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Title: Transforming the carbon economy: challenges and opportunities in the convergence of low-cost electricity and reductive CO 2 utilization

Abstract

Renewable electricity can be leveraged to produce fuels and chemicals from CO 2 , offering sustainable routes to reduce the carbon intensity of our energy and products-driven economy.

Authors:
 [1];  [1];  [1];  [1]; ORCiD logo [1]; ORCiD logo [1]
  1. National Renewable Energy Laboratory, Golden, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1576021
Grant/Contract Number:  
AC36-08GO28308
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Energy & Environmental Science
Additional Journal Information:
Journal Name: Energy & Environmental Science; Journal ID: ISSN 1754-5692
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Grim, R. Gary, Huang, Zhe, Guarnieri, Michael T., Ferrell, Jack R., Tao, Ling, and Schaidle, Joshua A. Transforming the carbon economy: challenges and opportunities in the convergence of low-cost electricity and reductive CO 2 utilization. United Kingdom: N. p., 2020. Web. doi:10.1039/C9EE02410G.
Grim, R. Gary, Huang, Zhe, Guarnieri, Michael T., Ferrell, Jack R., Tao, Ling, & Schaidle, Joshua A. Transforming the carbon economy: challenges and opportunities in the convergence of low-cost electricity and reductive CO 2 utilization. United Kingdom. doi:10.1039/C9EE02410G.
Grim, R. Gary, Huang, Zhe, Guarnieri, Michael T., Ferrell, Jack R., Tao, Ling, and Schaidle, Joshua A. Wed . "Transforming the carbon economy: challenges and opportunities in the convergence of low-cost electricity and reductive CO 2 utilization". United Kingdom. doi:10.1039/C9EE02410G.
@article{osti_1576021,
title = {Transforming the carbon economy: challenges and opportunities in the convergence of low-cost electricity and reductive CO 2 utilization},
author = {Grim, R. Gary and Huang, Zhe and Guarnieri, Michael T. and Ferrell, Jack R. and Tao, Ling and Schaidle, Joshua A.},
abstractNote = {Renewable electricity can be leveraged to produce fuels and chemicals from CO 2 , offering sustainable routes to reduce the carbon intensity of our energy and products-driven economy.},
doi = {10.1039/C9EE02410G},
journal = {Energy & Environmental Science},
number = ,
volume = ,
place = {United Kingdom},
year = {2020},
month = {1}
}

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Works referenced in this record:

Bioelectrochemical systems for simultaneously production of methane and acetate from carbon dioxide at relatively high rate
journal, March 2013


Suppressing methanogens and enriching electrogens in bioelectrochemical systems
journal, April 2019


Benchmarking Hydrogen Evolving Reaction and Oxygen Evolving Reaction Electrocatalysts for Solar Water Splitting Devices
journal, March 2015

  • McCrory, Charles C. L.; Jung, Suho; Ferrer, Ivonne M.
  • Journal of the American Chemical Society, Vol. 137, Issue 13
  • DOI: 10.1021/ja510442p

The use of solar energy can enhance the conversion of carbon dioxide into energy-rich products: stepping towards artificial photosynthesis
journal, August 2013

  • Aresta, Michele; Dibenedetto, Angela; Angelini, Antonella
  • Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 371, Issue 1996
  • DOI: 10.1098/rsta.2012.0111

Diesel Production from Fischer−Tropsch: The Past, the Present, and New Concepts
journal, May 2009


How to deal with negative power price spikes?—Flexible voluntary curtailment agreements for large-scale integration of wind
journal, June 2011


Metagenomics-guided analysis of microbial chemolithoautotrophic phosphite oxidation yields evidence of a seventh natural CO 2 fixation pathway
journal, November 2017

  • Figueroa, Israel A.; Barnum, Tyler P.; Somasekhar, Pranav Y.
  • Proceedings of the National Academy of Sciences, Vol. 115, Issue 1
  • DOI: 10.1073/pnas.1715549114

Highly efficient reversible protonic ceramic electrochemical cells for power generation and fuel production
journal, March 2019


Carbon Corrosion in PEM Fuel Cells and the Development of Accelerated Stress Tests
journal, January 2018

  • Macauley, Natalia; Papadias, Dennis D.; Fairweather, Joseph
  • Journal of The Electrochemical Society, Vol. 165, Issue 6
  • DOI: 10.1149/2.0061806jes

Extremely Thermophilic Routes to Microbial Electrofuels
journal, July 2011

  • Hawkins, Aaron S.; Han, Yejun; Lian, Hong
  • ACS Catalysis, Vol. 1, Issue 9
  • DOI: 10.1021/cs2003017

Towards sustainable fuels and chemicals through the electrochemical reduction of CO 2 : lessons from water electrolysis
journal, January 2015

  • Martín, Antonio J.; Larrazábal, Gastón O.; Pérez-Ramírez, Javier
  • Green Chemistry, Vol. 17, Issue 12
  • DOI: 10.1039/C5GC01893E

Particle Size Effects in the Catalytic Electroreduction of CO 2 on Cu Nanoparticles
journal, May 2014

  • Reske, Rulle; Mistry, Hemma; Behafarid, Farzad
  • Journal of the American Chemical Society, Vol. 136, Issue 19
  • DOI: 10.1021/ja500328k

Effects of Reactor Packing Materials on H2 Production by CO2 Reforming of CH4 in a Dielectric Barrier Discharge
journal, November 2011

  • Gallon, Helen J.; Tu, Xin; Whitehead, J. Christopher
  • Plasma Processes and Polymers, Vol. 9, Issue 1
  • DOI: 10.1002/ppap.201100130

Synthesis of lower olefins by hydrogenation of carbon dioxide over supported iron catalysts
journal, October 2013


K and Mn doped iron-based CO2 hydrogenation catalysts: Detection of KAlH4 as part of the catalyst's active phase
journal, January 2010

  • Dorner, Robert W.; Hardy, Dennis R.; Williams, Frederick W.
  • Applied Catalysis A: General, Vol. 373, Issue 1-2
  • DOI: 10.1016/j.apcata.2009.11.005

Nanoporous Copper–Silver Alloys by Additive-Controlled Electrodeposition for the Selective Electroreduction of CO 2 to Ethylene and Ethanol
journal, April 2018

  • Hoang, Thao T. H.; Verma, Sumit; Ma, Sichao
  • Journal of the American Chemical Society, Vol. 140, Issue 17
  • DOI: 10.1021/jacs.8b01868

Conversion of Greenhouse Gases to Synthesis Gas and Higher Hydrocarbons
journal, March 2001

  • Zhang, Kui; Kogelschatz, Ulrich; Eliasson, Baldur
  • Energy & Fuels, Vol. 15, Issue 2
  • DOI: 10.1021/ef000161o

Optimizing C–C Coupling on Oxide-Derived Copper Catalysts for Electrochemical CO 2 Reduction
journal, June 2017

  • Lum, Yanwei; Yue, Binbin; Lobaccaro, Peter
  • The Journal of Physical Chemistry C, Vol. 121, Issue 26
  • DOI: 10.1021/acs.jpcc.7b03673

PEM fuel cell electrocatalyst durability measurements
journal, December 2006


A Gross-Margin Model for Defining Technoeconomic Benchmarks in the Electroreduction of CO 2
journal, June 2016

  • Verma, Sumit; Kim, Byoungsu; Jhong, Huei-Ru “Molly”
  • ChemSusChem, Vol. 9, Issue 15
  • DOI: 10.1002/cssc.201600394

Highly active catalyst derived from a 3D foam of Fe(PO 3 ) 2 /Ni 2 P for extremely efficient water oxidation
journal, May 2017

  • Zhou, Haiqing; Yu, Fang; Sun, Jingying
  • Proceedings of the National Academy of Sciences, Vol. 114, Issue 22
  • DOI: 10.1073/pnas.1701562114

Use of a non-thermal plasma for the production of synthesis gas from biogas
journal, February 2009

  • Goujard, Valentin; Tatibouët, Jean-Michel; Batiot-Dupeyrat, Catherine
  • Applied Catalysis A: General, Vol. 353, Issue 2
  • DOI: 10.1016/j.apcata.2008.10.050

Introducing a New NIST Reference Material: Multiwall Carbon Nanotube Soot
journal, July 2016

  • Chiaramonti, Ann N.; White, Ryan M.; Holm, Jason
  • Microscopy and Microanalysis, Vol. 22, Issue S3
  • DOI: 10.1017/S143192761600310X

Climate change mitigation potential of carbon capture and utilization in the chemical industry
journal, May 2019

  • Kätelhön, Arne; Meys, Raoul; Deutz, Sarah
  • Proceedings of the National Academy of Sciences, Vol. 116, Issue 23
  • DOI: 10.1073/pnas.1821029116

Directly converting CO2 into a gasoline fuel
journal, May 2017

  • Wei, Jian; Ge, Qingjie; Yao, Ruwei
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms15174

CO2 dissociation in a packed bed DBD reactor: First steps towards a better understanding of plasma catalysis
journal, October 2017


Effect of dielectric packing materials on the decomposition of carbon dioxide using DBD microplasma reactor
journal, November 2014

  • Duan, Xiaofei; Hu, Zongyuan; Li, Yanping
  • AIChE Journal, Vol. 61, Issue 3
  • DOI: 10.1002/aic.14682

Structure effects on the energetics of the electrochemical reduction of CO2 by copper surfaces
journal, August 2011


Carbon support oxidation in PEM fuel cell cathodes
journal, February 2008


Mediator-free enzymatic electrosynthesis of formate by the Methanococcus maripaludis heterodisulfide reductase supercomplex
journal, April 2018


Renewable Power-to-Gas: A technological and economic review
journal, January 2016


A Direct Grain-Boundary-Activity Correlation for CO Electroreduction on Cu Nanoparticles
journal, March 2016


Long-term open circuit microbial electrosynthesis system promotes methanogenesis
journal, February 2020


Clostridium ljungdahlii represents a microbial production platform based on syngas
journal, July 2010

  • Kopke, M.; Held, C.; Hujer, S.
  • Proceedings of the National Academy of Sciences, Vol. 107, Issue 29, p. 13087-13092
  • DOI: 10.1073/pnas.1004716107

Selective CO 2 reduction to C 3 and C 4 oxyhydrocarbons on nickel phosphides at overpotentials as low as 10 mV
journal, January 2018

  • Calvinho, Karin U. D.; Laursen, Anders B.; Yap, Kyra M. K.
  • Energy & Environmental Science, Vol. 11, Issue 9
  • DOI: 10.1039/C8EE00936H

Hydrogen and oxygen generation with polymer electrolyte membrane (PEM)-based electrolytic technology
journal, April 2006


Recent advances in industrial CO2 electroreduction
journal, April 2019

  • Sánchez, Oriol Gutiérrez; Birdja, Yuvraj Y.; Bulut, Metin
  • Current Opinion in Green and Sustainable Chemistry, Vol. 16
  • DOI: 10.1016/j.cogsc.2019.01.005

Electrochemical Reduction of CO at a Copper Electrode
journal, September 1997

  • Hori, Yoshio; Takahashi, Ryutaro; Yoshinami, Yuzuru
  • The Journal of Physical Chemistry B, Vol. 101, Issue 36
  • DOI: 10.1021/jp970284i

Electrochemical reduction of CO2 to formate at high current density using gas diffusion electrodes
journal, August 2014


Bringing High-Rate, CO 2 -Based Microbial Electrosynthesis Closer to Practical Implementation through Improved Electrode Design and Operating Conditions
journal, January 2016

  • Jourdin, Ludovic; Freguia, Stefano; Flexer, Victoria
  • Environmental Science & Technology, Vol. 50, Issue 4
  • DOI: 10.1021/acs.est.5b04431

Carbon dioxide splitting using an electro-thermochemical hybrid looping strategy
journal, January 2018

  • Luc, Wesley; Jouny, Matthew; Rosen, Jonathan
  • Energy & Environmental Science, Vol. 11, Issue 10
  • DOI: 10.1039/C8EE00532J

Synthesis of DME from CO2/H2 gas mixture
journal, February 2011


Electroactive bacteria—molecular mechanisms and genetic tools
journal, August 2014

  • Sydow, Anne; Krieg, Thomas; Mayer, Florian
  • Applied Microbiology and Biotechnology, Vol. 98, Issue 20
  • DOI: 10.1007/s00253-014-6005-z

Butanol Tolerance in a Selection of Microorganisms
journal, December 2008


Microbial Electrolytic Carbon Capture for Carbon Negative and Energy Positive Wastewater Treatment
journal, June 2015

  • Lu, Lu; Huang, Zhe; Rau, Greg H.
  • Environmental Science & Technology, Vol. 49, Issue 13
  • DOI: 10.1021/acs.est.5b00875

Plasma technology – a novel solution for CO 2 conversion?
journal, January 2017

  • Snoeckx, Ramses; Bogaerts, Annemie
  • Chemical Society Reviews, Vol. 46, Issue 19
  • DOI: 10.1039/C6CS00066E

Carbon nanotube wools made directly from CO2 by molten electrolysis: Value driven pathways to carbon dioxide greenhouse gas mitigation
journal, September 2017


Hydrogenation of carbon oxides over promoted Fe-Mn catalysts prepared by the microemulsion methodology
journal, September 2006


Selective Electrochemical Reduction of Carbon Dioxide to Ethylene and Ethanol on Copper(I) Oxide Catalysts
journal, March 2015

  • Ren, Dan; Deng, Yilin; Handoko, Albertus Denny
  • ACS Catalysis, Vol. 5, Issue 5
  • DOI: 10.1021/cs502128q

The production of acetic acid from carbon dioxide and hydrogen by an anaerobic bacterium
journal, May 1990


Thermodynamic assessment of CO2 to carbon nanofiber transformation for carbon sequestration in a combined cycle gas or a coal power plant
journal, August 2016


Effect of the electric supply interruption on a microbial electrosynthesis system converting inorganic carbon into acetate
journal, October 2018


Conversion of greenhouse gases into syngas via combined effects of discharge activation and catalysis
journal, February 2010


Enhanced Electrochemical Methanation of Carbon Dioxide with a Dispersible Nanoscale Copper Catalyst
journal, September 2014

  • Manthiram, Karthish; Beberwyck, Brandon J.; Alivisatos, A. Paul
  • Journal of the American Chemical Society, Vol. 136, Issue 38
  • DOI: 10.1021/ja5065284

Microbial electrosynthesis — revisiting the electrical route for microbial production
journal, October 2010

  • Rabaey, Korneel; Rozendal, René A.
  • Nature Reviews Microbiology, Vol. 8, Issue 10, p. 706-716
  • DOI: 10.1038/nrmicro2422

Plasma-driven dissociation of CO 2 for fuel synthesis
journal, September 2016

  • Bongers, Waldo; Bouwmeester, Henny; Wolf, Bram
  • Plasma Processes and Polymers, Vol. 14, Issue 6
  • DOI: 10.1002/ppap.201600126

Synergistic geometric and electronic effects for electrochemical reduction of carbon dioxide using gold–copper bimetallic nanoparticles
journal, September 2014

  • Kim, Dohyung; Resasco, Joaquin; Yu, Yi
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms5948

Using a One-Electron Shuttle for the Multielectron Reduction of CO2 to Methanol: Kinetic, Mechanistic, and Structural Insights
journal, August 2010

  • Barton Cole, Emily; Lakkaraju, Prasad S.; Rampulla, David M.
  • Journal of the American Chemical Society, Vol. 132, Issue 33, p. 11539-11551
  • DOI: 10.1021/ja1023496

New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
journal, January 2012

  • Kuhl, Kendra P.; Cave, Etosha R.; Abram, David N.
  • Energy & Environmental Science, Vol. 5, Issue 5
  • DOI: 10.1039/c2ee21234j

Reduction Characteristics of Carbon Dioxide Using a Plasmatron
journal, October 2013

  • Kim, Seong Cheon; Lim, Mun Sup; Chun, Young Nam
  • Plasma Chemistry and Plasma Processing, Vol. 34, Issue 1
  • DOI: 10.1007/s11090-013-9499-8

Non-thermal plasma approaches in CO2 utilization
journal, March 1999


Hydrogen or batteries for grid storage? A net energy analysis
journal, January 2015

  • Pellow, Matthew A.; Emmott, Christopher J. M.; Barnhart, Charles J.
  • Energy & Environmental Science, Vol. 8, Issue 7
  • DOI: 10.1039/C4EE04041D

Economic and energetic analysis of capturing CO2 from ambient air
journal, December 2011

  • House, K. Z.; Baclig, A. C.; Ranjan, M.
  • Proceedings of the National Academy of Sciences, Vol. 108, Issue 51
  • DOI: 10.1073/pnas.1012253108

Microbial electrolysis cell platform for simultaneous waste biorefinery and clean electrofuels generation: Current situation, challenges and future perspectives
journal, November 2017

  • Zhen, Guangyin; Lu, Xueqin; Kumar, Gopalakrishnan
  • Progress in Energy and Combustion Science, Vol. 63
  • DOI: 10.1016/j.pecs.2017.07.003

Methanation of CO2: Structural response of a Ni-based catalyst under fluctuating reaction conditions unraveled by operando spectroscopy
journal, July 2015


Steering post-C–C coupling selectivity enables high efficiency electroreduction of carbon dioxide to multi-carbon alcohols
journal, June 2018


Alamethicin Suppresses Methanogenesis and Promotes Acetogenesis in Bioelectrochemical Systems
journal, March 2015

  • Zhu, Xiuping; Siegert, Michael; Yates, Matthew D.
  • Applied and Environmental Microbiology, Vol. 81, Issue 11
  • DOI: 10.1128/AEM.00594-15

Tuning the Catalytic Activity and Selectivity of Cu for CO 2 Electroreduction in the Presence of Halides
journal, February 2016


CO2 Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu2O Films
journal, April 2012

  • Li, Christina W.; Kanan, Matthew W.
  • Journal of the American Chemical Society, Vol. 134, Issue 17, p. 7231-7234
  • DOI: 10.1021/ja3010978

An experimental study of CO2 hydrogenation into methanol involving a zeolite membrane reactor
journal, August 2004

  • Gallucci, Fausto; Paturzo, Luca; Basile, Angelo
  • Chemical Engineering and Processing: Process Intensification, Vol. 43, Issue 8
  • DOI: 10.1016/j.cep.2003.10.005

Microbes paired for biological gas-to-liquids (Bio-GTL) process
journal, March 2016

  • Pfleger, Brian F.
  • Proceedings of the National Academy of Sciences, Vol. 113, Issue 14
  • DOI: 10.1073/pnas.1601926113

Dry Reforming of Methane in a Dielectric Barrier Discharge Reactor with Ni/Al 2 O 3 Catalyst: Interaction of Catalyst and Plasma
journal, August 2009

  • Wang, Qi; Yan, Bin-Hang; Jin, Yong
  • Energy & Fuels, Vol. 23, Issue 8
  • DOI: 10.1021/ef900286j

Electrosynthesis of Organic Compounds from Carbon Dioxide Is Catalyzed by a Diversity of Acetogenic Microorganisms
journal, March 2011

  • Nevin, Kelly P.; Hensley, Sarah A.; Franks, Ashley E.
  • Applied and Environmental Microbiology, Vol. 77, Issue 9, p. 2882-2886
  • DOI: 10.1128/AEM.02642-10

Essential prerequisites for successful bioprocess development of biological CH 4 production from CO 2 and H 2
journal, September 2013


Modeling Plasma-based CO 2 and CH 4 Conversion in Mixtures with N 2 , O 2 , and H 2 O: The Bigger Plasma Chemistry Picture
journal, January 2018

  • Wang, Weizong; Snoeckx, Ramses; Zhang, Xuming
  • The Journal of Physical Chemistry C, Vol. 122, Issue 16
  • DOI: 10.1021/acs.jpcc.7b10619

What would it take for renewably powered electrosynthesis to displace petrochemical processes?
journal, April 2019


Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
journal, April 2014

  • Li, Christina W.; Ciston, Jim; Kanan, Matthew W.
  • Nature, Vol. 508, Issue 7497
  • DOI: 10.1038/nature13249

Biotransformation of carbon dioxide in bioelectrochemical systems: State of the art and future prospects
journal, July 2017


Power to Gas projects review: Lab, pilot and demo plants for storing renewable energy and CO2
journal, March 2017

  • Bailera, Manuel; Lisbona, Pilar; Romeo, Luis M.
  • Renewable and Sustainable Energy Reviews, Vol. 69
  • DOI: 10.1016/j.rser.2016.11.130

Growth of Methanobacterium thermoautotrophicum on H2CO2: High CH4 productivities in continuous culture
journal, January 1990


Fischer–Tropsch synthesis: A review of water effects on the performances of unsupported and supported Co catalysts
journal, September 2008


Electrocatalytic process of CO selectivity in electrochemical reduction of CO2 at metal electrodes in aqueous media
journal, August 1994

  • Hori, Yoshio; Wakebe, Hidetoshi; Tsukamoto, Toshio
  • Electrochimica Acta, Vol. 39, Issue 11-12, p. 1833-1839
  • DOI: 10.1016/0013-4686(94)85172-7

CO2 valorisation via Reverse Water-Gas Shift reaction using advanced Cs doped Fe-Cu/Al2O3 catalysts
journal, October 2017


Direct Conversion of Greenhouse Gases to Synthesis Gas and C 4 Hydrocarbons over Zeolite HY Promoted by a Dielectric-Barrier Discharge
journal, March 2002

  • Zhang, Kui; Eliasson, Baldur; Kogelschatz, Ulrich
  • Industrial & Engineering Chemistry Research, Vol. 41, Issue 6
  • DOI: 10.1021/ie0105021

Cell-free metabolic engineering: Biomanufacturing beyond the cell
journal, October 2014

  • Dudley, Quentin M.; Karim, Ashty S.; Jewett, Michael C.
  • Biotechnology Journal, Vol. 10, Issue 1
  • DOI: 10.1002/biot.201400330

Non-thermal plasma technology for the conversion of CO 2
journal, February 2017


C1-carbon sources for chemical and fuel production by microbial gas fermentation
journal, December 2015


Application of gas diffusion biocathode in microbial electrosynthesis from carbon dioxide
journal, July 2016

  • Bajracharya, Suman; Vanbroekhoven, Karolien; Buisman, Cees J. N.
  • Environmental Science and Pollution Research, Vol. 23, Issue 22
  • DOI: 10.1007/s11356-016-7196-x

Taming microwave plasma to beat thermodynamics in CO 2 dissociation
journal, January 2015

  • van Rooij, G. J.; van den Bekerom, D. C. M.; den Harder, N.
  • Faraday Discussions, Vol. 183
  • DOI: 10.1039/C5FD00045A

Assessment of Carbon Dioxide Dissociation as a New Route for Syngas Production: A Comparative Review and Potential of Plasma-Based Technologies
journal, April 2013

  • Lebouvier, Alexandre; Iwarere, Samuel A.; d’Argenlieu, Philippe
  • Energy & Fuels, Vol. 27, Issue 5
  • DOI: 10.1021/ef301991d

An overview of cathode materials for microbial electrosynthesis of chemicals from carbon dioxide
journal, January 2017

  • Aryal, Nabin; Ammam, Fariza; Patil, Sunil A.
  • Green Chemistry, Vol. 19, Issue 24
  • DOI: 10.1039/C7GC01801K

Adding value to carbon dioxide from ethanol fermentations
journal, May 2010


A Circular Bioeconomy with Biobased Products from CO 2 Sequestration
journal, June 2016


Frontiers in microbial 1-butanol and isobutanol production
journal, January 2016

  • Chen, Chang-Ting; Liao, James C.
  • FEMS Microbiology Letters, Vol. 363, Issue 5
  • DOI: 10.1093/femsle/fnw020

The formate bio-economy
journal, December 2016

  • Yishai, Oren; Lindner, Steffen N.; Gonzalez de la Cruz, Jorge
  • Current Opinion in Chemical Biology, Vol. 35
  • DOI: 10.1016/j.cbpa.2016.07.005

Nickel–Gallium-Catalyzed Electrochemical Reduction of CO 2 to Highly Reduced Products at Low Overpotentials
journal, February 2016

  • Torelli, Daniel A.; Francis, Sonja A.; Crompton, J. Chance
  • ACS Catalysis, Vol. 6, Issue 3
  • DOI: 10.1021/acscatal.5b02888

Electrochemical reduction of carbon dioxide at various series of copper single crystal electrodes
journal, May 2003


Mechanistic Insights into the Selective Electroreduction of Carbon Dioxide to Ethylene on Cu 2 O-Derived Copper Catalysts
journal, September 2016

  • Handoko, Albertus D.; Ong, Cheng Wai; Huang, Yun
  • The Journal of Physical Chemistry C, Vol. 120, Issue 36
  • DOI: 10.1021/acs.jpcc.6b07128

Conversion of H2 and CO2 to CH4 and acetate in fed-batch biogas reactors by mixed biogas community: a novel route for the power-to-gas concept
journal, May 2016

  • Szuhaj, Márk; Ács, Norbert; Tengölics, Roland
  • Biotechnology for Biofuels, Vol. 9, Issue 1
  • DOI: 10.1186/s13068-016-0515-0

Pathways to Industrial-Scale Fuel Out of Thin Air from CO2 Electrolysis
journal, August 2019


Microbial electrosynthesis (MES) from CO2 is resilient to fluctuations in renewable energy supply
journal, December 2018


Direct Conversion of Methane and Carbon Dioxide to Higher Hydrocarbons Using Catalytic Dielectric-Barrier Discharges with Zeolites
journal, May 2000

  • Eliasson, Baldur; Liu, Chang-jun; Kogelschatz, Ulrich
  • Industrial & Engineering Chemistry Research, Vol. 39, Issue 5
  • DOI: 10.1021/ie990804r

Succinic Acid: A New Platform Chemical for Biobased Polymers from Renewable Resources
journal, May 2008

  • Bechthold, I.; Bretz, K.; Kabasci, S.
  • Chemical Engineering & Technology, Vol. 31, Issue 5, p. 647-654
  • DOI: 10.1002/ceat.200800063

Towards full one-pass conversion of carbon dioxide to methanol and methanol-derived products
journal, January 2014


Long-term Operation of Microbial Electrosynthesis Systems Improves Acetate Production by Autotrophic Microbiomes
journal, May 2013

  • Marshall, Christopher W.; Ross, Daniel E.; Fichot, Erin B.
  • Environmental Science & Technology, Vol. 47, Issue 11, p. 6023-6029
  • DOI: 10.1021/es400341b

Effect of manganese on an iron-based Fischer–Tropsch synthesis catalyst prepared from ferrous sulfate
journal, May 2007


Progress and Perspective of Electrocatalytic CO 2 Reduction for Renewable Carbonaceous Fuels and Chemicals
journal, September 2017


Carbon nanotube containing Ag catalyst layers for efficient and selective reduction of carbon dioxide
journal, January 2016

  • Ma, Sichao; Luo, Raymond; Gold, Jake I.
  • Journal of Materials Chemistry A, Vol. 4, Issue 22
  • DOI: 10.1039/C6TA00427J

Direct and selective hydrogenation of CO 2 to ethylene and propene by bifunctional catalysts
journal, January 2017

  • Gao, Jiajian; Jia, Chunmiao; Liu, Bin
  • Catalysis Science & Technology, Vol. 7, Issue 23
  • DOI: 10.1039/C7CY01549F

Recent advances in catalytic hydrogenation of carbon dioxide
journal, January 2011

  • Wang, Wei; Wang, Shengping; Ma, Xinbin
  • Chemical Society Reviews, Vol. 40, Issue 7
  • DOI: 10.1039/c1cs15008a

Plasma methane conversion using dielectric-barrier discharges with zeolite A
journal, March 2002


Oxidative Coupling and Reforming of Methane with Carbon Dioxide Using a High-Frequency Pulsed Plasma
journal, July 2000

  • Yao, S. L.; Ouyang, F.; Nakayama, A.
  • Energy & Fuels, Vol. 14, Issue 4
  • DOI: 10.1021/ef000016a

Integrated Electromicrobial Conversion of CO2 to Higher Alcohols
journal, March 2012

  • Li, H.; Opgenorth, P. H.; Wernick, D. G.
  • Science, Vol. 335, Issue 6076, p. 1596-1596
  • DOI: 10.1126/science.1217643

New and revisited insights into the promotion of methanol synthesis catalysts by CO2
journal, January 2013

  • Martin, Oliver; Pérez-Ramírez, Javier
  • Catalysis Science & Technology, Vol. 3, Issue 12
  • DOI: 10.1039/c3cy00573a

Electrochemical conversion of CO2 to formic acid utilizing Sustainion™ membranes
journal, July 2017


Continuous long-term electricity-driven bioproduction of carboxylates and isopropanol from CO 2 with a mixed microbial community
journal, July 2017


General Techno-Economic Analysis of CO 2 Electrolysis Systems
journal, February 2018

  • Jouny, Matthew; Luc, Wesley; Jiao, Feng
  • Industrial & Engineering Chemistry Research, Vol. 57, Issue 6
  • DOI: 10.1021/acs.iecr.7b03514

Highly Dense Cu Nanowires for Low-Overpotential CO2 Reduction
journal, September 2015


CH4–CO2 reforming by plasma – challenges and opportunities
journal, April 2011


The Quest for Value-Added Products from Carbon Dioxide and Water in a Dielectric Barrier Discharge: A Chemical Kinetics Study
journal, November 2016


Current trends in enzymatic electrosynthesis for CO2 reduction
journal, April 2019

  • Chiranjeevi, P.; Bulut, Metin; Breugelmans, Tom
  • Current Opinion in Green and Sustainable Chemistry, Vol. 16
  • DOI: 10.1016/j.cogsc.2019.02.007

Fischer–Tropsch synthesis on a Co/Al2O3 catalyst with CO2 containing syngas
journal, February 2009

  • Visconti, Carlo Giorgio; Lietti, Luca; Tronconi, Enrico
  • Applied Catalysis A: General, Vol. 355, Issue 1-2
  • DOI: 10.1016/j.apcata.2008.11.027

CO 2 electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface
journal, May 2018


Calculation for the cathode surface concentrations in the electrochemical reduction of CO2 in KHCO3 solutions
journal, October 2005

  • Gupta, N.; Gattrell, M.; MacDougall, B.
  • Journal of Applied Electrochemistry, Vol. 36, Issue 2
  • DOI: 10.1007/s10800-005-9058-y

Selective Enrichment Establishes a Stable Performing Community for Microbial Electrosynthesis of Acetate from CO 2
journal, June 2015

  • Patil, Sunil A.; Arends, Jan B. A.; Vanwonterghem, Inka
  • Environmental Science & Technology, Vol. 49, Issue 14
  • DOI: 10.1021/es506149d

Microbial Electrosynthesis: Feeding Microbes Electricity To Convert Carbon Dioxide and Water to Multicarbon Extracellular Organic Compounds
journal, May 2010

  • Nevin, K. P.; Woodard, T. L.; Franks, A. E.
  • mBio, Vol. 1, Issue 2, Article No. e00103-10
  • DOI: 10.1128/mBio.00103-10

Enhancing CO2 electrolysis through synergistic control of non-stoichiometry and doping to tune cathode surface structures
journal, March 2017

  • Ye, Lingting; Zhang, Minyi; Huang, Ping
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms14785

Towards membrane-electrode assembly systems for CO 2 reduction: a modeling study
journal, January 2019

  • Weng, Lien-Chun; Bell, Alexis T.; Weber, Adam Z.
  • Energy & Environmental Science, Vol. 12, Issue 6
  • DOI: 10.1039/C9EE00909D

Routes to increase the conversion and the energy efficiency in the splitting of CO 2 by a dielectric barrier discharge
journal, January 2017

  • Ozkan, A.; Bogaerts, A.; Reniers, F.
  • Journal of Physics D: Applied Physics, Vol. 50, Issue 8
  • DOI: 10.1088/1361-6463/aa562c

CO 2 reduction on gas-diffusion electrodes and why catalytic performance must be assessed at commercially-relevant conditions
journal, January 2019

  • Burdyny, Thomas; Smith, Wilson A.
  • Energy & Environmental Science, Vol. 12, Issue 5
  • DOI: 10.1039/C8EE03134G

Biological conversion of carbon dioxide and hydrogen into liquid fuels and industrial chemicals
journal, June 2013

  • Hawkins, Aaron S.; McTernan, Patrick M.; Lian, Hong
  • Current Opinion in Biotechnology, Vol. 24, Issue 3, p. 376-384
  • DOI: 10.1016/j.copbio.2013.02.017

Electrolytic CO 2 Reduction in a Flow Cell
journal, March 2018

  • Weekes, David M.; Salvatore, Danielle A.; Reyes, Angelica
  • Accounts of Chemical Research, Vol. 51, Issue 4
  • DOI: 10.1021/acs.accounts.8b00010

Electro-biocatalytic conversion of carbon dioxide to alcohols using gas diffusion electrode
journal, October 2018


A review of the catalytic hydrogenation of carbon dioxide into value-added hydrocarbons
journal, January 2017

  • Yang, Haiyan; Zhang, Chen; Gao, Peng
  • Catalysis Science & Technology, Vol. 7, Issue 20
  • DOI: 10.1039/C7CY01403A

Carbon Dioxide Conversion by Reverse Water–Gas Shift Chemical Looping on Perovskite-Type Oxides
journal, March 2014

  • Daza, Yolanda A.; Kent, Ryan A.; Yung, Matthew M.
  • Industrial & Engineering Chemistry Research, Vol. 53, Issue 14
  • DOI: 10.1021/ie5002185

Water splitting–biosynthetic system with CO 2 reduction efficiencies exceeding photosynthesis
journal, June 2016


A comprehensive review on PEM water electrolysis
journal, April 2013

  • Carmo, Marcelo; Fritz, David L.; Mergel, Jürgen
  • International Journal of Hydrogen Energy, Vol. 38, Issue 12, p. 4901-4934
  • DOI: 10.1016/j.ijhydene.2013.01.151

CO2 reforming of methane by the combination of dielectric-barrier discharges and catalysis
journal, January 2001

  • Kraus, Martin; Eliasson, Baldur; Kogelschatz, Ulrich
  • Physical Chemistry Chemical Physics, Vol. 3, Issue 3
  • DOI: 10.1039/b007015g

The Solubility of Carbon Dioxide in Water at Low Pressure
journal, November 1991

  • Carroll, John J.; Slupsky, John D.; Mather, Alan E.
  • Journal of Physical and Chemical Reference Data, Vol. 20, Issue 6
  • DOI: 10.1063/1.555900