Polyoxometalates as bifunctional templates: engineering metal oxides with mesopores and reactive surfaces for catalysis
Abstract
For the first time, Keggin type POMs were found to be excellent bifunctional templates for generating not only mesopores but also reactive surfaces in metal oxides.
- Authors:
-
[2];
[3];
[4]
- The Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122
- Department of Chemistry, University of Tennessee, Knoxville, USA
- School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China
- Department of Chemistry, University of Tennessee, Knoxville, USA, Chemical Sciences Division
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1575782
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Journal of Materials Chemistry. A
- Additional Journal Information:
- Journal Name: Journal of Materials Chemistry. A Journal Volume: 7 Journal Issue: 48; Journal ID: ISSN 2050-7488
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
Citation Formats
Leng, Yan, Liu, Jixing, Zhang, Zihao, Chen, Hao, Zhang, Pengfei, and Dai, Sheng. Polyoxometalates as bifunctional templates: engineering metal oxides with mesopores and reactive surfaces for catalysis. United Kingdom: N. p., 2019.
Web. doi:10.1039/C9TA09614K.
Leng, Yan, Liu, Jixing, Zhang, Zihao, Chen, Hao, Zhang, Pengfei, & Dai, Sheng. Polyoxometalates as bifunctional templates: engineering metal oxides with mesopores and reactive surfaces for catalysis. United Kingdom. doi:https://doi.org/10.1039/C9TA09614K
Leng, Yan, Liu, Jixing, Zhang, Zihao, Chen, Hao, Zhang, Pengfei, and Dai, Sheng. Tue .
"Polyoxometalates as bifunctional templates: engineering metal oxides with mesopores and reactive surfaces for catalysis". United Kingdom. doi:https://doi.org/10.1039/C9TA09614K.
@article{osti_1575782,
title = {Polyoxometalates as bifunctional templates: engineering metal oxides with mesopores and reactive surfaces for catalysis},
author = {Leng, Yan and Liu, Jixing and Zhang, Zihao and Chen, Hao and Zhang, Pengfei and Dai, Sheng},
abstractNote = {For the first time, Keggin type POMs were found to be excellent bifunctional templates for generating not only mesopores but also reactive surfaces in metal oxides.},
doi = {10.1039/C9TA09614K},
journal = {Journal of Materials Chemistry. A},
number = 48,
volume = 7,
place = {United Kingdom},
year = {2019},
month = {12}
}
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DOI: https://doi.org/10.1039/C9TA09614K
DOI: https://doi.org/10.1039/C9TA09614K
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Works referenced in this record:
A Review on Design Strategies for Carbon Based Metal Oxides and Sulfides Nanocomposites for High Performance Li and Na Ion Battery Anodes
journal, December 2016
- Zhao, Yi; Wang, Luyuan Paul; Sougrati, Moulay Tahar
- Advanced Energy Materials, Vol. 7, Issue 9
Catalytic removal of chlorinated compounds over ordered mesoporous cobalt oxides synthesised by hard-templating
journal, March 2018
- González-Prior, J.; López-Fonseca, R.; Gutiérrez-Ortiz, J. I.
- Applied Catalysis B: Environmental, Vol. 222
General Self-Template Synthesis of Transition-Metal Oxide and Chalcogenide Mesoporous Nanotubes with Enhanced Electrochemical Performances
journal, May 2016
- Wang, Huan; Zhuo, Sifei; Liang, Yu
- Angewandte Chemie International Edition, Vol. 55, Issue 31
Recent Advances in Polyoxometalate-Catalyzed Reactions
journal, May 2015
- Wang, Sa-Sa; Yang, Guo-Yu
- Chemical Reviews, Vol. 115, Issue 11
Three-dimensional nitrogen-doped porous carbon anchored CeO 2 quantum dots as an efficient catalyst for formaldehyde oxidation
journal, January 2018
- Luo, Dong; Chen, Bingbing; Li, Xingyun
- Journal of Materials Chemistry A, Vol. 6, Issue 17
Low-temperature CO oxidation over Co3O4-based catalysts: Significant promoting effect of Bi2O3 on Co3O4 catalyst
journal, March 2014
- Lou, Yang; Wang, Li; Zhao, Zhenyang
- Applied Catalysis B: Environmental, Vol. 146
A general soft-enveloping strategy in the templating synthesis of mesoporous metal nanostructures
journal, February 2018
- Fang, Jixiang; Zhang, Lingling; Li, Jiang
- Nature Communications, Vol. 9, Issue 1
Clean Alternative for Adipic Acid Synthesis Via Liquid-Phase Oxidation of Cyclohexanone and Cyclohexanol Over H3−2xCoxPMo12O40 Catalysts with Hydrogen Peroxide
journal, May 2013
- Benadji, S.; Mazari, T.; Dermeche, L.
- Catalysis Letters, Vol. 143, Issue 8
N-Doped carbon encapsulated molybdenum carbide as an efficient catalyst for oxidant-free dehydrogenation of alcohols
journal, January 2017
- Leng, Yan; Li, Jingjing; Zhang, Chenjun
- Journal of Materials Chemistry A, Vol. 5, Issue 33
Robust Polyoxometalate/Nickel Foam Composite Electrodes for Sustained Electrochemical Oxygen Evolution at High pH
journal, April 2017
- Luo, Wenjing; Hu, Jun; Diao, Hongling
- Angewandte Chemie International Edition, Vol. 56, Issue 18
Low-Temperature CO Oxidation over Co3O4/Al2O3
journal, August 2000
- Jansson, Jonas
- Journal of Catalysis, Vol. 194, Issue 1
Thermally stable single atom Pt/m-Al2O3 for selective hydrogenation and CO oxidation
journal, July 2017
- Zhang, Zailei; Zhu, Yihan; Asakura, Hiroyuki
- Nature Communications, Vol. 8, Issue 1
Solvent-Free Chemical Approach to Synthesize Various Morphological Co 3 O 4 for CO Oxidation
journal, May 2017
- Wang, Kun; Cao, Yali; Hu, Jindou
- ACS Applied Materials & Interfaces, Vol. 9, Issue 19
Facile general strategy toward hierarchical mesoporous transition metal oxides arrays on three-dimensional macroporous foam with superior lithium storage properties
journal, April 2015
- Zhang, Qiaobao; Wang, Jiexi; Dong, Jichen
- Nano Energy, Vol. 13
Nanoporous networks as caging supports for uniform, surfactant-free Co 3 O 4 nanocrystals and their applications in energy storage and conversion
journal, January 2015
- Byun, Jeehye; Patel, Hasmukh A.; Kim, Dong Jun
- Journal of Materials Chemistry A, Vol. 3, Issue 30
Three-dimensionally ordered mesoporous Co 3 O 4 -supported Au–Pd alloy nanoparticles: High-performance catalysts for methane combustion
journal, December 2015
- Wu, Zhixing; Deng, Jiguang; Liu, Yuxi
- Journal of Catalysis, Vol. 332
Promoting Effects of In 2 O 3 on Co 3 O 4 for CO Oxidation: Tuning O 2 Activation and CO Adsorption Strength Simultaneously
journal, October 2014
- Lou, Yang; Ma, Jian; Cao, Xiaoming
- ACS Catalysis, Vol. 4, Issue 11
Facile Synthesis of Highly Porous Metal Oxides by Mechanochemical Nanocasting
journal, April 2018
- Xiao, Weiming; Yang, Shize; Zhang, Pengfei
- Chemistry of Materials, Vol. 30, Issue 9
Mesoporous cobalt/manganese oxide: a highly selective bifunctional catalyst for amine–imine transformations
journal, January 2018
- Dutta, Biswanath; March, Seth; Achola, Laura
- Green Chemistry, Vol. 20, Issue 14
Highly Dispersed Copper Oxide Clusters as Active Species in Copper-Ceria Catalyst for Preferential Oxidation of Carbon Monoxide
journal, March 2015
- Wang, Wei-Wei; Du, Pei-Pei; Zou, Shi-Hui
- ACS Catalysis, Vol. 5, Issue 4
Polyoxometalate-decorated nanoparticles
journal, January 2012
- Wang, Yifeng; Weinstock, Ira A.
- Chemical Society Reviews, Vol. 41, Issue 22
Nanoarchitectures for Mesoporous Metals
journal, October 2015
- Malgras, Victor; Ataee-Esfahani, Hamed; Wang, Hongjing
- Advanced Materials, Vol. 28, Issue 6
Decoration of one-dimensional MnO 2 with Co 3 O 4 nanoparticles: A heterogeneous interface for remarkably promoting catalytic oxidation activity
journal, December 2016
- Tang, Wenxiang; Yao, Mingshui; Deng, Yuzhou
- Chemical Engineering Journal, Vol. 306
Mesoporous Iron Oxide Synthesized Using Poly(styrene- b -acrylic acid- b -ethylene glycol) Block Copolymer Micelles as Templates for Colorimetric and Electrochemical Detection of Glucose
journal, December 2017
- Tanaka, Shunsuke; Kaneti, Yusuf Valentino; Bhattacharjee, Ripon
- ACS Applied Materials & Interfaces, Vol. 10, Issue 1
Nanocrystals@Hollow Mesoporous Silica Reverse‐Bumpy‐Ball Structure Nanoreactors by a Versatile Microemulsion‐Templated Approach
journal, June 2018
- Shang, Lu; Shi, Run; Waterhouse, Geoffrey I. N.
- Small Methods, Vol. 2, Issue 12
Environmentally benign polyoxometalate materials
journal, March 2015
- Omwoma, Solomon; Gore, Christopher T.; Ji, Yuanchun
- Coordination Chemistry Reviews, Vol. 286
Metal–Organic Framework-Derived Nanoporous Metal Oxides toward Supercapacitor Applications: Progress and Prospects
journal, May 2017
- Salunkhe, Rahul R.; Kaneti, Yusuf V.; Yamauchi, Yusuke
- ACS Nano, Vol. 11, Issue 6
Catalytic activity of mesoporous cobalt oxides with controlled porosity and crystallite sizes: Evaluation using the reduction of 4-nitrophenol
journal, December 2016
- Mogudi, Batsile M.; Ncube, Phendukani; Meijboom, Reinout
- Applied Catalysis B: Environmental, Vol. 198
Recent advances in ordered meso/macroporous metal oxides for heterogeneous catalysis: a review
journal, January 2017
- Wang, Yuan; Arandiyan, Hamidreza; Scott, Jason
- Journal of Materials Chemistry A, Vol. 5, Issue 19
Ultrathin mesoporous Co 3 O 4 nanosheets with excellent photo-/thermo-catalytic activity
journal, January 2016
- Zheng, Yali; Wang, Wenzhong; Jiang, Dong
- Journal of Materials Chemistry A, Vol. 4, Issue 1
Study of catalytic activity at the Ag/Al-SBA-15 catalysts for CO oxidation and selective CO oxidation
journal, January 2016
- Zhang, Xiaodong; Dong, Han; Wang, Yin
- Chemical Engineering Journal, Vol. 283
Synthesis, characterization, and catalytic evaluation of Co 3 O 4 /γ-Al 2 O 3 as methane combustion catalysts: Significance of Co species and the redox cycle
journal, June 2015
- Wang, Qing; Peng, Yue; Fu, Jie
- Applied Catalysis B: Environmental, Vol. 168-169
Co 3 O 4 –CuCoO 2 Nanomesh: An Interface-Enhanced Substrate that Simultaneously Promotes CO Adsorption and O 2 Activation in H 2 Purification
journal, January 2019
- Ding, Junfang; Li, Liping; Zheng, Haorui
- ACS Applied Materials & Interfaces, Vol. 11, Issue 6
In Situ Formation of Cobalt Oxide Nanocubanes as Efficient Oxygen Evolution Catalysts
journal, March 2015
- Hutchings, Gregory S.; Zhang, Yan; Li, Jian
- Journal of the American Chemical Society, Vol. 137, Issue 12
Highly Ordered Mesoporous Cobalt-Containing Oxides: Structure, Catalytic Properties, and Active Sites in Oxidation of Carbon Monoxide
journal, August 2015
- Gu, Dong; Jia, Chun-Jiang; Weidenthaler, Claudia
- Journal of the American Chemical Society, Vol. 137, Issue 35
Hollow Mesoporous Co 3 O 4 –CeO 2 Composite Nanotubes with Open Ends for Efficient Catalytic CO Oxidation
journal, February 2019
- He, Jiaqin; Chen, Dongyun; Li, Najun
- ChemSusChem, Vol. 12, Issue 5
Robust Mesoporous Manganese Oxide Catalysts for Water Oxidation
journal, February 2015
- Kuo, Chung-Hao; Mosa, Islam M.; Poyraz, Altug S.
- ACS Catalysis, Vol. 5, Issue 3
High combustion activity of CH4 and catalluminescence properties of CO oxidation over porous Co3O4 nanorods
journal, November 2011
- Teng, Fei; Chen, Mindong; Li, Guiqing
- Applied Catalysis B: Environmental, Vol. 110
Low-temperature oxidation of CO catalysed by Co3O4 nanorods
journal, April 2009
- Xie, Xiaowei; Li, Yong; Liu, Zhi-Quan
- Nature, Vol. 458, Issue 7239, p. 746-749
Constructing Hierarchical Interfaces: TiO 2 -Supported PtFe–FeO x Nanowires for Room Temperature CO Oxidation
journal, August 2015
- Zhu, Huiyuan; Wu, Zili; Su, Dong
- Journal of the American Chemical Society, Vol. 137, Issue 32
Ordered Crystalline Mesoporous Oxides as Catalysts for CO Oxidation
journal, March 2009
- Ren, Yu; Ma, Zhen; Qian, Linping
- Catalysis Letters, Vol. 131, Issue 1-2
Ordered mesoporous metal oxides: synthesis and applications
journal, January 2012
- Ren, Yu; Ma, Zhen; Bruce, Peter G.
- Chemical Society Reviews, Vol. 41, Issue 14
Highly Ordered Dual Porosity Mesoporous Cobalt Oxide for Sodium-Ion Batteries
journal, November 2015
- Yang, Jianping; Zhou, Tengfei; Zhu, Rui
- Advanced Materials Interfaces, Vol. 3, Issue 3
Operando XAS and NAP-XPS studies of preferential CO oxidation on Co3O4 and CeO2-Co3O4 catalysts
journal, December 2016
- Lukashuk, Liliana; Föttinger, Karin; Kolar, Elisabeth
- Journal of Catalysis, Vol. 344
One-pot and general synthesis of crystalline mesoporous metal oxides nanoparticles by protective etching: potential materials for catalytic applications
journal, January 2015
- Yang, Nating; Pang, Fei; Ge, Jianping
- Journal of Materials Chemistry A, Vol. 3, Issue 3
Co 3 O 4 –SiO 2 Nanocomposite: A Very Active Catalyst for CO Oxidation with Unusual Catalytic Behavior
journal, July 2011
- Jia, Chun-Jiang; Schwickardi, Manfred; Weidenthaler, Claudia
- Journal of the American Chemical Society, Vol. 133, Issue 29
Three-dimensional mesoporous manganese oxides and cobalt oxides: High-efficiency catalysts for the removal of toluene and carbon monoxide
journal, November 2012
- Du, Yucheng; Meng, Qi; Wang, Jinshu
- Microporous and Mesoporous Materials, Vol. 162
POMzites: A Family of Zeolitic Polyoxometalate Frameworks from a Minimal Building Block Library
journal, April 2017
- Boyd, Thomas; Mitchell, Scott G.; Gabb, David
- Journal of the American Chemical Society, Vol. 139, Issue 16
Protocol for the Nanocasting Method: Preparation of Ordered Mesoporous Metal Oxides
journal, September 2016
- Deng, Xiaohui; Chen, Kun; Tüysüz, Harun
- Chemistry of Materials, Vol. 29, Issue 1
Mesoporous Co 3 O 4 and Au/Co 3 O 4 Catalysts for Low-Temperature Oxidation of Trace Ethylene
journal, March 2010
- Ma, Chun Yan; Mu, Zhen; Li, Jin Jun
- Journal of the American Chemical Society, Vol. 132, Issue 8
Immobilization of Ultrafine Metal Nanoparticles to High-Surface-Area Materials and Their Catalytic Applications
journal, August 2016
- Zhu, Qi-Long; Xu, Qiang
- Chem, Vol. 1, Issue 2