Flexibility in Metal–Organic Frameworks: A fundamental understanding

doi:10.1016/j.ccr.2017.11.022

Title: Flexibility in Metal–Organic Frameworks: A fundamental understanding

Full Record
Other Related Research

Authors:: Elsaidi, Sameh K.; Mohamed, Mona H.; Banerjee, Debasis; Thallapally, Praveen K.

Publication Date:: 2018-03-01

Sponsoring Org.:: USDOE Office of Nuclear Energy (NE); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Geothermal Technologies Office (EE-4G)

OSTI Identifier:: 1576843

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Coordination Chemistry Reviews

Additional Journal Information:: Journal Name: Coordination Chemistry Reviews Journal Volume: 358 Journal Issue: C; Journal ID: ISSN 0010-8545

Publisher:: Elsevier

Country of Publication:: Netherlands

Language:: English

Citation Formats


                    Elsaidi, Sameh K., Mohamed, Mona H., Banerjee, Debasis, and Thallapally, Praveen K. Flexibility in Metal–Organic Frameworks: A fundamental understanding.  Netherlands: N. p., 2018. 
        Web.  doi:10.1016/j.ccr.2017.11.022.

Copy to clipboard


                    Elsaidi, Sameh K., Mohamed, Mona H., Banerjee, Debasis, & Thallapally, Praveen K. Flexibility in Metal–Organic Frameworks: A fundamental understanding.  Netherlands.  doi:10.1016/j.ccr.2017.11.022.

Copy to clipboard


                    Elsaidi, Sameh K., Mohamed, Mona H., Banerjee, Debasis, and Thallapally, Praveen K. Thu .  
        "Flexibility in Metal–Organic Frameworks: A fundamental understanding".  Netherlands.  doi:10.1016/j.ccr.2017.11.022.

Copy to clipboard


                    
@article{osti_1576843,

  title        = {Flexibility in Metal–Organic Frameworks: A fundamental understanding},

  author       = {Elsaidi, Sameh K. and Mohamed, Mona H. and Banerjee, Debasis and Thallapally, Praveen K.},

  abstractNote = {},

  doi          = {10.1016/j.ccr.2017.11.022},

  journal      = {Coordination Chemistry Reviews},

  number       = C,

  volume       = 358,

  place        = {Netherlands},

  year         = {2018},

  month        = {3}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
DOI: 10.1016/j.ccr.2017.11.022

Other availability

Search WorldCat to find libraries that may hold this journal

Save / Share:

Export Metadata

Save to My Library

Similar records in OSTI.GOV collections:

Multifaceted Modularity: A Key for Stepwise Building of Hierarchical Complexity in Actinide Metal–Organic Frameworks

Journal Article Dolgopolova, Ekaterina A. ; Ejegbavwo, Otega A. ; Martin, Corey R. ; ... - Journal of the American Chemical Society

Growing necessity for efficient nuclear waste management is a driving force for development of alternative architectures towards fundamental understanding of mechanisms involved in actinide integration inside extended structures. In this manuscript, metal-organic frameworks (MOFs) were investigated as a model system for engineering radionuclide containing materials through utilization of unprecedented MOF modularity, which cannot be replicated in any other type of materials. Through the implementation of recent synthetic advances in the MOF field, hierarchical complexity of An-materials were built stepwise, which was only feasible due to preparation of the first examples of actinide-based frameworks with “unsaturated” metal nodes. The first successfulmore »« less
DOI: 10.1021/jacs.7b09496
Hydrogen Storage in Metal-Organic Frameworks

Technical Report Long, Jeffrey R.

The design and characterization of new materials for hydrogen storage is an important area of research, as the ability to store hydrogen at lower pressures and higher temperatures than currently feasible would lower operating costs for small hydrogen fuel cell vehicles. In particular, metal-organic frameworks (MOFs) represent promising materials for use in storing hydrogen in this capacity. MOFs are highly porous, three-dimensional crystalline solids that are formed via linkages between metal ions (e.g., iron, nickel, and zinc) and organic molecules. MOFs can store hydrogen via strong adsorptive interactions between the gas molecules and the pores of the framework, providing amore »« less
DOI: 10.2172/1348879

Full Text Available
Theoretical Studies of Spin Crossover Metal-Organic Frameworks

Technical Report Paesani, Francesco

The research carried out within this grant focused on characterizing spin crossover (SCO) transitions, i.e., the change in spin state, in metal-organic frameworks (MOFs). MOFs are three-dimensional networks in which metal ions or clusters are connected to multidentate ligands. By combining high porosity, large surface area, guest selectivity, structural flexibility, and SCO properties, MOFs provide a promising platform for the development of multifunctional materials, such as molecular switches, memory devices, and chemical sensors. To characterize the SCO properties of MOFs at the molecular level, we have developed a hybrid Monte Carlo / molecular dynamics (MC/MD) method that builds upon themore »« less
DOI: 10.2172/1436510

Full Text Available
Electronic properties of bimetallic metal–organic frameworks (MOFs): Tailoring the density of electronic states through MOF modularity

Journal Article Dolgopolova, Ekaterina A. ; Brandt, Amy J. ; Ejegbavwo, Otega A. ; ... - Journal of the American Chemical Society

The development of porous well-defined hybrid materials (e.g., metal-organic frameworks or MOFs) will add a new dimension to a wide number of applications ranging from supercapacitors and electrodes to 'smart' membranes and thermoelectrics. From this perspective, the understanding and tailoring of the electronic properties of MOFs are key fundamental challenges that could unlock the full potential of these materials. In this work, we focused on the fundamental insights responsible for the electronic properties of three distinct classes of bimetallic systems, M _x-yM' _y-MOFs, M _xM' _y- MOFs, and M _x(ligand-M' _y)-MOFs, in which the second metal (M') incorporation occurs throughmore »« less
Cited by 12
DOI: 10.1021/jacs.7b01125

Full Text Available
Tuning the Adsorption-Induced Phase Change in the Flexible Metal–Organic Framework Co(bdp)

Journal Article Taylor, Mercedes K. ; Runčevski, Tomče ; Oktawiec, Julia ; ... - Journal of the American Chemical Society

Metal–organic frameworks that flex to undergo structural phase changes upon gas adsorption are promising materials for gas storage and separations, and achieving synthetic control over the pressure at which these changes occur is crucial to the design of such materials for specific applications. To this end, a new family of materials based on the flexible metal–organic framework Co(bdp) (bdp ^2– = 1,4-benzenedipyrazolate) has been prepared via the introduction of fluorine, deuterium, and methyl functional groups on the bdp ^2– ligand, namely, Co(F-bdp), Co(p-F ₂-bdp), Co(o-F ₂-bdp), Co(D ₄-bdp), and Co(p-Me ₂-bdp). These frameworks are isoreticular to the parent framework andmore »« less
Cited by 8
DOI: 10.1021/jacs.6b09155

Similar Records