skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on November 8, 2020

Title: Improving LMOF luminescence quantum yield through guest-mediated rigidification

Abstract

Rotation of a specific pyridyl ring in LMOF-236 is locked by loading guest molecules into the MOF's pore, improving quantum yield by nearly 400%–an example of a generalizable strategy for maximizing quantum yield via guest-packing rigidification.

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [1]
  1. Chemistry & Chemical Biology, Rutgers University, Piscataway, USA
  2. Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1576034
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Materials Chemistry C
Additional Journal Information:
Journal Name: Journal of Materials Chemistry C Journal Volume: 7 Journal Issue: 46; Journal ID: ISSN 2050-7526
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Lustig, William P., Teat, Simon J., and Li, Jing. Improving LMOF luminescence quantum yield through guest-mediated rigidification. United Kingdom: N. p., 2019. Web. doi:10.1039/C9TC05216J.
Lustig, William P., Teat, Simon J., & Li, Jing. Improving LMOF luminescence quantum yield through guest-mediated rigidification. United Kingdom. doi:10.1039/C9TC05216J.
Lustig, William P., Teat, Simon J., and Li, Jing. Thu . "Improving LMOF luminescence quantum yield through guest-mediated rigidification". United Kingdom. doi:10.1039/C9TC05216J.
@article{osti_1576034,
title = {Improving LMOF luminescence quantum yield through guest-mediated rigidification},
author = {Lustig, William P. and Teat, Simon J. and Li, Jing},
abstractNote = {Rotation of a specific pyridyl ring in LMOF-236 is locked by loading guest molecules into the MOF's pore, improving quantum yield by nearly 400%–an example of a generalizable strategy for maximizing quantum yield via guest-packing rigidification.},
doi = {10.1039/C9TC05216J},
journal = {Journal of Materials Chemistry C},
number = 46,
volume = 7,
place = {United Kingdom},
year = {2019},
month = {11}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on November 8, 2020
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Nanocomposites of Zr(IV)-Based Metal–Organic Frameworks and Reduced Graphene Oxide for Electrochemically Sensing Ciprofloxacin in Water
journal, March 2019

  • Fang, Xian; Chen, Xiaoyan; Liu, Ying
  • ACS Applied Nano Materials, Vol. 2, Issue 4
  • DOI: 10.1021/acsanm.9b00243

Ultrabright Luminescence from Gold Nanoclusters: Rigidifying the Au(I)–Thiolate Shell
journal, June 2015

  • Pyo, Kyunglim; Thanthirige, Viraj Dhanushka; Kwak, Kyuju
  • Journal of the American Chemical Society, Vol. 137, Issue 25
  • DOI: 10.1021/jacs.5b04210

Twist Angles and Rotational Energy Barriers of Biphenyl and Substituted Biphenyls
journal, April 2002

  • Grein, Friedrich
  • The Journal of Physical Chemistry A, Vol. 106, Issue 15
  • DOI: 10.1021/jp0122124

Luminescent metal–organic frameworks for chemical sensing and explosive detection
journal, January 2014

  • Hu, Zhichao; Deibert, Benjamin J.; Li, Jing
  • Chem. Soc. Rev., Vol. 43, Issue 16
  • DOI: 10.1039/C4CS00010B

Ultrastable Luminescent Hybrid Bromide Perovskite@MOF Nanocomposites for the Degradation of Organic Pollutants in Water
journal, February 2019

  • Mollick, Samraj; Mandal, Tarak Nath; Jana, Atanu
  • ACS Applied Nano Materials, Vol. 2, Issue 3
  • DOI: 10.1021/acsanm.8b02214

Stable Metal-Organic Frameworks: Design, Synthesis, and Applications
journal, February 2018


Metal–organic frameworks: functional luminescent and photonic materials for sensing applications
journal, January 2017

  • Lustig, William P.; Mukherjee, Soumya; Rudd, Nathan D.
  • Chemical Society Reviews, Vol. 46, Issue 11
  • DOI: 10.1039/C6CS00930A

A local density functional study of the structure and vibrational frequencies of molecular transition-metal compounds
journal, August 1992

  • Sosa, Carlos; Andzelm, Jan; Elkin, Brad C.
  • The Journal of Physical Chemistry, Vol. 96, Issue 16
  • DOI: 10.1021/j100195a022

Gadolinium(III)-Based Porous Luminescent Metal-Organic Frameworks for Bimodal Imaging
journal, June 2016

  • Kundu, Tanay; Mitra, Shouvik; Díaz Díaz, David
  • ChemPlusChem, Vol. 81, Issue 8
  • DOI: 10.1002/cplu.201600233

Assembly of Framework-Isomeric 4 d-4 f Heterometallic Metal-Organic Frameworks with Neutral/Anionic Micropores and Guest-Tuned Luminescence Properties
journal, February 2013

  • Ma, Jing-xin; Huang, Xiao-feng; Song, Xue-qin
  • Chemistry - A European Journal, Vol. 19, Issue 11
  • DOI: 10.1002/chem.201204022

High-Performance Blue-Excitable Yellow Phosphor Obtained from an Activated Solvochromic Bismuth-Fluorophore Metal–Organic Framework
journal, July 2016

  • Deibert, Benjamin J.; Velasco, Ever; Liu, Wei
  • Crystal Growth & Design, Vol. 16, Issue 8
  • DOI: 10.1021/acs.cgd.6b00622

Toxic Aromatics Induced Responsive Facets for a Pore Surface Functionalized Luminescent Coordination Polymer
journal, May 2017


Luminescent metal-organic frameworks as potential sensory materials for various environmental toxic agents
journal, December 2019


Metal–Organic Framework-Based Sensors for Environmental Contaminant Sensing
journal, July 2018


Molecular decoding using luminescence from an entangled porous framework
journal, January 2011

  • Takashima, Yohei; Martínez, Virginia Martínez; Furukawa, Shuhei
  • Nature Communications, Vol. 2, Issue 1
  • DOI: 10.1038/ncomms1170

Luminescent Functional Metal–Organic Frameworks
journal, June 2011

  • Cui, Yuanjing; Yue, Yanfeng; Qian, Guodong
  • Chemical Reviews, Vol. 112, Issue 2
  • DOI: 10.1021/cr200101d

Strategies to fabricate metal–organic framework (MOF)-based luminescent sensing platforms
journal, January 2019

  • Liu, Yang; Xie, Xiao-Yu; Cheng, Chen
  • Journal of Materials Chemistry C, Vol. 7, Issue 35
  • DOI: 10.1039/C9TC03208H

A heterometallic sodium–europium-cluster-based metal–organic framework as a versatile and water-stable chemosensor for antibiotics and explosives
journal, January 2017

  • Han, Min-Le; Wen, Guo-Xuan; Dong, Wen-Wen
  • Journal of Materials Chemistry C, Vol. 5, Issue 33
  • DOI: 10.1039/C7TC02885G

An Interpenetrated Framework Material with Hysteretic CO 2 Uptake
journal, January 2010

  • Mulfort, Karen L.; Farha, Omar K.; Malliakas, Christos D.
  • Chemistry - A European Journal, Vol. 16, Issue 1
  • DOI: 10.1002/chem.200902104

A new mixing of Hartree–Fock and local density‐functional theories
journal, January 1993

  • Becke, Axel D.
  • The Journal of Chemical Physics, Vol. 98, Issue 2
  • DOI: 10.1063/1.464304

Dynamic Structural Behavior and Anion-Responsive Tunable Luminescence of a Flexible Cationic Metal-Organic Framework
journal, December 2012

  • Manna, Biplab; Chaudhari, Abhijeet K.; Joarder, Biplab
  • Angewandte Chemie International Edition, Vol. 52, Issue 3
  • DOI: 10.1002/anie.201206724

Rigidifying Fluorescent Linkers by Metal–Organic Framework Formation for Fluorescence Blue Shift and Quantum Yield Enhancement
journal, May 2014

  • Wei, Zhangwen; Gu, Zhi-Yuan; Arvapally, Ravi K.
  • Journal of the American Chemical Society, Vol. 136, Issue 23
  • DOI: 10.1021/ja5006866

Selective Turn-On Ammonia Sensing Enabled by High-Temperature Fluorescence in Metal–Organic Frameworks with Open Metal Sites
journal, August 2013

  • Shustova, Natalia B.; Cozzolino, Anthony F.; Reineke, Sebastian
  • Journal of the American Chemical Society, Vol. 135, Issue 36
  • DOI: 10.1021/ja407778a

Hydrogen-bond rigidified BODIPY dyes
journal, January 2010

  • Jacobsen, Jennifer A.; Stork, Jay R.; Magde, Douglas
  • Dalton Trans., Vol. 39, Issue 3
  • DOI: 10.1039/B921772J

Self‐consistent molecular orbital methods 25. Supplementary functions for Gaussian basis sets
journal, April 1984

  • Frisch, Michael J.; Pople, John A.; Binkley, J. Stephen
  • The Journal of Chemical Physics, Vol. 80, Issue 7
  • DOI: 10.1063/1.447079

Strategies for Characterization of Large-Pore Metal-Organic Frameworks by Combined Experimental and Computational Methods
journal, October 2009

  • Bae, Youn-Sang; Dubbeldam, David; Nelson, Andrew
  • Chemistry of Materials, Vol. 21, Issue 20
  • DOI: 10.1021/cm803218f

Achieving exceptionally high luminescence quantum efficiency by immobilizing an AIE molecular chromophore into a metal–organic framework
journal, January 2015

  • Hu, Zhichao; Huang, Guangxi; Lustig, William P.
  • Chemical Communications, Vol. 51, Issue 15
  • DOI: 10.1039/C4CC07642G

Chromophore-immobilized luminescent metal–organic frameworks as potential lighting phosphors and chemical sensors
journal, January 2016

  • Wang, Fangming; Liu, Wei; Teat, Simon J.
  • Chemical Communications, Vol. 52, Issue 67
  • DOI: 10.1039/C6CC05290H

Luminescent metal–organic frameworks
journal, January 2009

  • Allendorf, M. D.; Bauer, C. A.; Bhakta, R. K.
  • Chemical Society Reviews, Vol. 38, Issue 5
  • DOI: 10.1039/b802352m

Exploring Atypical Fluorine-Hydrogen Bonds and Their Effects on Nucleoside Conformations
journal, October 2018

  • O'Reilly, Daniel; Stein, Robin S.; Patrascu, Mihai Burai
  • Chemistry - A European Journal, Vol. 24, Issue 61
  • DOI: 10.1002/chem.201803940

Chromophore-Based Luminescent Metal–Organic Frameworks as Lighting Phosphors
journal, May 2016


Hypersensitive dual-function luminescence switching of a silver-chalcogenolate cluster-based metal–organic framework
journal, February 2017

  • Huang, Ren-Wu; Wei, Yong-Sheng; Dong, Xi-Yan
  • Nature Chemistry, Vol. 9, Issue 7
  • DOI: 10.1038/nchem.2718

Two-Dimensional Metal–Organic Framework with Wide Channels and Responsive Turn-On Fluorescence for the Chemical Sensing of Volatile Organic Compounds
journal, May 2014

  • Zhang, Mei; Feng, Guangxue; Song, Zhegang
  • Journal of the American Chemical Society, Vol. 136, Issue 20
  • DOI: 10.1021/ja502643p

Photoluminescent, upconversion luminescent and nonlinear optical metal-organic frameworks: From fundamental photophysics to potential applications
journal, December 2018

  • Nguyen, Tu N.; Ebrahim, Fatmah Mish; Stylianou, Kyriakos C.
  • Coordination Chemistry Reviews, Vol. 377
  • DOI: 10.1016/j.ccr.2018.08.024

Enhancement of the π-electron delocalization and fluorescence efficiency of 1,6-diphenyl-1,3,5-hexatriene by covalent rigidification
journal, June 2000


Solution Processable MOF Yellow Phosphor with Exceptionally High Quantum Efficiency
journal, November 2014

  • Gong, Qihan; Hu, Zhichao; Deibert, Benjamin J.
  • Journal of the American Chemical Society, Vol. 136, Issue 48
  • DOI: 10.1021/ja509446h