Silver-Containing α-MnO2 Nanorods: Electrochemistry in Rechargeable Aqueous Zn-MnO2 Batteries
Abstract
The reduction and subsequent oxidation of silver hollandite nanorods, Ag1.5Mn8O16, were explored in aqueous ZnSO4 electrolyte for the first time. The impact of reduction on the electrodes was probed where images of recovered cathodes were collected to evaluate the changes in morphology, structural, and electrochemical properties as a function of varying potential. Ag metal particle formation upon reduction was observed on reduction through a reduction-displacement reaction as confirmed by SEM/EDS, XRD, and XAS results accompanied by a decrease in charge transfer impedance, as determined by electrochemical impedance spectroscopy. On charge, in contrast to the reduction/oxidation electrochemistry in non-aqueous media where irreversible formation of silver metal was observed, disappearance of the silver metal is observed indicating oxidation of the silver centers is facilitated in aqueous electrolyte.
- Authors:
-
[1];
[2];
[3];
[4];
[4];
[5]
- Brookhaven National Lab. (BNL), Upton, NY (United States). Energy Sciences Directorate
- Stony Brook Univ., Stony Brook, NY (United States). Dept. of Chemistry
- Stony Brook Univ., Stony Brook, NY (United States). Dept. of Materials Science and Chemical Engineering
- Brookhaven National Lab. (BNL), Upton, NY (United States). Energy Sciences Directorate; Stony Brook Univ., Stony Brook, NY (United States). Dept. of Chemistry and Dept. of Materials Science and Chemical Engineering
- Stony Brook Univ., Stony Brook, NY (United States). Dept. of Chemistry and Dept. of Materials Science and Chemical Engineering
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2mt); Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1575426
- Report Number(s):
- BNL-212371-2019-JAAM
Journal ID: ISSN 0013-4651
- Grant/Contract Number:
- SC0012704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the Electrochemical Society
- Additional Journal Information:
- Journal Volume: 166; Journal Issue: 15; Journal ID: ISSN 0013-4651
- Publisher:
- The Electrochemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 77 NANOSCIENCE AND NANOTECHNOLOGY; batteries; batteries - aqueous; energy storage; aqueous battery; manganese oxide; zinc-ion battery
Citation Formats
Wang, Lei, Wu, Qiyuan, Abraham, Alyson, West, Patrick J., Housel, Lisa M., Singh, Gurpreet, Sadique, Nahian, Quilty, Calvin D., Wu, Daren, Takeuchi, Esther S., Marschilok, Amy C., and Takeuchi, Kenneth J. Silver-Containing α-MnO2 Nanorods: Electrochemistry in Rechargeable Aqueous Zn-MnO2 Batteries. United States: N. p., 2019.
Web. doi:10.1149/2.0101915jes.
Wang, Lei, Wu, Qiyuan, Abraham, Alyson, West, Patrick J., Housel, Lisa M., Singh, Gurpreet, Sadique, Nahian, Quilty, Calvin D., Wu, Daren, Takeuchi, Esther S., Marschilok, Amy C., & Takeuchi, Kenneth J. Silver-Containing α-MnO2 Nanorods: Electrochemistry in Rechargeable Aqueous Zn-MnO2 Batteries. United States. https://doi.org/10.1149/2.0101915jes
Wang, Lei, Wu, Qiyuan, Abraham, Alyson, West, Patrick J., Housel, Lisa M., Singh, Gurpreet, Sadique, Nahian, Quilty, Calvin D., Wu, Daren, Takeuchi, Esther S., Marschilok, Amy C., and Takeuchi, Kenneth J. Wed .
"Silver-Containing α-MnO2 Nanorods: Electrochemistry in Rechargeable Aqueous Zn-MnO2 Batteries". United States. https://doi.org/10.1149/2.0101915jes. https://www.osti.gov/servlets/purl/1575426.
@article{osti_1575426,
title = {Silver-Containing α-MnO2 Nanorods: Electrochemistry in Rechargeable Aqueous Zn-MnO2 Batteries},
author = {Wang, Lei and Wu, Qiyuan and Abraham, Alyson and West, Patrick J. and Housel, Lisa M. and Singh, Gurpreet and Sadique, Nahian and Quilty, Calvin D. and Wu, Daren and Takeuchi, Esther S. and Marschilok, Amy C. and Takeuchi, Kenneth J.},
abstractNote = {The reduction and subsequent oxidation of silver hollandite nanorods, Ag1.5Mn8O16, were explored in aqueous ZnSO4 electrolyte for the first time. The impact of reduction on the electrodes was probed where images of recovered cathodes were collected to evaluate the changes in morphology, structural, and electrochemical properties as a function of varying potential. Ag metal particle formation upon reduction was observed on reduction through a reduction-displacement reaction as confirmed by SEM/EDS, XRD, and XAS results accompanied by a decrease in charge transfer impedance, as determined by electrochemical impedance spectroscopy. On charge, in contrast to the reduction/oxidation electrochemistry in non-aqueous media where irreversible formation of silver metal was observed, disappearance of the silver metal is observed indicating oxidation of the silver centers is facilitated in aqueous electrolyte.},
doi = {10.1149/2.0101915jes},
journal = {Journal of the Electrochemical Society},
number = 15,
volume = 166,
place = {United States},
year = {2019},
month = {10}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 4 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Reversible aqueous zinc/manganese oxide energy storage from conversion reactions
journal, April 2016
- Pan, Huilin; Shao, Yuyan; Yan, Pengfei
- Nature Energy, Vol. 1, Issue 5
Energetic Zinc Ion Chemistry: The Rechargeable Zinc Ion Battery
journal, December 2011
- Xu, Chengjun; Li, Baohua; Du, Hongda
- Angewandte Chemie International Edition, Vol. 51, Issue 4
Combining battery-like and pseudocapacitive charge storage in 3D MnO x @carbon electrode architectures for zinc-ion cells
journal, January 2018
- Ko, Jesse S.; Sassin, Megan B.; Parker, Joseph F.
- Sustainable Energy & Fuels, Vol. 2, Issue 3
Suppressing Manganese Dissolution in Potassium Manganate with Rich Oxygen Defects Engaged High‐Energy‐Density and Durable Aqueous Zinc‐Ion Battery
journal, February 2019
- Fang, Guozhao; Zhu, Chuyu; Chen, Minghui
- Advanced Functional Materials, Vol. 29, Issue 15
Recent Advances in Aqueous Zinc-Ion Batteries
journal, September 2018
- Fang, Guozhao; Zhou, Jiang; Pan, Anqiang
- ACS Energy Letters, Vol. 3, Issue 10
Silver-Containing α-MnO 2 Nanorods: Electrochemistry in Na-Based Battery Systems
journal, September 2016
- Huang, Jianping; Poyraz, Altug S.; Lee, Seung-Yong
- ACS Applied Materials & Interfaces, Vol. 9, Issue 5
Zn/MnO 2 Battery Chemistry With H + and Zn 2+ Coinsertion
journal, July 2017
- Sun, Wei; Wang, Fei; Hou, Singyuk
- Journal of the American Chemical Society, Vol. 139, Issue 29
Reaction Mechanisms for Long-Life Rechargeable Zn/MnO 2 Batteries
journal, June 2018
- Li, Yun; Wang, Shanyu; Salvador, James R.
- Chemistry of Materials, Vol. 31, Issue 6
In situ visualization of Li/Ag2VP2O8 batteries revealing rate-dependent discharge mechanism
journal, January 2015
- Kirshenbaum, K.; Bock, D. C.; Lee, C. -Y.
- Science, Vol. 347, Issue 6218
A layered δ-MnO 2 nanoflake cathode with high zinc-storage capacities for eco-friendly battery applications
journal, November 2015
- Alfaruqi, Muhammad Hilmy; Gim, Jihyeon; Kim, Sungjin
- Electrochemistry Communications, Vol. 60
Rechargeable aqueous zinc-manganese dioxide batteries with high energy and power densities
journal, September 2017
- Zhang, Ning; Cheng, Fangyi; Liu, Junxiang
- Nature Communications, Vol. 8, Issue 1
Investigation of α-MnO 2 Tunneled Structures as Model Cation Hosts for Energy Storage
journal, February 2018
- Housel, Lisa M.; Wang, Lei; Abraham, Alyson
- Accounts of Chemical Research, Vol. 51, Issue 3
Electrochemically-induced reversible transition from the tunneled to layered polymorphs of manganese dioxide
journal, August 2014
- Lee, Boeun; Yoon, Chong Seung; Lee, Hae Ri
- Scientific Reports, Vol. 4, Issue 1
Enhanced reversible divalent zinc storage in a structurally stable α-MnO 2 nanorod electrode
journal, August 2015
- Alfaruqi, Muhammad Hilmy; Gim, Jihyeon; Kim, Sungjin
- Journal of Power Sources, Vol. 288
The Electrochemistry of Silver Hollandite Nanorods, Ag x Mn 8 O 16 : Enhancement of Electrochemical Battery Performance via Dimensional and Compositional Control
journal, January 2013
- Takeuchi, Kenneth J.; Yau, Shali Z.; Subramanian, Aditya
- Journal of The Electrochemical Society, Vol. 160, Issue 5
The Effect of Silver Ion Occupancy on Hollandite Lattice Structure
journal, January 2018
- Brady, Alexander B.; Huang, Jianping; Durham, Jessica L.
- MRS Advances, Vol. 3, Issue 10
Electrochemical Reduction of Silver Vanadium Phosphorus Oxide, Ag 2 VO 2 PO 4 : The Formation of Electrically Conductive Metallic Silver Nanoparticles
journal, October 2009
- Takeuchi, Esther S.; Marschilok, Amy C.; Tanzil, Kevin
- Chemistry of Materials, Vol. 21, Issue 20
Visualization of lithium-ion transport and phase evolution within and between manganese oxide nanorods
journal, May 2017
- Xu, Feng; Wu, Lijun; Meng, Qingping
- Nature Communications, Vol. 8, Issue 1
Observation of combination displacement/intercalation reaction in aqueous zinc-ion battery
journal, March 2019
- Shan, Lutong; Yang, Yongqiang; Zhang, Wanying
- Energy Storage Materials, Vol. 18
Reversible Zn-driven reduction displacement reaction in aqueous zinc-ion battery
journal, January 2019
- Shan, Lutong; Zhou, Jiang; Han, Mingming
- Journal of Materials Chemistry A, Vol. 7, Issue 13
V2O5 Nanospheres with Mixed Vanadium Valences as High Electrochemically Active Aqueous Zinc-Ion Battery Cathode
journal, March 2019
- Liu, Fei; Chen, Zixian; Fang, Guozhao
- Nano-Micro Letters, Vol. 11, Issue 1
Synthetic Control of Composition and Crystallite Size of Silver Hollandite, Ag x Mn 8 O 16 : Impact on Electrochemistry
journal, September 2012
- Takeuchi, Kenneth J.; Yau, Shali Z.; Menard, Melissa C.
- ACS Applied Materials & Interfaces, Vol. 4, Issue 10
Ag1.8Mn8O16: Square Planar Coordinated Ag⊕ Ions in the Channels of a Novel Hollandite Variant
journal, November 1984
- Chang, Fung Ming; Jansen, Martin
- Angewandte Chemie International Edition in English, Vol. 23, Issue 11
Assessment of the corrosion protection of aluminium substrates by a Mg-rich primer: EIS, SVET and SECM study
journal, October 2008
- Simões, Alda; Battocchi, Dante; Tallman, Dennis
- Progress in Organic Coatings, Vol. 63, Issue 3
Localized Corrosion of Magnesium in Chloride-Containing Electrolyte Studied by a Scanning Vibrating Electrode Technique
journal, January 2008
- Williams, Geraint; Neil McMurray, H.
- Journal of The Electrochemical Society, Vol. 155, Issue 7
Effect of aluminium spacer on galvanic corrosion between magnesium and mild steel using numerical model and SVET experiments
journal, September 2012
- Deshpande, Kiran B.
- Corrosion Science, Vol. 62
An Ultrasensitive Vibrating Probe for Measuring Steady Extracellular Currents
journal, November 1974
- Jaffe, L. F.
- The Journal of Cell Biology, Vol. 63, Issue 2
Effective recycling of manganese oxide cathodes for lithium based batteries
journal, January 2016
- Poyraz, Altug S.; Huang, Jianping; Cheng, Shaobo
- Green Chemistry, Vol. 18, Issue 11
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005
- Ravel, B.; Newville, M.
- Journal of Synchrotron Radiation, Vol. 12, Issue 4
Capacity Retention for (De)lithiation of Silver Containing α-MnO 2 : Impact of Structural Distortion and Transition Metal Dissolution
journal, January 2018
- Huang, Jianping; Housel, Lisa M.; Quilty, Calvin D.
- Journal of The Electrochemical Society, Vol. 165, Issue 11
Synthesis and Characterization of Ag−Hollandite Nanofibers and Its Catalytic Application in Ethanol Oxidation
journal, August 2007
- Chen, Junli; Tang, Xingfu; Liu, Junlong
- Chemistry of Materials, Vol. 19, Issue 17
ESCA and thermodynamic studies of alkali metal ion exchange reactions on an α-MnO2 phase with the tunnel structure
journal, January 2000
- Tanaka, Y.; Tsuji, M.; Tamaura, Y.
- Physical Chemistry Chemical Physics, Vol. 2, Issue 7
Large-Scale Synthesis of Silver Manganese Oxide Nanofibers and Their Oxygen Reduction Properties
journal, November 2013
- Huang, Hui; Meng, Yongtao; Labonte, Alec
- The Journal of Physical Chemistry C, Vol. 117, Issue 48
Electrochemical reduction of Ag 2 VP 2 O 8 composite electrodes visualized via in situ energy dispersive X-ray diffraction (EDXRD): unexpected conductive additive effects
journal, January 2015
- Kirshenbaum, Kevin C.; Bock, David C.; Zhong, Zhong
- Journal of Materials Chemistry A, Vol. 3, Issue 35
Inhibition of Aluminium Alloy AA2024-T3 pitting corrosion by copper complexing compounds
journal, August 2010
- Williams, Geraint; Coleman, Andrew J.; McMurray, H. Neil
- Electrochimica Acta, Vol. 55, Issue 20
A SVET study of the inhibitive effects of benzotriazole and cerium chloride solely and combined on an aluminium/copper galvanic coupling model
journal, September 2016
- Coelho, L. B.; Mouanga, M.; Druart, M. -E.
- Corrosion Science, Vol. 110
Synthesis and Characterization of Ag—Hollandite Nanofibers and Its Catalytic Application in Ethanol Oxidation.
journal, October 2007
- Chen, Junli; Tang, Xingfu; Liu, Junlong
- ChemInform, Vol. 38, Issue 44