Switching in Metal–Organic Frameworks
Abstract
Abstract In recent years, metal–organic frameworks (MOFs) have become an area of intense research interest because of their adjustable pores and nearly limitless structural diversity deriving from the design of different organic linkers and metal structural building units (SBUs). Among the recent great challenges for scientists include switchable MOFs and their corresponding applications. Switchable MOFs are a type of smart material that undergo distinct, reversible, chemical changes in their structure upon exposure to external stimuli, yielding interesting technological applicability. Although the process of switching shares similarities with flexibility, very limited studies have been devoted specifically to switching, while a fairly large amount of research and a number of Reviews have covered flexibility in MOFs. This Review focuses on the properties and general design of switchable MOFs. The switching activity has been delineated based on the cause of the switching: light, spin crossover (SCO), redox, temperature, and wettability.
- Authors:
-
- Tarbiat Modares Univ., Tehran (Iran). Dept. of Chemistry. Faculty of Sciences
- Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry
- Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry. Dept. of Materials Science and Engineering
- Publication Date:
- Research Org.:
- Univ. of California, Berkeley, CA (United States). Center for Gas Separations (CGS) (EFRC)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1801399
- Alternate Identifier(s):
- OSTI ID: 1576802
- Grant/Contract Number:
- SC0001015
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Angewandte Chemie (International Edition)
- Additional Journal Information:
- Journal Name: Angewandte Chemie (International Edition); Journal Volume: 59; Journal Issue: 12; Journal ID: ISSN 1433-7851
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; switchable materials; molecular devices; metal–organic frameworks; host–guest systems; adsorption
Citation Formats
Bigdeli, Fahime, Lollar, Christina T., Morsali, Ali, and Zhou, Hong‐Cai. Switching in Metal–Organic Frameworks. United States: N. p., 2019.
Web. doi:10.1002/anie.201900666.
Bigdeli, Fahime, Lollar, Christina T., Morsali, Ali, & Zhou, Hong‐Cai. Switching in Metal–Organic Frameworks. United States. https://doi.org/10.1002/anie.201900666
Bigdeli, Fahime, Lollar, Christina T., Morsali, Ali, and Zhou, Hong‐Cai. Mon .
"Switching in Metal–Organic Frameworks". United States. https://doi.org/10.1002/anie.201900666. https://www.osti.gov/servlets/purl/1801399.
@article{osti_1801399,
title = {Switching in Metal–Organic Frameworks},
author = {Bigdeli, Fahime and Lollar, Christina T. and Morsali, Ali and Zhou, Hong‐Cai},
abstractNote = {Abstract In recent years, metal–organic frameworks (MOFs) have become an area of intense research interest because of their adjustable pores and nearly limitless structural diversity deriving from the design of different organic linkers and metal structural building units (SBUs). Among the recent great challenges for scientists include switchable MOFs and their corresponding applications. Switchable MOFs are a type of smart material that undergo distinct, reversible, chemical changes in their structure upon exposure to external stimuli, yielding interesting technological applicability. Although the process of switching shares similarities with flexibility, very limited studies have been devoted specifically to switching, while a fairly large amount of research and a number of Reviews have covered flexibility in MOFs. This Review focuses on the properties and general design of switchable MOFs. The switching activity has been delineated based on the cause of the switching: light, spin crossover (SCO), redox, temperature, and wettability.},
doi = {10.1002/anie.201900666},
journal = {Angewandte Chemie (International Edition)},
number = 12,
volume = 59,
place = {United States},
year = {Mon May 27 00:00:00 EDT 2019},
month = {Mon May 27 00:00:00 EDT 2019}
}
Web of Science
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