This content will become publicly available on November 8, 2020
Adding diffusion ordered NMR spectroscopy (DOSY) to the arsenal for characterizing paramagnetic complexes
Abstract
Herein we report the development of diffusion ordered NMR spectroscopy (DOSY) for its use to characterize metal complexes containing paramagnetic first row transition metal elements.
- Authors:
-
[2];
[1]
- Department of Chemistry, Boston College, Eugene F. Merkert Chemistry Center, Chestnut Hill, USA
- Department of Chemistry, Brandeis University, Waltham, USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1576032
- Grant/Contract Number:
- SC0019179
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Name: ChemComm Journal Volume: 55 Journal Issue: 96; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
Citation Formats
Crockett, M. P., Zhang, H., Thomas, C. M., and Byers, J. A. Adding diffusion ordered NMR spectroscopy (DOSY) to the arsenal for characterizing paramagnetic complexes. United Kingdom: N. p., 2019.
Web. doi:10.1039/C9CC08229H.
Crockett, M. P., Zhang, H., Thomas, C. M., & Byers, J. A. Adding diffusion ordered NMR spectroscopy (DOSY) to the arsenal for characterizing paramagnetic complexes. United Kingdom. doi:10.1039/C9CC08229H.
Crockett, M. P., Zhang, H., Thomas, C. M., and Byers, J. A. Thu .
"Adding diffusion ordered NMR spectroscopy (DOSY) to the arsenal for characterizing paramagnetic complexes". United Kingdom. doi:10.1039/C9CC08229H.
@article{osti_1576032,
title = {Adding diffusion ordered NMR spectroscopy (DOSY) to the arsenal for characterizing paramagnetic complexes},
author = {Crockett, M. P. and Zhang, H. and Thomas, C. M. and Byers, J. A.},
abstractNote = {Herein we report the development of diffusion ordered NMR spectroscopy (DOSY) for its use to characterize metal complexes containing paramagnetic first row transition metal elements.},
doi = {10.1039/C9CC08229H},
journal = {ChemComm},
number = 96,
volume = 55,
place = {United Kingdom},
year = {2019},
month = {11}
}
Free Publicly Available Full Text
This content will become publicly available on November 8, 2020
Publisher's Version of Record
DOI: 10.1039/C9CC08229H
Other availability
Search WorldCat to find libraries that may hold this journal
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Kernresonanzfluoreszenz von Gammastrahlung in Ir191
journal, April 1958
- M�ssbauer, Rudolf L.
- Zeitschrift f�r Physik, Vol. 151, Issue 2
A one-shot sequence for high-resolution diffusion-ordered spectroscopy
journal, January 2002
- Pelta, Michelle D.; Morris, Gareth A.; Stchedroff, Marc J.
- Magnetic Resonance in Chemistry, Vol. 40, Issue 13
Solution Structures of Hauser Base i Pr 2 NMgCl and Turbo -Hauser Base i Pr 2 NMgCl·LiCl in THF and the Influence of LiCl on the Schlenk-Equilibrium
journal, March 2016
- Neufeld, Roman; Teuteberg, Thorsten L.; Herbst-Irmer, Regine
- Journal of the American Chemical Society, Vol. 138, Issue 14
Bis(2-pyridylimino)isoindolato iron(ii) and cobalt(ii) complexes: Structural chemistry and paramagnetic NMR spectroscopy
journal, January 2011
- Kruck, Matthias; Sauer, Désirée C.; Enders, Markus
- Dalton Transactions, Vol. 40, Issue 40
Nuclear Magnetic Resonance Chemical Shift in an Arbitrary Electronic Spin State
journal, April 2008
- Pennanen, Teemu O.; Vaara, Juha
- Physical Review Letters, Vol. 100, Issue 13
Block Copolymerization of Lactide and an Epoxide Facilitated by a Redox Switchable Iron-Based Catalyst
journal, March 2016
- Biernesser, Ashley B.; Delle Chiaie, Kayla R.; Curley, Julia B.
- Angewandte Chemie International Edition, Vol. 55, Issue 17
1 H Pure Shift DOSY: a handy tool to evaluate the aggregation and solvation of organolithium derivatives
journal, January 2014
- Hamdoun, G.; Sebban, M.; Cossoul, E.
- Chem. Commun., Vol. 50, Issue 31
Improved compositional analysis of block copolymers using Diffusion Ordered NMR Spectroscopy
journal, November 2009
- Viel, Stéphane; Mazarin, Michaël; Giordanengo, Rémi
- Analytica Chimica Acta, Vol. 654, Issue 1
Self-assembly of tetravalent Goldberg polyhedra from 144 small components
journal, December 2016
- Fujita, Daishi; Ueda, Yoshihiro; Sato, Sota
- Nature, Vol. 540, Issue 7634
Paramagnetic DOSY: An Accurate Tool for the Analysis of the Supramolecular Interactions between Lanthanide Complexes and Proteins
journal, November 2016
- Denis-Quanquin, Sandrine; Riobé, François; Delsuc, Marc-André
- Chemistry - A European Journal, Vol. 22, Issue 50
New External Calibration Curves (ECCs) for the Estimation of Molecular Weights in Various Common NMR Solvents
journal, May 2016
- Bachmann, Sebastian; Neufeld, Roman; Dzemski, Martin
- Chemistry - A European Journal, Vol. 22, Issue 25
Molecular Weight Estimation of Molecules Incorporating Heavier Elements from van-der-Waals Corrected ECC-DOSY
journal, August 2017
- Kreyenschmidt, Anne-Kathrin; Bachmann, Sebastian; Niklas, Thomas
- ChemistrySelect, Vol. 2, Issue 24
Stoichiometric C═O Bond Oxidative Addition of Benzophenone by a Discrete Radical Intermediate To Form a Cobalt(I) Carbene
journal, April 2013
- Marquard, Seth L.; Bezpalko, Mark W.; Foxman, Bruce M.
- Journal of the American Chemical Society, Vol. 135, Issue 16
Diffusion-ordered two-dimensional nuclear magnetic resonance spectroscopy
journal, April 1992
- Morris, Kevin F.; Johnson, Charles S.
- Journal of the American Chemical Society, Vol. 114, Issue 8
Accurate molecular weight determination of small molecules via DOSY-NMR by using external calibration curves with normalized diffusion coefficients
journal, January 2015
- Neufeld, Roman; Stalke, Dietmar
- Chemical Science, Vol. 6, Issue 6
Multielectron Redox Activity Facilitated by Metal−Metal Interactions in Early/Late Heterobimetallics: Co/Zr Complexes Supported by Phosphinoamide Ligands
journal, July 2009
- Greenwood, Bennett P.; Forman, Scott I.; Rowe, Gerard T.
- Inorganic Chemistry, Vol. 48, Issue 13
Characterization of Reactive Intermediates by Multinuclear Diffusion-Ordered NMR Spectroscopy (DOSY)
journal, February 2009
- Li, Deyu; Keresztes, Ivan; Hopson, Russell
- Accounts of Chemical Research, Vol. 42, Issue 2
Disclosing the multi-faceted world of weakly interacting inorganic systems by means of NMR spectroscopy
journal, January 2016
- Rocchigiani, Luca; Macchioni, Alceo
- Dalton Transactions, Vol. 45, Issue 7
NMR Measure of Translational Diffusion and Fractal Dimension. Application to Molecular Mass Measurement
journal, February 2009
- Augé, Sophie; Schmit, Pierre-Olivier; Crutchfield, Christopher A.
- The Journal of Physical Chemistry B, Vol. 113, Issue 7
Iron Catalysis in Organic Synthesis
journal, March 2015
- Bauer, Ingmar; Knölker, Hans-Joachim
- Chemical Reviews, Vol. 115, Issue 9
New Measurement of the Electron Magnetic Moment Using a One-Electron Quantum Cyclotron
journal, July 2006
- Odom, B.; Hanneke, D.; D’Urso, B.
- Physical Review Letters, Vol. 97, Issue 3
Sensitive SQUID magnetometry for studying nanomagnetism
journal, April 2011
- Sawicki, M.; Stefanowicz, W.; Ney, A.
- Semiconductor Science and Technology, Vol. 26, Issue 6
Resolution of discrete and continuous molecular size distributions by means of diffusion-ordered 2D NMR spectroscopy
journal, May 1993
- Morris, Kevin F.; Johnson, Charles S.
- Journal of the American Chemical Society, Vol. 115, Issue 10
Diffusion-Ordered NMR Spectroscopy: A Versatile Tool for the Molecular Weight Determination of Uncharged Polysaccharides
journal, November 2003
- Viel, Stéphane; Capitani, Donatella; Mannina, Luisa
- Biomacromolecules, Vol. 4, Issue 6
Sequence Selective Polymerization Catalysis: A New Route to ABA Block Copoly(ester- b -carbonate- b -ester)
journal, August 2015
- Paul, Shyeni; Romain, Charles; Shaw, John
- Macromolecules, Vol. 48, Issue 17
Role of Organolithium Aggregates and Mixed Aggregates in Organolithium Mechanisms
journal, August 2013
- Reich, Hans J.
- Chemical Reviews, Vol. 113, Issue 9
Catalytic Hydrosilylation of Ketones Using a Co/Zr Heterobimetallic Complex: Evidence for an Unusual Mechanism Involving Ketyl Radicals
journal, February 2013
- Zhou, Wen; Marquard, Seth L.; Bezpalko, Mark W.
- Organometallics, Vol. 32, Issue 6