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Title: Controlling dinitrogen functionalization at rhenium through alkali metal ion pairing

Abstract

The rhenium( i ) salt Na[Re(η 5 -Cp)(BDI)] can be cooled in solution under a dinitrogen atmosphere to selectively access complexes containing rhenium( iii ) centers bound to direduced, doubly-bonded N 2 ( i.e. diazenide) fragments.

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [1]
  1. Department of Chemistry, University of California, Berkeley, USA, Chemical Sciences Division
  2. Department of Chemistry, University of California, Berkeley, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1576825
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions Journal Volume: 48 Journal Issue: 48; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Lohrey, Trevor D., Bergman, Robert G., and Arnold, John. Controlling dinitrogen functionalization at rhenium through alkali metal ion pairing. United Kingdom: N. p., 2019. Web. doi:10.1039/C9DT04489B.
Lohrey, Trevor D., Bergman, Robert G., & Arnold, John. Controlling dinitrogen functionalization at rhenium through alkali metal ion pairing. United Kingdom. doi:10.1039/C9DT04489B.
Lohrey, Trevor D., Bergman, Robert G., and Arnold, John. Tue . "Controlling dinitrogen functionalization at rhenium through alkali metal ion pairing". United Kingdom. doi:10.1039/C9DT04489B.
@article{osti_1576825,
title = {Controlling dinitrogen functionalization at rhenium through alkali metal ion pairing},
author = {Lohrey, Trevor D. and Bergman, Robert G. and Arnold, John},
abstractNote = {The rhenium( i ) salt Na[Re(η 5 -Cp)(BDI)] can be cooled in solution under a dinitrogen atmosphere to selectively access complexes containing rhenium( iii ) centers bound to direduced, doubly-bonded N 2 ( i.e. diazenide) fragments.},
doi = {10.1039/C9DT04489B},
journal = {Dalton Transactions},
number = 48,
volume = 48,
place = {United Kingdom},
year = {2019},
month = {12}
}

Journal Article:
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