skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on November 27, 2020

Title: Enhanced photoredox activity of CsPbBr 3 nanocrystals by quantitative colloidal ligand exchange

Authors:
ORCiD logo [1];  [2];  [2];  [2]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [1]
  1. Chemistry and Nanoscience Center, National Renewable Energy Laboratory, Golden, Colorado 80401, USA
  2. Department of Chemistry and Biochemistry, San Diego State University, San Diego, California 92182, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1575950
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Chemical Physics
Additional Journal Information:
Journal Name: Journal of Chemical Physics Journal Volume: 151 Journal Issue: 20; Journal ID: ISSN 0021-9606
Publisher:
American Institute of Physics
Country of Publication:
United States
Language:
English

Citation Formats

Lu, Haipeng, Zhu, Xiaolin, Miller, Collin, San Martin, Jovan, Chen, Xihan, Miller, Elisa M., Yan, Yong, and Beard, Matthew C. Enhanced photoredox activity of CsPbBr 3 nanocrystals by quantitative colloidal ligand exchange. United States: N. p., 2019. Web. doi:10.1063/1.5129261.
Lu, Haipeng, Zhu, Xiaolin, Miller, Collin, San Martin, Jovan, Chen, Xihan, Miller, Elisa M., Yan, Yong, & Beard, Matthew C. Enhanced photoredox activity of CsPbBr 3 nanocrystals by quantitative colloidal ligand exchange. United States. doi:10.1063/1.5129261.
Lu, Haipeng, Zhu, Xiaolin, Miller, Collin, San Martin, Jovan, Chen, Xihan, Miller, Elisa M., Yan, Yong, and Beard, Matthew C. Thu . "Enhanced photoredox activity of CsPbBr 3 nanocrystals by quantitative colloidal ligand exchange". United States. doi:10.1063/1.5129261.
@article{osti_1575950,
title = {Enhanced photoredox activity of CsPbBr 3 nanocrystals by quantitative colloidal ligand exchange},
author = {Lu, Haipeng and Zhu, Xiaolin and Miller, Collin and San Martin, Jovan and Chen, Xihan and Miller, Elisa M. and Yan, Yong and Beard, Matthew C.},
abstractNote = {},
doi = {10.1063/1.5129261},
journal = {Journal of Chemical Physics},
number = 20,
volume = 151,
place = {United States},
year = {2019},
month = {11}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on November 27, 2020
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Designing Janus Ligand Shells on PbS Quantum Dots using Ligand–Ligand Cooperativity
journal, March 2019

  • Bronstein, Noah D.; Martinez, Marissa S.; Kroupa, Daniel M.
  • ACS Nano, Vol. 13, Issue 4
  • DOI: 10.1021/acsnano.9b00191

Ligand Mediated Transformation of Cesium Lead Bromide Perovskite Nanocrystals to Lead Depleted Cs 4 PbBr 6 Nanocrystals
journal, April 2017

  • Liu, Zeke; Bekenstein, Yehonadav; Ye, Xingchen
  • Journal of the American Chemical Society, Vol. 139, Issue 15
  • DOI: 10.1021/jacs.7b01409

Perovskite Quantum Dot Photovoltaic Materials beyond the Reach of Thin Films: Full-Range Tuning of A-Site Cation Composition
journal, September 2018


Targeted Ligand-Exchange Chemistry on Cesium Lead Halide Perovskite Quantum Dots for High-Efficiency Photovoltaics
journal, July 2018

  • Wheeler, Lance M.; Sanehira, Erin M.; Marshall, Ashley R.
  • Journal of the American Chemical Society, Vol. 140, Issue 33
  • DOI: 10.1021/jacs.8b04984

Subpicosecond Photoinduced Hole Transfer from a CdS Quantum Dot to a Molecular Acceptor Bound Through an Exciton-Delocalizing Ligand
journal, May 2016


Enhancing the Rate of Quantum-Dot-Photocatalyzed Carbon–Carbon Coupling by Tuning the Composition of the Dot’s Ligand Shell
journal, March 2017

  • Zhang, Zhengyi; Edme, Kedy; Lian, Shichen
  • Journal of the American Chemical Society, Vol. 139, Issue 12
  • DOI: 10.1021/jacs.6b13220

Lead Halide Perovskite Nanocrystals in the Research Spotlight: Stability and Defect Tolerance
journal, August 2017


Electron Transfer as a Probe of the Permeability of Organic Monolayers on the Surfaces of Colloidal PbS Quantum Dots
journal, July 2013

  • Knowles, Kathryn E.; Tagliazucchi, Mario; Malicki, Michał
  • The Journal of Physical Chemistry C, Vol. 117, Issue 30
  • DOI: 10.1021/jp406485y

Exciton-to-Dopant Energy Transfer in Mn-Doped Cesium Lead Halide Perovskite Nanocrystals
journal, November 2016


Enhanced mobility CsPbI 3 quantum dot arrays for record-efficiency, high-voltage photovoltaic cells
journal, October 2017

  • Sanehira, Erin M.; Marshall, Ashley R.; Christians, Jeffrey A.
  • Science Advances, Vol. 3, Issue 10
  • DOI: 10.1126/sciadv.aao4204

Fast Anion-Exchange in Highly Luminescent Nanocrystals of Cesium Lead Halide Perovskites (CsPbX 3 , X = Cl, Br, I)
journal, July 2015


Polar Solvent Induced Lattice Distortion of Cubic CsPbI 3 Nanocubes and Hierarchical Self-Assembly into Orthorhombic Single-Crystalline Nanowires
journal, August 2018

  • Sun, Jian-Kun; Huang, Sheng; Liu, Xiao-Zhi
  • Journal of the American Chemical Society, Vol. 140, Issue 37
  • DOI: 10.1021/jacs.8b05949

Ultrafast Interfacial Electron and Hole Transfer from CsPbBr 3 Perovskite Quantum Dots
journal, September 2015

  • Wu, Kaifeng; Liang, Guijie; Shang, Qiongyi
  • Journal of the American Chemical Society, Vol. 137, Issue 40
  • DOI: 10.1021/jacs.5b08520

Tuning colloidal quantum dot band edge positions through solution-phase surface chemistry modification
journal, May 2017

  • Kroupa, Daniel M.; Vörös, Márton; Brawand, Nicholas P.
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms15257

Optical Absorbance Enhancement in PbS QD/Cinnamate Ligand Complexes
journal, June 2018

  • Kroupa, Daniel M.; Vörös, Márton; Brawand, Nicholas P.
  • The Journal of Physical Chemistry Letters, Vol. 9, Issue 12
  • DOI: 10.1021/acs.jpclett.8b01451

Lead-Halide Perovskites for Photocatalytic α-Alkylation of Aldehydes
journal, January 2019

  • Zhu, Xiaolin; Lin, Yixiong; Sun, Yue
  • Journal of the American Chemical Society, Vol. 141, Issue 2
  • DOI: 10.1021/jacs.8b08720

Quantum dot-induced phase stabilization of  -CsPbI3 perovskite for high-efficiency photovoltaics
journal, October 2016


The Cooperative Molecular Field Effect
journal, October 2005

  • Cahen, D.; Naaman, R.; Vager, Z.
  • Advanced Functional Materials, Vol. 15, Issue 10
  • DOI: 10.1002/adfm.200500187

Highly Dynamic Ligand Binding and Light Absorption Coefficient of Cesium Lead Bromide Perovskite Nanocrystals
journal, January 2016


Lead halide perovskites for photocatalytic organic synthesis
journal, June 2019


Nanocrystals of Cesium Lead Halide Perovskites (CsPbX 3 , X = Cl, Br, and I): Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut
journal, February 2015

  • Protesescu, Loredana; Yakunin, Sergii; Bodnarchuk, Maryna I.
  • Nano Letters, Vol. 15, Issue 6
  • DOI: 10.1021/nl5048779

Ligand Exchange and the Stoichiometry of Metal Chalcogenide Nanocrystals: Spectroscopic Observation of Facile Metal-Carboxylate Displacement and Binding
journal, November 2013

  • Anderson, Nicholas C.; Hendricks, Mark P.; Choi, Joshua J.
  • Journal of the American Chemical Society, Vol. 135, Issue 49, p. 18536-18548
  • DOI: 10.1021/ja4086758

Phase-Stable Red-Emitting CsPbI 3 Nanocrystals: Successes and Challenges
journal, February 2019


Amine-Free Synthesis of Cesium Lead Halide Perovskite Quantum Dots for Efficient Light-Emitting Diodes
journal, October 2016

  • Yassitepe, Emre; Yang, Zhenyu; Voznyy, Oleksandr
  • Advanced Functional Materials, Vol. 26, Issue 47
  • DOI: 10.1002/adfm.201604580