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Title: Long-term chemothermal stability of delithiated NCA in polymer solid-state batteries

Abstract

Changes in nickel oxidation state of chemically delithiated Li 0.3 Ni 0.8 Co 0.15 Al 0.05 O 2 (NCA) in bulk and surface after 35 days @ 80 °C are strongly depending on the type of polymer and lithium salt in the catholyte matrix.

Authors:
ORCiD logo [1];  [2];  [3];  [3];  [4];  [4]; ORCiD logo [3];  [5]; ORCiD logo [6]; ORCiD logo [3]
  1. Robert Bosch LLC, Research and Technology Center, Sunnyvale, USA, Dept. of Mech. Engineering, Karlsruhe Institute of Technology (KIT)
  2. Robert Bosch LLC, Research and Technology Center, Sunnyvale, USA, Institute of Physics and Chemistry of Materials of Strasbourg (IPCMS), UMR 7504
  3. Robert Bosch LLC, Research and Technology Center, Sunnyvale, USA
  4. Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Menlo Park, USA
  5. Dept. of Mech. Engineering, Karlsruhe Institute of Technology (KIT), Karlsruhe 76131, Germany, Materials Research Institute
  6. Lawrence Berkeley National Laboratory, Energy Storage and Distributed Resources Division, University of California, Berkeley, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1575301
Grant/Contract Number:  
AC02-05CH11231; AC02-76SF00515
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Name: Journal of Materials Chemistry. A Journal Volume: 7 Journal Issue: 47; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Besli, Münir M., Usubelli, Camille, Metzger, Michael, Hellstrom, Sondra, Sainio, Sami, Nordlund, Dennis, Christensen, Jake, Schneider, Gerhard, Doeff, Marca M., and Kuppan, Saravanan. Long-term chemothermal stability of delithiated NCA in polymer solid-state batteries. United Kingdom: N. p., 2019. Web. doi:10.1039/C9TA11103D.
Besli, Münir M., Usubelli, Camille, Metzger, Michael, Hellstrom, Sondra, Sainio, Sami, Nordlund, Dennis, Christensen, Jake, Schneider, Gerhard, Doeff, Marca M., & Kuppan, Saravanan. Long-term chemothermal stability of delithiated NCA in polymer solid-state batteries. United Kingdom. doi:10.1039/C9TA11103D.
Besli, Münir M., Usubelli, Camille, Metzger, Michael, Hellstrom, Sondra, Sainio, Sami, Nordlund, Dennis, Christensen, Jake, Schneider, Gerhard, Doeff, Marca M., and Kuppan, Saravanan. Tue . "Long-term chemothermal stability of delithiated NCA in polymer solid-state batteries". United Kingdom. doi:10.1039/C9TA11103D.
@article{osti_1575301,
title = {Long-term chemothermal stability of delithiated NCA in polymer solid-state batteries},
author = {Besli, Münir M. and Usubelli, Camille and Metzger, Michael and Hellstrom, Sondra and Sainio, Sami and Nordlund, Dennis and Christensen, Jake and Schneider, Gerhard and Doeff, Marca M. and Kuppan, Saravanan},
abstractNote = {Changes in nickel oxidation state of chemically delithiated Li 0.3 Ni 0.8 Co 0.15 Al 0.05 O 2 (NCA) in bulk and surface after 35 days @ 80 °C are strongly depending on the type of polymer and lithium salt in the catholyte matrix.},
doi = {10.1039/C9TA11103D},
journal = {Journal of Materials Chemistry. A},
number = 47,
volume = 7,
place = {United Kingdom},
year = {2019},
month = {12}
}

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