FSI-inspired solvent and “full fluorosulfonyl” electrolyte for 4 V class lithium-metal batteries
Abstract
A new “full fluorosulfonyl” (FFS) electrolyte is developed for highly reversible 4 V class lithium-metal batteries (LMBs).
- Authors:
-
- Department of Nuclear Science and Engineering, Massachusetts Institute of Technology, Cambridge, USA
- Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, USA
- Department of Chemistry, Massachusetts Institute of Technology, Cambridge, USA
- Department of Chemical Engineering, Massachusetts Institute of Technology, Cambridge, USA
- Research Laboratory of Electronics, Massachusetts Institute of Technology, Cambridge, USA
- Department of Chemistry, Massachusetts Institute of Technology, Cambridge, USA, Research Laboratory of Electronics
- Research Laboratory of Electronics, Massachusetts Institute of Technology, Cambridge, USA, Department of Mechanical Engineering
- Department of Nuclear Science and Engineering, Massachusetts Institute of Technology, Cambridge, USA, Department of Materials Science and Engineering, Massachusetts Institute of Technology
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1576022
- Resource Type:
- Published Article
- Journal Name:
- Energy & Environmental Science
- Additional Journal Information:
- Journal Name: Energy & Environmental Science Journal Volume: 13 Journal Issue: 1; Journal ID: ISSN 1754-5692
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
Citation Formats
Xue, Weijiang, Shi, Zhe, Huang, Mingjun, Feng, Shuting, Wang, Chao, Wang, Fei, Lopez, Jeffrey, Qiao, Bo, Xu, Guiyin, Zhang, Wenxu, Dong, Yanhao, Gao, Rui, Shao-Horn, Yang, Johnson, Jeremiah A., and Li, Ju. FSI-inspired solvent and “full fluorosulfonyl” electrolyte for 4 V class lithium-metal batteries. United Kingdom: N. p., 2020.
Web. doi:10.1039/C9EE02538C.
Xue, Weijiang, Shi, Zhe, Huang, Mingjun, Feng, Shuting, Wang, Chao, Wang, Fei, Lopez, Jeffrey, Qiao, Bo, Xu, Guiyin, Zhang, Wenxu, Dong, Yanhao, Gao, Rui, Shao-Horn, Yang, Johnson, Jeremiah A., & Li, Ju. FSI-inspired solvent and “full fluorosulfonyl” electrolyte for 4 V class lithium-metal batteries. United Kingdom. https://doi.org/10.1039/C9EE02538C
Xue, Weijiang, Shi, Zhe, Huang, Mingjun, Feng, Shuting, Wang, Chao, Wang, Fei, Lopez, Jeffrey, Qiao, Bo, Xu, Guiyin, Zhang, Wenxu, Dong, Yanhao, Gao, Rui, Shao-Horn, Yang, Johnson, Jeremiah A., and Li, Ju. Tue .
"FSI-inspired solvent and “full fluorosulfonyl” electrolyte for 4 V class lithium-metal batteries". United Kingdom. https://doi.org/10.1039/C9EE02538C.
@article{osti_1576022,
title = {FSI-inspired solvent and “full fluorosulfonyl” electrolyte for 4 V class lithium-metal batteries},
author = {Xue, Weijiang and Shi, Zhe and Huang, Mingjun and Feng, Shuting and Wang, Chao and Wang, Fei and Lopez, Jeffrey and Qiao, Bo and Xu, Guiyin and Zhang, Wenxu and Dong, Yanhao and Gao, Rui and Shao-Horn, Yang and Johnson, Jeremiah A. and Li, Ju},
abstractNote = {A new “full fluorosulfonyl” (FFS) electrolyte is developed for highly reversible 4 V class lithium-metal batteries (LMBs).},
doi = {10.1039/C9EE02538C},
journal = {Energy & Environmental Science},
number = 1,
volume = 13,
place = {United Kingdom},
year = {2020},
month = {1}
}
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1039/C9EE02538C
https://doi.org/10.1039/C9EE02538C
Other availability
Cited by: 8 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Highly Fluorinated Interphases Enable High-Voltage Li-Metal Batteries
journal, January 2018
- Fan, Xiulin; Chen, Long; Ji, Xiao
- Chem, Vol. 4, Issue 1
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
Problem, Status, and Possible Solutions for Lithium Metal Anode of Rechargeable Batteries
journal, February 2018
- Zhang, Sheng S.
- ACS Applied Energy Materials, Vol. 1, Issue 3
Decomposition of the fluoroethylene carbonate additive and the glue effect of lithium fluoride products for the solid electrolyte interphase: an ab initio study
journal, January 2016
- Okuno, Yukihiro; Ushirogata, Keisuke; Sodeyama, Keitaro
- Physical Chemistry Chemical Physics, Vol. 18, Issue 12
Low-Temperature Carbon Coating of Nanosized Li 1.015 Al 0.06 Mn 1.925 O 4 and High-Density Electrode for High-Power Li-Ion Batteries
journal, May 2017
- Lee, Min-Joon; Lho, Eunsol; Bai, Peng
- Nano Letters, Vol. 17, Issue 6
Pathways for practical high-energy long-cycling lithium metal batteries
journal, February 2019
- Liu, Jun; Bao, Zhenan; Cui, Yi
- Nature Energy, Vol. 4, Issue 3
Sulfonyl Fluorides (SFs): More Than Click Reagents?: Sulfonyl Fluorides (SFs): More Than Click Reagents?
journal, July 2018
- Chinthakindi, Praveen K.; Arvidsson, Per I.
- European Journal of Organic Chemistry, Vol. 2018, Issue 27-28
Review—Superconcentrated Electrolytes for Lithium Batteries
journal, January 2015
- Yamada, Yuki; Yamada, Atsuo
- Journal of The Electrochemical Society, Vol. 162, Issue 14
Electrolyte additive enabled fast charging and stable cycling lithium metal batteries
journal, March 2017
- Zheng, Jianming; Engelhard, Mark H.; Mei, Donghai
- Nature Energy, Vol. 2, Issue 3
Projector augmented-wave method
journal, December 1994
- Blöchl, P. E.
- Physical Review B, Vol. 50, Issue 24, p. 17953-17979
Hybrid functionals based on a screened Coulomb potential
journal, May 2003
- Heyd, Jochen; Scuseria, Gustavo E.; Ernzerhof, Matthias
- The Journal of Chemical Physics, Vol. 118, Issue 18
Sulfur(VI) Fluoride Exchange (SuFEx): Another Good Reaction for Click Chemistry
journal, August 2014
- Dong, Jiajia; Krasnova, Larissa; Finn, M. G.
- Angewandte Chemie International Edition, Vol. 53, Issue 36
Recent advances in all-solid-state rechargeable lithium batteries
journal, March 2017
- Sun, Chunwen; Liu, Jin; Gong, Yudong
- Nano Energy, Vol. 33
Self-smoothing anode for achieving high-energy lithium metal batteries under realistic conditions
journal, April 2019
- Niu, Chaojiang; Pan, Huilin; Xu, Wu
- Nature Nanotechnology, Vol. 14, Issue 6
Highly Stable Lithium Metal Batteries Enabled by Regulating the Solvation of Lithium Ions in Nonaqueous Electrolytes
journal, March 2018
- Zhang, Xue-Qiang; Chen, Xiang; Cheng, Xin-Bing
- Angewandte Chemie International Edition, Vol. 57, Issue 19
Fast ion transport at solid–solid interfaces in hybrid battery anodes
journal, March 2018
- Tu, Zhengyuan; Choudhury, Snehashis; Zachman, Michael J.
- Nature Energy, Vol. 3, Issue 4
How Solid-Electrolyte Interphase Forms in Aqueous Electrolytes
journal, December 2017
- Suo, Liumin; Oh, Dahyun; Lin, Yuxiao
- Journal of the American Chemical Society, Vol. 139, Issue 51
Solid-state polymer electrolytes with in-built fast interfacial transport for secondary lithium batteries
journal, March 2019
- Zhao, Qing; Liu, Xiaotun; Stalin, Sanjuna
- Nature Energy, Vol. 4, Issue 5
High-Concentration Ether Electrolytes for Stable High-Voltage Lithium Metal Batteries
journal, March 2019
- Ren, Xiaodi; Zou, Lianfeng; Jiao, Shuhong
- ACS Energy Letters, Vol. 4, Issue 4
High-power all-solid-state batteries using sulfide superionic conductors
journal, March 2016
- Kato, Yuki; Hori, Satoshi; Saito, Toshiya
- Nature Energy, Vol. 1, Issue 4
A Concentrated Ternary‐Salts Electrolyte for High Reversible Li Metal Battery with Slight Excess Li
journal, December 2018
- Qiu, Feilong; Li, Xiang; Deng, Han
- Advanced Energy Materials, Vol. 9, Issue 6
Regulating Anions in the Solvation Sheath of Lithium Ions for Stable Lithium Metal Batteries
journal, January 2019
- Zhang, Xue-Qiang; Chen, Xiang; Hou, Li-Peng
- ACS Energy Letters, Vol. 4, Issue 2
Bisalt ether electrolytes: a pathway towards lithium metal batteries with Ni-rich cathodes
journal, January 2019
- Alvarado, Judith; Schroeder, Marshall A.; Pollard, Travis P.
- Energy & Environmental Science, Vol. 12, Issue 2
Perspective—Fluorinating Interphases
journal, December 2018
- Wang, Chunsheng; Meng, Ying Shirley; Xu, Kang
- Journal of The Electrochemical Society, Vol. 166, Issue 3
High-energy lithium metal pouch cells with limited anode swelling and long stable cycles
journal, May 2019
- Niu, Chaojiang; Lee, Hongkyung; Chen, Shuru
- Nature Energy, Vol. 4, Issue 7
Stable cycling of high-voltage lithium metal batteries in ether electrolytes
journal, July 2018
- Jiao, Shuhong; Ren, Xiaodi; Cao, Ruiguo
- Nature Energy, Vol. 3, Issue 9
Simple and Effective Gas-Phase Doping for Lithium Metal Protection in Lithium Metal Batteries
journal, October 2017
- Moon, Sehwan; Park, Hyeokjun; Yoon, Gabin
- Chemistry of Materials, Vol. 29, Issue 21
A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu
journal, April 2010
- Grimme, Stefan; Antony, Jens; Ehrlich, Stephan
- The Journal of Chemical Physics, Vol. 132, Issue 15
High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes
journal, March 2018
- Chen, Shuru; Zheng, Jianming; Mei, Donghai
- Advanced Materials, Vol. 30, Issue 21
Cryo-STEM mapping of solid–liquid interfaces and dendrites in lithium-metal batteries
journal, August 2018
- Zachman, Michael J.; Tu, Zhengyuan; Choudhury, Snehashis
- Nature, Vol. 560, Issue 7718
Key Issues Hindering a Practical Lithium-Metal Anode
journal, May 2019
- Fang, Chengcheng; Wang, Xuefeng; Meng, Ying Shirley
- Trends in Chemistry, Vol. 1, Issue 2
Advancing Lithium Metal Batteries
journal, May 2018
- Liu, Bin; Zhang, Ji-Guang; Xu, Wu
- Joule, Vol. 2, Issue 5
Uniform High Ionic Conducting Lithium Sulfide Protection Layer for Stable Lithium Metal Anode
journal, April 2019
- Chen, Hao; Pei, Allen; Lin, Dingchang
- Advanced Energy Materials, Vol. 9, Issue 22
Self-healing SEI enables full-cell cycling of a silicon-majority anode with a coulombic efficiency exceeding 99.9%
journal, January 2017
- Jin, Yang; Li, Sa; Kushima, Akihiro
- Energy & Environmental Science, Vol. 10, Issue 2
The synergetic effect of lithium polysulfide and lithium nitrate to prevent lithium dendrite growth
journal, June 2015
- Li, Weiyang; Yao, Hongbin; Yan, Kai
- Nature Communications, Vol. 6, Issue 1
Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density
journal, January 1988
- Lee, Chengteh; Yang, Weitao; Parr, Robert G.
- Physical Review B, Vol. 37, Issue 2
SuFEx-Based Synthesis of Polysulfates
journal, August 2014
- Dong, Jiajia; Sharpless, K. Barry; Kwisnek, Luke
- Angewandte Chemie International Edition, Vol. 53, Issue 36
Study of the Initial Stage of Solid Electrolyte Interphase Formation upon Chemical Reaction of Lithium Metal and N -Methyl- N -Propyl-Pyrrolidinium-Bis(Fluorosulfonyl)Imide
journal, September 2012
- Budi, Akin; Basile, Andrew; Opletal, George
- The Journal of Physical Chemistry C, Vol. 116, Issue 37
Gravimetric and volumetric energy densities of lithium-sulfur batteries
journal, December 2017
- Xue, Weijiang; Miao, Lixiao; Qie, Long
- Current Opinion in Electrochemistry, Vol. 6, Issue 1
Localized High-Concentration Sulfone Electrolytes for High-Efficiency Lithium-Metal Batteries
journal, August 2018
- Ren, Xiaodi; Chen, Shuru; Lee, Hongkyung
- Chem, Vol. 4, Issue 8
Special points for Brillouin-zone integrations
journal, June 1976
- Monkhorst, Hendrik J.; Pack, James D.
- Physical Review B, Vol. 13, Issue 12, p. 5188-5192
Reviving the lithium metal anode for high-energy batteries
journal, March 2017
- Lin, Dingchang; Liu, Yayuan; Cui, Yi
- Nature Nanotechnology, Vol. 12, Issue 3
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996
- Kresse, G.; Furthmüller, J.
- Physical Review B, Vol. 54, Issue 16, p. 11169-11186
Research Progress towards Understanding the Unique Interfaces between Concentrated Electrolytes and Electrodes for Energy Storage Applications
journal, March 2017
- Zheng, Jianming; Lochala, Joshua A.; Kwok, Alexander
- Advanced Science, Vol. 4, Issue 8
Non-flammable electrolyte enables Li-metal batteries with aggressive cathode chemistries
journal, July 2018
- Fan, Xiulin; Chen, Long; Borodin, Oleg
- Nature Nanotechnology, Vol. 13, Issue 8
Enabling High-Voltage Lithium-Metal Batteries under Practical Conditions
journal, July 2019
- Ren, Xiaodi; Zou, Lianfeng; Cao, Xia
- Joule, Vol. 3, Issue 7
Why Bis(fluorosulfonyl)imide Is a “Magic Anion” for Electrochemistry
journal, August 2014
- Shkrob, Ilya A.; Marin, Timothy W.; Zhu, Ye
- The Journal of Physical Chemistry C, Vol. 118, Issue 34
Sulfonyl fluorides as privileged warheads in chemical biology
journal, January 2015
- Narayanan, Arjun; Jones, Lyn H.
- Chemical Science, Vol. 6, Issue 5
The Effect of Electrode-Electrolyte Interface on the Electrochemical Impedance Spectra for Positive Electrode in Li-Ion Battery
journal, November 2018
- Tatara, Ryoichi; Karayaylali, Pinar; Yu, Yang
- Journal of The Electrochemical Society, Vol. 166, Issue 3
Dendrite-Free Lithium Deposition via Self-Healing Electrostatic Shield Mechanism
journal, March 2013
- Ding, Fei; Xu, Wu; Graff, Gordon L.
- Journal of the American Chemical Society, Vol. 135, Issue 11, p. 4450-4456
Very Stable Lithium Metal Stripping–Plating at a High Rate and High Areal Capacity in Fluoroethylene Carbonate-Based Organic Electrolyte Solution
journal, May 2017
- Markevich, Elena; Salitra, Gregory; Chesneau, Frederick
- ACS Energy Letters, Vol. 2, Issue 6
Intercalation-conversion hybrid cathodes enabling Li–S full-cell architectures with jointly superior gravimetric and volumetric energy densities
journal, March 2019
- Xue, Weijiang; Shi, Zhe; Suo, Liumin
- Nature Energy, Vol. 4, Issue 5
A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries
journal, February 2013
- Suo, Liumin; Hu, Yong-Sheng; Li, Hong
- Nature Communications, Vol. 4, Issue 1
Effect of Fluoroethylene Carbonate Electrolytes on the Nanostructure of the Solid Electrolyte Interphase and Performance of Lithium Metal Anodes
journal, June 2018
- Brown, Zachary L.; Jurng, Sunhyung; Nguyen, Cao Cuong
- ACS Applied Energy Materials, Vol. 1, Issue 7
Surface Fluorination of Reactive Battery Anode Materials for Enhanced Stability
journal, August 2017
- Zhao, Jie; Liao, Lei; Shi, Feifei
- Journal of the American Chemical Society, Vol. 139, Issue 33
Fluorine-donating electrolytes enable highly reversible 5-V-class Li metal batteries
journal, January 2018
- Suo, Liumin; Xue, Weijiang; Gobet, Mallory
- Proceedings of the National Academy of Sciences, Vol. 115, Issue 6
Manipulating Sulfur Mobility Enables Advanced Li-S Batteries
journal, October 2019
- Xue, Weijiang; Yu, Daiwei; Suo, Liumin
- Matter, Vol. 1, Issue 4
Status and challenges in enabling the lithium metal electrode for high-energy and low-cost rechargeable batteries
journal, December 2017
- Albertus, Paul; Babinec, Susan; Litzelman, Scott
- Nature Energy, Vol. 3, Issue 1
A Review of Solid Electrolyte Interphases on Lithium Metal Anode
journal, November 2015
- Cheng, Xin-Bing; Zhang, Rui; Zhao, Chen-Zi
- Advanced Science, Vol. 3, Issue 3
High rate and stable cycling of lithium metal anode
journal, February 2015
- Qian, Jiangfeng; Henderson, Wesley A.; Xu, Wu
- Nature Communications, Vol. 6, Issue 1