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Title: Efficient and selective carbon–carbon coupling on coke-resistant PdAu single-atom alloys

Abstract

We demonstrate that PdAu single-atom alloy model catalysts offer a heterogeneous route to selective Würtz-type C–C coupling.

Authors:
ORCiD logo [1];  [2];  [2];  [2];  [2]; ORCiD logo [1]; ORCiD logo [2]
  1. Thomas Young Centre and Department of Chemical Engineering, University College London, Roberts Building, London WC1E 7JE, UK
  2. Department of Chemistry, Tufts University, Medford, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1576638
Grant/Contract Number:  
SC0012573
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Name: ChemComm Journal Volume: 55 Journal Issue: 100; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Réocreux, Romain, Uhlman, Matthew, Thuening, Theodore, Kress, Paul, Hannagan, Ryan, Stamatakis, Michail, and Sykes, E. Charles H. Efficient and selective carbon–carbon coupling on coke-resistant PdAu single-atom alloys. United Kingdom: N. p., 2019. Web. doi:10.1039/C9CC07932G.
Réocreux, Romain, Uhlman, Matthew, Thuening, Theodore, Kress, Paul, Hannagan, Ryan, Stamatakis, Michail, & Sykes, E. Charles H. Efficient and selective carbon–carbon coupling on coke-resistant PdAu single-atom alloys. United Kingdom. doi:10.1039/C9CC07932G.
Réocreux, Romain, Uhlman, Matthew, Thuening, Theodore, Kress, Paul, Hannagan, Ryan, Stamatakis, Michail, and Sykes, E. Charles H. Thu . "Efficient and selective carbon–carbon coupling on coke-resistant PdAu single-atom alloys". United Kingdom. doi:10.1039/C9CC07932G.
@article{osti_1576638,
title = {Efficient and selective carbon–carbon coupling on coke-resistant PdAu single-atom alloys},
author = {Réocreux, Romain and Uhlman, Matthew and Thuening, Theodore and Kress, Paul and Hannagan, Ryan and Stamatakis, Michail and Sykes, E. Charles H.},
abstractNote = {We demonstrate that PdAu single-atom alloy model catalysts offer a heterogeneous route to selective Würtz-type C–C coupling.},
doi = {10.1039/C9CC07932G},
journal = {ChemComm},
number = 100,
volume = 55,
place = {United Kingdom},
year = {2019},
month = {12}
}

Journal Article:
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Works referenced in this record:

Surface-Catalyzed C–C Covalent Coupling Strategies toward the Synthesis of Low-Dimensional Carbon-Based Nanostructures
journal, July 2015


The Promotional Effect of Gold in Catalysis by Palladium-Gold
journal, October 2005


Mechanisms of the Ullmann coupling reaction in adsorbed monolayers
journal, August 1993

  • Xi, Ming; Bent, Brian E.
  • Journal of the American Chemical Society, Vol. 115, Issue 16
  • DOI: 10.1021/ja00069a048

Sonogashira Coupling on an Extended Gold Surface in Vacuo: Reaction of Phenylacetylene with Iodobenzene on Au(111)
journal, June 2010

  • Kanuru, Vijay K.; Kyriakou, Georgios; Beaumont, Simon K.
  • Journal of the American Chemical Society, Vol. 132, Issue 23
  • DOI: 10.1021/ja1011542

Thermal stability of the methyl group adsorbed on the palladium(100) surface
journal, November 1991

  • Solymosi, Frigyes; Revesz, Karoly
  • Journal of the American Chemical Society, Vol. 113, Issue 24
  • DOI: 10.1021/ja00024a019

Parallel kinetic Monte Carlo simulation framework incorporating accurate models of adsorbate lateral interactions
journal, December 2013

  • Nielsen, Jens; d’Avezac, Mayeul; Hetherington, James
  • The Journal of Chemical Physics, Vol. 139, Issue 22
  • DOI: 10.1063/1.4840395

Elucidating the Stability and Reactivity of Surface Intermediates on Single-Atom Alloy Catalysts
journal, April 2018

  • Darby, Matthew T.; Réocreux, Romain; Sykes, E. Charles. H.
  • ACS Catalysis, Vol. 8, Issue 6
  • DOI: 10.1021/acscatal.8b00881

Carbon-carbon coupling of methyl groups on Pt(111)
journal, April 1993


Metallaphotoredox-catalysed sp3–sp3 cross-coupling of carboxylic acids with alkyl halides
journal, August 2016

  • Johnston, Craig P.; Smith, Russell T.; Allmendinger, Simon
  • Nature, Vol. 536, Issue 7616
  • DOI: 10.1038/nature19056

An Overview of Palladium Nanocatalysts: Surface and Molecular Reactivity
journal, August 2008

  • Durand, Jérôme; Teuma, Emmanuelle; Gómez, Montserrat
  • European Journal of Inorganic Chemistry, Vol. 2008, Issue 23
  • DOI: 10.1002/ejic.200800569

C–C Coupling on Single-Atom-Based Heterogeneous Catalyst
journal, January 2018

  • Zhang, Xiaoyan; Sun, Zaicheng; Wang, Bin
  • Journal of the American Chemical Society, Vol. 140, Issue 3
  • DOI: 10.1021/jacs.7b09314

Spectroscopic study on the adsorption and dissociation of CH3I on Pd(100): thermal and photo effects
journal, January 1993


A graph-theoretical kinetic Monte Carlo framework for on-lattice chemical kinetics
journal, June 2011

  • Stamatakis, Michail; Vlachos, Dionisios G.
  • The Journal of Chemical Physics, Vol. 134, Issue 21
  • DOI: 10.1063/1.3596751

Alkyl Coupling on Copper, Silver, and Gold: Correlation Between the Coupling Rate and the Metal-Alkyl Bond Strength
journal, May 1994


An infrared spectroscopic and temperature-programmed desorption study of methyl iodide hydrogenation on Pd()
journal, February 2003


Decomposition Mechanism of Anisole on Pt(111): Combining Single-Crystal Experiments and First-Principles Calculations
journal, November 2016

  • Réocreux, Romain; Ould Hamou, Cherif A.; Michel, Carine
  • ACS Catalysis, Vol. 6, Issue 12
  • DOI: 10.1021/acscatal.6b02253

H 2 Activation and Spillover on Catalytically Relevant Pt–Cu Single Atom Alloys
journal, August 2015

  • Lucci, Felicia R.; Marcinkowski, Matthew D.; Lawton, Timothy J.
  • The Journal of Physical Chemistry C, Vol. 119, Issue 43
  • DOI: 10.1021/acs.jpcc.5b05562

On the Nature of the Active Species in Palladium Catalyzed Mizoroki–Heck and Suzuki–Miyaura Couplings – Homogeneous or Heterogeneous Catalysis, A Critical Review
journal, April 2006

  • Phan, Nam T. S.; Van Der Sluys, Matthew; Jones, Christopher W.
  • Advanced Synthesis & Catalysis, Vol. 348, Issue 6
  • DOI: 10.1002/adsc.200505473

Atomic-Scale Geometry and Electronic Structure of Catalytically Important Pd/Au Alloys
journal, February 2010

  • Baber, Ashleigh E.; Tierney, Heather L.; Sykes, E. Charles H.
  • ACS Nano, Vol. 4, Issue 3
  • DOI: 10.1021/nn901390y

Chemisorption and Transformation of CH x Fragments ( x = 0−3) on a Pd(111) Surface:  A Periodic Density Functional Study
journal, February 1998

  • Paul, J. -F.; Sautet, P.
  • The Journal of Physical Chemistry B, Vol. 102, Issue 9
  • DOI: 10.1021/jp9733227

Carbon−Carbon Coupling Reactions Catalyzed by Heterogeneous Palladium Catalysts
journal, January 2007

  • Yin, ; Liebscher, Jürgen
  • Chemical Reviews, Vol. 107, Issue 1
  • DOI: 10.1021/cr0505674

Controlling Hydrogen Activation, Spillover, and Desorption with Pd–Au Single-Atom Alloys
journal, January 2016

  • Lucci, Felicia R.; Darby, Matthew T.; Mattera, Michael F. G.
  • The Journal of Physical Chemistry Letters, Vol. 7, Issue 3
  • DOI: 10.1021/acs.jpclett.5b02400

Unraveling the Complexity of Catalytic Reactions via Kinetic Monte Carlo Simulation: Current Status and Frontiers
journal, November 2012

  • Stamatakis, Michail; Vlachos, Dionisios G.
  • ACS Catalysis, Vol. 2, Issue 12
  • DOI: 10.1021/cs3005709

Palladium(0) nanoparticles formed in situ in the Suzuki–Miyaura reaction: The effect of a palladium(II) precursor
journal, April 2010