Controlling dinitrogen functionalization at rhenium through alkali metal ion pairing
Abstract
The rhenium( i ) salt Na[Re(η 5 -Cp)(BDI)] can be cooled in solution under a dinitrogen atmosphere to selectively access complexes containing rhenium( iii ) centers bound to direduced, doubly-bonded N 2 ( i.e. diazenide) fragments.
- Authors:
-
- Department of Chemistry, University of California, Berkeley, USA, Chemical Sciences Division
- Department of Chemistry, University of California, Berkeley, USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1576825
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Dalton Transactions
- Additional Journal Information:
- Journal Name: Dalton Transactions Journal Volume: 48 Journal Issue: 48; Journal ID: ISSN 1477-9226
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
Citation Formats
Lohrey, Trevor D., Bergman, Robert G., and Arnold, John. Controlling dinitrogen functionalization at rhenium through alkali metal ion pairing. United Kingdom: N. p., 2019.
Web. doi:10.1039/C9DT04489B.
Lohrey, Trevor D., Bergman, Robert G., & Arnold, John. Controlling dinitrogen functionalization at rhenium through alkali metal ion pairing. United Kingdom. https://doi.org/10.1039/C9DT04489B
Lohrey, Trevor D., Bergman, Robert G., and Arnold, John. Tue .
"Controlling dinitrogen functionalization at rhenium through alkali metal ion pairing". United Kingdom. https://doi.org/10.1039/C9DT04489B.
@article{osti_1576825,
title = {Controlling dinitrogen functionalization at rhenium through alkali metal ion pairing},
author = {Lohrey, Trevor D. and Bergman, Robert G. and Arnold, John},
abstractNote = {The rhenium( i ) salt Na[Re(η 5 -Cp)(BDI)] can be cooled in solution under a dinitrogen atmosphere to selectively access complexes containing rhenium( iii ) centers bound to direduced, doubly-bonded N 2 ( i.e. diazenide) fragments.},
doi = {10.1039/C9DT04489B},
journal = {Dalton Transactions},
number = 48,
volume = 48,
place = {United Kingdom},
year = {Tue Dec 10 00:00:00 EST 2019},
month = {Tue Dec 10 00:00:00 EST 2019}
}
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1039/C9DT04489B
https://doi.org/10.1039/C9DT04489B
Other availability
Cited by: 12 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
An Fe-N 2 Complex That Generates Hydrazine and Ammonia via Fe═NNH 2 : Demonstrating a Hybrid Distal-to-Alternating Pathway for N 2 Reduction
journal, March 2016
- Rittle, Jonathan; Peters, Jonas C.
- Journal of the American Chemical Society, Vol. 138, Issue 12
Carbynes generated from metal carbonyl and isocyanide complexes; intermediates in the reductive coupling of carbonyl and CNR ligands
journal, April 1988
- Vrtis, Raymond N.; Rao, C. Pulla.; Warner, Steve.
- Journal of the American Chemical Society, Vol. 110, Issue 8
Dinitrogen Coordination Chemistry: On the Biomimetic Borderlands
journal, February 2004
- MacKay, Bruce A.; Fryzuk, Michael D.
- Chemical Reviews, Vol. 104, Issue 2
N 2 Functionalization at Iron Metallaboratranes
journal, November 2011
- Moret, Marc-Etienne; Peters, Jonas C.
- Journal of the American Chemical Society, Vol. 133, Issue 45
Mechanism of Chemical and Electrochemical N 2 Splitting by a Rhenium Pincer Complex
journal, May 2018
- Lindley, Brian M.; van Alten, Richt S.; Finger, Markus
- Journal of the American Chemical Society, Vol. 140, Issue 25
Lewis base behavior of einitrogen and carbonyl complexes of rhenium toward titanium tetrachloride and related species
journal, February 1974
- Robson, R.
- Inorganic Chemistry, Vol. 13, Issue 2
Catalytic conversion of nitrogen to ammonia by an iron model complex
journal, September 2013
- Anderson, John S.; Rittle, Jonathan; Peters, Jonas C.
- Nature, Vol. 501, Issue 7465
Preparation of Heterobimetallic Complexes with a Bridging Dinitrogen Ligand, [WX(PMe2Ph)4(.mu.-N2)MCp2Cl] (M = Ti, X = Cl; M = Zr, and Hf, X = I), and X-ray Structure of [WI(PMe2Ph)3(py)(.mu.-N2)ZrCp2Cl] (py = pyridine)
journal, October 1994
- Mizobe, Yasushi; Yokobayashi, Youhei; Oshita, Hiroyuki
- Organometallics, Vol. 13, Issue 10
Insight into the Iron–Molybdenum Cofactor of Nitrogenase from Synthetic Iron Complexes with Sulfur, Carbon, and Hydride Ligands
journal, June 2016
- Čorić, Ilija; Holland, Patrick L.
- Journal of the American Chemical Society, Vol. 138, Issue 23
Coordination chemistry insights into the role of alkali metal promoters in dinitrogen reduction
journal, May 2017
- Connor, Gannon P.; Holland, Patrick L.
- Catalysis Today, Vol. 286
Nitrogen Fixation via a Terminal Fe(IV) Nitride
journal, October 2017
- Thompson, Niklas B.; Green, Michael T.; Peters, Jonas C.
- Journal of the American Chemical Society, Vol. 139, Issue 43
The controlled relay of multiple protons required at the active site of nitrogenase
journal, January 2012
- Dance, Ian
- Dalton Transactions, Vol. 41, Issue 25
Oxidation and Reduction of Bis(imino)pyridine Iron Dinitrogen Complexes: Evidence for Formation of a Chelate Trianion.
journal, December 2012
- Tondreau, Aaron M.; Stieber, S. Chantal E.; Milsmann, Carsten
- Inorganic Chemistry, Vol. 52, Issue 2
Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage
journal, January 2014
- Hoffman, Brian M.; Lukoyanov, Dmitriy; Yang, Zhi-Yong
- Chemical Reviews, Vol. 114, Issue 8
On the rate-determining step and the role of potassium in the catalytic synthesis of ammonia
journal, January 1992
- Spencer, M. S.
- Catalysis Letters, Vol. 13, Issue 1-2
Chemical Evidence concerning the Function of Molybdenum in Nitrogenase
journal, December 1969
- Chatt, J.; Dilworth, J. R.; Richards, R. L.
- Nature, Vol. 224, Issue 5225
Catalytic Nitrogen-to-Ammonia Conversion by Osmium and Ruthenium Complexes
journal, November 2017
- Fajardo, Javier; Peters, Jonas C.
- Journal of the American Chemical Society, Vol. 139, Issue 45
Catalytic Silylation of Dinitrogen by a Family of Triiron Complexes
journal, July 2018
- Ferreira, Ricardo B.; Cook, Brian J.; Knight, Brian J.
- ACS Catalysis, Vol. 8, Issue 8
The chemistry of metal carbonyl anions
journal, October 1975
- Ellis, John E.; Flom, Elroy A.
- Journal of Organometallic Chemistry, Vol. 99, Issue 2
Studies Relevant to Catalytic Reduction of Dinitrogen to Ammonia by Molybdenum Triamidoamine Complexes
journal, February 2005
- Yandulov, Dmitry V.; Schrock, Richard R.
- Inorganic Chemistry, Vol. 44, Issue 4
Transformation of Acyclic Alkenes to Hydrido Carbynes by (PNP R )Re Complexes
journal, May 2004
- Ozerov, Oleg V.; Watson, Lori A.; Pink, Maren
- Journal of the American Chemical Society, Vol. 126, Issue 20
Ligand binding to the FeMo-cofactor: Structures of CO-bound and reactivated nitrogenase
journal, September 2014
- Spatzal, T.; Perez, K. A.; Einsle, O.
- Science, Vol. 345, Issue 6204
Synthesis and characterization of titanium tetraisocyanide complexes, [CpTi(CNXyl)4E], E=I, SnPh3, and SnMe3
journal, April 2008
- Allen, Jessica M.; Ellis, John E.
- Journal of Organometallic Chemistry, Vol. 693, Issue 8-9
Expanding Boundaries: N 2 Cleavage and Functionalization beyond Early Transition Metals
journal, June 2016
- Bezdek, Máté J.; Chirik, Paul J.
- Angewandte Chemie International Edition, Vol. 55, Issue 28
Conversion of Dinitrogen into Acetonitrile under Ambient Conditions
journal, March 2016
- Klopsch, Isabel; Kinauer, Markus; Finger, Markus
- Angewandte Chemie International Edition, Vol. 55, Issue 15
Polynuclear dinitrogen complexes
journal, January 1970
- Chatt, J.; Dilworth, J. R.; Leigh, G. J.
- Journal of the Chemical Society D: Chemical Communications, Issue 15
CO Coupling Chemistry of a Terminal Mo Carbide: Sequential Addition of Proton, Hydride, and CO Releases Ethenone
journal, September 2019
- Buss, Joshua A.; Bailey, Gwendolyn A.; Oppenheim, Julius
- Journal of the American Chemical Society, Vol. 141, Issue 39
Dinitrogen activation by group 4 and group 5 metal complexes supported by phosphine-amido containing ligand manifolds
journal, March 2017
- Burford, Richard J.; Yeo, Alyssa; Fryzuk, Michael D.
- Coordination Chemistry Reviews, Vol. 334
Fe-N2/CO complexes that model a possible role for the interstitial C atom of FeMo-cofactor (FeMoco)
journal, September 2013
- Rittle, J.; Peters, J. C.
- Proceedings of the National Academy of Sciences, Vol. 110, Issue 40
Derivatization of Dinitrogen by Molybdenum in Triamidoamine Complexes
journal, October 1998
- O'Donoghue, Myra B.; Davis, William M.; Schrock, Richard R.
- Inorganic Chemistry, Vol. 37, Issue 20
Recent advances in catalytic silylation of dinitrogen using transition metal complexes
journal, June 2019
- Tanabe, Yoshiaki; Nishibayashi, Yoshiaki
- Coordination Chemistry Reviews, Vol. 389
Metathetical reactions of rhenium(VII) alkylidene-alkylidyne complexes of the type Re(CR')(CHR')[OCMe(CF3)2]2 (R' = CMe3 or CMe2Ph) with terminal and internal olefins
journal, January 1993
- Toreki, Robert; Vaughan, G. Alan; Schrock, Richard R.
- Journal of the American Chemical Society, Vol. 115, Issue 1
Synthesis of tungsten complexes that contain hexaisopropylterphenyl-substituted triamidoamine ligands, and reactions relevant to the reduction of dinitrogen to ammonia
journal, April 2005
- Yandulov, Dmitry V.; Schrock, Richard R.
- Canadian Journal of Chemistry, Vol. 83, Issue 4
The Effect of the Redox Potential on the Activity of the Nitrogenase and on the Fe-Protein of Azotobacter vinelandi
journal, January 1982
- Braaksma, Arnold; Haaker, Huub; Grande, Hans J.
- European Journal of Biochemistry, Vol. 121, Issue 3
Evaluating Molecular Cobalt Complexes for the Conversion of N 2 to NH 3
journal, May 2015
- Del Castillo, Trevor J.; Thompson, Niklas B.; Suess, Daniel L. M.
- Inorganic Chemistry, Vol. 54, Issue 19
A molybdenum complex bearing PNP-type pincer ligands leads to the catalytic reduction of dinitrogen into ammonia
journal, December 2010
- Arashiba, Kazuya; Miyake, Yoshihiro; Nishibayashi, Yoshiaki
- Nature Chemistry, Vol. 3, Issue 2
Molybdenum-catalysed ammonia production with samarium diiodide and alcohols or water
journal, April 2019
- Ashida, Yuya; Arashiba, Kazuya; Nakajima, Kazunari
- Nature, Vol. 568, Issue 7753
O -Functionalization of a cobalt carbonyl generates a terminal cobalt carbyne
journal, January 2019
- Deegan, Meaghan M.; Peters, Jonas C.
- Chemical Communications, Vol. 55, Issue 64
H 2 Activation and Direct Access to Terminal Nitride and cyclo -P 3 Complexes by an Acceptor-Free Rhenium(II) β-Diketiminate
journal, September 2019
- Lohrey, Trevor D.; Rao, Guodong; Britt, R. David
- Inorganic Chemistry, Vol. 58, Issue 19
Recent advances in the chemistry of nitrogen fixation
journal, December 1978
- Chatt, Joseph.; Dilworth, Jonathan R.; Richards, Raymond L.
- Chemical Reviews, Vol. 78, Issue 6
Recent Progress in Transition-Metal-Catalyzed Reduction of Molecular Dinitrogen under Ambient Reaction Conditions
journal, July 2015
- Nishibayashi, Yoshiaki
- Inorganic Chemistry, Vol. 54, Issue 19
Testing the Push–Pull Hypothesis: Lewis Acid Augmented N 2 Activation at Iron
journal, April 2017
- Geri, Jacob B.; Shanahan, James P.; Szymczak, Nathaniel K.
- Journal of the American Chemical Society, Vol. 139, Issue 16
Binding of dinitrogen to an iron–sulfur–carbon site
journal, September 2015
- Čorić, Ilija; Mercado, Brandon Q.; Bill, Eckhard
- Nature, Vol. 526, Issue 7571
Dinitrogen functionalization at a ditantalum center. Balancing N 2 displacement and N 2 functionalization in the reaction of coordinated N 2 with CS 2
journal, January 2018
- Burford, Richard J.; Castro, Ludovic; Maron, Laurent
- Dalton Transactions, Vol. 47, Issue 24
A Uranium Tri-Rhenium Triple Inverse Sandwich Compound
journal, March 2019
- Boreen, Michael A.; Lohrey, Trevor D.; Rao, Guodong
- Journal of the American Chemical Society, Vol. 141, Issue 13
Direct formation of acylazo- and aroylazo-rhenium(III) complexes from rhenium(I) dinitrogen complexes
journal, September 1973
- Chatt, Joseph; Heath, Graham A.; Hooper, Norman E.
- Journal of Organometallic Chemistry, Vol. 57, Issue 2
On the role of promoters in promoted iron catalysts used in the industrial synthesis of ammonia
journal, August 1990
- Vandervell, H. D.; Waugh, K. C.
- Chemical Physics Letters, Vol. 171, Issue 5-6
Supramolecular chemistry of gold(I) thiocyanate complexes with thiophene, phosphine and isocyanide ligands, and the structure of 2,6-dimethylphenyl isocyanide
journal, January 2001
- Mathieson, Trevor; Schier, Annette; Schmidbaur, Hubert
- Journal of the Chemical Society, Dalton Transactions, Issue 8
A Multi-iron System Capable of Rapid N 2 Formation and N 2 Cleavage
journal, July 2014
- MacLeod, K. Cory; Vinyard, David J.; Holland, Patrick L.
- Journal of the American Chemical Society, Vol. 136, Issue 29
Heterotetrametallic Re–Zn–Zn–Re Complex Generated by an Anionic Rhenium(I) β-Diketiminate
journal, December 2018
- Lohrey, Trevor D.; Maron, Laurent; Bergman, Robert G.
- Journal of the American Chemical Society, Vol. 141, Issue 2
A CO-Derived Iron Dicarbyne That Releases Olefin upon Hydrogenation
journal, August 2013
- Suess, Daniel L. M.; Peters, Jonas C.
- Journal of the American Chemical Society, Vol. 135, Issue 34
Efficient Catalytic Conversion of Dinitrogen to N(SiMe 3 ) 3 Using a Homogeneous Mononuclear Cobalt Complex
journal, March 2018
- Suzuki, Tatsuya; Fujimoto, Keisuke; Takemoto, Yoshiyuki
- ACS Catalysis, Vol. 8, Issue 4
Kinetic, spectroscopic, and structural evidence for carbene-carbyne intermediates in carbyne/CO coupling
journal, January 1993
- Protasiewicz, John D.; Masschelein, Axel; Lippard, Stephen J.
- Journal of the American Chemical Society, Vol. 115, Issue 2
Direct Synthesis of Silylamine from N 2 and a Silane: Mediated by a Tridentate Phosphine Molybdenum Fragment
journal, August 2016
- Liao, Qian; Cavaillé, Anthony; Saffon-Merceron, Nathalie
- Angewandte Chemie International Edition, Vol. 55, Issue 37
Preparation and properties of molybdenum and tungsten dinitrogen complexes. 25. Catalytic conversion of molecular nitrogen into silylamines using molybdenum and tungsten dinitrogen complexes
journal, March 1989
- Komori, Keiko; Oshita, Hiroyuki; Mizobe, Yasushi
- Journal of the American Chemical Society, Vol. 111, Issue 5
Catalytic Reduction of Dinitrogen to Ammonia at a Single Molybdenum Center
journal, July 2003
- Yandulov, D. V.
- Science, Vol. 301, Issue 5629
Electrostatic polarization of nonpolar substrates: a study of interactions between simple cations and Mo-bound N 2
journal, January 2019
- Pap, Levente G.; Couldridge, Adam; Arulsamy, Navamoney
- Dalton Transactions, Vol. 48, Issue 29
Diazo Complexes of Rhenium: Preparations and Crystal Structures of the Bis(dinitrogen), [Re(N 2 ) 2 {PPh(OEt) 2 } 4 ][BPh 4 ] and Methyldiazenido [ReCl(CH 3 N 2 )(CH 3 NHNH 2 ){PPh(OEt) 2 } 3 ][BPh 4 ] Derivatives
journal, July 2000
- Albertin, Gabriele; Antoniutti, Stefano; Bacchi, Alessia
- Inorganic Chemistry, Vol. 39, Issue 15
Heterobimetallic Dinitrogen Complexes That Contain the {[N 3 N]Mo−NN} - Ligand
journal, January 1999
- O'Donoghue, Myra B.; Davis, William M.; Schrock, Richard R.
- Inorganic Chemistry, Vol. 38, Issue 2
Four-electron deoxygenative reductive coupling of carbon monoxide at a single metal site
journal, December 2015
- Buss, Joshua A.; Agapie, Theodor
- Nature, Vol. 529, Issue 7584
Dinitrogen Splitting and Functionalization in the Coordination Sphere of Rhenium
journal, May 2014
- Klopsch, Isabel; Finger, Markus; Würtele, Christian
- Journal of the American Chemical Society, Vol. 136, Issue 19
Redox-Catalyzed Binding of Dinitrogen by Molybdenum N - tert -Hydrocarbylanilide Complexes: Implications for Dinitrogen Functionalization and Reductive Cleavage
journal, November 1999
- Peters, Jonas C.; Cherry, John-Paul F.; Thomas, J. Christopher
- Journal of the American Chemical Society, Vol. 121, Issue 43
Terminal Phosphide and Dinitrogen Molybdenum Compounds Obtained from Pnictide-Bridged Precursors
journal, December 2001
- Cherry, John-Paul F.; Stephens, Frances H.; Johnson, Marc J. A.
- Inorganic Chemistry, Vol. 40, Issue 27
Recent Advances in the Chemistry of Dinitrogen Complexes
journal, June 1995
- Hidai, Masanobu.; Mizobe, Yasushi.
- Chemical Reviews, Vol. 95, Issue 4
Nitrogen reduction and functionalization by a multimetallic uranium nitride complex
journal, July 2017
- Falcone, Marta; Chatelain, Lucile; Scopelliti, Rosario
- Nature, Vol. 547, Issue 7663