The role of ozone in the formation and structural evolution of graphene oxide obtained from nanographite

Groveman, Sam; Peng, Jing; Itin, Boris; Diallo, Ibrahim; Pratt, Lawrence M.; Greer, Alexander; Biddinger, Elizabeth J.; Greenbaum, Steve G.; Drain, Charles Michael; Francesconi, Lynn; Vittadello, Michele

doi:10.1016/j.carbon.2017.06.092

Title: The role of ozone in the formation and structural evolution of graphene oxide obtained from nanographite

Full Record
Other Related Research

Authors:

Groveman, Sam; Peng, Jing; Itin, Boris; Diallo, Ibrahim; Pratt, Lawrence M.; Greer, Alexander; Biddinger, Elizabeth J.; Greenbaum, Steve G.; Drain, Charles Michael; Francesconi, Lynn;

Publication Date:: 2017-10-01

Sponsoring Org.:: USDOE

OSTI Identifier:: 1576043

Grant/Contract Number:: AC02-05CH11231

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Carbon

Additional Journal Information:: Journal Name: Carbon Journal Volume: 122 Journal Issue: C; Journal ID: ISSN 0008-6223

Publisher:: Elsevier

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Groveman, Sam, Peng, Jing, Itin, Boris, Diallo, Ibrahim, Pratt, Lawrence M., Greer, Alexander, Biddinger, Elizabeth J., Greenbaum, Steve G., Drain, Charles Michael, Francesconi, Lynn, and Vittadello, Michele. The role of ozone in the formation and structural evolution of graphene oxide obtained from nanographite.  United Kingdom: N. p., 2017. 
        Web.  doi:10.1016/j.carbon.2017.06.092.

Copy to clipboard


                    Groveman, Sam, Peng, Jing, Itin, Boris, Diallo, Ibrahim, Pratt, Lawrence M., Greer, Alexander, Biddinger, Elizabeth J., Greenbaum, Steve G., Drain, Charles Michael, Francesconi, Lynn, & Vittadello, Michele. The role of ozone in the formation and structural evolution of graphene oxide obtained from nanographite.  United Kingdom.  doi:https://doi.org/10.1016/j.carbon.2017.06.092

Copy to clipboard


                    Groveman, Sam, Peng, Jing, Itin, Boris, Diallo, Ibrahim, Pratt, Lawrence M., Greer, Alexander, Biddinger, Elizabeth J., Greenbaum, Steve G., Drain, Charles Michael, Francesconi, Lynn, and Vittadello, Michele. Sun .  
        "The role of ozone in the formation and structural evolution of graphene oxide obtained from nanographite".  United Kingdom.  doi:https://doi.org/10.1016/j.carbon.2017.06.092.

Copy to clipboard


                    
@article{osti_1576043,

  title        = {The role of ozone in the formation and structural evolution of graphene oxide obtained from nanographite},

  author       = {Groveman, Sam and Peng, Jing and Itin, Boris and Diallo, Ibrahim and Pratt, Lawrence M. and Greer, Alexander and Biddinger, Elizabeth J. and Greenbaum, Steve G. and Drain, Charles Michael and Francesconi, Lynn and Vittadello, Michele},

  abstractNote = {},

  doi          = {10.1016/j.carbon.2017.06.092},

  journal      = {Carbon},

  number       = C,

  volume       = 122,

  place        = {United Kingdom},

  year         = {2017},

  month        = {10}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
DOI: https://doi.org/10.1016/j.carbon.2017.06.092

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 6 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Similar Records in DOE PAGES and OSTI.GOV collections:

The role of ozone in the formation and structural evolution of graphene oxide obtained from nanographite

Journal Article Groveman, Sam ; Peng, Jing ; Itin, Boris ; ... - Carbon

Chemical exfoliation of graphite under strong oxidizing conditions yields graphene oxide nanosheetswith oxy functional groups on the carbon basal plane. The importance of ozone in the chemical oxidation mechanism of graphite by the widely-used Hummers' method has been largely overlooked. Herein we demonstrate that the ozonolysis of graphite leads to the formation of secondary epoxy and perox-ymonosulfate ester functional groups arising from a rotationally hindered Criegee intermediate and sulfuric acid, in a strongly favored thermodynamic process. This mechanistic step is followed by formation of adjacent epoxy and hydroxy groups as major functionalities on graphene oxides via a radical process, andmore »« less
DOI: https://doi.org/10.1016/j.carbon.2017.06.092
Assessment of the role of nitrogen oxides in nonurban ozone formation

Technical Report Altshuller, A P

Technical issues related to ozone and other photochemically generated products formed in the atmosphere is presented. An earlier survey was carried out to examine the hypothesis that NO(sup x) was the limiting precursor species with respect to photochemical formation of O3 over nonurban areas. If this hypothesis could be proved, it would indicate that increases in NO(sup x) concentrations could lead to higher concentration levels of nonurban O3. Because of the fragmentary knowledge of the interactions between NO(sup x) and O3 in nonurban areas, the authors of the survey could not arrive at any definite conclusions. Based on these recentmore »« less
Role of nitrogen oxides in nonurban ozone formation in the planetary boundary layer over N (North) America, W (Western) Europe, and adjacent areas of ocean

Technical Report Altshuller, A P

The status of knowledge on photochemical ozone formation and the effects of nitrogen oxides and peroxyacyl nitrates on such formation was evaluated. The literature is reviewed on nonurban ozone and nitrogen oxide concentration distributions, ozone lifetimes, nitrogen oxide lifetimes, and ozone formation in plumes as related to nitrogen oxide. The modeling approaches applied to ozone formation with urban plumes, power plant plumes, high-pressure systems, and during longer-range transport of ozone formation associated with reactions of natural hydrocarbons and nitrogen oxide near ground level as well as photochemical ozone formation associated with reactions of carbon monoxide and more-persistent organic species withmore »« less
Analysis of the Structural Evolution of Zinc Oxide Powders Obtained by Mechanical High-Energy Grinding

Journal Article Averin, I. A. ; Pronin, I. A., E-mail: pronin-i90@mail.ru ; Yakushova, N. D. ; ... - Technical Physics

Zinc oxide powders made by mechanical high-energy grinding have been investigated using the methods of scanning electron microscopy, thermal nitrogen desorption, and Raman spectroscopy of infrared Fourier spectroscopy. Their structural evolution, including reduction of the average size of crystallites, increase in specific surface area, as well as changes in the number and ratio of adsorption centers, has been demonstrated. The data on the reconstruction of the surface of zinc oxide powders and multiple bond breaking in near-surface areas resulting from long-term dispersion have been presented.
DOI: https://doi.org/10.1134/S1063784219090020
Structures, relative stabilities, and vibrational spectra of isomers of Cl sub 2 O sub 2 : The role of the chlorine oxide dimer in Antarctic ozone depleting mechanisms

Journal Article McGrath, M P ; Clemitshaw, K C ; Rowland, F S ; ... - Journal of Physical Chemistry; (USA)

Quantitative ab initio molecular orbital calculations have been applied to he description of the structures, relative stabilities, and vibrational spectra of isomers of Cl{sub 2}O{sub 2}. The highest level of calculations performed (MP2/6-31+G (3d)//MP2/6-31G*) suggests that C{sub 2} symmetry ClOOCl (chlorine peroxide) is the lowest energy form but that the hypervalent, C{sub s} symmetry species ClClO{sub 2} (chloryl chloride) is only about 1 kcal/mol higher in energy. A third form, C{sub 1} symmetry ClOClO (chlorine chlorite), lies higher in energy by 7 kcal/mol. The theoretical results are compared with experimentally determined thermochemical and vibrational data, and the role of themore »« less
DOI: https://doi.org/10.1021/j100378a089

Similar Records