This content will become publicly available on November 28, 2020
Unveiling Nickel Chemistry in Stabilizing High‐Voltage Cobalt‐Rich Cathodes for Lithium‐Ion Batteries
- Authors:
-
[1]
- Department of Energy EngineeringSchool of Energy and Chemical EngineeringUlsan National Institute of Science and Technology (UNIST) 50 UNIST‐gil Ulsan 44919 Republic of Korea
- Department of Nuclear Science and Engineering &, Department of Materials Science and EngineeringMassachusetts Institute of Technology Cambridge MA 02139 USA
- Publication Date:
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- OSTI Identifier:
- 1576652
- Grant/Contract Number:
- DE‐SC0002633
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Advanced Functional Materials
- Additional Journal Information:
- Journal Name: Advanced Functional Materials; Journal ID: ISSN 1616-301X
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Yoon, Moonsu, Dong, Yanhao, Yoo, Youngbin, Myeong, Seungjun, Hwang, Jaeseong, Kim, Junhyeok, Choi, Seong‐Hyeon, Sung, Jaekyung, Kang, Seok Ju, Li, Ju, and Cho, Jaephil. Unveiling Nickel Chemistry in Stabilizing High‐Voltage Cobalt‐Rich Cathodes for Lithium‐Ion Batteries. Germany: N. p., 2019.
Web. doi:10.1002/adfm.201907903.
Yoon, Moonsu, Dong, Yanhao, Yoo, Youngbin, Myeong, Seungjun, Hwang, Jaeseong, Kim, Junhyeok, Choi, Seong‐Hyeon, Sung, Jaekyung, Kang, Seok Ju, Li, Ju, & Cho, Jaephil. Unveiling Nickel Chemistry in Stabilizing High‐Voltage Cobalt‐Rich Cathodes for Lithium‐Ion Batteries. Germany. doi:10.1002/adfm.201907903.
Yoon, Moonsu, Dong, Yanhao, Yoo, Youngbin, Myeong, Seungjun, Hwang, Jaeseong, Kim, Junhyeok, Choi, Seong‐Hyeon, Sung, Jaekyung, Kang, Seok Ju, Li, Ju, and Cho, Jaephil. Fri .
"Unveiling Nickel Chemistry in Stabilizing High‐Voltage Cobalt‐Rich Cathodes for Lithium‐Ion Batteries". Germany. doi:10.1002/adfm.201907903.
@article{osti_1576652,
title = {Unveiling Nickel Chemistry in Stabilizing High‐Voltage Cobalt‐Rich Cathodes for Lithium‐Ion Batteries},
author = {Yoon, Moonsu and Dong, Yanhao and Yoo, Youngbin and Myeong, Seungjun and Hwang, Jaeseong and Kim, Junhyeok and Choi, Seong‐Hyeon and Sung, Jaekyung and Kang, Seok Ju and Li, Ju and Cho, Jaephil},
abstractNote = {},
doi = {10.1002/adfm.201907903},
journal = {Advanced Functional Materials},
number = ,
volume = ,
place = {Germany},
year = {2019},
month = {11}
}
Free Publicly Available Full Text
This content will become publicly available on November 28, 2020
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
LiCoO 2 Degradation Behavior in the High-Voltage Phase Transition Region and Improved Reversibility with Surface Coating
journal, November 2016
- Yano, Akira; Shikano, Masahiro; Ueda, Atsushi
- Journal of The Electrochemical Society, Vol. 164, Issue 1
Challenges for Rechargeable Li Batteries
journal, February 2010
- Goodenough, John B.; Kim, Youngsik
- Chemistry of Materials, Vol. 22, Issue 3, p. 587-603
Surface Engineering Strategies of Layered LiCoO 2 Cathode Material to Realize High-Energy and High-Voltage Li-Ion Cells
journal, October 2016
- Kalluri, Sujith; Yoon, Moonsu; Jo, Minki
- Advanced Energy Materials, Vol. 7, Issue 1
Why transition metal (di) oxides are the most attractive materials for batteries
journal, August 1994
- Ohzuku, T.; Ueda, A.
- Solid State Ionics, Vol. 69, Issue 3-4
Degradation of Ethylene Carbonate Electrolytes of Lithium Ion Batteries via Ring Opening Activated by LiCoO 2 Cathode Surfaces and Electrolyte Species
journal, September 2016
- Tebbe, Jonathon L.; Fuerst, Thomas F.; Musgrave, Charles B.
- ACS Applied Materials & Interfaces, Vol. 8, Issue 40
Synthesis of Mg and Mn Doped LiCoO 2 and Effects on High Voltage Cycling
journal, January 2017
- Liu, Aaron; Li, Jing; Shunmugasundaram, Ramesh
- Journal of The Electrochemical Society, Vol. 164, Issue 7
Lattice doping regulated interfacial reactions in cathode for enhanced cycling stability
journal, August 2019
- Zou, Lianfeng; Li, Jianyu; Liu, Zhenyu
- Nature Communications, Vol. 10, Issue 1
Engineering the surface of LiCoO2 electrodes using atomic layer deposition for stable high-voltage lithium ion batteries
journal, July 2017
- Xie, Jin; Zhao, Jie; Liu, Yayuan
- Nano Research, Vol. 10, Issue 11
Correction to Unveiling the Intrinsic Cycle Reversibility of a LiCoO 2 Electrode at 4.8-V Cutoff Voltage through Subtractive Surface Modification for Lithium-Ion Batteries
journal, November 2018
- Seong, Won Mo; Yoon, Kyungho; Lee, Myeong Hwan
- Nano Letters, Vol. 18, Issue 12
Oxygen Release Degradation in Li‐Ion Battery Cathode Materials: Mechanisms and Mitigating Approaches
journal, April 2019
- Sharifi‐Asl, Soroosh; Lu, Jun; Amine, Khalil
- Advanced Energy Materials, Vol. 9, Issue 22
Effect of Mg doping on the local structure of LiMgyCo1−yO2 cathode material investigated by X-ray absorption spectroscopy
journal, April 2014
- Cheng, J. H.; Pan, C. J.; Nithya, C.
- Journal of Power Sources, Vol. 252
Electrode–Electrolyte Interface in Li-Ion Batteries: Current Understanding and New Insights
journal, October 2015
- Gauthier, Magali; Carney, Thomas J.; Grimaud, Alexis
- The Journal of Physical Chemistry Letters, Vol. 6, Issue 22
Hexagonal to Cubic Spinel Transformation in Lithiated Cobalt Oxide
journal, January 2004
- Gabrisch, Heike; Yazami, Rachid; Fultz, Brent
- Journal of The Electrochemical Society, Vol. 151, Issue 6
Fluorinated Electrolytes for 5-V Li-Ion Chemistry: Probing Voltage Stability of Electrolytes with Electrochemical Floating Test
journal, January 2015
- He, Meinan; Hu, Libo; Xue, Zheng
- Journal of The Electrochemical Society, Vol. 162, Issue 9
Layered LiCoO[sub 2] with a Different Oxygen Stacking (O2 Structure) as a Cathode Material for Rechargeable Lithium Batteries
journal, January 2000
- Paulsen, J. M.; Mueller-Neuhaus, J. R.; Dahn, J. R.
- Journal of The Electrochemical Society, Vol. 147, Issue 2
Mechanism of hydrofluoric acid formation in ethylene carbonate electrolytes with fluorine salt additives
journal, November 2015
- Tebbe, Jonathon L.; Fuerst, Thomas F.; Musgrave, Charles B.
- Journal of Power Sources, Vol. 297
The stability of the SEI layer, surface composition and the oxidation state of transition metals at the electrolyte–cathode interface impacted by the electrochemical cycling: X-ray photoelectron spectroscopy investigation
journal, January 2012
- Cherkashinin, Gennady; Nikolowski, Kristian; Ehrenberg, Helmut
- Physical Chemistry Chemical Physics, Vol. 14, Issue 35
Electrolyte Reactions with the Surface of High Voltage LiNi[sub 0.5]Mn[sub 1.5]O[sub 4] Cathodes for Lithium-Ion Batteries
journal, January 2010
- Yang, Li; Ravdel, Boris; Lucht, Brett L.
- Electrochemical and Solid-State Letters, Vol. 13, Issue 8
Fluorinated electrolytes for 5 V lithium-ion battery chemistry
journal, January 2013
- Zhang, Zhengcheng; Hu, Libo; Wu, Huiming
- Energy & Environmental Science, Vol. 6, Issue 6
First-Principles Evidence for Stage Ordering in Li[sub x]CoO[sub 2]
journal, January 1998
- Van der Ven, Anton
- Journal of The Electrochemical Society, Vol. 145, Issue 6
First In Situ Observation of the LiCoO 2 Electrode/Electrolyte Interface by Total-Reflection X-ray Absorption Spectroscopy
journal, October 2012
- Takamatsu, Daiko; Koyama, Yukinori; Orikasa, Yuki
- Angewandte Chemie International Edition, Vol. 51, Issue 46
Electrical Energy Storage for the Grid: A Battery of Choices
journal, November 2011
- Dunn, B.; Kamath, H.; Tarascon, J. -M.
- Science, Vol. 334, Issue 6058
Fundamental degradation mechanisms of layered oxide Li-ion battery cathode materials: Methodology, insights and novel approaches
journal, February 2015
- Hausbrand, R.; Cherkashinin, G.; Ehrenberg, H.
- Materials Science and Engineering: B, Vol. 192
Profiling the nanoscale gradient in stoichiometric layered cathode particles for lithium-ion batteries
journal, January 2014
- Lin, Feng; Nordlund, Dennis; Markus, Isaac M.
- Energy & Environmental Science, Vol. 7, Issue 9
The investigation of Ti-modified LiCoO2 materials for lithium ion battery
journal, September 2014
- Yu, Jinpeng; Han, Zenghui; Hu, Xiaohong
- Journal of Power Sources, Vol. 262
Effects of cationic substitution on structural defects in layered cathode materials LiNiO2
journal, January 2014
- Chen, Hungru; Dawson, James A.; Harding, John H.
- Journal of Materials Chemistry A, Vol. 2, Issue 21
Probing the Origin of Enhanced Stability of “AlPO4” Nanoparticle Coated LiCoO2 during Cycling to High Voltages: Combined XRD and XPS Studies
journal, October 2009
- Lu, Yi-Chun; Mansour, Azzam N.; Yabuuchi, Naoaki
- Chemistry of Materials, Vol. 21, Issue 19, p. 4408-4424
A first-order Mott transition in LixCoO2
journal, August 2004
- Marianetti, C. A.; Kotliar, G.; Ceder, G.
- Nature Materials, Vol. 3, Issue 9
The cathode–electrolyte interface in the Li-ion battery
journal, November 2004
- Edström, K.; Gustafsson, T.; Thomas, J. O.
- Electrochimica Acta, Vol. 50, Issue 2-3
Effect of Cr dopant on the cathodic behavior of LiCoO2
journal, December 2002
- Madhavi, S.; Subba Rao, G. V.; Chowdari, B. V. R.
- Electrochimica Acta, Vol. 48, Issue 3
Dynamic evolution of cathode electrolyte interphase (CEI) on high voltage LiCoO2 cathode and its interaction with Li anode
journal, September 2018
- Zhang, Jie-Nan; Li, Qinghao; Wang, Yi
- Energy Storage Materials, Vol. 14
Chemical States of Overcharged LiCoO 2 Particle Surfaces and Interiors Observed Using Electron Energy-Loss Spectroscopy
journal, June 2015
- Kikkawa, Jun; Terada, Shohei; Gunji, Akira
- The Journal of Physical Chemistry C, Vol. 119, Issue 28
Chemical Reactivity Descriptor for the Oxide-Electrolyte Interface in Li-Ion Batteries
journal, August 2017
- Giordano, Livia; Karayaylali, Pinar; Yu, Yang
- The Journal of Physical Chemistry Letters, Vol. 8, Issue 16
Electrochemical surface passivation of LiCoO2 particles at ultrahigh voltage and its applications in lithium-based batteries
journal, November 2018
- Qian, Jiawei; Liu, Lei; Yang, Jixiang
- Nature Communications, Vol. 9, Issue 1
Unexpected Improved Performance of ALD Coated LiCoO 2 /Graphite Li-Ion Batteries
journal, September 2012
- Jung, Yoon Seok; Lu, Peng; Cavanagh, Andrew S.
- Advanced Energy Materials, Vol. 3, Issue 2
Electrode–electrolyte interfaces in lithium-based batteries
journal, January 2018
- Yu, Xingwen; Manthiram, Arumugam
- Energy & Environmental Science, Vol. 11, Issue 3
An Outlook on Lithium Ion Battery Technology
journal, September 2017
- Manthiram, Arumugam
- ACS Central Science, Vol. 3, Issue 10
Relative Impact of Al or Mg Substitution on the Thermal Stability of LiCo[sub 1−z]M[sub z]O[sub 2] (M=Al or Mg) by Accelerating Rate Calorimetry
journal, January 2009
- Zhou, Fu; Luo, Wenbin; Zhao, Xuemei
- Journal of The Electrochemical Society, Vol. 156, Issue 11
Understanding voltage decay in lithium-excess layered cathode materials through oxygen-centred structural arrangement
journal, August 2018
- Myeong, Seungjun; Cho, Woongrae; Jin, Wooyoung
- Nature Communications, Vol. 9, Issue 1
The Influence of Ni Doping on the Structure and Electrochemical Properties of LiCoO 2 Materials
journal, January 2018
- Jin, Yahui; Xu, Shiguo; Li, Zhitao
- Journal of The Electrochemical Society, Vol. 165, Issue 10
Comparison of the chemical stability of the high energy density cathodes of lithium-ion batteries
journal, November 2001
- Chebiam, R. V.; Kannan, A. M.; Prado, F.
- Electrochemistry Communications, Vol. 3, Issue 11
Oxygen Contribution on Li-Ion Intercalation−Deintercalation in LiCoO 2 Investigated by O K-Edge and Co L-Edge X-ray Absorption Spectroscopy
journal, March 2002
- Yoon, Won-Sub; Kim, Kwang-Bum; Kim, Min-Gyu
- The Journal of Physical Chemistry B, Vol. 106, Issue 10
Critical Role of Cations in Lithium Sites on Extended Electrochemical Reversibility of Co-Rich Layered Oxide
journal, March 2017
- Cho, Woongrae; Myeong, Seungjun; Kim, Namhyung
- Advanced Materials, Vol. 29, Issue 21
Crystal structures, electrical conductivities and electrochemical properties of LiCo1−xMgxO2 (0≤x≤0.11)
journal, September 2006
- Kim, Ho-Jin; Jeong, Yeon Uk; Lee, Joon-Hyung
- Journal of Power Sources, Vol. 159, Issue 1
Staging Phase Transitions in Li[sub x]CoO[sub 2]
journal, January 2002
- Chen, Zhaohui; Lu, Zhonghua; Dahn, J. R.
- Journal of The Electrochemical Society, Vol. 149, Issue 12
Towards greener and more sustainable batteries for electrical energy storage
journal, November 2014
- Larcher, D.; Tarascon, J-M.
- Nature Chemistry, Vol. 7, Issue 1
Approaching the capacity limit of lithium cobalt oxide in lithium ion batteries via lanthanum and aluminium doping
journal, June 2018
- Liu, Qi; Su, Xin; Lei, Dan
- Nature Energy, Vol. 3, Issue 11
A highly stabilized nickel-rich cathode material by nanoscale epitaxy control for high-energy lithium-ion batteries
journal, January 2018
- Kim, Junhyeok; Ma, Hyunsoo; Cha, Hyungyeon
- Energy & Environmental Science, Vol. 11, Issue 6
Defect Chemistry in Layered Li M O 2 ( M = Co, Ni, Mn, and Li 1/3 Mn 2/3 ) by First-Principles Calculations
journal, October 2012
- Koyama, Yukinori; Arai, Hajime; Tanaka, Isao
- Chemistry of Materials, Vol. 24, Issue 20
Electrical energy storage for transportation—approaching the limits of, and going beyond, lithium-ion batteries
journal, January 2012
- Thackeray, Michael M.; Wolverton, Christopher; Isaacs, Eric D.
- Energy & Environmental Science, Vol. 5, Issue 7
Nickel-Rich and Lithium-Rich Layered Oxide Cathodes: Progress and Perspectives
journal, October 2015
- Manthiram, Arumugam; Knight, James C.; Myung, Seung-Taek
- Advanced Energy Materials, Vol. 6, Issue 1
Dynamic behaviour of interphases and its implication on high-energy-density cathode materials in lithium-ion batteries
journal, April 2017
- Li, Wangda; Dolocan, Andrei; Oh, Pilgun
- Nature Communications, Vol. 8, Issue 1
Methods to obtain excellent capacity retention in LiCoO2 cycled to 4.5 V
journal, March 2004
- Chen, Zhaohui; Dahn, J. R.
- Electrochimica Acta, Vol. 49, Issue 7
Mixed Electronic and Ionic Conductor-Coated Cathode Material for High-Voltage Lithium Ion Battery
journal, May 2016
- Shim, Jae-Hyun; Han, Jung-Min; Lee, Joon-Hyung
- ACS Applied Materials & Interfaces, Vol. 8, Issue 19
LiCoO[sub 2] Cathode Material That Does Not Show a Phase Transition from Hexagonal to Monoclinic Phase
journal, January 2001
- Cho, Jaephil; Kim, Yong Jeong; Park, Byungwoo
- Journal of The Electrochemical Society, Vol. 148, Issue 10
Performance of LiM 0.05 Co 0.95 O 2 Cathode Materials in Lithium Rechargeable Cells When Cycled up to 4.5 V
journal, March 2005
- Zou, Meijing; Yoshio, Masaki; Gopukumar, S.
- Chemistry of Materials, Vol. 17, Issue 6