Adding diffusion ordered NMR spectroscopy (DOSY) to the arsenal for characterizing paramagnetic complexes

doi:10.1039/C9CC08229H

Title: Adding diffusion ordered NMR spectroscopy (DOSY) to the arsenal for characterizing paramagnetic complexes

Abstract

Herein we report the development of diffusion ordered NMR spectroscopy (DOSY) for its use to characterize metal complexes containing paramagnetic first row transition metal elements.

Authors:

Crockett, M. P. ^[1]; Zhang, H. ^[2];

^[2];

^[1]

Department of Chemistry, Boston College, Eugene F. Merkert Chemistry Center, Chestnut Hill, USA
Department of Chemistry, Brandeis University, Waltham, USA

Publication Date:: 2019-11-28

Sponsoring Org.:: USDOE

OSTI Identifier:: 1576032

Grant/Contract Number:: SC0019179

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: ChemComm

Additional Journal Information:: Journal Name: ChemComm Journal Volume: 55 Journal Issue: 96; Journal ID: ISSN 1359-7345

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Crockett, M. P., Zhang, H., Thomas, C. M., and Byers, J. A. Adding diffusion ordered NMR spectroscopy (DOSY) to the arsenal for characterizing paramagnetic complexes.  United Kingdom: N. p., 2019. 
        Web.  doi:10.1039/C9CC08229H.

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                    Crockett, M. P., Zhang, H., Thomas, C. M., & Byers, J. A. Adding diffusion ordered NMR spectroscopy (DOSY) to the arsenal for characterizing paramagnetic complexes.  United Kingdom.  doi:10.1039/C9CC08229H.

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                    Crockett, M. P., Zhang, H., Thomas, C. M., and Byers, J. A. Thu .  
        "Adding diffusion ordered NMR spectroscopy (DOSY) to the arsenal for characterizing paramagnetic complexes".  United Kingdom.  doi:10.1039/C9CC08229H.

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@article{osti_1576032,

  title        = {Adding diffusion ordered NMR spectroscopy (DOSY) to the arsenal for characterizing paramagnetic complexes},

  author       = {Crockett, M. P. and Zhang, H. and Thomas, C. M. and Byers, J. A.},

  abstractNote = {Herein we report the development of diffusion ordered NMR spectroscopy (DOSY) for its use to characterize metal complexes containing paramagnetic first row transition metal elements.},

  doi          = {10.1039/C9CC08229H},

  journal      = {ChemComm},

  number       = 96,

  volume       = 55,

  place        = {United Kingdom},

  year         = {2019},

  month        = {11}

}

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Free Publicly Available Full Text

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DOI: 10.1039/C9CC08229H

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Similar Records

Title: Adding diffusion ordered NMR spectroscopy (DOSY) to the arsenal for characterizing paramagnetic complexes

Abstract

Citation Formats

Kernresonanzfluoreszenz von Gammastrahlung in Ir191 journal, April 1958

A one-shot sequence for high-resolution diffusion-ordered spectroscopy journal, January 2002

Solution Structures of Hauser Base i Pr 2 NMgCl and Turbo -Hauser Base i Pr 2 NMgCl·LiCl in THF and the Influence of LiCl on the Schlenk-Equilibrium journal, March 2016

Bis(2-pyridylimino)isoindolato iron(ii) and cobalt(ii) complexes: Structural chemistry and paramagnetic NMR spectroscopy journal, January 2011

Nuclear Magnetic Resonance Chemical Shift in an Arbitrary Electronic Spin State journal, April 2008

Block Copolymerization of Lactide and an Epoxide Facilitated by a Redox Switchable Iron-Based Catalyst journal, March 2016

1 H Pure Shift DOSY: a handy tool to evaluate the aggregation and solvation of organolithium derivatives journal, January 2014

Improved compositional analysis of block copolymers using Diffusion Ordered NMR Spectroscopy journal, November 2009

Self-assembly of tetravalent Goldberg polyhedra from 144 small components journal, December 2016

Paramagnetic DOSY: An Accurate Tool for the Analysis of the Supramolecular Interactions between Lanthanide Complexes and Proteins journal, November 2016

New External Calibration Curves (ECCs) for the Estimation of Molecular Weights in Various Common NMR Solvents journal, May 2016

Molecular Weight Estimation of Molecules Incorporating Heavier Elements from van-der-Waals Corrected ECC-DOSY journal, August 2017

Stoichiometric C═O Bond Oxidative Addition of Benzophenone by a Discrete Radical Intermediate To Form a Cobalt(I) Carbene journal, April 2013

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Accurate molecular weight determination of small molecules via DOSY-NMR by using external calibration curves with normalized diffusion coefficients journal, January 2015

Multielectron Redox Activity Facilitated by Metal−Metal Interactions in Early/Late Heterobimetallics: Co/Zr Complexes Supported by Phosphinoamide Ligands journal, July 2009

Characterization of Reactive Intermediates by Multinuclear Diffusion-Ordered NMR Spectroscopy (DOSY) journal, February 2009

Disclosing the multi-faceted world of weakly interacting inorganic systems by means of NMR spectroscopy journal, January 2016

NMR Measure of Translational Diffusion and Fractal Dimension. Application to Molecular Mass Measurement journal, February 2009

Iron Catalysis in Organic Synthesis journal, March 2015

New Measurement of the Electron Magnetic Moment Using a One-Electron Quantum Cyclotron journal, July 2006

Sensitive SQUID magnetometry for studying nanomagnetism journal, April 2011

Resolution of discrete and continuous molecular size distributions by means of diffusion-ordered 2D NMR spectroscopy journal, May 1993

Diffusion-Ordered NMR Spectroscopy: A Versatile Tool for the Molecular Weight Determination of Uncharged Polysaccharides journal, November 2003

Sequence Selective Polymerization Catalysis: A New Route to ABA Block Copoly(ester- b -carbonate- b -ester) journal, August 2015

Role of Organolithium Aggregates and Mixed Aggregates in Organolithium Mechanisms journal, August 2013

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Kernresonanzfluoreszenz von Gammastrahlung in Ir191
journal, April 1958

A one-shot sequence for high-resolution diffusion-ordered spectroscopy
journal, January 2002

Solution Structures of Hauser Base ⁱ Pr ₂ NMgCl and Turbo -Hauser Base ⁱ Pr ₂ NMgCl·LiCl in THF and the Influence of LiCl on the Schlenk-Equilibrium
journal, March 2016

Bis(2-pyridylimino)isoindolato iron(ii) and cobalt(ii) complexes: Structural chemistry and paramagnetic NMR spectroscopy
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Nuclear Magnetic Resonance Chemical Shift in an Arbitrary Electronic Spin State
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Block Copolymerization of Lactide and an Epoxide Facilitated by a Redox Switchable Iron-Based Catalyst
journal, March 2016

¹ H Pure Shift DOSY: a handy tool to evaluate the aggregation and solvation of organolithium derivatives
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Self-assembly of tetravalent Goldberg polyhedra from 144 small components
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New External Calibration Curves (ECCs) for the Estimation of Molecular Weights in Various Common NMR Solvents
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Molecular Weight Estimation of Molecules Incorporating Heavier Elements from van-der-Waals Corrected ECC-DOSY
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Stoichiometric C═O Bond Oxidative Addition of Benzophenone by a Discrete Radical Intermediate To Form a Cobalt(I) Carbene
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Iron Catalysis in Organic Synthesis
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Resolution of discrete and continuous molecular size distributions by means of diffusion-ordered 2D NMR spectroscopy
journal, May 1993

Diffusion-Ordered NMR Spectroscopy: A Versatile Tool for the Molecular Weight Determination of Uncharged Polysaccharides
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Role of Organolithium Aggregates and Mixed Aggregates in Organolithium Mechanisms
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