skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Manipulating molecules with strong coupling: harvesting triplet excitons in organic exciton microcavities

Abstract

Exciton-polaritons are quasiparticles with mixed photon and exciton character with the potential to modify chemical properties of materials. Here, they are used to provide dark, high-spin triplet-pair states a new pathway to emit light.

Authors:
 [1];  [1]; ORCiD logo [1]; ORCiD logo [2];  [3];  [3];  [1]; ORCiD logo [1];  [1];  [1]; ORCiD logo [4]; ORCiD logo [3]; ORCiD logo [2];  [1]; ORCiD logo [1]; ORCiD logo [5]
+ Show Author Affiliations
  1. Department of Physics and Astronomy, University of Sheffield, Sheffield S3 7RH, UK
  2. Department of Chemistry and Biochemistry, University of California San Diego, La Jolla, USA
  3. Department of Chemistry, University of Cambridge, Cambridge CB2 1EW, UK
  4. Department of Chemistry, University of Kentucky, Lexington, USA
  5. Department of Physics and Astronomy, University of Sheffield, Sheffield S3 7RH, UK, Department of Chemistry and Biochemistry
Publication Date:
Research Org.:
Univ. of California, San Diego, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1575943
Alternate Identifier(s):
OSTI ID: 1624984
Grant/Contract Number:  
DESC0019188; SC0019188
Resource Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science Journal Volume: 11 Journal Issue: 2; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English
Subject:
Chemistry

Citation Formats

Polak, Daniel, Jayaprakash, Rahul, Lyons, Thomas P., Martínez-Martínez, Luis Á., Leventis, Anastasia, Fallon, Kealan J., Coulthard, Harriet, Bossanyi, David G., Georgiou, Kyriacos, Petty, II, Anthony J., Anthony, John, Bronstein, Hugo, Yuen-Zhou, Joel, Tartakovskii, Alexander I., Clark, Jenny, and Musser, Andrew J. Manipulating molecules with strong coupling: harvesting triplet excitons in organic exciton microcavities. United Kingdom: N. p., 2020. Web. doi:10.1039/C9SC04950A.
Copy to clipboard
Polak, Daniel, Jayaprakash, Rahul, Lyons, Thomas P., Martínez-Martínez, Luis Á., Leventis, Anastasia, Fallon, Kealan J., Coulthard, Harriet, Bossanyi, David G., Georgiou, Kyriacos, Petty, II, Anthony J., Anthony, John, Bronstein, Hugo, Yuen-Zhou, Joel, Tartakovskii, Alexander I., Clark, Jenny, & Musser, Andrew J. Manipulating molecules with strong coupling: harvesting triplet excitons in organic exciton microcavities. United Kingdom. doi:10.1039/C9SC04950A.
Copy to clipboard
Polak, Daniel, Jayaprakash, Rahul, Lyons, Thomas P., Martínez-Martínez, Luis Á., Leventis, Anastasia, Fallon, Kealan J., Coulthard, Harriet, Bossanyi, David G., Georgiou, Kyriacos, Petty, II, Anthony J., Anthony, John, Bronstein, Hugo, Yuen-Zhou, Joel, Tartakovskii, Alexander I., Clark, Jenny, and Musser, Andrew J. Thu . "Manipulating molecules with strong coupling: harvesting triplet excitons in organic exciton microcavities". United Kingdom. doi:10.1039/C9SC04950A.
Copy to clipboard
@article{osti_1575943,
title = {Manipulating molecules with strong coupling: harvesting triplet excitons in organic exciton microcavities},
author = {Polak, Daniel and Jayaprakash, Rahul and Lyons, Thomas P. and Martínez-Martínez, Luis Á. and Leventis, Anastasia and Fallon, Kealan J. and Coulthard, Harriet and Bossanyi, David G. and Georgiou, Kyriacos and Petty, II, Anthony J. and Anthony, John and Bronstein, Hugo and Yuen-Zhou, Joel and Tartakovskii, Alexander I. and Clark, Jenny and Musser, Andrew J.},
abstractNote = {Exciton-polaritons are quasiparticles with mixed photon and exciton character with the potential to modify chemical properties of materials. Here, they are used to provide dark, high-spin triplet-pair states a new pathway to emit light.},
doi = {10.1039/C9SC04950A},
journal = {Chemical Science},
number = 2,
volume = 11,
place = {United Kingdom},
year = {2020},
month = {1}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C9SC04950A
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Citation Metrics:
Cited by: 4 works
Citation information provided by
Web of Science
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

The road towards polaritonic devices
journal, July 2016

  • Sanvitto, Daniele; Kéna-Cohen, Stéphane
  • Nature Materials, Vol. 15, Issue 10
  • DOI: 10.1038/nmat4668

Geminate and Nongeminate Recombination of Triplet Excitons Formed by Singlet Fission
journal, June 2014

Polariton-Induced Enhanced Emission from an Organic Dye under the Strong Coupling Regime
journal, August 2014

  • Ballarini, Dario; De Giorgi, Milena; Gambino, Salvatore
  • Advanced Optical Materials, Vol. 2, Issue 11
  • DOI: 10.1002/adom.201400226

Electrical pumping and tuning of exciton-polaritons in carbon nanotube microcavities
journal, July 2017

  • Graf, Arko; Held, Martin; Zakharko, Yuriy
  • Nature Materials, Vol. 16, Issue 9
  • DOI: 10.1038/nmat4940

Enhanced Delayed Fluorescence in Tetracene Crystals by Strong Light‐Matter Coupling
journal, July 2019

  • Berghuis, Anton Matthijs; Halpin, Alexei; Le‐Van, Quynh
  • Advanced Functional Materials, Vol. 29, Issue 36
  • DOI: 10.1002/adfm.201901317

Strongly exchange-coupled triplet pairs in an organic semiconductor
journal, October 2016

  • Weiss, Leah R.; Bayliss, Sam L.; Kraffert, Felix
  • Nature Physics, Vol. 13, Issue 2
  • DOI: 10.1038/nphys3908

Real-time observation of multiexcitonic states in ultrafast singlet fission using coherent 2D electronic spectroscopy
journal, October 2015

  • Bakulin, Artem A.; Morgan, Sarah E.; Kehoe, Tom B.
  • Nature Chemistry, Vol. 8, Issue 1
  • DOI: 10.1038/nchem.2371

Ultrastrong Coupling of Electrically Pumped Near-Infrared Exciton-Polaritons in High Mobility Polymers
journal, December 2017

  • Held, Martin; Graf, Arko; Zakharko, Yuriy
  • Advanced Optical Materials, Vol. 6, Issue 3
  • DOI: 10.1002/adom.201700962

A Yellow Polariton Condensate in a Dye Filled Microcavity
journal, July 2017

  • Cookson, Tamsin; Georgiou, Kyriacos; Zasedatelev, Anton
  • Advanced Optical Materials, Vol. 5, Issue 18
  • DOI: 10.1002/adom.201700203

Quintet multiexciton dynamics in singlet fission
journal, October 2016

  • Tayebjee, Murad J. Y.; Sanders, Samuel N.; Kumarasamy, Elango
  • Nature Physics, Vol. 13, Issue 2
  • DOI: 10.1038/nphys3909

An electrically pumped polariton laser
journal, May 2013

  • Schneider, Christian; Rahimi-Iman, Arash; Kim, Na Young
  • Nature, Vol. 497, Issue 7449
  • DOI: 10.1038/nature12036

Noncoherent Low-Power Upconversion in Solid Polymer Films
journal, October 2007

  • Islangulov, Radiy R.; Lott, Joseph; Weder, Christoph
  • Journal of the American Chemical Society, Vol. 129, Issue 42
  • DOI: 10.1021/ja075014k

Efficient Singlet Fission and Triplet-Pair Emission in a Family of Zethrene Diradicaloids
journal, December 2017

  • Lukman, Steven; Richter, Johannes M.; Yang, Le
  • Journal of the American Chemical Society, Vol. 139, Issue 50
  • DOI: 10.1021/jacs.7b10762

Selective manipulation of electronically excited states through strong light–matter interactions
journal, June 2018

Charge-Transfer Excitations Steer the Davydov Splitting and Mediate Singlet Exciton Fission in Pentacene
journal, May 2013

Coherent coupling of molecular resonators with a microcavity mode
journal, January 2015

  • Shalabney, A.; George, J.; Hutchison, J.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms6981

Conductivity in organic semiconductors hybridized with the vacuum field
journal, September 2015

  • Orgiu, E.; George, J.; Hutchison, J. A.
  • Nature Materials, Vol. 14, Issue 11
  • DOI: 10.1038/nmat4392

Cavity-Controlled Chemistry in Molecular Ensembles
journal, June 2016

Atoms and molecules in cavities, from weak to strong coupling in quantum-electrodynamics (QED) chemistry
journal, March 2017

  • Flick, Johannes; Ruggenthaler, Michael; Appel, Heiko
  • Proceedings of the National Academy of Sciences, Vol. 114, Issue 12
  • DOI: 10.1073/pnas.1615509114

Theory of Singlet Fission in Polyenes, Acene Crystals, and Covalently Linked Acene Dimers
journal, March 2015

  • Aryanpour, Karan; Shukla, Alok; Mazumdar, Sumit
  • The Journal of Physical Chemistry C, Vol. 119, Issue 13
  • DOI: 10.1021/jp5124019

Magnetic effects on triplet exciton interactions
journal, January 1971

Strong exciton–photon coupling in an organic semiconductor microcavity
journal, September 1998

  • Lidzey, D. G.; Bradley, D. D. C.; Skolnick, M. S.
  • Nature, Vol. 395, Issue 6697
  • DOI: 10.1038/25692

Ultra-strong coupling of molecular materials: spectroscopy and dynamics
journal, January 2015

  • George, Jino; Wang, Shaojun; Chervy, Thibault
  • Faraday Discussions, Vol. 178
  • DOI: 10.1039/C4FD00197D

Unified model for singlet fission within a non-conjugated covalent pentacene dimer
journal, May 2017

  • Basel, Bettina S.; Zirzlmeier, Johannes; Hetzer, Constantin
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms15171

Polaritonic Chemistry with Organic Molecules
journal, October 2017

Polariton-Assisted Singlet Fission in Acene Aggregates
journal, March 2018

  • Martínez-Martínez, Luis A.; Du, Matthew; Ribeiro, Raphael F.
  • The Journal of Physical Chemistry Letters, Vol. 9, Issue 8
  • DOI: 10.1021/acs.jpclett.8b00008

Realizing the classical XY Hamiltonian in polariton simulators
journal, September 2017

  • Berloff, Natalia G.; Silva, Matteo; Kalinin, Kirill
  • Nature Materials, Vol. 16, Issue 11
  • DOI: 10.1038/nmat4971

Theory for polariton-assisted remote energy transfer
journal, January 2018

  • Du, Matthew; Martínez-Martínez, Luis A.; Ribeiro, Raphael F.
  • Chemical Science, Vol. 9, Issue 32
  • DOI: 10.1039/C8SC00171E

Modifying Chemical Landscapes by Coupling to Vacuum Fields
journal, January 2012

  • Hutchison, James A.; Schwartz, Tal; Genet, Cyriaque
  • Angewandte Chemie International Edition, Vol. 51, Issue 7
  • DOI: 10.1002/anie.201107033

Ultra-fast spin-mixing in a diketopyrrolopyrrole monomer/fullerene blend charge transfer state
journal, January 2017

  • Salvadori, Enrico; Luke, Nathaniel; Shaikh, Jordan
  • Journal of Materials Chemistry A, Vol. 5, Issue 46
  • DOI: 10.1039/C7TA07381J

Site-selective measurement of coupled spin pairs in an organic semiconductor
journal, May 2018

  • Bayliss, S. L.; Weiss, L. R.; Mitioglu, A.
  • Proceedings of the National Academy of Sciences, Vol. 115, Issue 20
  • DOI: 10.1073/pnas.1718868115

Magnetic field effects and the role of spin states in singlet fission
journal, October 2013

Kinetic Analysis of Photochemical Upconversion by Triplet−Triplet Annihilation: Beyond Any Spin Statistical Limit
journal, May 2010

  • Cheng, Yuen Yap; Fückel, Burkhard; Khoury, Tony
  • The Journal of Physical Chemistry Letters, Vol. 1, Issue 12
  • DOI: 10.1021/jz100566u

Multiexciton Dynamics Depending on Intramolecular Orientations in Pentacene Dimers: Recombination and Dissociation of Correlated Triplet Pairs
journal, May 2018

  • Sakai, Hayato; Inaya, Ryutaro; Nagashima, Hiroki
  • The Journal of Physical Chemistry Letters, Vol. 9, Issue 12
  • DOI: 10.1021/acs.jpclett.8b01184

Vibronically coherent ultrafast triplet-pair formation and subsequent thermally activated dissociation control efficient endothermic singlet fission
journal, September 2017

  • Stern, Hannah L.; Cheminal, Alexandre; Yost, Shane R.
  • Nature Chemistry, Vol. 9, Issue 12
  • DOI: 10.1038/nchem.2856

Synthesis and Exciton Dynamics of Donor-Orthogonal Acceptor Conjugated Polymers: Reducing the Singlet–Triplet Energy Gap
journal, June 2017

  • Freeman, David M. E.; Musser, Andrew J.; Frost, Jarvist M.
  • Journal of the American Chemical Society, Vol. 139, Issue 32
  • DOI: 10.1021/jacs.7b03327

Triplet harvesting in the polaritonic regime: A variational polaron approach
journal, August 2019

  • Martínez-Martínez, Luis A.; Eizner, Elad; Kéna-Cohen, Stéphane
  • The Journal of Chemical Physics, Vol. 151, Issue 5
  • DOI: 10.1063/1.5100192

The nature of singlet excitons in oligoacene molecular crystals
journal, May 2011

  • Yamagata, H.; Norton, J.; Hontz, E.
  • The Journal of Chemical Physics, Vol. 134, Issue 20
  • DOI: 10.1063/1.3590871

Triplet dynamics in fluorescent polymer light-emitting diodes
journal, January 2012

Excitonic processes in molecular crystalline materials
journal, January 2013

Photon upconversion based on sensitized triplet–triplet annihilation
journal, November 2010

  • Singh-Rachford, Tanya N.; Castellano, Felix N.
  • Coordination Chemistry Reviews, Vol. 254, Issue 21-22
  • DOI: 10.1016/j.ccr.2010.01.003

What Can Be Learned from Magnetic Field Effects on Singlet Fission: Role of Exchange Interaction in Excited Triplet Pairs
journal, November 2015

  • Wakasa, Masanobu; Kaise, Mana; Yago, Tomoaki
  • The Journal of Physical Chemistry C, Vol. 119, Issue 46
  • DOI: 10.1021/acs.jpcc.5b10176

Polariton-mediated energy transfer between organic dyes in a strongly coupled optical microcavity
journal, May 2014

  • Coles, David M.; Somaschi, Niccolo; Michetti, Paolo
  • Nature Materials, Vol. 13, Issue 7
  • DOI: 10.1038/nmat3950

The role of spin in the kinetic control of recombination in organic photovoltaics
journal, August 2013

  • Rao, Akshay; Chow, Philip C. Y.; Gélinas, Simon
  • Nature, Vol. 500, Issue 7463
  • DOI: 10.1038/nature12339

Nonlinear interactions in an organic polariton condensate
journal, February 2014

  • Daskalakis, K. S.; Maier, S. A.; Murray, R.
  • Nature Materials, Vol. 13, Issue 3
  • DOI: 10.1038/nmat3874

Vibrationally Assisted Polariton-Relaxation Processes in Strongly Coupled Organic-Semiconductor Microcavities
journal, July 2011

  • Coles, David M.; Michetti, Paolo; Clark, Caspar
  • Advanced Functional Materials, Vol. 21, Issue 19
  • DOI: 10.1002/adfm.201100756

Singlet Fission
journal, November 2010

  • Smith, Millicent B.; Michl, Josef
  • Chemical Reviews, Vol. 110, Issue 11
  • DOI: 10.1021/cr1002613

Room-temperature polariton lasing in an organic single-crystal microcavity
journal, April 2010

Identifying triplet pathways in dilute pentacene films
journal, October 2018

  • Lubert-Perquel, Daphné; Salvadori, Enrico; Dyson, Matthew
  • Nature Communications, Vol. 9, Issue 1
  • DOI: 10.1038/s41467-018-06330-x

Dynamics of the Excitonic Coupling in Organic Crystals
journal, January 2015

Quantum Beats in Crystalline Tetracene Delayed Fluorescence Due to Triplet Pair Coherences Produced by Direct Singlet Fission
journal, May 2012

  • Burdett, Jonathan J.; Bardeen, Christopher J.
  • Journal of the American Chemical Society, Vol. 134, Issue 20
  • DOI: 10.1021/ja301683w

Singlet-Fission-Born Quintet State: Sublevel Selections and Trapping by Multiexciton Thermodynamics
journal, September 2018

  • Nagashima, Hiroki; Kawaoka, Shuhei; Akimoto, Seiji
  • The Journal of Physical Chemistry Letters, Vol. 9, Issue 19
  • DOI: 10.1021/acs.jpclett.8b02396

External Quantum Efficiency Above 100% in a Singlet-Exciton-Fission-Based Organic Photovoltaic Cell
journal, April 2013

Fission of singlet excitons into pairs of triplet excitons in tetracene crystals
journal, March 1969

Tunable Third-Harmonic Generation from Polaritons in the Ultrastrong Coupling Regime
journal, August 2017

Triplet-Pair States in Organic Semiconductors
journal, June 2019

On the efficiency limit of triplet–triplet annihilation for photochemical upconversion
journal, January 2010

  • Cheng, Yuen Yap; Khoury, Tony; Clady, Raphaël G. C. R.
  • Phys. Chem. Chem. Phys., Vol. 12, Issue 1
  • DOI: 10.1039/B913243K

Room-temperature superfluidity in a polariton condensate
journal, June 2017

  • Lerario, Giovanni; Fieramosca, Antonio; Barachati, Fábio
  • Nature Physics, Vol. 13, Issue 9
  • DOI: 10.1038/nphys4147

Intermolecular states in organic dye dispersions: excimers vs. aggregates
journal, January 2017

  • Musser, A. J.; Rajendran, S. K.; Georgiou, K.
  • Journal of Materials Chemistry C, Vol. 5, Issue 33
  • DOI: 10.1039/C7TC02655B

Fission of Entangled Spins: An Electronic Structure Perspective
journal, November 2013

  • Feng, Xintian; Luzanov, Anatoliy V.; Krylov, Anna I.
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 22
  • DOI: 10.1021/jz402122m

Hybrid Light–Matter States in a Molecular and Material Science Perspective
journal, October 2016

Bose–Einstein condensation of exciton polaritons
journal, September 2006

  • Kasprzak, J.; Richard, M.; Kundermann, S.
  • Nature, Vol. 443, Issue 7110
  • DOI: 10.1038/nature05131

Organic Photodiodes with an Extended Responsivity Using Ultrastrong Light–Matter Coupling
journal, December 2017

Spin-Vibronic Mechanism for Intersystem Crossing
journal, March 2018

Physical Mechanisms of Generation and Deactivation of Singlet Oxygen
journal, May 2003

  • Schweitzer, Claude; Schmidt, Reinhard
  • Chemical Reviews, Vol. 103, Issue 5
  • DOI: 10.1021/cr010371d

Room-temperature Bose–Einstein condensation of cavity exciton–polaritons in a polymer
journal, December 2013

  • Plumhof, Johannes D.; Stöferle, Thilo; Mai, Lijian
  • Nature Materials, Vol. 13, Issue 3
  • DOI: 10.1038/nmat3825

Highly efficient phosphorescent emission from organic electroluminescent devices
journal, September 1998

  • Baldo, M. A.; O'Brien, D. F.; You, Y.
  • Nature, Vol. 395, Issue 6698, p. 151-154
  • DOI: 10.1038/25954

Efficient Radiative Pumping of Polaritons in a Strongly Coupled Microcavity by a Fluorescent Molecular Dye
journal, July 2016

  • Grant, Richard T.; Michetti, Paolo; Musser, Andrew J.
  • Advanced Optical Materials, Vol. 4, Issue 10
  • DOI: 10.1002/adom.201600337

Recent advances in organic thermally activated delayed fluorescence materials
journal, January 2017

  • Yang, Zhiyong; Mao, Zhu; Xie, Zongliang
  • Chemical Society Reviews, Vol. 46, Issue 3
  • DOI: 10.1039/C6CS00368K

Tilting a ground-state reactivity landscape by vibrational strong coupling
journal, February 2019

The entangled triplet pair state in acene and heteroacene materials
journal, July 2017

  • Yong, Chaw Keong; Musser, Andrew J.; Bayliss, Sam L.
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms15953

Collective fluid dynamics of a polariton condensate in a semiconductor microcavity
journal, January 2009

Triplet states in organic semiconductors
journal, November 2009

Fission of singlet excitons into pairs of triplet excitons in tetracene crystals
journal, June 1969

Strongly exchange-coupled triplet pairs in an organic semiconductor
text, January 2016

  • Weiss, Leah; Bayliss, Sam L.; Kraffert, Felix
  • Apollo - University of Cambridge Repository
  • DOI: 10.17863/cam.5906
    [ × clear filter / sort ]

    Similar Records in DOE PAGES and OSTI.GOV collections: