchs, Alain; Cheetham, Anthony K. Dalton Transactions, Vol. 45, Issue 10 https://doi.org/10.1039/C6DT90026G	journal	January 2016
Effect of ring rotation upon gas adsorption in SIFSIX-3-M (M = Fe, Ni) pillared square grid networks Elsaidi, Sameh K.; Mohamed, Mona H.; Simon, Cory M. Chemical Science, Vol. 8, Issue 3 https://doi.org/10.1039/C6SC05012C	journal	January 2017
Synthesis, structure determination and properties of MIL-53as and MIL-53ht: the first Criii hybrid inorganic–organic microporous solids: Criii(OH)·{O2C–C6H4–CO2}·{HO2C–C6H4–CO2H}xElectronic supplementary information (ESI) available: crystal data, atomic coordinates and metrical parameters for MIL-53as and MIL-53ht. See http://www.rsc.org/suppdata/cc/b2/b201381a/ Millange, Franck; Serre, Christian; Férey, Gérard Chemical Communications, Issue 8 https://doi.org/10.1039/b201381a	journal	March 2002
Engineering coordination polymers towards applications Janiak, Christoph Dalton Transactions, Issue 14 https://doi.org/10.1039/b305705b	journal	January 2003
Dynamic porous properties of coordination polymers inspired by hydrogen bonds Kitagawa, Susumu; Uemura, Kazuhiro Chemical Society Reviews, Vol. 34, Issue 2 https://doi.org/10.1039/b313997m	journal	January 2005
Selective guest sorption in an interdigitated porous framework with hydrophobic pore surfaces Horike, Satoshi; Tanaka, Daisuke; Nakagawa, Keiji Chemical Communications, Issue 32 https://doi.org/10.1039/b703502k	journal	January 2007
Selective gas adsorption and separation in metal–organic frameworks Li, Jian-Rong; Kuppler, Ryan J.; Zhou, Hong-Cai Chemical Society Reviews, Vol. 38, Issue 5, p. 1477-1504 https://doi.org/10.1039/b802426j	journal	January 2009
Large breathing effects in three-dimensional porous hybrid matter: facts, analyses, rules and consequences Férey, Gérard; Serre, Christian Chemical Society Reviews, Vol. 38, Issue 5 https://doi.org/10.1039/b804302g	journal	January 2009
Metal–organic framework materials as catalysts Lee, JeongYong; Farha, Omar K.; Roberts, John Chemical Society Reviews, Vol. 38, Issue 5, p. 1450-1459 https://doi.org/10.1039/b807080f	journal	January 2009
Design and synthesis of metal–organic frameworks using metal–organic polyhedra as supermolecular building blocks Perry IV, John J.; Perman, Jason A.; Zaworotko, Michael J. Chemical Society Reviews, Vol. 38, Issue 5 https://doi.org/10.1039/b807086p	journal	January 2009
Effect of the nature of the metal on the breathing steps in MOFs with dynamic frameworks Millange, Franck; Guillou, Nathalie; Walton, Richard I. Chemical Communications, Issue 39 https://doi.org/10.1039/b809419e	journal	January 2008
Some suggested perspectives for multifunctional hybrid porous solids Férey, Gérard Dalton Transactions, Issue 23 https://doi.org/10.1039/b817360p	journal	January 2009
XRD and IR structural investigations of a particular breathing effect in the MOF-type gallium terephthalate MIL-53(Ga) Volkringer, Christophe; Loiseau, Thierry; Guillou, Nathalie Dalton Transactions, Issue 12 https://doi.org/10.1039/b817563b	journal	January 2009
A nanotubular metal–organic framework with permanent porosity: structure analysis and gas sorption studies Ma, Shengqian; Simmons, Jason M.; Yuan, Daqiang Chemical Communications, Issue 27 https://doi.org/10.1039/b906605e	journal	January 2009
Monitoring adsorption-induced switching by 129Xe NMR spectroscopy in a new metal–organic framework Ni2(2,6-ndc)2(dabco) Klein, Nicole; Herzog, Christin; Sabo, Michal Physical Chemistry Chemical Physics, Vol. 12, Issue 37 https://doi.org/10.1039/c003835k	journal	January 2010
Isoreticular synthesis and modification of frameworks with the UiO-66 topology Garibay, Sergio J.; Cohen, Seth M. Chemical Communications, Vol. 46, Issue 41, p. 7700-7702 https://doi.org/10.1039/c0cc02990d	journal	January 2010
The first porous MOF with photoswitchable linker molecules Modrow, Antje; Zargarani, Dordaneh; Herges, Rainer Dalton Transactions, Vol. 40, Issue 16 https://doi.org/10.1039/c0dt01629b	journal	January 2011
Role of hydrocarbons in pore expansion and contraction of a flexible metal–organic framework Motkuri, Radha Kishan; Thallapally, Praveen K.; Nune, Satish K. Chemical Communications, Vol. 47, Issue 25 https://doi.org/10.1039/c1cc11738f	journal	January 2011
Amorphization of the prototypical zeolitic imidazolate framework ZIF-8 by ball-milling Cao, Shuai; Bennett, Thomas D.; Keen, David A. Chemical Communications, Vol. 48, Issue 63 https://doi.org/10.1039/c2cc33773h	journal	January 2012
A highly porous metal–organic framework, constructed from a cuboctahedral super-molecular building block, with exceptionally high methane uptake Stoeck, Ulrich; Krause, Simon; Bon, Volodymyr Chemical Communications, Vol. 48, Issue 88 https://doi.org/10.1039/c2cc34840c	journal	January 2012
Flexibility and swing effect on the adsorption of energy-related gases on ZIF-8: combined experimental and simulation study Fairen-Jimenez, David; Galvelis, Raimondas; Torrisi, Antonio Dalton Transactions, Vol. 41, Issue 35 https://doi.org/10.1039/c2dt30774j	journal	January 2012
Structural flexibility and intrinsic dynamics in the M2(2,6-ndc)2(dabco) (M = Ni, Cu, Co, Zn) metal–organic frameworks Klein, Nicole; Hoffmann, Herbert C.; Cadiau, Amandine Journal of Materials Chemistry, Vol. 22, Issue 20 https://doi.org/10.1039/c2jm15601f	journal	January 2012
Large breathing of the MOF MIL-47(VIV) under mechanical pressure: a joint experimental–modelling exploration Yot, Pascal G.; Ma, Qintian; Haines, Julien Chemical Science, Vol. 3, Issue 4 https://doi.org/10.1039/c2sc00745b	journal	January 2012
Exceptional surface area from coordination copolymers derived from two linear linkers of differing lengths Koh, Kyoungmoo; Van Oosterhout, Jacob D.; Roy, Saikat Chemical Science, Vol. 3, Issue 8 https://doi.org/10.1039/c2sc20407j	journal	January 2012
Supramolecular mechanics in a metal–organic framework Ogborn, Joseph M.; Collings, Ines E.; Moggach, Stephen A. Chemical Science, Vol. 3, Issue 10 https://doi.org/10.1039/c2sc20596c	journal	January 2012
Two-step crystal engineering of porous nets from [Cr3(μ3-O)(RCO2)6] and [Cu3(μ3-Cl)(RNH2)6Cl6] molecular building blocks Elsaidi, Sameh K.; Mohamed, Mona H.; Wojtas, Lukasz Chemical Communications, Vol. 49, Issue 74 https://doi.org/10.1039/c3cc44133d	journal	January 2013
Partially fluorinated MIL-47 and Al-MIL-53 frameworks: influence of functionalization on sorption and breathing properties Biswas, Shyam; Rémy, Tom; Couck, Sarah Physical Chemistry Chemical Physics, Vol. 15, Issue 10 https://doi.org/10.1039/c3cp44204g	journal	January 2013
Photophysical pore control in an azobenzene-containing metal–organic framework Brown, Jonathan W.; Henderson, Bryana L.; Kiesz, Matthew D. Chemical Science, Vol. 4, Issue 7 https://doi.org/10.1039/c3sc21659d	journal	January 2013
Free energy analysis for adsorption-induced lattice transition of flexible coordination framework Watanabe, Satoshi; Sugiyama, Hayato; Adachi, Hirobumi The Journal of Chemical Physics, Vol. 130, Issue 16 https://doi.org/10.1063/1.3122988	journal	April 2009
Simulation study for adsorption-induced structural transition in stacked-layer porous coordination polymers: Equilibrium and hysteretic adsorption behaviors Numaguchi, Ryohei; Tanaka, Hideki; Watanabe, Satoshi The Journal of Chemical Physics, Vol. 138, Issue 5 https://doi.org/10.1063/1.4789810	journal	February 2013
Statistical mechanical model of gas adsorption in porous crystals with dynamic moieties Simon, Cory M.; Braun, Efrem; Carraro, Carlo Proceedings of the National Academy of Sciences, Vol. 114, Issue 3 https://doi.org/10.1073/pnas.1613874114	journal	January 2017
Chemistry and application of flexible porous coordination polymers Bureekaew, Sareeya; Shimomura, Satoru; Kitagawa, Susumu Science and Technology of Advanced Materials, Vol. 9, Issue 1 https://doi.org/10.1088/1468-6996/9/1/014108	journal	January 2008
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage Eddaoudi, Mohamed; Kim, Jaheon; Rosi, Nathaniel Science, Vol. 295, Issue 5554, p. 469-472 https://doi.org/10.1126/science.1067208	journal	January 2002
Hysteretic Adsorption and Desorption of Hydrogen by Nanoporous Metal-Organic Frameworks Zhao, X. Science, Vol. 306, Issue 5698 https://doi.org/10.1126/science.1101982	journal	November 2004
A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area Ferey, G.; Mellot-Draznieks, C.; Serre, C. Science, Vol. 309, Issue 5743, p. 2040-2042 https://doi.org/10.1126/science.1116275	journal	September 2005
Role of Solvent-Host Interactions That Lead to Very Large Swelling of Hybrid Frameworks Serre, C.; Mellot-Draznieks, C.; Surble, S. Science, Vol. 315, Issue 5820 https://doi.org/10.1126/science.1137975	journal	March 2007
Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks Deng, H.; Doonan, C. J.; Furukawa, H. Science, Vol. 327, Issue 5967, p. 846-850 https://doi.org/10.1126/science.1181761	journal	February 2010
An Adaptable Peptide-Based Porous Material Rabone, J.; Yue, Y. - F.; Chong, S. Y. Science, Vol. 329, Issue 5995 https://doi.org/10.1126/science.1190672	journal	August 2010
Shape-Memory Nanopores Induced in Coordination Frameworks by Crystal Downsizing Sakata, Y.; Furukawa, S.; Kondo, M. Science, Vol. 339, Issue 6116 https://doi.org/10.1126/science.1231451	journal	January 2013
Self-Accelerating CO Sorption in a Soft Nanoporous Crystal Sato, H.; Kosaka, W.; Matsuda, R. Science, Vol. 343, Issue 6167 https://doi.org/10.1126/science.1246423	journal	December 2013
A Chemically Functionalizable Nanoporous Material [Cu₃(TMA)₂(H₂O)₃]_n Chui, Stephen S.-Y.; Lo, Samuel M.-F.; Charmant, Jonathan P. H. Science, Vol. 283, Issue 5405, p. 1148-1150 https://doi.org/10.1126/science.283.5405.1148	journal	February 1999
Functionalized IRMOF-3: An Efficient Heterogeneous Catalyst for the Cycloaddition of Allyl Glycidyl Ether and CO₂ Kim, Yu-Jin; Park, Dae-Won Journal of Nanoscience and Nanotechnology, Vol. 13, Issue 3 https://doi.org/10.1166/jnn.2013.6878	journal	March 2013
Terminology of metal–organic frameworks and coordination polymers (IUPAC Recommendations 2013) Batten, Stuart R.; Champness, Neil R.; Chen, Xiao-Ming Pure and Applied Chemistry, Vol. 85, Issue 8 https://doi.org/10.1351/PAC-REC-12-11-20	journal	July 2013

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