Corrosion/Passivation Behavior of Concentrated Ionic Liquid Electrolytes and Its Impact on the Li-Ion Battery Performance

doi:10.1149/2.0161916jes

Title: Corrosion/Passivation Behavior of Concentrated Ionic Liquid Electrolytes and Its Impact on the Li-Ion Battery Performance

Abstract

The corrosion/passivation phenomenon of Al and stainless steel (SS) with an ionic liquid-based electrolyte N-methyl-N-propyl-piperidinium bis(fluorosulfonyl)imide (PMpipFSI)-LiFSI was systematically studied by cyclic voltammetry, and its impact on the battery performance was evaluated in NMC532/Li cell. Our results showed that these electrolytes could eliminate the Al corrosion due to their capability of forming a passivation layer during the first anodic scan after 3 V vs Li⁺/Li. In contrast, no passivation behavior was observed for SS electrode, and the corrosion reaction was kinetically suppressed when the lithium salt concentration increases. We demonstrated that while 1 M LiFSI-PMpipFSI extensively corrodes SS in a NMC532/Li cell, the 5 M electrolyte does not and actually enables the normal cycling of the cell both using SS-2032-coin cells. Further, when an Al-coated coin cells were used, the Coulombic efficiency dramatically improved from 90% to >99.9% with superior capacity retention at both room temperature and 55 degrees C.

Authors:

Liu, Qian; Dzwiniel, Trevor L.; Pupek, Krzysztof Z.;

Publication Date:: 2019-12-02

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office

OSTI Identifier:: 1576697

Alternate Identifier(s):: OSTI ID: 1607633

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Published Article

Journal Name:: Journal of the Electrochemical Society

Additional Journal Information:: Journal Name: Journal of the Electrochemical Society Journal Volume: 166 Journal Issue: 16; Journal ID: ISSN 0013-4651

Publisher:: IOP Publishing - The Electrochemical Society

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE

Citation Formats


                    Liu, Qian, Dzwiniel, Trevor L., Pupek, Krzysztof Z., and Zhang, Zhengcheng. Corrosion/Passivation Behavior of Concentrated Ionic Liquid Electrolytes and Its Impact on the Li-Ion Battery Performance.  United States: N. p., 2019. 
        Web.  doi:10.1149/2.0161916jes.

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                    Liu, Qian, Dzwiniel, Trevor L., Pupek, Krzysztof Z., & Zhang, Zhengcheng. Corrosion/Passivation Behavior of Concentrated Ionic Liquid Electrolytes and Its Impact on the Li-Ion Battery Performance.  United States.  doi:10.1149/2.0161916jes.

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                    Liu, Qian, Dzwiniel, Trevor L., Pupek, Krzysztof Z., and Zhang, Zhengcheng. Mon .  
        "Corrosion/Passivation Behavior of Concentrated Ionic Liquid Electrolytes and Its Impact on the Li-Ion Battery Performance".  United States.  doi:10.1149/2.0161916jes.

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@article{osti_1576697,

  title        = {Corrosion/Passivation Behavior of Concentrated Ionic Liquid Electrolytes and Its Impact on the Li-Ion Battery Performance},

  author       = {Liu, Qian and Dzwiniel, Trevor L. and Pupek, Krzysztof Z. and Zhang, Zhengcheng},

  abstractNote = {The corrosion/passivation phenomenon of Al and stainless steel (SS) with an ionic liquid-based electrolyte N-methyl-N-propyl-piperidinium bis(fluorosulfonyl)imide (PMpipFSI)-LiFSI was systematically studied by cyclic voltammetry, and its impact on the battery performance was evaluated in NMC532/Li cell. Our results showed that these electrolytes could eliminate the Al corrosion due to their capability of forming a passivation layer during the first anodic scan after 3 V vs Li+/Li. In contrast, no passivation behavior was observed for SS electrode, and the corrosion reaction was kinetically suppressed when the lithium salt concentration increases. We demonstrated that while 1 M LiFSI-PMpipFSI extensively corrodes SS in a NMC532/Li cell, the 5 M electrolyte does not and actually enables the normal cycling of the cell both using SS-2032-coin cells. Further, when an Al-coated coin cells were used, the Coulombic efficiency dramatically improved from 90% to >99.9% with superior capacity retention at both room temperature and 55 degrees C.},

  doi          = {10.1149/2.0161916jes},

  journal      = {Journal of the Electrochemical Society},

  number       = 16,

  volume       = 166,

  place        = {United States},

  year         = {2019},

  month        = {12}

}

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DOI: 10.1149/2.0161916jes

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Title: Corrosion/Passivation Behavior of Concentrated Ionic Liquid Electrolytes and Its Impact on the Li-Ion Battery Performance

Abstract

Citation Formats

Electrochemical oxidation of propylene carbonate (containing various salts) on aluminium electrodes journal, September 1995

Fast Charge/Discharge of Li Metal Batteries Using an Ionic Liquid Electrolyte journal, January 2013

Investigation of the anodic behavior of Al current collector in room temperature ionic liquid electrolytes journal, May 2008

Issues and challenges facing rechargeable lithium batteries journal, November 2001

Novel Ionic Liquids Based Electrolytes for Secondary Lithium-Ion Batteries journal, April 2013

The Corrosion Study of Al Current Collector in Phosphonium Ionic Liquid as Solvent for Lithium Ion Battery journal, August 2011

Voltammetric and impedance studies of the electropolishing of type 316 stainless steel in a choline chloride based ionic liquid journal, June 2006

30 Years of Lithium-Ion Batteries journal, June 2018

Concentrated electrolytes: decrypting electrolyte properties and reassessing Al corrosion mechanisms journal, January 2014

Corrosion behaviour of ionic liquids journal, January 2005

Corrosion of aluminum at high voltages in non-aqueous electrolytes containing perfluoroalkylsulfonyl imides; new lithium salts for lithium-ion cells journal, October 1997

Inhibition of anodic corrosion of aluminum cathode current collector on recharging in lithium imide electrolytes journal, May 2000

Linear-Sweep Thermammetry Study on Corrosion Behavior of Al Current Collector in Ionic Liquid Solvent journal, January 2010

Electropolishing of stainless steels in a choline chloride based ionic liquid: an electrochemical study with surface characterisation using SEM and atomic force microscopy journal, January 2006

Electrochemical behavior of current collectors for lithium batteries in non-aqueous alkyl carbonate solution and surface analysis by ToF-SIMS journal, December 2009

Exceptional long-life performance of lithium-ion batteries using ionic liquid-based electrolytes journal, January 2016

Effect of organic solvent addition to PYR13FSI + LiFSI electrolytes on aluminum oxidation and rate performance of Li(Ni1/3Mn1/3Co1/3)O2 cathodes journal, November 2014

Corrosion/passivation of aluminum current collector in bis(fluorosulfonyl)imide-based ionic liquid for lithium-ion batteries journal, August 2012

Corrosion of stainless steel battery components by bis(fluorosulfonyl)imide based ionic liquid electrolytes journal, December 2014

Lithium bis(fluorosulfonyl)imide (LiFSI) as conducting salt for nonaqueous liquid electrolytes for lithium-ion batteries: Physicochemical and electrochemical properties journal, April 2011

Aluminium corrosion in room temperature molten salt journal, May 2004

N-Methyl-N-propylpiperidinium bis(trifluoromethanesulfonyl)imide (PP13–TFSI) – novel electrolyte base for Li battery journal, July 2003

Corrosion Prevention Mechanism of Aluminum Metal in Superconcentrated Electrolytes journal, July 2015

Improved Stability and Rate Capability of Ionic Liquid Electrolyte with High Concentration of LiFSI journal, January 2019

Electrochemical characterization of AISI 316L stainless steel in contact with simulated body fluid under infection conditions journal, November 2007

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Anodic behavior of aluminum in organic solutions with different electrolytic salts for lithium ion batteries journal, July 2002

Coupled LiPF 6 Decomposition and Carbonate Dehydrogenation Enhanced by Highly Covalent Metal Oxides in High-Energy Li-Ion Batteries journal, October 2018

N-Alkyl-N-methylpyrrolidinium difluoro(oxalato)borate ionic liquids: Physical/electrochemical properties and Al corrosion journal, September 2013

Different roles of ionic liquids in lithium batteries journal, December 2016

LiFePO4 and graphite electrodes with ionic liquids based on bis(fluorosulfonyl)imide (FSI)− for Li-ion batteries journal, January 2008

Li-ion battery materials: present and future journal, June 2015

Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries journal, October 2004

Development of safe, green and high performance ionic liquids-based batteries (ILLIBATT project) journal, November 2011

Ionic liquids as electrolytes for Li-ion batteries—An overview of electrochemical studies journal, December 2009

Fast cycling of Li/LiCoO2 cell with low-viscosity ionic liquids based on bis(fluorosulfonyl)imide [FSI]− journal, October 2006

Electrochemical Behavior of Al Current Collector of Rechargeable Lithium Batteries in Propylene Carbonate with LiCF[sub 3]SO[sub 3], Li(CF[sub 3]SO[sub 2])[sub 2]N, or Li(C[sub 4]F[sub 9]SO[sub 2])(CF[sub 3]SO[sub 2])N journal, January 2002

The Li-Ion Rechargeable Battery: A Perspective journal, January 2013

High-Energy Nickel-Rich Layered Cathode Stabilized by Ionic Liquid Electrolyte journal, January 2019

Ionic Liquid Electrolytes for Safer Lithium Batteries: I. Investigation around Optimal Formulation journal, September 2016

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Electrochemical oxidation of propylene carbonate (containing various salts) on aluminium electrodes
journal, September 1995

Fast Charge/Discharge of Li Metal Batteries Using an Ionic Liquid Electrolyte
journal, January 2013

Investigation of the anodic behavior of Al current collector in room temperature ionic liquid electrolytes
journal, May 2008

Issues and challenges facing rechargeable lithium batteries
journal, November 2001

Novel Ionic Liquids Based Electrolytes for Secondary Lithium-Ion Batteries
journal, April 2013

The Corrosion Study of Al Current Collector in Phosphonium Ionic Liquid as Solvent for Lithium Ion Battery
journal, August 2011

Voltammetric and impedance studies of the electropolishing of type 316 stainless steel in a choline chloride based ionic liquid
journal, June 2006

30 Years of Lithium-Ion Batteries
journal, June 2018

Concentrated electrolytes: decrypting electrolyte properties and reassessing Al corrosion mechanisms
journal, January 2014

Corrosion behaviour of ionic liquids
journal, January 2005

Corrosion of aluminum at high voltages in non-aqueous electrolytes containing perfluoroalkylsulfonyl imides; new lithium salts for lithium-ion cells
journal, October 1997

Inhibition of anodic corrosion of aluminum cathode current collector on recharging in lithium imide electrolytes
journal, May 2000

Linear-Sweep Thermammetry Study on Corrosion Behavior of Al Current Collector in Ionic Liquid Solvent
journal, January 2010

Electropolishing of stainless steels in a choline chloride based ionic liquid: an electrochemical study with surface characterisation using SEM and atomic force microscopy
journal, January 2006

Electrochemical behavior of current collectors for lithium batteries in non-aqueous alkyl carbonate solution and surface analysis by ToF-SIMS
journal, December 2009

Exceptional long-life performance of lithium-ion batteries using ionic liquid-based electrolytes
journal, January 2016

Effect of organic solvent addition to PYR13FSI + LiFSI electrolytes on aluminum oxidation and rate performance of Li(Ni1/3Mn1/3Co1/3)O2 cathodes
journal, November 2014

Corrosion/passivation of aluminum current collector in bis(fluorosulfonyl)imide-based ionic liquid for lithium-ion batteries
journal, August 2012

Corrosion of stainless steel battery components by bis(fluorosulfonyl)imide based ionic liquid electrolytes
journal, December 2014

Lithium bis(fluorosulfonyl)imide (LiFSI) as conducting salt for nonaqueous liquid electrolytes for lithium-ion batteries: Physicochemical and electrochemical properties
journal, April 2011

Aluminium corrosion in room temperature molten salt
journal, May 2004

N-Methyl-N-propylpiperidinium bis(trifluoromethanesulfonyl)imide (PP13–TFSI) – novel electrolyte base for Li battery
journal, July 2003

Corrosion Prevention Mechanism of Aluminum Metal in Superconcentrated Electrolytes
journal, July 2015

Improved Stability and Rate Capability of Ionic Liquid Electrolyte with High Concentration of LiFSI
journal, January 2019

Electrochemical characterization of AISI 316L stainless steel in contact with simulated body fluid under infection conditions
journal, November 2007

Factors That Influence Formation of AlF[sub 3] Passive Film on Aluminum in Li-Ion Battery Electrolytes with LiPF[sub 6]
journal, January 2006

Building better batteries
journal, February 2008

Ni3+/Ni2+ redox potential in LiNiPO4
journal, March 2005

Anodic behavior of aluminum in organic solutions with different electrolytic salts for lithium ion batteries
journal, July 2002

Coupled LiPF ₆ Decomposition and Carbonate Dehydrogenation Enhanced by Highly Covalent Metal Oxides in High-Energy Li-Ion Batteries
journal, October 2018

N-Alkyl-N-methylpyrrolidinium difluoro(oxalato)borate ionic liquids: Physical/electrochemical properties and Al corrosion
journal, September 2013

Different roles of ionic liquids in lithium batteries
journal, December 2016

LiFePO4 and graphite electrodes with ionic liquids based on bis(fluorosulfonyl)imide (FSI)− for Li-ion batteries
journal, January 2008

Li-ion battery materials: present and future
journal, June 2015

Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries
journal, October 2004

Development of safe, green and high performance ionic liquids-based batteries (ILLIBATT project)
journal, November 2011

Ionic liquids as electrolytes for Li-ion batteries—An overview of electrochemical studies
journal, December 2009

Fast cycling of Li/LiCoO2 cell with low-viscosity ionic liquids based on bis(fluorosulfonyl)imide [FSI]−
journal, October 2006

Electrochemical Behavior of Al Current Collector of Rechargeable Lithium Batteries in Propylene Carbonate with LiCF[sub 3]SO[sub 3], Li(CF[sub 3]SO[sub 2])[sub 2]N, or Li(C[sub 4]F[sub 9]SO[sub 2])(CF[sub 3]SO[sub 2])N
journal, January 2002

The Li-Ion Rechargeable Battery: A Perspective
journal, January 2013

High-Energy Nickel-Rich Layered Cathode Stabilized by Ionic Liquid Electrolyte
journal, January 2019

Ionic Liquid Electrolytes for Safer Lithium Batteries: I. Investigation around Optimal Formulation
journal, September 2016

Effect of Ionic Liquids as Additives on Lithium Electrolytes: Conductivity, Electrochemical Stability, and Aluminum Corrosion ^†
journal, May 2010

EMIIm and EMIBeti on Aluminum Anodic Stability Dependence on Lithium Salt and Propylene Carbonate
journal, January 1999