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Title: Unveiling Nickel Chemistry in Stabilizing High‐Voltage Cobalt‐Rich Cathodes for Lithium‐Ion Batteries

Authors:
 [1];  [2];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [2]; ORCiD logo [1]
  1. Department of Energy EngineeringSchool of Energy and Chemical EngineeringUlsan National Institute of Science and Technology (UNIST) 50 UNIST‐gil Ulsan 44919 Republic of Korea
  2. Department of Nuclear Science and Engineering &, Department of Materials Science and EngineeringMassachusetts Institute of Technology Cambridge MA 02139 USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1576652
Grant/Contract Number:  
DE‐SC0002633
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Functional Materials
Additional Journal Information:
Journal Name: Advanced Functional Materials; Journal ID: ISSN 1616-301X
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Yoon, Moonsu, Dong, Yanhao, Yoo, Youngbin, Myeong, Seungjun, Hwang, Jaeseong, Kim, Junhyeok, Choi, Seong‐Hyeon, Sung, Jaekyung, Kang, Seok Ju, Li, Ju, and Cho, Jaephil. Unveiling Nickel Chemistry in Stabilizing High‐Voltage Cobalt‐Rich Cathodes for Lithium‐Ion Batteries. Germany: N. p., 2019. Web. doi:10.1002/adfm.201907903.
Yoon, Moonsu, Dong, Yanhao, Yoo, Youngbin, Myeong, Seungjun, Hwang, Jaeseong, Kim, Junhyeok, Choi, Seong‐Hyeon, Sung, Jaekyung, Kang, Seok Ju, Li, Ju, & Cho, Jaephil. Unveiling Nickel Chemistry in Stabilizing High‐Voltage Cobalt‐Rich Cathodes for Lithium‐Ion Batteries. Germany. doi:10.1002/adfm.201907903.
Yoon, Moonsu, Dong, Yanhao, Yoo, Youngbin, Myeong, Seungjun, Hwang, Jaeseong, Kim, Junhyeok, Choi, Seong‐Hyeon, Sung, Jaekyung, Kang, Seok Ju, Li, Ju, and Cho, Jaephil. Fri . "Unveiling Nickel Chemistry in Stabilizing High‐Voltage Cobalt‐Rich Cathodes for Lithium‐Ion Batteries". Germany. doi:10.1002/adfm.201907903.
@article{osti_1576652,
title = {Unveiling Nickel Chemistry in Stabilizing High‐Voltage Cobalt‐Rich Cathodes for Lithium‐Ion Batteries},
author = {Yoon, Moonsu and Dong, Yanhao and Yoo, Youngbin and Myeong, Seungjun and Hwang, Jaeseong and Kim, Junhyeok and Choi, Seong‐Hyeon and Sung, Jaekyung and Kang, Seok Ju and Li, Ju and Cho, Jaephil},
abstractNote = {},
doi = {10.1002/adfm.201907903},
journal = {Advanced Functional Materials},
number = ,
volume = ,
place = {Germany},
year = {2019},
month = {11}
}

Journal Article:
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Works referenced in this record:

LiCoO 2 Degradation Behavior in the High-Voltage Phase Transition Region and Improved Reversibility with Surface Coating
journal, November 2016

  • Yano, Akira; Shikano, Masahiro; Ueda, Atsushi
  • Journal of The Electrochemical Society, Vol. 164, Issue 1
  • DOI: 10.1149/2.0181701jes

Challenges for Rechargeable Li Batteries
journal, February 2010

  • Goodenough, John B.; Kim, Youngsik
  • Chemistry of Materials, Vol. 22, Issue 3, p. 587-603
  • DOI: 10.1021/cm901452z

Surface Engineering Strategies of Layered LiCoO 2 Cathode Material to Realize High-Energy and High-Voltage Li-Ion Cells
journal, October 2016

  • Kalluri, Sujith; Yoon, Moonsu; Jo, Minki
  • Advanced Energy Materials, Vol. 7, Issue 1
  • DOI: 10.1002/aenm.201601507

Why transition metal (di) oxides are the most attractive materials for batteries
journal, August 1994


Degradation of Ethylene Carbonate Electrolytes of Lithium Ion Batteries via Ring Opening Activated by LiCoO 2 Cathode Surfaces and Electrolyte Species
journal, September 2016

  • Tebbe, Jonathon L.; Fuerst, Thomas F.; Musgrave, Charles B.
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 40
  • DOI: 10.1021/acsami.6b06157

Synthesis of Mg and Mn Doped LiCoO 2 and Effects on High Voltage Cycling
journal, January 2017

  • Liu, Aaron; Li, Jing; Shunmugasundaram, Ramesh
  • Journal of The Electrochemical Society, Vol. 164, Issue 7
  • DOI: 10.1149/2.1381707jes

Lattice doping regulated interfacial reactions in cathode for enhanced cycling stability
journal, August 2019


Oxygen Release Degradation in Li‐Ion Battery Cathode Materials: Mechanisms and Mitigating Approaches
journal, April 2019

  • Sharifi‐Asl, Soroosh; Lu, Jun; Amine, Khalil
  • Advanced Energy Materials, Vol. 9, Issue 22
  • DOI: 10.1002/aenm.201900551

Electrode–Electrolyte Interface in Li-Ion Batteries: Current Understanding and New Insights
journal, October 2015

  • Gauthier, Magali; Carney, Thomas J.; Grimaud, Alexis
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 22
  • DOI: 10.1021/acs.jpclett.5b01727

Hexagonal to Cubic Spinel Transformation in Lithiated Cobalt Oxide
journal, January 2004

  • Gabrisch, Heike; Yazami, Rachid; Fultz, Brent
  • Journal of The Electrochemical Society, Vol. 151, Issue 6
  • DOI: 10.1149/1.1738677

Fluorinated Electrolytes for 5-V Li-Ion Chemistry: Probing Voltage Stability of Electrolytes with Electrochemical Floating Test
journal, January 2015

  • He, Meinan; Hu, Libo; Xue, Zheng
  • Journal of The Electrochemical Society, Vol. 162, Issue 9
  • DOI: 10.1149/2.0231509jes

Layered LiCoO[sub 2] with a Different Oxygen Stacking (O2 Structure) as a Cathode Material for Rechargeable Lithium Batteries
journal, January 2000

  • Paulsen, J. M.; Mueller-Neuhaus, J. R.; Dahn, J. R.
  • Journal of The Electrochemical Society, Vol. 147, Issue 2
  • DOI: 10.1149/1.1393225

Mechanism of hydrofluoric acid formation in ethylene carbonate electrolytes with fluorine salt additives
journal, November 2015


Electrolyte Reactions with the Surface of High Voltage LiNi[sub 0.5]Mn[sub 1.5]O[sub 4] Cathodes for Lithium-Ion Batteries
journal, January 2010

  • Yang, Li; Ravdel, Boris; Lucht, Brett L.
  • Electrochemical and Solid-State Letters, Vol. 13, Issue 8
  • DOI: 10.1149/1.3428515

Fluorinated electrolytes for 5 V lithium-ion battery chemistry
journal, January 2013

  • Zhang, Zhengcheng; Hu, Libo; Wu, Huiming
  • Energy & Environmental Science, Vol. 6, Issue 6
  • DOI: 10.1039/c3ee24414h

First-Principles Evidence for Stage Ordering in Li[sub x]CoO[sub 2]
journal, January 1998

  • Van der Ven, Anton
  • Journal of The Electrochemical Society, Vol. 145, Issue 6
  • DOI: 10.1149/1.1838610

First In Situ Observation of the LiCoO 2 Electrode/Electrolyte Interface by Total-Reflection X-ray Absorption Spectroscopy
journal, October 2012

  • Takamatsu, Daiko; Koyama, Yukinori; Orikasa, Yuki
  • Angewandte Chemie International Edition, Vol. 51, Issue 46
  • DOI: 10.1002/anie.201203910

Electrical Energy Storage for the Grid: A Battery of Choices
journal, November 2011


Fundamental degradation mechanisms of layered oxide Li-ion battery cathode materials: Methodology, insights and novel approaches
journal, February 2015


Profiling the nanoscale gradient in stoichiometric layered cathode particles for lithium-ion batteries
journal, January 2014

  • Lin, Feng; Nordlund, Dennis; Markus, Isaac M.
  • Energy & Environmental Science, Vol. 7, Issue 9
  • DOI: 10.1039/C4EE01400F

The investigation of Ti-modified LiCoO2 materials for lithium ion battery
journal, September 2014


Effects of cationic substitution on structural defects in layered cathode materials LiNiO2
journal, January 2014

  • Chen, Hungru; Dawson, James A.; Harding, John H.
  • Journal of Materials Chemistry A, Vol. 2, Issue 21
  • DOI: 10.1039/c4ta00637b

Probing the Origin of Enhanced Stability of “AlPO4” Nanoparticle Coated LiCoO2 during Cycling to High Voltages: Combined XRD and XPS Studies
journal, October 2009

  • Lu, Yi-Chun; Mansour, Azzam N.; Yabuuchi, Naoaki
  • Chemistry of Materials, Vol. 21, Issue 19, p. 4408-4424
  • DOI: 10.1021/cm900862v

A first-order Mott transition in LixCoO2
journal, August 2004

  • Marianetti, C. A.; Kotliar, G.; Ceder, G.
  • Nature Materials, Vol. 3, Issue 9
  • DOI: 10.1038/nmat1178

The cathode–electrolyte interface in the Li-ion battery
journal, November 2004


Effect of Cr dopant on the cathodic behavior of LiCoO2
journal, December 2002


Dynamic evolution of cathode electrolyte interphase (CEI) on high voltage LiCoO2 cathode and its interaction with Li anode
journal, September 2018


Chemical States of Overcharged LiCoO 2 Particle Surfaces and Interiors Observed Using Electron Energy-Loss Spectroscopy
journal, June 2015

  • Kikkawa, Jun; Terada, Shohei; Gunji, Akira
  • The Journal of Physical Chemistry C, Vol. 119, Issue 28
  • DOI: 10.1021/acs.jpcc.5b02303

Chemical Reactivity Descriptor for the Oxide-Electrolyte Interface in Li-Ion Batteries
journal, August 2017

  • Giordano, Livia; Karayaylali, Pinar; Yu, Yang
  • The Journal of Physical Chemistry Letters, Vol. 8, Issue 16
  • DOI: 10.1021/acs.jpclett.7b01655

Electrochemical surface passivation of LiCoO2 particles at ultrahigh voltage and its applications in lithium-based batteries
journal, November 2018


Unexpected Improved Performance of ALD Coated LiCoO 2 /Graphite Li-Ion Batteries
journal, September 2012

  • Jung, Yoon Seok; Lu, Peng; Cavanagh, Andrew S.
  • Advanced Energy Materials, Vol. 3, Issue 2
  • DOI: 10.1002/aenm.201200370

Electrode–electrolyte interfaces in lithium-based batteries
journal, January 2018

  • Yu, Xingwen; Manthiram, Arumugam
  • Energy & Environmental Science, Vol. 11, Issue 3
  • DOI: 10.1039/C7EE02555F

An Outlook on Lithium Ion Battery Technology
journal, September 2017


Relative Impact of Al or Mg Substitution on the Thermal Stability of LiCo[sub 1−z]M[sub z]O[sub 2] (M=Al or Mg) by Accelerating Rate Calorimetry
journal, January 2009

  • Zhou, Fu; Luo, Wenbin; Zhao, Xuemei
  • Journal of The Electrochemical Society, Vol. 156, Issue 11
  • DOI: 10.1149/1.3223910

Understanding voltage decay in lithium-excess layered cathode materials through oxygen-centred structural arrangement
journal, August 2018


The Influence of Ni Doping on the Structure and Electrochemical Properties of LiCoO 2 Materials
journal, January 2018

  • Jin, Yahui; Xu, Shiguo; Li, Zhitao
  • Journal of The Electrochemical Society, Vol. 165, Issue 10
  • DOI: 10.1149/2.0401810jes

Comparison of the chemical stability of the high energy density cathodes of lithium-ion batteries
journal, November 2001


Oxygen Contribution on Li-Ion Intercalation−Deintercalation in LiCoO 2 Investigated by O K-Edge and Co L-Edge X-ray Absorption Spectroscopy
journal, March 2002

  • Yoon, Won-Sub; Kim, Kwang-Bum; Kim, Min-Gyu
  • The Journal of Physical Chemistry B, Vol. 106, Issue 10
  • DOI: 10.1021/jp013735e

Critical Role of Cations in Lithium Sites on Extended Electrochemical Reversibility of Co-Rich Layered Oxide
journal, March 2017

  • Cho, Woongrae; Myeong, Seungjun; Kim, Namhyung
  • Advanced Materials, Vol. 29, Issue 21
  • DOI: 10.1002/adma.201605578

Crystal structures, electrical conductivities and electrochemical properties of LiCo1−xMgxO2 (0≤x≤0.11)
journal, September 2006


Staging Phase Transitions in Li[sub x]CoO[sub 2]
journal, January 2002

  • Chen, Zhaohui; Lu, Zhonghua; Dahn, J. R.
  • Journal of The Electrochemical Society, Vol. 149, Issue 12
  • DOI: 10.1149/1.1519850

Towards greener and more sustainable batteries for electrical energy storage
journal, November 2014


A highly stabilized nickel-rich cathode material by nanoscale epitaxy control for high-energy lithium-ion batteries
journal, January 2018

  • Kim, Junhyeok; Ma, Hyunsoo; Cha, Hyungyeon
  • Energy & Environmental Science, Vol. 11, Issue 6
  • DOI: 10.1039/C8EE00155C

Defect Chemistry in Layered Li M O 2 ( M = Co, Ni, Mn, and Li 1/3 Mn 2/3 ) by First-Principles Calculations
journal, October 2012

  • Koyama, Yukinori; Arai, Hajime; Tanaka, Isao
  • Chemistry of Materials, Vol. 24, Issue 20
  • DOI: 10.1021/cm3018314

Electrical energy storage for transportation—approaching the limits of, and going beyond, lithium-ion batteries
journal, January 2012

  • Thackeray, Michael M.; Wolverton, Christopher; Isaacs, Eric D.
  • Energy & Environmental Science, Vol. 5, Issue 7
  • DOI: 10.1039/c2ee21892e

Nickel-Rich and Lithium-Rich Layered Oxide Cathodes: Progress and Perspectives
journal, October 2015

  • Manthiram, Arumugam; Knight, James C.; Myung, Seung-Taek
  • Advanced Energy Materials, Vol. 6, Issue 1
  • DOI: 10.1002/aenm.201501010

Dynamic behaviour of interphases and its implication on high-energy-density cathode materials in lithium-ion batteries
journal, April 2017

  • Li, Wangda; Dolocan, Andrei; Oh, Pilgun
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms14589

Methods to obtain excellent capacity retention in LiCoO2 cycled to 4.5 V
journal, March 2004


Mixed Electronic and Ionic Conductor-Coated Cathode Material for High-Voltage Lithium Ion Battery
journal, May 2016

  • Shim, Jae-Hyun; Han, Jung-Min; Lee, Joon-Hyung
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 19
  • DOI: 10.1021/acsami.6b03113

LiCoO[sub 2] Cathode Material That Does Not Show a Phase Transition from Hexagonal to Monoclinic Phase
journal, January 2001

  • Cho, Jaephil; Kim, Yong Jeong; Park, Byungwoo
  • Journal of The Electrochemical Society, Vol. 148, Issue 10
  • DOI: 10.1149/1.1397772

Performance of LiM 0.05 Co 0.95 O 2 Cathode Materials in Lithium Rechargeable Cells When Cycled up to 4.5 V
journal, March 2005

  • Zou, Meijing; Yoshio, Masaki; Gopukumar, S.
  • Chemistry of Materials, Vol. 17, Issue 6
  • DOI: 10.1021/cm048734o