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Title: ZrO 2 atomic layer deposition into Sr 0.5 Sm 0.5 CoO 3−δ –Ce 0.9 Gd 0.1 O 2−δ solid oxide fuel cell cathodes: mechanisms of stability enhancement

Abstract

Atomic layer deposition of ZrO 2 creates reactive islands that limit coarsening and improve the stability of fuel cell cathode Sr 0.5 Sm 0.5 CoO 3−δ –Ce 0.9 Gd 0.1 O 2−δ .

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]
  1. Department of Materials Science and Engineering, Northwestern University, Evanston, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1576680
Grant/Contract Number:  
SC0016965
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Name: Journal of Materials Chemistry. A Journal Volume: 7 Journal Issue: 48; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Schmauss, Travis A., Railsback, Justin G., Lu, Matthew Y., Zhao, Kevin Y., and Barnett, Scott A. ZrO 2 atomic layer deposition into Sr 0.5 Sm 0.5 CoO 3−δ –Ce 0.9 Gd 0.1 O 2−δ solid oxide fuel cell cathodes: mechanisms of stability enhancement. United Kingdom: N. p., 2019. Web. doi:10.1039/C9TA09214E.
Schmauss, Travis A., Railsback, Justin G., Lu, Matthew Y., Zhao, Kevin Y., & Barnett, Scott A. ZrO 2 atomic layer deposition into Sr 0.5 Sm 0.5 CoO 3−δ –Ce 0.9 Gd 0.1 O 2−δ solid oxide fuel cell cathodes: mechanisms of stability enhancement. United Kingdom. doi:10.1039/C9TA09214E.
Schmauss, Travis A., Railsback, Justin G., Lu, Matthew Y., Zhao, Kevin Y., and Barnett, Scott A. Tue . "ZrO 2 atomic layer deposition into Sr 0.5 Sm 0.5 CoO 3−δ –Ce 0.9 Gd 0.1 O 2−δ solid oxide fuel cell cathodes: mechanisms of stability enhancement". United Kingdom. doi:10.1039/C9TA09214E.
@article{osti_1576680,
title = {ZrO 2 atomic layer deposition into Sr 0.5 Sm 0.5 CoO 3−δ –Ce 0.9 Gd 0.1 O 2−δ solid oxide fuel cell cathodes: mechanisms of stability enhancement},
author = {Schmauss, Travis A. and Railsback, Justin G. and Lu, Matthew Y. and Zhao, Kevin Y. and Barnett, Scott A.},
abstractNote = {Atomic layer deposition of ZrO 2 creates reactive islands that limit coarsening and improve the stability of fuel cell cathode Sr 0.5 Sm 0.5 CoO 3−δ –Ce 0.9 Gd 0.1 O 2−δ .},
doi = {10.1039/C9TA09214E},
journal = {Journal of Materials Chemistry. A},
number = 48,
volume = 7,
place = {United Kingdom},
year = {2019},
month = {12}
}

Journal Article:
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Works referenced in this record:

Ln1−xSrxCoO3(Ln = Sm, Dy) for the electrode of solid oxide fuel cells
journal, October 1997


The Scherrer equation versus the 'Debye-Scherrer equation'
journal, August 2011


Atomic Layer Deposition Functionalized Composite SOFC Cathode La 0.6 Sr 0.4 Fe 0.8 Co 0.2 O 3-δ -Gd 0.2 Ce 0.8 O 1.9 : Enhanced Long-Term Stability
journal, October 2013

  • Gong, Yunhui; Patel, Rajankumar L.; Liang, Xinhua
  • Chemistry of Materials, Vol. 25, Issue 21
  • DOI: 10.1021/cm402879r

10. Coatings on High Aspect Ratio Structures
book, November 2011


Degradation of nano-scale cathodes: a new paradigm for selecting low-temperature solid oxide cell materials
journal, January 2016

  • Call, Ann V.; Railsback, Justin G.; Wang, Hongqian
  • Physical Chemistry Chemical Physics, Vol. 18, Issue 19
  • DOI: 10.1039/C6CP02590K

Atomic Layer Deposition for Coating of High Aspect Ratio TiO 2 Nanotube Layers
journal, October 2016


Atomic Layer Deposition for Surface Engineering of Solid Oxide Fuel Cell Electrodes
journal, March 2019

  • Shim, Joon Hyung; Han, Gwon Deok; Choi, Hyung Jong
  • International Journal of Precision Engineering and Manufacturing-Green Technology, Vol. 6, Issue 3
  • DOI: 10.1007/s40684-019-00092-7

Performance Degradation of Lanthanum Strontium Cobaltite after Surface Modification
journal, January 2015

  • Choi, Hyung Jong; Bae, Kiho; Jang, Dong Young
  • Journal of The Electrochemical Society, Vol. 162, Issue 6
  • DOI: 10.1149/2.0971506jes

A perspective on low-temperature solid oxide fuel cells
journal, January 2016

  • Gao, Zhan; Mogni, Liliana V.; Miller, Elizabeth C.
  • Energy & Environmental Science, Vol. 9, Issue 5
  • DOI: 10.1039/C5EE03858H

Time-dependent performance changes in LSCF-infiltrated SOFC cathodes: The role of nano-particle coarsening
journal, April 2011


An innovative efficient oxygen electrode for SOFC: Pr 6 O 11 infiltrated into Gd-doped ceria backbone
journal, September 2016

  • Nicollet, Clément; Flura, Aurélien; Vibhu, Vaibhav
  • International Journal of Hydrogen Energy, Vol. 41, Issue 34
  • DOI: 10.1016/j.ijhydene.2016.04.024

Solid oxide fuel cell cathodes by infiltration of La0.6Sr0.4Co0.2Fe0.8O3−δ into Gd-Doped Ceria
journal, October 2008


Sr Segregation in Perovskite Oxides: Why It Happens and How It Exists
journal, August 2018


Atomic-layer-controlled deposition of TEMAZ/O2–ZrO2 oxidation resistance inner surface coatings for solid oxide fuel cells
journal, February 2016


Island growth in the atomic layer deposition of zirconium oxide and aluminum oxide on hydrogen-terminated silicon: Growth mode modeling and transmission electron microscopy
journal, November 2004

  • Puurunen, Riikka L.; Vandervorst, Wilfried; Besling, Wim F. A.
  • Journal of Applied Physics, Vol. 96, Issue 9
  • DOI: 10.1063/1.1787624

Cubic-phase zirconia nano-island growth using atomic layer deposition and application in low-power charge-trapping nonvolatile-memory devices
journal, October 2017


Stabilizing Nanostructured Solid Oxide Fuel Cell Cathode with Atomic Layer Deposition
journal, August 2013

  • Gong, Yunhui; Palacio, Diego; Song, Xueyan
  • Nano Letters, Vol. 13, Issue 9
  • DOI: 10.1021/nl402138w

Crystallinity-Controlled Synthesis of Zirconium Oxide Thin Films on Nitrogen-Doped Carbon Nanotubes by Atomic Layer Deposition
journal, June 2012

  • Liu, Jian; Meng, Xiangbo; Banis, Mohammad Norouzi
  • The Journal of Physical Chemistry C, Vol. 116, Issue 27
  • DOI: 10.1021/jp3028462

Degradation of La 0.6 Sr 0.4 Fe 0.8 Co 0.2 O 3-δ Oxygen Electrodes on Ce 0.9 Gd 0.1 O 2-δ Electrolytes during Reversing Current Operation
journal, January 2017

  • Railsback, Justin G.; Wang, Hongqian; Liu, Qinyuan
  • Journal of The Electrochemical Society, Vol. 164, Issue 10
  • DOI: 10.1149/2.0111710jes

Mechanisms of Performance Degradation of (La,Sr)(Co,Fe)O 3-δ Solid Oxide Fuel Cell Cathodes
journal, January 2016

  • Wang, Hongqian; Yakal-Kremski, Kyle J.; Yeh, Ted
  • Journal of The Electrochemical Society, Vol. 163, Issue 6
  • DOI: 10.1149/2.0031607jes

Atomic Layer Deposition: An Overview
journal, January 2010

  • George, Steven M.
  • Chemical Reviews, Vol. 110, Issue 1, p. 111-131
  • DOI: 10.1021/cr900056b

Modeling precursor diffusion and reaction of atomic layer deposition in porous structures
journal, January 2015

  • Keuter, Thomas; Menzler, Norbert Heribert; Mauer, Georg
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 33, Issue 1, Article No. 01A104
  • DOI: 10.1116/1.4892385

Atomic Layer Deposition of Hafnium and Zirconium Oxides Using Metal Amide Precursors
journal, October 2002

  • Hausmann, Dennis M.; Kim, Esther; Becker, Jill
  • Chemistry of Materials, Vol. 14, Issue 10
  • DOI: 10.1021/cm020357x

Matplotlib: A 2D Graphics Environment
journal, January 2007


Investigation of Sm0.5Sr0.5CoO3−δ/Co3O4 composite cathode for intermediate-temperature solid oxide fuel cells
journal, October 2008


An Investigation of Oxygen Reduction Kinetics in LSF Electrodes
journal, December 2012

  • Küngas, Rainer; Yu, Anthony S.; Levine, Julie
  • Journal of The Electrochemical Society, Vol. 160, Issue 2
  • DOI: 10.1149/2.011303jes

TEM and ETEM Study on SrZrO 3 Formation at the LSCF/GDC/YSZ Interfaces
journal, May 2017

  • Matsuda, Junko; Kanae, Shu; Kawabata, Tsutomu
  • ECS Transactions, Vol. 78, Issue 1
  • DOI: 10.1149/07801.0993ecst

Modification of SOFC Cathodes by Atomic Layer Deposition
journal, January 2013

  • Yu, Anthony S.; Küngas, Rainer; Vohs, John M.
  • Journal of The Electrochemical Society, Vol. 160, Issue 11
  • DOI: 10.1149/2.045311jes

The NumPy Array: A Structure for Efficient Numerical Computation
journal, March 2011

  • van der Walt, Stéfan; Colbert, S. Chris; Varoquaux, Gaël
  • Computing in Science & Engineering, Vol. 13, Issue 2
  • DOI: 10.1109/MCSE.2011.37

Solid Oxide Fuel Cell Cathodes: Polarization Mechanisms and Modeling of the Electrochemical Performance
journal, August 2003


Modification of LSF-YSZ Composite Cathodes by Atomic Layer Deposition
journal, January 2017

  • Rahmanipour, M.; Cheng, Y.; Onn, T. M.
  • Journal of The Electrochemical Society, Vol. 164, Issue 7
  • DOI: 10.1149/2.0181709jes

Structural and electrical properties of Sr(Ti, Fe)O3-δ materials for SOFC cathodes
journal, January 2012

  • Molin, Sebastian; Lewandowska-Iwaniak, Weronika; Kusz, Boguslaw
  • Journal of Electroceramics, Vol. 28, Issue 1
  • DOI: 10.1007/s10832-012-9683-x

Enhancing SOFC cathode performance by surface modification through infiltration
journal, January 2014

  • Ding, Dong; Li, Xiaxi; Lai, Samson Yuxiu
  • Energy & Environmental Science, Vol. 7, Issue 2
  • DOI: 10.1039/c3ee42926a

Surface Tuning of Solid Oxide Fuel Cell Cathode by Atomic Layer Deposition
journal, October 2018

  • Choi, Hyung Jong; Bae, Kiho; Grieshammer, Steffen
  • Advanced Energy Materials, Vol. 8, Issue 33
  • DOI: 10.1002/aenm.201802506