Revealing electrolyte oxidation via carbonate dehydrogenation on Ni-based oxides in Li-ion batteries by in situ Fourier transform infrared spectroscopy
Abstract
Carbonate oxidation via dehydrogenation on LiNi 0.8 Co 0.1 Mn 0.1 O 2 at voltages as low as 3.8 V Li was revealed by in situ FT-IR measurements.
- Authors:
-
- Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, USA
- Research Laboratory of Electronics, Massachusetts Institute of Technology, Cambridge, USA, Department of Applied Chemistry
- Research Laboratory of Electronics, Massachusetts Institute of Technology, Cambridge, USA
- Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, USA, Research Laboratory of Electronics
- Department of Material Science and Engineering, Massachusetts Institute of Technology, Cambridge, USA
- Department of Chemical Engineering, Massachusetts Institute of Technology, Cambridge, USA
- BMW Group, 80788 München, Germany
- Department of Chemical Engineering, Massachusetts Institute of Technology, Cambridge, USA, Department of Mathematics
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1575298
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Published Article
- Journal Name:
- Energy & Environmental Science
- Additional Journal Information:
- Journal Name: Energy & Environmental Science Journal Volume: 13 Journal Issue: 1; Journal ID: ISSN 1754-5692
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
Citation Formats
Zhang, Yirui, Katayama, Yu, Tatara, Ryoichi, Giordano, Livia, Yu, Yang, Fraggedakis, Dimitrios, Sun, Jame Guangwen, Maglia, Filippo, Jung, Roland, Bazant, Martin Z., and Shao-Horn, Yang. Revealing electrolyte oxidation via carbonate dehydrogenation on Ni-based oxides in Li-ion batteries by in situ Fourier transform infrared spectroscopy. United Kingdom: N. p., 2020.
Web. doi:10.1039/C9EE02543J.
Zhang, Yirui, Katayama, Yu, Tatara, Ryoichi, Giordano, Livia, Yu, Yang, Fraggedakis, Dimitrios, Sun, Jame Guangwen, Maglia, Filippo, Jung, Roland, Bazant, Martin Z., & Shao-Horn, Yang. Revealing electrolyte oxidation via carbonate dehydrogenation on Ni-based oxides in Li-ion batteries by in situ Fourier transform infrared spectroscopy. United Kingdom. doi:10.1039/C9EE02543J.
Zhang, Yirui, Katayama, Yu, Tatara, Ryoichi, Giordano, Livia, Yu, Yang, Fraggedakis, Dimitrios, Sun, Jame Guangwen, Maglia, Filippo, Jung, Roland, Bazant, Martin Z., and Shao-Horn, Yang. Tue .
"Revealing electrolyte oxidation via carbonate dehydrogenation on Ni-based oxides in Li-ion batteries by in situ Fourier transform infrared spectroscopy". United Kingdom. doi:10.1039/C9EE02543J.
@article{osti_1575298,
title = {Revealing electrolyte oxidation via carbonate dehydrogenation on Ni-based oxides in Li-ion batteries by in situ Fourier transform infrared spectroscopy},
author = {Zhang, Yirui and Katayama, Yu and Tatara, Ryoichi and Giordano, Livia and Yu, Yang and Fraggedakis, Dimitrios and Sun, Jame Guangwen and Maglia, Filippo and Jung, Roland and Bazant, Martin Z. and Shao-Horn, Yang},
abstractNote = {Carbonate oxidation via dehydrogenation on LiNi 0.8 Co 0.1 Mn 0.1 O 2 at voltages as low as 3.8 V Li was revealed by in situ FT-IR measurements.},
doi = {10.1039/C9EE02543J},
journal = {Energy & Environmental Science},
number = 1,
volume = 13,
place = {United Kingdom},
year = {2020},
month = {1}
}
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DOI: 10.1039/C9EE02543J
DOI: 10.1039/C9EE02543J
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Works referenced in this record:
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
In-situ Fourier transform infrared spectroscopic analysis on dynamic behavior of electrolyte solution on LiFePO4 cathode
journal, October 2013
- Akita, Yasuhiro; Segawa, Midori; Munakata, Hirokazu
- Journal of Power Sources, Vol. 239
Cycle life improvement of ZrO2-coated spherical LiNi1/3Co1/3Mn1/3O2 cathode material for lithium ion batteries
journal, March 2009
- Hu, Shao-Kang; Cheng, Geng-Hao; Cheng, Ming-Yao
- Journal of Power Sources, Vol. 188, Issue 2
Solvate Structures and Computational/Spectroscopic Characterization of LiPF 6 Electrolytes
journal, April 2015
- Han, Sang-Don; Yun, Sung-Hyun; Borodin, Oleg
- The Journal of Physical Chemistry C, Vol. 119, Issue 16
Comparison of Al2O3- and AlPO4-coated LiCoO2 cathode materials for a Li-ion cell
journal, August 2005
- Cho, Jaephil; Kim, Tae-Gon; Kim, Chunjoong
- Journal of Power Sources, Vol. 146, Issue 1-2
Novel LiCoO2 Cathode Material with Al2O3 Coating for a Li Ion Cell
journal, December 2000
- Cho, Jaephil; Kim, Yong Jeong; Park, Byungwoo
- Chemistry of Materials, Vol. 12, Issue 12, p. 3788-3791
Synthesis of Ni-Rich Thin-Film Cathode as Model System for Lithium Ion Batteries
journal, January 2019
- Phillip, Nathan D.; Ruther, Rose E.; Sang, Xiahan
- ACS Applied Energy Materials, Vol. 2, Issue 2
Review—Superconcentrated Electrolytes for Lithium Batteries
journal, January 2015
- Yamada, Yuki; Yamada, Atsuo
- Journal of The Electrochemical Society, Vol. 162, Issue 14
Optimization of reference electrode position in a three-electrode cell for impedance measurements in lithium-ion rechargeable battery by finite element method
journal, August 2015
- Hoshi, Yoshinao; Narita, Yuki; Honda, Keiichiro
- Journal of Power Sources, Vol. 288
A novel concentration-gradient Li[Ni0.83Co0.07Mn0.10]O2 cathode material for high-energy lithium-ion batteries
journal, January 2011
- Sun, Yang-Kook; Lee, Bo-Ram; Noh, Hyung-Ju
- Journal of Materials Chemistry, Vol. 21, Issue 27
Improved Cycle Performance of LiNi 0.8 Co 0.1 Mn 0.1 O 2 Positive Electrode Material in Highly Concentrated LiBF 4 /DMC
journal, January 2019
- Cao, Ziyang; Hashinokuchi, Michihiro; Doi, Takayuki
- Journal of The Electrochemical Society, Vol. 166, Issue 2
Measurement of the electrochemical oxidation of organic electrolytes used in lithium batteries by microelectrode
journal, January 2001
- Egashira, Minato; Takahashi, Hideki; Okada, Shigeto
- Journal of Power Sources, Vol. 92, Issue 1-2
Editors' Choice—Coating-Dependent Electrode-Electrolyte Interface for Ni-Rich Positive Electrodes in Li-Ion Batteries
journal, January 2019
- Karayaylali, Pinar; Tatara, Ryoichi; Zhang, Yirui
- Journal of The Electrochemical Society, Vol. 166, Issue 6
Measuring Oxygen Release from Delithiated LiNi x Mn y Co 1-x-y O 2 and Its Effects on the Performance of High Voltage Li-Ion Cells
journal, January 2017
- Xiong, D. J.; Ellis, L. D.; Li, J.
- Journal of The Electrochemical Society, Vol. 164, Issue 13
Electron-energy-loss spectra and the structural stability of nickel oxide: An LSDA+U study
journal, January 1998
- Dudarev, S. L.; Botton, G. A.; Savrasov, S. Y.
- Physical Review B, Vol. 57, Issue 3, p. 1505-1509
The structure–activity relationship studies of binary room temperature complex electrolytes based on LiTFSI and organic compounds with acylamino group
journal, July 2007
- Chen, Renjie; Wu, Feng; Li, Li
- Vibrational Spectroscopy, Vol. 44, Issue 2
Singlet Oxygen Reactivity with Carbonate Solvents Used for Li-Ion Battery Electrolytes
journal, October 2018
- Freiberg, Anna T. S.; Roos, Matthias K.; Wandt, Johannes
- The Journal of Physical Chemistry A, Vol. 122, Issue 45
Studies on electrochemical oxidation of non-aqueous electrolyte on the LiCoO2 thin film electrode
journal, December 1996
- Kanamura, Kiyoshi; Toriyama, Shigetaka; Shiraishi, Soshi
- Journal of Electroanalytical Chemistry, Vol. 419, Issue 1
High-voltage performance of concentration-gradient Li[Ni0.67Co0.15Mn0.18]O2 cathode material for lithium-ion batteries
journal, December 2010
- Sun, Yang-Kook; Kim, Dong-Hui; Jung, Hun-Gi
- Electrochimica Acta, Vol. 55, Issue 28
Three-Electrode Setups for Lithium-Ion Batteries: II. Experimental Study of Different Reference Electrode Designs and Their Implications for Half-Cell Impedance Spectra
journal, December 2016
- Costard, J.; Ender, M.; Weiss, M.
- Journal of The Electrochemical Society, Vol. 164, Issue 2
Ab initiomolecular dynamics for liquid metals
journal, January 1993
- Kresse, G.; Hafner, J.
- Physical Review B, Vol. 47, Issue 1, p. 558-561
Surface layer formation of LiCoO2 thin film electrodes in non-aqueous electrolyte containing lithium bis(oxalate)borate
journal, July 2012
- Matsui, Masaki; Dokko, Kaoru; Akita, Yasuhiro
- Journal of Power Sources, Vol. 210
Enhanced Cycling Performance of Ni-Rich Positive Electrodes (NMC) in Li-Ion Batteries by Reducing Electrolyte Free-Solvent Activity
journal, June 2019
- Tatara, Ryoichi; Yu, Yang; Karayaylali, Pinar
- ACS Applied Materials & Interfaces, Vol. 11, Issue 38
The Impact of Electrolyte Additives and Upper Cut-off Voltage on the Formation of a Rocksalt Surface Layer in LiNi 0.8 Mn 0.1 Co 0.1 O 2 Electrodes
journal, January 2017
- Li, Jing; Liu, Hanshuo; Xia, Jian
- Journal of The Electrochemical Society, Vol. 164, Issue 4
SnO 2 Anode Surface Passivation by Atomic Layer Deposited HfO 2 Improves Li-Ion Battery Performance
journal, March 2014
- Yesibolati, Nulati; Shahid, Muhammad; Chen, Wei
- Small, Vol. 10, Issue 14
A Study of the Physical Properties of Li-Ion Battery Electrolytes Containing Esters
journal, January 2018
- Logan, E. R.; Tonita, Erin M.; Gering, K. L.
- Journal of The Electrochemical Society, Vol. 165, Issue 2
The Study of Surface Phenomena Related to Electrochemical Lithium Intercalation into Li[sub x]MO[sub y] Host Materials (M = Ni, Mn)
journal, January 2000
- Aurbach, Doron; Gamolsky, Kira; Markovsky, Boris
- Journal of The Electrochemical Society, Vol. 147, Issue 4
Molecular Design of Stable Sulfamide- and Sulfonamide-Based Electrolytes for Aprotic Li-O2 Batteries
journal, October 2019
- Feng, Shuting; Huang, Mingjun; Lamb, Jessica R.
- Chem, Vol. 5, Issue 10
Decomposition of LiPF 6 in High Energy Lithium-Ion Batteries Studied with Online Electrochemical Mass Spectrometry
journal, January 2016
- Guéguen, Aurélie; Streich, Daniel; He, Minglong
- Journal of The Electrochemical Society, Vol. 163, Issue 6
Evaluating the Free Energies of Solvation and Electronic Structures of Lithium-Ion Battery Electrolytes
journal, June 2016
- Shakourian-Fard, Mehdi; Kamath, Ganesh; Sankaranarayanan, Subramanian K. R. S.
- ChemPhysChem, Vol. 17, Issue 18
Study of full concentration-gradient Li(Ni0.8Co0.1Mn0.1)O2 cathode material for lithium ion batteries
journal, November 2014
- Hua, Chuanshan; Du, Ke; Tan, Chaopu
- Journal of Alloys and Compounds, Vol. 614
Probing the Origin of Enhanced Stability of “AlPO4” Nanoparticle Coated LiCoO2 during Cycling to High Voltages: Combined XRD and XPS Studies
journal, October 2009
- Lu, Yi-Chun; Mansour, Azzam N.; Yabuuchi, Naoaki
- Chemistry of Materials, Vol. 21, Issue 19, p. 4408-4424
Oxidation of propylene carbonate containing LiBF4 or LiPF6 on LiCoO2 thin film electrode for lithium batteries
journal, October 2001
- Kanamura, Kiyoshi; Umegaki, Takao; Ohashi, Masahiro
- Electrochimica Acta, Vol. 47, Issue 3
Electrochemical Kinetics of SEI Growth on Carbon Black: Part II. Modeling
journal, January 2019
- Das, Supratim; Attia, Peter M.; Chueh, William C.
- Journal of The Electrochemical Society, Vol. 166, Issue 4
Differential Thermal Analysis of Li-Ion Cells as an Effective Probe of Liquid Electrolyte Evolution during Aging
journal, January 2015
- Day, R. P.; Xia, J.; Petibon, R.
- Journal of The Electrochemical Society, Vol. 162, Issue 14
Review—Development of Diagnostic Process for Commercially Available Batteries, Especially Lithium Ion Battery, by Electrochemical Impedance Spectroscopy
journal, January 2015
- Osaka, Tetsuya; Mukoyama, Daikichi; Nara, Hiroki
- Journal of The Electrochemical Society, Vol. 162, Issue 14
Determination of the mechanism and extent of surface degradation in Ni-based cathode materials after repeated electrochemical cycling
journal, September 2016
- Hwang, Sooyeon; Kim, Se Young; Chung, Kyung Yoon
- APL Materials, Vol. 4, Issue 9
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996
- Kresse, G.; Furthmüller, J.
- Physical Review B, Vol. 54, Issue 16, p. 11169-11186
XPS Study on Al[sub 2]O[sub 3]- and AlPO[sub 4]-Coated LiCoO[sub 2] Cathode Material for High-Capacity Li Ion Batteries
journal, January 2007
- Verdier, S.; El Ouatani, L.; Dedryvère, R.
- Journal of The Electrochemical Society, Vol. 154, Issue 12
The Effect of Electrode-Electrolyte Interface on the Electrochemical Impedance Spectra for Positive Electrode in Li-Ion Battery
journal, November 2018
- Tatara, Ryoichi; Karayaylali, Pinar; Yu, Yang
- Journal of The Electrochemical Society, Vol. 166, Issue 3
Concentrated Electrolytes for Enhanced Stability of Al-Alloy Negative Electrodes in Li-Ion Batteries
journal, January 2019
- Chan, Averey K.; Tatara, Ryoichi; Feng, Shuting
- Journal of The Electrochemical Society, Vol. 166, Issue 10
Coupled LiPF 6 Decomposition and Carbonate Dehydrogenation Enhanced by Highly Covalent Metal Oxides in High-Energy Li-Ion Batteries
journal, October 2018
- Yu, Yang; Karayaylali, Pinar; Katayama, Yu
- The Journal of Physical Chemistry C, Vol. 122, Issue 48
In Situ DRIFTS Analysis of Solid-Electrolyte Interphase Formation on Li-Rich Li 1.2 Ni 0.2 Mn 0.6 O 2 and LiCoO 2 Cathodes during Oxidative Electrolyte Decomposition
journal, November 2015
- Teshager, Minbale Admas; Lin, Shawn D.; Hwang, Bing-Joe
- ChemElectroChem, Vol. 3, Issue 2
Three-Electrode Setups for Lithium-Ion Batteries: I. Fem-Simulation of Different Reference Electrode Designs and Their Implications for Half-Cell Impedance Spectra
journal, December 2016
- Ender, M.; Illig, J.; Ivers-Tiffée, E.
- Journal of The Electrochemical Society, Vol. 164, Issue 2
The role of Li-ion battery electrolyte reactivity in performance decline and self-discharge
journal, June 2003
- Sloop, Steven E.; Kerr, John B.; Kinoshita, Kim
- Journal of Power Sources, Vol. 119-121, p. 330-337
Understanding the Role of Temperature and Cathode Composition on Interface and Bulk: Optimizing Aluminum Oxide Coatings for Li-Ion Cathodes
journal, April 2017
- Han, Binghong; Paulauskas, Tadas; Key, Baris
- ACS Applied Materials & Interfaces, Vol. 9, Issue 17
Direct evidence of oxygen evolution from Li1+x (Ni1/3Mn1/3Co1/3)1−x O2 at high potentials
journal, February 2008
- La Mantia, Fabio; Rosciano, Fabio; Tran, Nicolas
- Journal of Applied Electrochemistry, Vol. 38, Issue 7
High-energy cathode material for long-life and safe lithium batteries
journal, March 2009
- Sun, Yang-Kook; Myung, Seung-Taek; Park, Byung-Chun
- Nature Materials, Vol. 8, Issue 4
Characterization of ALCVD-Al2O3 and ZrO2 layer using X-ray photoelectron spectroscopy
journal, May 2002
- Nohira, H.; Tsai, W.; Besling, W.
- Journal of Non-Crystalline Solids, Vol. 303, Issue 1
The Application of In Situ FTIR Spectroscopy to the Study of Surface Films Formed on Lithium and Noble Metals at Low Potentials in Li Battery Electrolytes
journal, January 1991
- Goren, Elisha
- Journal of The Electrochemical Society, Vol. 138, Issue 5
Using Atomic Layer Deposition to Hinder Solvent Decomposition in Lithium Ion Batteries: First-Principles Modeling and Experimental Studies
journal, September 2011
- Leung, Kevin; Qi, Yue; Zavadil, Kevin R.
- Journal of the American Chemical Society, Vol. 133, Issue 37
A Study of Electrochemical Reduction of Ethylene and Propylene Carbonate Electrolytes on Graphite Using ATR-FTIR Spectroscopy
journal, January 2005
- Zhuang, Guorong V.; Yang, Hui; Blizanac, Berislav
- Electrochemical and Solid-State Letters, Vol. 8, Issue 9
Artificial solid-electrolyte interphase (SEI) for improved cycleability and safety of lithium–ion cells for EV applications
journal, September 2009
- Menkin, S.; Golodnitsky, D.; Peled, E.
- Electrochemistry Communications, Vol. 11, Issue 9
Tailoring the Morphology of LiCoO 2 : A First Principles Study
journal, August 2009
- Kramer, Denis; Ceder, Gerbrand
- Chemistry of Materials, Vol. 21, Issue 16
Challenges for Rechargeable Li Batteries
journal, February 2010
- Goodenough, John B.; Kim, Youngsik
- Chemistry of Materials, Vol. 22, Issue 3, p. 587-603
Oxidation of Ethylene Carbonate on Li Metal Oxide Surfaces
journal, April 2018
- Østergaard, Thomas M.; Giordano, Livia; Castelli, Ivano E.
- The Journal of Physical Chemistry C, Vol. 122, Issue 19
Superconcentrated Electrolytes to Create New Interfacial Chemistry in Non-aqueous and Aqueous Rechargeable Batteries
journal, August 2017
- Yamada, Yuki; Yamada, Atsuo
- Chemistry Letters, Vol. 46, Issue 8
Solvation-controlled ester-based concentrated electrolyte solutions for high-voltage lithium-ion batteries
journal, June 2018
- Doi, Takayuki; Hashinokuchi, Michihiro; Inaba, Minoru
- Current Opinion in Electrochemistry, Vol. 9
Using Real-Time Electron Microscopy To Explore the Effects of Transition-Metal Composition on the Local Thermal Stability in Charged Li x Ni y Mn z Co 1– y – z O 2 Cathode Materials
journal, May 2015
- Hwang, Sooyeon; Kim, Seung Min; Bak, Seong-Min
- Chemistry of Materials, Vol. 27, Issue 11
Electrode–Electrolyte Interface in Li-Ion Batteries: Current Understanding and New Insights
journal, October 2015
- Gauthier, Magali; Carney, Thomas J.; Grimaud, Alexis
- The Journal of Physical Chemistry Letters, Vol. 6, Issue 22
LiTDI: A Highly Efficient Additive for Electrolyte Stabilization in Lithium-Ion Batteries
journal, February 2017
- Xu, Chao; Renault, Stéven; Ebadi, Mahsa
- Chemistry of Materials, Vol. 29, Issue 5
In Situ FTIR Spectroscopy Study of Li/LiNi[sub 0.8]Co[sub 0.15]Al[sub 0.05]O[sub 2] Cells with Ionic Liquid-Based Electrolytes in Overcharge Condition
journal, January 2010
- Sharabi, R.; Markevich, E.; Borgel, V.
- Electrochemical and Solid-State Letters, Vol. 13, Issue 4
The Effect of Some Nitriles as Electrolyte Additives in Li-Ion Batteries
journal, December 2014
- Kim, Gu-Yeon; Dahn, J. R.
- Journal of The Electrochemical Society, Vol. 162, Issue 3
Effect of Al 2 O 3 Coating on Stabilizing LiNi 0.4 Mn 0.4 Co 0.2 O 2 Cathodes
journal, August 2015
- Wise, Anna M.; Ban, Chunmei; Weker, Johanna Nelson
- Chemistry of Materials, Vol. 27, Issue 17
Ring-Opening Polymerization of Ethylene Carbonate and Depolymerization of Poly(ethylene oxide- c o -ethylene carbonate)
journal, March 2000
- Lee, Jong-Chan; Litt, Morton H.
- Macromolecules, Vol. 33, Issue 5
Probing Surface Chemistry Changes Using LiCoO 2 -only Electrodes in Li-Ion Batteries
journal, January 2018
- Gauthier, Magali; Karayaylali, Pinar; Giordano, Livia
- Journal of The Electrochemical Society, Vol. 165, Issue 7
XSEDE: Accelerating Scientific Discovery
journal, September 2014
- Towns, John; Cockerill, Timothy; Dahan, Maytal
- Computing in Science & Engineering, Vol. 16, Issue 5
Electrochemical Properties of Quaternary Ammonium Salts for Electrochemical Capacitors
journal, January 1997
- Ue, Makoto
- Journal of The Electrochemical Society, Vol. 144, Issue 8
Density Functional Theory Study of the Role of Anions on the Oxidative Decomposition Reaction of Propylene Carbonate
journal, December 2011
- Xing, Lidan; Borodin, Oleg; Smith, Grant D.
- The Journal of Physical Chemistry A, Vol. 115, Issue 47
Liquid Structures and Transport Properties of Lithium Bis(fluorosulfonyl)amide/Glyme Solvate Ionic Liquids for Lithium Batteries
journal, January 2019
- Terada, Shoshi; Ikeda, Kohei; Ueno, Kazuhide
- Australian Journal of Chemistry, Vol. 72, Issue 2
Evaluation of phenyl carbonates as electrolyte additives in lithium-ion batteries
journal, August 2015
- Petibon, R.; Rotermund, L. M.; Dahn, J. R.
- Journal of Power Sources, Vol. 287
Direct In situ Observation of Li 2 O Evolution on Li-Rich High-Capacity Cathode Material, Li[Ni x Li (1–2 x )/3 Mn (2– x )/3 ]O 2 (0 ≤ x ≤0.5)
journal, January 2014
- Hy, Sunny; Felix, Felix; Rick, John
- Journal of the American Chemical Society, Vol. 136, Issue 3
Electrolytes and Interphases in Li-Ion Batteries and Beyond
journal, October 2014
- Xu, Kang
- Chemical Reviews, Vol. 114, Issue 23
Oxygen Reduction Reaction in Highly Concentrated Electrolyte Solutions of Lithium Bis(trifluoromethanesulfonyl)amide/Dimethyl Sulfoxide
journal, April 2017
- Tatara, Ryoichi; Kwabi, David G.; Batcho, Thomas P.
- The Journal of Physical Chemistry C, Vol. 121, Issue 17
Combinations of LiPO 2 F 2 and Other Electrolyte Additives in Li[Ni 0.5 Mn 0.3 Co 0.2 ]O 2 /Graphite Pouch Cells
journal, January 2018
- Ma, Lin; Ellis, Leah; Glazier, S. L.
- Journal of The Electrochemical Society, Vol. 165, Issue 9
Ligand-Dependent Energetics for Dehydrogenation: Implications in Li-Ion Battery Electrolyte Stability and Selective Oxidation Catalysis of Hydrogen-Containing Molecules
journal, July 2019
- Giordano, Livia; Østergaard, Thomas M.; Muy, Sokseiha
- Chemistry of Materials, Vol. 31, Issue 15
Crystal Surface and State of Charge Dependencies of Electrolyte Decomposition on LiMn 2 O 4 Cathode
journal, January 2014
- Kumar, Nitin; Leung, Kevin; Siegel, Donald J.
- Journal of The Electrochemical Society, Vol. 161, Issue 8
Microstructure Evolution of Concentration Gradient Li[Ni 0.75 Co 0.10 Mn 0.15 ]O 2 Cathode for Lithium-Ion Batteries
journal, May 2018
- Yoon, Chong S.; Kim, Suk Jun; Kim, Un-Hyuck
- Advanced Functional Materials, Vol. 28, Issue 28
Comparison of the structural and electrochemical properties of layered Li[NixCoyMnz]O2 (x = 1/3, 0.5, 0.6, 0.7, 0.8 and 0.85) cathode material for lithium-ion batteries
journal, July 2013
- Noh, Hyung-Joo; Youn, Sungjune; Yoon, Chong Seung
- Journal of Power Sources, Vol. 233
Degradation mechanism of alkyl carbonate solvents used in lithium-ion cells during initial charging
journal, October 1997
- Yoshida, H.; Fukunaga, T.; Hazama, T.
- Journal of Power Sources, Vol. 68, Issue 2
Quantum Chemistry Studies of the Oxidative Stability of Carbonate, Sulfone and Sulfonate-Based Electrolytes Doped with BF
conference, January 2011
- Borodin, Oleg; Jow, T. R.
- 218th ECS Meeting, ECS Transactions
Theoretical Investigations on Oxidative Stability of Solvents and Oxidative Decomposition Mechanism of Ethylene Carbonate for Lithium Ion Battery Use
journal, December 2009
- Xing, Lidan; Li, Weishan; Wang, Chaoyang
- The Journal of Physical Chemistry B, Vol. 113, Issue 52
The cathode–electrolyte interface in the Li-ion battery
journal, November 2004
- Edström, K.; Gustafsson, T.; Thomas, J. O.
- Electrochimica Acta, Vol. 50, Issue 2-3
Influence of Battery Cell Components and Water on the Thermal and Chemical Stability of LiPF6 Based Lithium Ion Battery Electrolytes
journal, December 2016
- Wiemers-Meyer, Simon; Jeremias, Sebastian; Winter, Martin
- Electrochimica Acta, Vol. 222
A review on electrolyte additives for lithium-ion batteries
journal, November 2006
- Zhang, Sheng Shui
- Journal of Power Sources, Vol. 162, Issue 2, p. 1379-1394
Electrochemical Kinetics of SEI Growth on Carbon Black: Part I. Experiments
journal, January 2019
- Attia, Peter M.; Das, Supratim; Harris, Stephen J.
- Journal of The Electrochemical Society, Vol. 166, Issue 4
Electrolyte additives for lithium ion battery electrodes: progress and perspectives
journal, January 2016
- Haregewoin, Atetegeb Meazah; Wotango, Aselefech Sorsa; Hwang, Bing-Joe
- Energy Environ. Sci., Vol. 9, Issue 6
In situ methods for Li-ion battery research: A review of recent developments
journal, August 2015
- Harks, P. P. R. M. L.; Mulder, F. M.; Notten, P. H. L.
- Journal of Power Sources, Vol. 288
Anion Solvation in Carbonate-Based Electrolytes
journal, November 2015
- von Wald Cresce, Arthur; Gobet, Mallory; Borodin, Oleg
- The Journal of Physical Chemistry C, Vol. 119, Issue 49
Ab Initio Modeling of Electrolyte Molecule Ethylene Carbonate Decomposition Reaction on Li(Ni,Mn,Co)O 2 Cathode Surface
journal, June 2017
- Xu, Shenzhen; Luo, Guangfu; Jacobs, Ryan
- ACS Applied Materials & Interfaces, Vol. 9, Issue 24
Electrolyte Solvation and Ionic Association II. Acetonitrile-Lithium Salt Mixtures: Highly Dissociated Salts
journal, January 2012
- Seo, Daniel M.; Borodin, Oleg; Han, Sang-Don
- Journal of The Electrochemical Society, Vol. 159, Issue 9
Chemical Reactivity Descriptor for the Oxide-Electrolyte Interface in Li-Ion Batteries
journal, August 2017
- Giordano, Livia; Karayaylali, Pinar; Yu, Yang
- The Journal of Physical Chemistry Letters, Vol. 8, Issue 16
Surface film formation on electrodes in a LiCoO2/graphite cell: A step by step XPS study
journal, December 2007
- Dedryvère, R.; Martinez, H.; Leroy, S.
- Journal of Power Sources, Vol. 174, Issue 2
Enhanced Cycleabity in Lithium Ion Batteries: Resulting from Atomic Layer Depostion of Al 2 O 3 or TiO 2 on LiCoO 2 Electrodes
journal, March 2012
- Cheng, Ho-Ming; Wang, Fu-Ming; Chu, Jinn P.
- The Journal of Physical Chemistry C, Vol. 116, Issue 14
Computation of Thermodynamic Oxidation Potentials of Organic Solvents Using Density Functional Theory
journal, January 2001
- Zhang, Xuerong; Pugh, James K.; Ross, Philip N.
- Journal of The Electrochemical Society, Vol. 148, Issue 5
LiBF 4 -Based Concentrated Electrolyte Solutions for Suppression of Electrolyte Decomposition and Rapid Lithium-Ion Transfer at LiNi 0.5 Mn 1.5 O 4 /Electrolyte Interface
journal, January 2016
- Doi, Takayuki; Shimizu, Yusuke; Hashinokuchi, Michihiro
- Journal of The Electrochemical Society, Vol. 163, Issue 10
First-Principles Modeling of the Initial Stages of Organic Solvent Decomposition on Li x Mn 2 O 4 (100) Surfaces
journal, April 2012
- Leung, Kevin
- The Journal of Physical Chemistry C, Vol. 116, Issue 18
On the capacity fading of LiCoO2 intercalation electrodes:
journal, October 2002
- Aurbach, D.; Markovsky, B.; Rodkin, A.
- Electrochimica Acta, Vol. 47, Issue 27
Li + solvation in glyme–Li salt solvate ionic liquids
journal, January 2015
- Ueno, Kazuhide; Tatara, Ryoichi; Tsuzuki, Seiji
- Physical Chemistry Chemical Physics, Vol. 17, Issue 12
Charge-transfer-energy-dependent oxygen evolution reaction mechanisms for perovskite oxides
journal, January 2017
- Hong, Wesley T.; Stoerzinger, Kelsey A.; Lee, Yueh-Lin
- Energy & Environmental Science, Vol. 10, Issue 10
Effect of LiPF6 concentration in Li[Ni0.4Mn0.4Co0.2]O2/graphite pouch cells operated at 4.5 V
journal, December 2015
- Petibon, R.; Madec, L.; Abarbanel, D. W.
- Journal of Power Sources, Vol. 300
Dynamic in situ fourier transform infrared measurements of chemical bonds of electrolyte solvents during the initial charging process in a Li ion battery
journal, December 2013
- Hongyou, Kenichi; Hattori, Takashi; Nagai, Youko
- Journal of Power Sources, Vol. 243
Chemical versus Electrochemical Electrolyte Oxidation on NMC111, NMC622, NMC811, LNMO, and Conductive Carbon
journal, September 2017
- Jung, Roland; Metzger, Michael; Maglia, Filippo
- The Journal of Physical Chemistry Letters, Vol. 8, Issue 19
Structural and Electrochemical Study of Al 2 O 3 and TiO 2 Coated Li 1.2 Ni 0.13 Mn 0.54 Co 0.13 O 2 Cathode Material Using ALD
journal, June 2013
- Zhang, Xiaofeng; Belharouak, Ilias; Li, Li
- Advanced Energy Materials, Vol. 3, Issue 10
The study of the anodic stability of alkyl carbonate solutions by in situ FTIR spectroscopy, EQCM, NMR and MS
journal, February 2001
- Moshkovich, M.; Cojocaru, M.; Gottlieb, H. E.
- Journal of Electroanalytical Chemistry, Vol. 497, Issue 1-2
Precision Measurements of the Coulombic Efficiency of Lithium-Ion Batteries and of Electrode Materials for Lithium-Ion Batteries
journal, January 2010
- Smith, A. J.; Burns, J. C.; Trussler, S.
- Journal of The Electrochemical Society, Vol. 157, Issue 2
Toward Reliable Values of Electrochemical Stability Limits for Electrolytes
journal, January 1999
- Xu, Kang
- Journal of The Electrochemical Society, Vol. 146, Issue 11
Oxidation energies of transition metal oxides within the framework
journal, May 2006
- Wang, Lei; Maxisch, Thomas; Ceder, Gerbrand
- Physical Review B, Vol. 73, Issue 19
Nickel-Rich Layered Cathode Materials for Automotive Lithium-Ion Batteries: Achievements and Perspectives
journal, December 2016
- Myung, Seung-Taek; Maglia, Filippo; Park, Kang-Joon
- ACS Energy Letters, Vol. 2, Issue 1
Raman intensity study of local structure in non-aqueous electrolyte solutions—I. Cation-solvent interaction in LiClO4/ethylene carbonate
journal, November 1989
- Hyodo, Shi-Aki; Okabayashi, Katsuaki
- Electrochimica Acta, Vol. 34, Issue 11
Ab initio energetics of ( , Fe, Co, and Ni) for solid oxide fuel cell cathodes
journal, December 2009
- Lee, Yueh-Lin; Kleis, Jesper; Rossmeisl, Jan
- Physical Review B, Vol. 80, Issue 22
Review on electrode–electrolyte solution interactions, related to cathode materials for Li-ion batteries
journal, March 2007
- Aurbach, Doron; Markovsky, Boris; Salitra, Gregory
- Journal of Power Sources, Vol. 165, Issue 2
Oxygen Release and Its Effect on the Cycling Stability of LiNi x Mn y Co z O 2 (NMC) Cathode Materials for Li-Ion Batteries
journal, January 2017
- Jung, Roland; Metzger, Michael; Maglia, Filippo
- Journal of The Electrochemical Society, Vol. 164, Issue 7
Preferential Adsorption of Solvents on the Cathode Surface of Lithium Ion Batteries
journal, April 2013
- Yu, Le; Liu, Huijin; Wang, Yan
- Angewandte Chemie, Vol. 125, Issue 22
Towards high throughput screening of electrochemical stability of battery electrolytes
journal, August 2015
- Borodin, Oleg; Olguin, Marco; Spear, Carrie E.
- Nanotechnology, Vol. 26, Issue 35
Oxidative-Stability Enhancement and Charge Transport Mechanism in Glyme–Lithium Salt Equimolar Complexes
journal, August 2011
- Yoshida, Kazuki; Nakamura, Megumi; Kazue, Yuichi
- Journal of the American Chemical Society, Vol. 133, Issue 33, p. 13121-13129