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Title: Gasification of coal, Chenopodium Album biomass, and co-gasification of a coal-biomass mixture by thermogravimetric-gas analysis

Abstract

Gasification studies were performed on sub-bituminous coal of the province Centro in Boyacá state of Colombia, vegetable biomass Chenopodium album (cenizo) and co-gasification of coal-biomass mixtures agglomerated with paraffin in a thermogravimetric analyzer. Biomass synergistically promoted thermochemical transformation of the coal was observed. Experimental results were compared to equilibrium composition simulations. Ash fusibility tests of the coal-biomass mixture were carried out, which allowed to clarify its behavior, such as dry or fluid ash according to own chemical composition, during the gasification process. The experimental tests allowed determining the differences in thermal decomposition, between coal, cenizo and coal-biomass blend, which are attributable to the physicochemical properties of each one solid fuel. During the tests, gas chromatography analyses were performed to establish the compositions of the syngas. The syngas obtained from biomass had the highest concentration of CO and the lowest H 2; the coal and the coal-biomass mixture were slightly minor respectively. Concentrations of CH 4, CO 2 and C 2H 4 were similar between coal and biomass. This result is consistent with the higher calorific value of the coal syngas. The production of syngas from the coal-biomass mixture had the lowest contents of H 2 and CO due to synergistic phenomenamore » that occur with the fuel mixture. The co-gasification of the mixture gave the highest syngas production, carbon conversion, and thermal efficiency. These results indicate the viability of co-gasification of coal- Chenopodium album agglomerated mixtures. In gasification of non-agglomerated mixtures of coal-cenizo, the biomass can be burned directly without producing syngas.« less

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [4]; ORCiD logo [4]; ORCiD logo [5]; ORCiD logo [6]; ORCiD logo [1]
  1. Univ. Pedagógica y Tecnológica de Colombia (Colombia)
  2. Univ. Nacional de Colombia (Colombia)
  3. National Renewable Energy Lab. (NREL), Golden, CO (United States)
  4. CARBOING S.A.S. (Colombia)
  5. Univ. del Atlántico (Colombia)
  6. Universidad Autónoma de Coahuila (Mexico)
Publication Date:
Research Org.:
National Renewable Energy Lab. (NREL), Golden, CO (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Bioenergy Technologies Office (EE-3B)
OSTI Identifier:
1576482
Report Number(s):
NREL/JA-2700-75172
Journal ID: ISSN 0121-1129
Grant/Contract Number:  
AC36-08GO28308
Resource Type:
Accepted Manuscript
Journal Name:
Revista Facultad de Ingeniería
Additional Journal Information:
Journal Volume: 28; Journal Issue: 53; Journal ID: ISSN 0121-1129
Country of Publication:
United States
Language:
English
Subject:
09 BIOMASS FUELS; agglomerated mixtures; chenopodium album; coal-biomass; co-gasification; synergy; syngas; BCPL

Citation Formats

Ardila-Barragán, Marco Antonio, Valdés-Rentería, Carlos Francisco, Pecha, Brennan, López-Díaz, Alfonso, Gil-Lancheros, Eduardo, Vanegas-Chamorro, Marley Cecilia, Camporredondo-Saucedo, Jesús Emilio, and Lozano-Gómez, Luis Fernando. Gasification of coal, Chenopodium Album biomass, and co-gasification of a coal-biomass mixture by thermogravimetric-gas analysis. United States: N. p., 2019. Web. doi:10.19053/01211129.v28.n53.2019.10147.
Ardila-Barragán, Marco Antonio, Valdés-Rentería, Carlos Francisco, Pecha, Brennan, López-Díaz, Alfonso, Gil-Lancheros, Eduardo, Vanegas-Chamorro, Marley Cecilia, Camporredondo-Saucedo, Jesús Emilio, & Lozano-Gómez, Luis Fernando. Gasification of coal, Chenopodium Album biomass, and co-gasification of a coal-biomass mixture by thermogravimetric-gas analysis. United States. doi:10.19053/01211129.v28.n53.2019.10147.
Ardila-Barragán, Marco Antonio, Valdés-Rentería, Carlos Francisco, Pecha, Brennan, López-Díaz, Alfonso, Gil-Lancheros, Eduardo, Vanegas-Chamorro, Marley Cecilia, Camporredondo-Saucedo, Jesús Emilio, and Lozano-Gómez, Luis Fernando. Wed . "Gasification of coal, Chenopodium Album biomass, and co-gasification of a coal-biomass mixture by thermogravimetric-gas analysis". United States. doi:10.19053/01211129.v28.n53.2019.10147. https://www.osti.gov/servlets/purl/1576482.
@article{osti_1576482,
title = {Gasification of coal, Chenopodium Album biomass, and co-gasification of a coal-biomass mixture by thermogravimetric-gas analysis},
author = {Ardila-Barragán, Marco Antonio and Valdés-Rentería, Carlos Francisco and Pecha, Brennan and López-Díaz, Alfonso and Gil-Lancheros, Eduardo and Vanegas-Chamorro, Marley Cecilia and Camporredondo-Saucedo, Jesús Emilio and Lozano-Gómez, Luis Fernando},
abstractNote = {Gasification studies were performed on sub-bituminous coal of the province Centro in Boyacá state of Colombia, vegetable biomass Chenopodium album (cenizo) and co-gasification of coal-biomass mixtures agglomerated with paraffin in a thermogravimetric analyzer. Biomass synergistically promoted thermochemical transformation of the coal was observed. Experimental results were compared to equilibrium composition simulations. Ash fusibility tests of the coal-biomass mixture were carried out, which allowed to clarify its behavior, such as dry or fluid ash according to own chemical composition, during the gasification process. The experimental tests allowed determining the differences in thermal decomposition, between coal, cenizo and coal-biomass blend, which are attributable to the physicochemical properties of each one solid fuel. During the tests, gas chromatography analyses were performed to establish the compositions of the syngas. The syngas obtained from biomass had the highest concentration of CO and the lowest H2; the coal and the coal-biomass mixture were slightly minor respectively. Concentrations of CH4, CO2 and C2H4 were similar between coal and biomass. This result is consistent with the higher calorific value of the coal syngas. The production of syngas from the coal-biomass mixture had the lowest contents of H2 and CO due to synergistic phenomena that occur with the fuel mixture. The co-gasification of the mixture gave the highest syngas production, carbon conversion, and thermal efficiency. These results indicate the viability of co-gasification of coal-Chenopodium album agglomerated mixtures. In gasification of non-agglomerated mixtures of coal-cenizo, the biomass can be burned directly without producing syngas.},
doi = {10.19053/01211129.v28.n53.2019.10147},
journal = {Revista Facultad de Ingeniería},
number = 53,
volume = 28,
place = {United States},
year = {2019},
month = {10}
}

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