FSI-inspired solvent and “full fluorosulfonyl” electrolyte for 4 V class lithium-metal batteries

Xue, Weijiang; Shi, Zhe; Huang, Mingjun; Feng, Shuting; Wang, Chao; Wang, Fei; Lopez, Jeffrey; Qiao, Bo; Xu, Guiyin; Zhang, Wenxu; Dong, Yanhao; Gao, Rui; Shao-Horn, Yang; Johnson, Jeremiah A.; Li, Ju

doi:10.1039/C9EE02538C

Title: FSI-inspired solvent and “full fluorosulfonyl” electrolyte for 4 V class lithium-metal batteries

Abstract

A new “full fluorosulfonyl” (FFS) electrolyte is developed for highly reversible 4 V class lithium-metal batteries (LMBs).

Authors:

^[1]; Shi, Zhe ^[2]; Huang, Mingjun ^[3]; Feng, Shuting ^[4];

^[1]; Wang, Fei ^[2];

^[5]; Qiao, Bo ^[6];

^[1]; Zhang, Wenxu ^[3]; Dong, Yanhao ^[1]; Gao, Rui ^[1];

^[7];

^[3];

^[8]

Department of Nuclear Science and Engineering, Massachusetts Institute of Technology, Cambridge, USA
Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, USA
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, USA
Department of Chemical Engineering, Massachusetts Institute of Technology, Cambridge, USA
Research Laboratory of Electronics, Massachusetts Institute of Technology, Cambridge, USA
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, USA, Research Laboratory of Electronics
Research Laboratory of Electronics, Massachusetts Institute of Technology, Cambridge, USA, Department of Mechanical Engineering
Department of Nuclear Science and Engineering, Massachusetts Institute of Technology, Cambridge, USA, Department of Materials Science and Engineering, Massachusetts Institute of Technology

Publication Date:: 2020-01-21

Sponsoring Org.:: USDOE

OSTI Identifier:: 1576022

Resource Type:: Published Article

Journal Name:: Energy & Environmental Science

Additional Journal Information:: Journal Name: Energy & Environmental Science Journal Volume: 13 Journal Issue: 1; Journal ID: ISSN 1754-5692

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Xue, Weijiang, Shi, Zhe, Huang, Mingjun, Feng, Shuting, Wang, Chao, Wang, Fei, Lopez, Jeffrey, Qiao, Bo, Xu, Guiyin, Zhang, Wenxu, Dong, Yanhao, Gao, Rui, Shao-Horn, Yang, Johnson, Jeremiah A., and Li, Ju. FSI-inspired solvent and “full fluorosulfonyl” electrolyte for 4 V class lithium-metal batteries.  United Kingdom: N. p., 2020. 
Web.  doi:10.1039/C9EE02538C.

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                    Xue, Weijiang, Shi, Zhe, Huang, Mingjun, Feng, Shuting, Wang, Chao, Wang, Fei, Lopez, Jeffrey, Qiao, Bo, Xu, Guiyin, Zhang, Wenxu, Dong, Yanhao, Gao, Rui, Shao-Horn, Yang, Johnson, Jeremiah A., & Li, Ju. FSI-inspired solvent and “full fluorosulfonyl” electrolyte for 4 V class lithium-metal batteries.  United Kingdom.  https://doi.org/10.1039/C9EE02538C

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                    Xue, Weijiang, Shi, Zhe, Huang, Mingjun, Feng, Shuting, Wang, Chao, Wang, Fei, Lopez, Jeffrey, Qiao, Bo, Xu, Guiyin, Zhang, Wenxu, Dong, Yanhao, Gao, Rui, Shao-Horn, Yang, Johnson, Jeremiah A., and Li, Ju. Tue .  
"FSI-inspired solvent and “full fluorosulfonyl” electrolyte for 4 V class lithium-metal batteries".  United Kingdom.  https://doi.org/10.1039/C9EE02538C.

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@article{osti_1576022,

  title        = {FSI-inspired solvent and “full fluorosulfonyl” electrolyte for 4 V class lithium-metal batteries},

  author       = {Xue, Weijiang and Shi, Zhe and Huang, Mingjun and Feng, Shuting and Wang, Chao and Wang, Fei and Lopez, Jeffrey and Qiao, Bo and Xu, Guiyin and Zhang, Wenxu and Dong, Yanhao and Gao, Rui and Shao-Horn, Yang and Johnson, Jeremiah A. and Li, Ju},

  abstractNote = {A new “full fluorosulfonyl” (FFS) electrolyte is developed for highly reversible 4 V class lithium-metal batteries (LMBs).},

  doi          = {10.1039/C9EE02538C},

  journal      = {Energy & Environmental Science},

  number       = 1,

  volume       = 13,

  place        = {United Kingdom},

  year         = {2020},

  month        = {1}

}

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Title: FSI-inspired solvent and “full fluorosulfonyl” electrolyte for 4 V class lithium-metal batteries

Abstract

Citation Formats

Highly Fluorinated Interphases Enable High-Voltage Li-Metal Batteries journal, January 2018

Generalized Gradient Approximation Made Simple journal, October 1996

Problem, Status, and Possible Solutions for Lithium Metal Anode of Rechargeable Batteries journal, February 2018

Decomposition of the fluoroethylene carbonate additive and the glue effect of lithium fluoride products for the solid electrolyte interphase: an ab initio study journal, January 2016

Low-Temperature Carbon Coating of Nanosized Li 1.015 Al 0.06 Mn 1.925 O 4 and High-Density Electrode for High-Power Li-Ion Batteries journal, May 2017

Pathways for practical high-energy long-cycling lithium metal batteries journal, February 2019

Sulfonyl Fluorides (SFs): More Than Click Reagents?: Sulfonyl Fluorides (SFs): More Than Click Reagents? journal, July 2018

Review—Superconcentrated Electrolytes for Lithium Batteries journal, January 2015

Electrolyte additive enabled fast charging and stable cycling lithium metal batteries journal, March 2017

Projector augmented-wave method journal, December 1994

Hybrid functionals based on a screened Coulomb potential journal, May 2003

Sulfur(VI) Fluoride Exchange (SuFEx): Another Good Reaction for Click Chemistry journal, August 2014

Recent advances in all-solid-state rechargeable lithium batteries journal, March 2017

Self-smoothing anode for achieving high-energy lithium metal batteries under realistic conditions journal, April 2019

Highly Stable Lithium Metal Batteries Enabled by Regulating the Solvation of Lithium Ions in Nonaqueous Electrolytes journal, March 2018

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Solid-state polymer electrolytes with in-built fast interfacial transport for secondary lithium batteries journal, March 2019

High-Concentration Ether Electrolytes for Stable High-Voltage Lithium Metal Batteries journal, March 2019

High-power all-solid-state batteries using sulfide superionic conductors journal, March 2016

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High-energy lithium metal pouch cells with limited anode swelling and long stable cycles journal, May 2019

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A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu journal, April 2010

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Cryo-STEM mapping of solid–liquid interfaces and dendrites in lithium-metal batteries journal, August 2018

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Uniform High Ionic Conducting Lithium Sulfide Protection Layer for Stable Lithium Metal Anode journal, April 2019

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The synergetic effect of lithium polysulfide and lithium nitrate to prevent lithium dendrite growth journal, June 2015

Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density journal, January 1988

SuFEx-Based Synthesis of Polysulfates journal, August 2014

Study of the Initial Stage of Solid Electrolyte Interphase Formation upon Chemical Reaction of Lithium Metal and N -Methyl- N -Propyl-Pyrrolidinium-Bis(Fluorosulfonyl)Imide journal, September 2012

Gravimetric and volumetric energy densities of lithium-sulfur batteries journal, December 2017

Localized High-Concentration Sulfone Electrolytes for High-Efficiency Lithium-Metal Batteries journal, August 2018

Special points for Brillouin-zone integrations journal, June 1976

Reviving the lithium metal anode for high-energy batteries journal, March 2017

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set journal, October 1996

Research Progress towards Understanding the Unique Interfaces between Concentrated Electrolytes and Electrodes for Energy Storage Applications journal, March 2017

Non-flammable electrolyte enables Li-metal batteries with aggressive cathode chemistries journal, July 2018

Enabling High-Voltage Lithium-Metal Batteries under Practical Conditions journal, July 2019

Why Bis(fluorosulfonyl)imide Is a “Magic Anion” for Electrochemistry journal, August 2014

Sulfonyl fluorides as privileged warheads in chemical biology journal, January 2015

The Effect of Electrode-Electrolyte Interface on the Electrochemical Impedance Spectra for Positive Electrode in Li-Ion Battery journal, November 2018

Dendrite-Free Lithium Deposition via Self-Healing Electrostatic Shield Mechanism journal, March 2013

Very Stable Lithium Metal Stripping–Plating at a High Rate and High Areal Capacity in Fluoroethylene Carbonate-Based Organic Electrolyte Solution journal, May 2017

Intercalation-conversion hybrid cathodes enabling Li–S full-cell architectures with jointly superior gravimetric and volumetric energy densities journal, March 2019

A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries journal, February 2013

Effect of Fluoroethylene Carbonate Electrolytes on the Nanostructure of the Solid Electrolyte Interphase and Performance of Lithium Metal Anodes journal, June 2018

Surface Fluorination of Reactive Battery Anode Materials for Enhanced Stability journal, August 2017

Fluorine-donating electrolytes enable highly reversible 5-V-class Li metal batteries journal, January 2018

Manipulating Sulfur Mobility Enables Advanced Li-S Batteries journal, October 2019

Status and challenges in enabling the lithium metal electrode for high-energy and low-cost rechargeable batteries journal, December 2017

A Review of Solid Electrolyte Interphases on Lithium Metal Anode journal, November 2015

High rate and stable cycling of lithium metal anode journal, February 2015

Highly Fluorinated Interphases Enable High-Voltage Li-Metal Batteries
journal, January 2018

Generalized Gradient Approximation Made Simple
journal, October 1996

Problem, Status, and Possible Solutions for Lithium Metal Anode of Rechargeable Batteries
journal, February 2018

Decomposition of the fluoroethylene carbonate additive and the glue effect of lithium fluoride products for the solid electrolyte interphase: an ab initio study
journal, January 2016

Low-Temperature Carbon Coating of Nanosized Li _1.015 Al _0.06 Mn _1.925 O ₄ and High-Density Electrode for High-Power Li-Ion Batteries
journal, May 2017

Pathways for practical high-energy long-cycling lithium metal batteries
journal, February 2019

Sulfonyl Fluorides (SFs): More Than Click Reagents?: Sulfonyl Fluorides (SFs): More Than Click Reagents?
journal, July 2018

Review—Superconcentrated Electrolytes for Lithium Batteries
journal, January 2015

Electrolyte additive enabled fast charging and stable cycling lithium metal batteries
journal, March 2017

Projector augmented-wave method
journal, December 1994

Hybrid functionals based on a screened Coulomb potential
journal, May 2003

Sulfur(VI) Fluoride Exchange (SuFEx): Another Good Reaction for Click Chemistry
journal, August 2014

Recent advances in all-solid-state rechargeable lithium batteries
journal, March 2017

Self-smoothing anode for achieving high-energy lithium metal batteries under realistic conditions
journal, April 2019

Highly Stable Lithium Metal Batteries Enabled by Regulating the Solvation of Lithium Ions in Nonaqueous Electrolytes
journal, March 2018

Fast ion transport at solid–solid interfaces in hybrid battery anodes
journal, March 2018

How Solid-Electrolyte Interphase Forms in Aqueous Electrolytes
journal, December 2017

Solid-state polymer electrolytes with in-built fast interfacial transport for secondary lithium batteries
journal, March 2019

High-Concentration Ether Electrolytes for Stable High-Voltage Lithium Metal Batteries
journal, March 2019

High-power all-solid-state batteries using sulfide superionic conductors
journal, March 2016

A Concentrated Ternary‐Salts Electrolyte for High Reversible Li Metal Battery with Slight Excess Li
journal, December 2018

Regulating Anions in the Solvation Sheath of Lithium Ions for Stable Lithium Metal Batteries
journal, January 2019

Bisalt ether electrolytes: a pathway towards lithium metal batteries with Ni-rich cathodes
journal, January 2019

Perspective—Fluorinating Interphases
journal, December 2018

High-energy lithium metal pouch cells with limited anode swelling and long stable cycles
journal, May 2019

Stable cycling of high-voltage lithium metal batteries in ether electrolytes
journal, July 2018

Simple and Effective Gas-Phase Doping for Lithium Metal Protection in Lithium Metal Batteries
journal, October 2017

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu
journal, April 2010

High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes
journal, March 2018

Cryo-STEM mapping of solid–liquid interfaces and dendrites in lithium-metal batteries
journal, August 2018

Key Issues Hindering a Practical Lithium-Metal Anode
journal, May 2019

Advancing Lithium Metal Batteries
journal, May 2018

Uniform High Ionic Conducting Lithium Sulfide Protection Layer for Stable Lithium Metal Anode
journal, April 2019

Self-healing SEI enables full-cell cycling of a silicon-majority anode with a coulombic efficiency exceeding 99.9%
journal, January 2017

The synergetic effect of lithium polysulfide and lithium nitrate to prevent lithium dendrite growth
journal, June 2015

Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density
journal, January 1988

SuFEx-Based Synthesis of Polysulfates
journal, August 2014

Study of the Initial Stage of Solid Electrolyte Interphase Formation upon Chemical Reaction of Lithium Metal and N -Methyl- N -Propyl-Pyrrolidinium-Bis(Fluorosulfonyl)Imide
journal, September 2012

Gravimetric and volumetric energy densities of lithium-sulfur batteries
journal, December 2017

Localized High-Concentration Sulfone Electrolytes for High-Efficiency Lithium-Metal Batteries
journal, August 2018

Special points for Brillouin-zone integrations
journal, June 1976

Reviving the lithium metal anode for high-energy batteries
journal, March 2017

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996

Research Progress towards Understanding the Unique Interfaces between Concentrated Electrolytes and Electrodes for Energy Storage Applications
journal, March 2017

Non-flammable electrolyte enables Li-metal batteries with aggressive cathode chemistries
journal, July 2018

Enabling High-Voltage Lithium-Metal Batteries under Practical Conditions
journal, July 2019

Why Bis(fluorosulfonyl)imide Is a “Magic Anion” for Electrochemistry
journal, August 2014

Sulfonyl fluorides as privileged warheads in chemical biology
journal, January 2015

The Effect of Electrode-Electrolyte Interface on the Electrochemical Impedance Spectra for Positive Electrode in Li-Ion Battery
journal, November 2018

Dendrite-Free Lithium Deposition via Self-Healing Electrostatic Shield Mechanism
journal, March 2013

Very Stable Lithium Metal Stripping–Plating at a High Rate and High Areal Capacity in Fluoroethylene Carbonate-Based Organic Electrolyte Solution
journal, May 2017

Intercalation-conversion hybrid cathodes enabling Li–S full-cell architectures with jointly superior gravimetric and volumetric energy densities
journal, March 2019

A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries
journal, February 2013

Effect of Fluoroethylene Carbonate Electrolytes on the Nanostructure of the Solid Electrolyte Interphase and Performance of Lithium Metal Anodes
journal, June 2018

Surface Fluorination of Reactive Battery Anode Materials for Enhanced Stability
journal, August 2017

Fluorine-donating electrolytes enable highly reversible 5-V-class Li metal batteries
journal, January 2018

Manipulating Sulfur Mobility Enables Advanced Li-S Batteries
journal, October 2019

Status and challenges in enabling the lithium metal electrode for high-energy and low-cost rechargeable batteries
journal, December 2017

A Review of Solid Electrolyte Interphases on Lithium Metal Anode
journal, November 2015

High rate and stable cycling of lithium metal anode
journal, February 2015