skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on November 24, 2020

Title: Structural Evolution During Perovskite Crystal Formation and Degradation: In Situ and Operando X‐Ray Diffraction Studies

Authors:
ORCiD logo [1]; ORCiD logo [1]
  1. SLAC National Accelerator Laboratory 2575 Sand Hill Rd Menlo Park CA 94025 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1575780
Grant/Contract Number:  
DE‐AC36‐08‐GO28308
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Energy Materials
Additional Journal Information:
Journal Name: Advanced Energy Materials; Journal ID: ISSN 1614-6832
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Mundt, Laura E., and Schelhas, Laura T. Structural Evolution During Perovskite Crystal Formation and Degradation: In Situ and Operando X‐Ray Diffraction Studies. Germany: N. p., 2019. Web. doi:10.1002/aenm.201903074.
Mundt, Laura E., & Schelhas, Laura T. Structural Evolution During Perovskite Crystal Formation and Degradation: In Situ and Operando X‐Ray Diffraction Studies. Germany. doi:10.1002/aenm.201903074.
Mundt, Laura E., and Schelhas, Laura T. Mon . "Structural Evolution During Perovskite Crystal Formation and Degradation: In Situ and Operando X‐Ray Diffraction Studies". Germany. doi:10.1002/aenm.201903074.
@article{osti_1575780,
title = {Structural Evolution During Perovskite Crystal Formation and Degradation: In Situ and Operando X‐Ray Diffraction Studies},
author = {Mundt, Laura E. and Schelhas, Laura T.},
abstractNote = {},
doi = {10.1002/aenm.201903074},
journal = {Advanced Energy Materials},
number = ,
volume = ,
place = {Germany},
year = {2019},
month = {11}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on November 24, 2020
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Enhanced perovskite electronic properties via a modified lead( ii ) chloride Lewis acid–base adduct and their effect in high-efficiency perovskite solar cells
journal, January 2017

  • Pham, Ngoc Duy; Tiong, Vincent Tiing; Chen, Peng
  • Journal of Materials Chemistry A, Vol. 5, Issue 10
  • DOI: 10.1039/C6TA11139D

The Impact of Phase Retention on the Structural and Optoelectronic Properties of Metal Halide Perovskites
journal, October 2016

  • Osherov, Anna; Hutter, Eline M.; Galkowski, Krzysztof
  • Advanced Materials, Vol. 28, Issue 48
  • DOI: 10.1002/adma.201604019

Moisture transport, adhesion, and corrosion protection of PV module packaging materials
journal, October 2006


Stabilizing Perovskite Structures by Tuning Tolerance Factor: Formation of Formamidinium and Cesium Lead Iodide Solid-State Alloys
journal, December 2015


Progress on Perovskite Materials and Solar Cells with Mixed Cations and Halide Anions
journal, July 2017

  • Ono, Luis K.; Juarez-Perez, Emilio J.; Qi, Yabing
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 36
  • DOI: 10.1021/acsami.7b06001

Reversible Hydration of CH 3 NH 3 PbI 3 in Films, Single Crystals, and Solar Cells
journal, April 2015


Thermal Phase Transitions in Superlattice Assemblies of Cuboidal CH 3 NH 3 PbI 3 Nanocrystals Followed by Grazing Incidence X-ray Scattering
journal, June 2019

  • Zhang, Yangning; Thomas, Cherrelle J.; Guillaussier, Adrien
  • The Journal of Physical Chemistry C, Vol. 123, Issue 28
  • DOI: 10.1021/acs.jpcc.9b03223

Chemical stability and instability of inorganic halide perovskites
journal, January 2019

  • Zhou, Yuanyuan; Zhao, Yixin
  • Energy & Environmental Science, Vol. 12, Issue 5
  • DOI: 10.1039/C8EE03559H

Solvent-controlled growth of inorganic perovskite films in dry environment for efficient and stable solar cells
journal, June 2018


Influence of Grain Size on Phase Transitions in Halide Perovskite Films
journal, August 2019

  • Stavrakas, Camille; Zelewski, Szymon J.; Frohna, Kyle
  • Advanced Energy Materials, Vol. 9, Issue 35
  • DOI: 10.1002/aenm.201901883

Fabrication of Efficient and Stable CsPbI 3 Perovskite Solar Cells through Cation Exchange Process
journal, August 2019

  • Lau, Cho Fai Jonathan; Wang, Zhiping; Sakai, Nobuya
  • Advanced Energy Materials, Vol. 9, Issue 36
  • DOI: 10.1002/aenm.201901685

Structures, Phase Transitions and Tricritical Behavior of the Hybrid Perovskite Methyl Ammonium Lead Iodide
journal, October 2016

  • Whitfield, P. S.; Herron, N.; Guise, W. E.
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep35685

Manipulating the Mixed‐Perovskite Crystallization Pathway Unveiled by In Situ GIWAXS
journal, April 2019


Emerging Characterizing Techniques in the Fine Structure Observation of Metal Halide Perovskite Crystal
journal, May 2018


Effects of substrate temperature on the crystallization process and properties of mixed-ion perovskite layers
journal, January 2019

  • Zhang, Haiyan; Zhao, Chen; Li, Deng
  • Journal of Materials Chemistry A, Vol. 7, Issue 6
  • DOI: 10.1039/C8TA10170A

Crystallization Kinetics of Organic–Inorganic Trihalide Perovskites and the Role of the Lead Anion in Crystal Growth
journal, February 2015

  • Moore, David T.; Sai, Hiroaki; Tan, Kwan W.
  • Journal of the American Chemical Society, Vol. 137, Issue 6
  • DOI: 10.1021/ja512117e

Structure formation and evolution in semiconductor films for perovskite and organic photovoltaics
journal, March 2017


Photovoltaic behaviour of lead methylammonium triiodide perovskite solar cells down to 80 K
journal, January 2015

  • Zhang, Hua; Qiao, Xianfeng; Shen, Yan
  • Journal of Materials Chemistry A, Vol. 3, Issue 22
  • DOI: 10.1039/C5TA02206A

Transformation from crystalline precursor to perovskite in PbCl2-derived MAPbI3
journal, August 2018


Challenges for commercializing perovskite solar cells
journal, September 2018


Relationships between Lead Halide Perovskite Thin-Film Fabrication, Morphology, and Performance in Solar Cells
journal, November 2015

  • Sharenko, Alexander; Toney, Michael F.
  • Journal of the American Chemical Society, Vol. 138, Issue 2
  • DOI: 10.1021/jacs.5b10723

3D-2D-0D Interface Profiling for Record Efficiency All-Inorganic CsPbBrI 2 Perovskite Solar Cells with Superior Stability
journal, January 2018

  • Zhang, Jingru; Bai, Dongliang; Jin, Zhiwen
  • Advanced Energy Materials, Vol. 8, Issue 15
  • DOI: 10.1002/aenm.201703246

Structural Study on Cubic–Tetragonal Transition of CH 3 NH 3 PbI 3
journal, July 2002

  • Kawamura, Yukihiko; Mashiyama, Hiroyuki; Hasebe, Katsuhiko
  • Journal of the Physical Society of Japan, Vol. 71, Issue 7
  • DOI: 10.1143/JPSJ.71.1694

A Layered Hybrid Perovskite Solar-Cell Absorber with Enhanced Moisture Stability
journal, September 2014

  • Smith, Ian C.; Hoke, Eric T.; Solis-Ibarra, Diego
  • Angewandte Chemie International Edition, Vol. 53, Issue 42
  • DOI: 10.1002/anie.201406466

Structurally Reconstructed CsPbI 2 Br Perovskite for Highly Stable and Square-Centimeter All-Inorganic Perovskite Solar Cells
journal, December 2018


Acetic acid production and glass transition concerns with ethylene-vinyl acetate used in photovoltaic devices
journal, February 2007

  • Kempe, Michael D.; Jorgensen, Gary J.; Terwilliger, Kent M.
  • Solar Energy Materials and Solar Cells, Vol. 91, Issue 4
  • DOI: 10.1016/j.solmat.2006.10.009

Chloride in Lead Chloride-Derived Organo-Metal Halides for Perovskite-Absorber Solar Cells
journal, December 2014

  • Unger, Eva L.; Bowring, Andrea R.; Tassone, Christopher J.
  • Chemistry of Materials, Vol. 26, Issue 24
  • DOI: 10.1021/cm503828b

Scalable Fabrication of Perovskite Solar Cells to Meet Climate Targets
journal, November 2018


Investigation of CH 3 NH 3 PbI 3 Degradation Rates and Mechanisms in Controlled Humidity Environments Using in Situ Techniques
journal, January 2015

  • Yang, Jinli; Siempelkamp, Braden D.; Liu, Dianyi
  • ACS Nano, Vol. 9, Issue 2
  • DOI: 10.1021/nn506864k

Room Temperature Phase Transition in Methylammonium Lead Iodide Perovskite Thin Films Induced by Hydrohalic Acid Additives
journal, September 2016

  • Soe, Chan Myae Myae; Stoumpos, Constantinos C.; Harutyunyan, Boris
  • ChemSusChem, Vol. 9, Issue 18, p. 2656-2665
  • DOI: 10.1002/cssc.201600879

Blade-Coated Hybrid Perovskite Solar Cells with Efficiency > 17%: An In Situ Investigation
journal, March 2018


The Influence of Water Vapor on the Stability and Processing of Hybrid Perovskite Solar Cells Made from Non-Stoichiometric Precursor Mixtures
journal, September 2016


In Situ Identification of Photo- and Moisture-Dependent Phase Evolution of Perovskite Solar Cells
journal, January 2017


CH3NH3PbX3, ein Pb(II)-System mit kubischer Perowskitstruktur / CH3NH3PbX3, a Pb(II)-System with Cubic Perovskite Structure
journal, December 1978


Thermal unequilibrium of strained black CsPbI 3 thin films
journal, July 2019


Interplay of Structural and Optoelectronic Properties in Formamidinium Mixed Tin-Lead Triiodide Perovskites
journal, June 2018

  • Parrott, Elizabeth S.; Green, Thomas; Milot, Rebecca L.
  • Advanced Functional Materials, Vol. 28, Issue 33
  • DOI: 10.1002/adfm.201802803

Roll-to-Roll Printing of Perovskite Solar Cells
journal, September 2018


The phase diagram of a mixed halide (Br, I) hybrid perovskite obtained by synchrotron X-ray diffraction
journal, January 2019

  • Lehmann, Frederike; Franz, Alexandra; Többens, Daniel M.
  • RSC Advances, Vol. 9, Issue 20
  • DOI: 10.1039/C8RA09398A

Recent advances toward high efficiency halide perovskite light emitting diodes: Review and perspective
journal, March 2018


In situ simultaneous photovoltaic and structural evolution of perovskite solar cells during film formation
journal, January 2018

  • Alsari, Mejd; Bikondoa, Oier; Bishop, James
  • Energy & Environmental Science, Vol. 11, Issue 2
  • DOI: 10.1039/C7EE03013D

Complete structure and cation orientation in the perovskite photovoltaic methylammonium lead iodide between 100 and 352 K
journal, January 2015

  • Weller, Mark T.; Weber, Oliver J.; Henry, Paul F.
  • Chemical Communications, Vol. 51, Issue 20
  • DOI: 10.1039/C4CC09944C

Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9%
journal, August 2012

  • Kim, Hui-Seon; Lee, Chang-Ryul; Im, Jeong-Hyeok
  • Scientific Reports, Vol. 2, Issue 1
  • DOI: 10.1038/srep00591

Scalable fabrication of perovskite solar cells
journal, March 2018


Electrochemical mechanisms of leakage-current-enhanced delamination and corrosion in Si photovoltaic modules
journal, December 2018


Kinetics of Ion-Exchange Reactions in Hybrid Organic–Inorganic Perovskite Thin Films Studied by In Situ Real-Time X-ray Scattering
journal, November 2018

  • Greco, Alessandro; Hinderhofer, Alexander; Dar, M. Ibrahim
  • The Journal of Physical Chemistry Letters, Vol. 9, Issue 23
  • DOI: 10.1021/acs.jpclett.8b02916

Switchable photovoltaic windows enabled by reversible photothermal complex dissociation from methylammonium lead iodide
journal, November 2017


Hybrid Perovskite Thin-Film Photovoltaics: In Situ Diagnostics and Importance of the Precursor Solvate Phases
journal, November 2016

  • Munir, Rahim; Sheikh, Arif D.; Abdelsamie, Maged
  • Advanced Materials, Vol. 29, Issue 2
  • DOI: 10.1002/adma.201604113

One-Year stable perovskite solar cells by 2D/3D interface engineering
journal, June 2017

  • Grancini, G.; Roldán-Carmona, C.; Zimmermann, I.
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms15684

Shedding Light on the Moisture Stability of 3D/2D Hybrid Perovskite Heterojunction Thin Films
journal, January 2019

  • Schlipf, Johannes; Hu, Yinghong; Pratap, Shambhavi
  • ACS Applied Energy Materials, Vol. 2, Issue 2
  • DOI: 10.1021/acsaem.9b00005

Thermal engineering of FAPbI3 perovskite material via radiative thermal annealing and in situ XRD
journal, January 2017

  • Pool, Vanessa L.; Dou, Benjia; Van Campen, Douglas G.
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms14075

Materials toward the Upscaling of Perovskite Solar Cells: Progress, Challenges, and Strategies
journal, November 2018

  • Wang, Fangfang; Cao, Yezhou; Chen, Cheng
  • Advanced Functional Materials, Vol. 28, Issue 52
  • DOI: 10.1002/adfm.201803753

Caffeine Improves the Performance and Thermal Stability of Perovskite Solar Cells
journal, June 2019


A Review of Perovskites Solar Cell Stability
journal, February 2019

  • Wang, Rui; Mujahid, Muhammad; Duan, Yu
  • Advanced Functional Materials, Vol. 29, Issue 47
  • DOI: 10.1002/adfm.201808843

Monitoring a Silent Phase Transition in CH 3 NH 3 PbI 3 Solar Cells via Operando X-ray Diffraction
journal, October 2016


Phase Transition Control for High-Performance Blade-Coated Perovskite Solar Cells
journal, July 2018


Insights into operational stability and processing of halide perovskite active layers
journal, January 2019

  • Schelhas, Laura T.; Li, Zhen; Christians, Jeffrey A.
  • Energy & Environmental Science, Vol. 12, Issue 4
  • DOI: 10.1039/C8EE03051K

Ionic and Optical Properties of Methylammonium Lead Iodide Perovskite across the Tetragonal-Cubic Structural Phase Transition
journal, September 2016


Thermal Stability of Mixed Cation Metal Halide Perovskites in Air
journal, January 2018

  • Tan, Wanliang; Bowring, Andrea R.; Meng, Andrew C.
  • ACS Applied Materials & Interfaces, Vol. 10, Issue 6
  • DOI: 10.1021/acsami.7b15263

Understanding Degradation Mechanisms and Improving Stability of Perovskite Photovoltaics
journal, November 2018


Lattice strain causes non-radiative losses in halide perovskites
journal, January 2019

  • Jones, Timothy W.; Osherov, Anna; Alsari, Mejd
  • Energy & Environmental Science, Vol. 12, Issue 2
  • DOI: 10.1039/C8EE02751J

Detailed Balance Analysis of Photovoltaic Windows
journal, August 2019


Structural and chemical evolution of methylammonium lead halide perovskites during thermal processing from solution
journal, January 2016

  • Nenon, David P.; Christians, Jeffrey A.; Wheeler, Lance M.
  • Energy & Environmental Science, Vol. 9, Issue 6
  • DOI: 10.1039/C6EE01047D

Antisolvent processing of lead halide perovskite thin films studied by in situ X-ray diffraction
journal, January 2018

  • Bruening, Karsten; Tassone, Christopher J.
  • Journal of Materials Chemistry A, Vol. 6, Issue 39
  • DOI: 10.1039/C8TA06025H

Uncovering the Veil of the Degradation in Perovskite CH 3 NH 3 PbI 3 upon Humidity Exposure: A First-Principles Study
journal, July 2015

  • Tong, Chuan-Jia; Geng, Wei; Tang, Zhen-Kun
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 16
  • DOI: 10.1021/acs.jpclett.5b01544

Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber
journal, October 2013

  • Stranks, S. D.; Eperon, G. E.; Grancini, G.
  • Science, Vol. 342, Issue 6156, p. 341-344
  • DOI: 10.1126/science.1243982

In situ X-ray scattering of perovskite solar cell active layers roll-to-roll coated on flexible substrates
journal, January 2016

  • Rossander, Lea H.; Larsen-Olsen, Thue T.; Dam, Henrik F.
  • CrystEngComm, Vol. 18, Issue 27
  • DOI: 10.1039/C6CE00382F

Synthesis and crystal chemistry of the hybrid perovskite (CH3NH3)PbI3 for solid-state sensitised solar cell applications
journal, January 2013

  • Baikie, Tom; Fang, Yanan; Kadro, Jeannette M.
  • Journal of Materials Chemistry A, Vol. 1, Issue 18
  • DOI: 10.1039/c3ta10518k

Tracking Structural Phase Transitions in Lead‐Halide Perovskites by Means of Thermal Expansion
journal, April 2019


Annealing Induced Re-crystallization in CH3NH3PbI3−xClx for High Performance Perovskite Solar Cells
journal, April 2017

  • Yang, Yingguo; Feng, Shanglei; Li, Meng
  • Scientific Reports, Vol. 7, Issue 1
  • DOI: 10.1038/srep46724

Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites
journal, October 2012


In Situ Observation of Crystallization Dynamics and Grain Orientation in Sequential Deposition of Metal Halide Perovskites
journal, June 2019

  • Meng, Ke; Wang, Xiao; Xu, Qiaofei
  • Advanced Functional Materials, Vol. 29, Issue 35
  • DOI: 10.1002/adfm.201902319

The Many Faces of Mixed Ion Perovskites: Unraveling and Understanding the Crystallization Process
journal, November 2017


Efficient and Stable Inorganic Perovskite Solar Cells Manufactured by Pulsed Flash Infrared Annealing
journal, September 2018

  • Sanchez, Sandy; Christoph, Neururer; Grobety, Bernard
  • Advanced Energy Materials, Vol. 8, Issue 30
  • DOI: 10.1002/aenm.201802060

Determination of Thermal Expansion Coefficients and Locating the Temperature-Induced Phase Transition in Methylammonium Lead Perovskites Using X-ray Diffraction
journal, October 2015


Characterization of an abnormal photoluminescence behavior upon crystal-phase transition of perovskite CH 3 NH 3 PbI 3
journal, January 2015

  • Kong, Weiguang; Ye, Zhenyu; Qi, Zhen
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 25
  • DOI: 10.1039/C5CP02605A

Thermochromic halide perovskite solar cells
journal, January 2018


Alkylammonium lead halides. Part 2. CH 3 NH 3 PbX 3 (X = Cl, Br, I) perovskites: cuboctahedral halide cages with isotropic cation reorientation
journal, March 1990

  • Knop, Osvald; Wasylishen, Roderick E.; White, Mary Anne
  • Canadian Journal of Chemistry, Vol. 68, Issue 3
  • DOI: 10.1139/v90-063

Thermochromic Perovskite Inks for Reversible Smart Window Applications
journal, April 2017


Structural and optical properties of methylammonium lead iodide across the tetragonal to cubic phase transition: implications for perovskite solar cells
journal, January 2016

  • Quarti, Claudio; Mosconi, Edoardo; Ball, James M.
  • Energy & Environmental Science, Vol. 9, Issue 1
  • DOI: 10.1039/C5EE02925B

Perovskite-Inspired Photovoltaic Materials: Toward Best Practices in Materials Characterization and Calculations
journal, February 2017


Lattice dynamics and the nature of structural transitions in organolead halide perovskites
journal, September 2016


Performance boosting strategy for perovskite light-emitting diodes
journal, September 2019

  • Sim, Kihyung; Jun, Taehwan; Bang, Joonho
  • Applied Physics Reviews, Vol. 6, Issue 3
  • DOI: 10.1063/1.5098871

Beneficial impact of materials with reduced dimensionality on the stability of perovskite-based photovoltaics
journal, August 2019

  • Petrović, Miloš; Rogdakis, Konstantinos; Kymakis, Emmanuel
  • Journal of Physics: Energy, Vol. 1, Issue 4
  • DOI: 10.1088/2515-7655/ab3585

Environmental Effects on the Photophysics of Organic–Inorganic Halide Perovskites
journal, June 2015

  • Galisteo-López, Juan F.; Anaya, M.; Calvo, M. E.
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 12
  • DOI: 10.1021/acs.jpclett.5b00785

Interaction of Organic Cation with Water Molecule in Perovskite MAPbI 3 : From Dynamic Orientational Disorder to Hydrogen Bonding
journal, October 2016