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Title: The sensitivity of Cu for electrochemical carbon dioxide reduction to hydrocarbons as revealed by high throughput experiments

Abstract

The uniqueness of Cu for CO 2 electroreduction is accompanied by high sensitivity to contaminants, but alloys can tune product selectivity.

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [2]
  1. Joint Center for Artificial Photosynthesis, California Institute of Technology, Pasadena, USA
  2. Joint Center for Artificial Photosynthesis, California Institute of Technology, Pasadena, USA, Division of Engineering and Applied Science
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1575099
Grant/Contract Number:  
SC0004993
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Name: Journal of Materials Chemistry. A Journal Volume: 7 Journal Issue: 47; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Lai, Yungchieh, Jones, Ryan J. R., Wang, Yu, Zhou, Lan, Richter, Matthias H., and Gregoire, John. The sensitivity of Cu for electrochemical carbon dioxide reduction to hydrocarbons as revealed by high throughput experiments. United Kingdom: N. p., 2019. Web. doi:10.1039/C9TA10111J.
Lai, Yungchieh, Jones, Ryan J. R., Wang, Yu, Zhou, Lan, Richter, Matthias H., & Gregoire, John. The sensitivity of Cu for electrochemical carbon dioxide reduction to hydrocarbons as revealed by high throughput experiments. United Kingdom. doi:10.1039/C9TA10111J.
Lai, Yungchieh, Jones, Ryan J. R., Wang, Yu, Zhou, Lan, Richter, Matthias H., and Gregoire, John. Tue . "The sensitivity of Cu for electrochemical carbon dioxide reduction to hydrocarbons as revealed by high throughput experiments". United Kingdom. doi:10.1039/C9TA10111J.
@article{osti_1575099,
title = {The sensitivity of Cu for electrochemical carbon dioxide reduction to hydrocarbons as revealed by high throughput experiments},
author = {Lai, Yungchieh and Jones, Ryan J. R. and Wang, Yu and Zhou, Lan and Richter, Matthias H. and Gregoire, John},
abstractNote = {The uniqueness of Cu for CO 2 electroreduction is accompanied by high sensitivity to contaminants, but alloys can tune product selectivity.},
doi = {10.1039/C9TA10111J},
journal = {Journal of Materials Chemistry. A},
number = 47,
volume = 7,
place = {United Kingdom},
year = {2019},
month = {12}
}

Journal Article:
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This content will become publicly available on November 14, 2020
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Works referenced in this record:

Generation of Cu–In alloy surfaces from CuInO 2 as selective catalytic sites for CO 2 electroreduction
journal, January 2015

  • Jedidi, Abdesslem; Rasul, Shahid; Masih, Dilshad
  • J. Mater. Chem. A, Vol. 3, Issue 37
  • DOI: 10.1039/C5TA05669A

A Highly Selective Copper-Indium Bimetallic Electrocatalyst for the Electrochemical Reduction of Aqueous CO 2 to CO
journal, December 2014

  • Rasul, Shahid; Anjum, Dalaver H.; Jedidi, Abdesslem
  • Angewandte Chemie International Edition, Vol. 54, Issue 7
  • DOI: 10.1002/anie.201410233

Mesoporous palladium–copper bimetallic electrodes for selective electrocatalytic reduction of aqueous CO 2 to CO
journal, January 2016

  • Li, Mu; Wang, Junjie; Li, Peng
  • Journal of Materials Chemistry A, Vol. 4, Issue 13
  • DOI: 10.1039/C6TA00487C

What would it take for renewably powered electrosynthesis to displace petrochemical processes?
journal, April 2019


Electrocatalytic process of CO selectivity in electrochemical reduction of CO2 at metal electrodes in aqueous media
journal, August 1994

  • Hori, Yoshio; Wakebe, Hidetoshi; Tsukamoto, Toshio
  • Electrochimica Acta, Vol. 39, Issue 11-12, p. 1833-1839
  • DOI: 10.1016/0013-4686(94)85172-7

Evidence for product-specific active sites on oxide-derived Cu catalysts for electrochemical CO2 reduction
journal, December 2018


Electrochemical Real-Time Mass Spectrometry (EC-RTMS): Monitoring Electrochemical Reaction Products in Real Time
journal, April 2019

  • Khanipour, Peyman; Löffler, Mario; Reichert, Andreas M.
  • Angewandte Chemie International Edition, Vol. 58, Issue 22
  • DOI: 10.1002/anie.201901923

Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces
journal, August 2014

  • Kuhl, Kendra P.; Hatsukade, Toru; Cave, Etosha R.
  • Journal of the American Chemical Society, Vol. 136, Issue 40
  • DOI: 10.1021/ja505791r

High-Throughput Synthesis of Mixed-Metal Electrocatalysts for CO 2 Reduction
journal, February 2017

  • He, Jingfu; Dettelbach, Kevan E.; Salvatore, Danielle A.
  • Angewandte Chemie International Edition, Vol. 56, Issue 22
  • DOI: 10.1002/anie.201612038

Selective electro- or photo-reduction of carbon dioxide to formic acid using a Cu–Zn alloy catalyst
journal, January 2017

  • Yin, Ge; Abe, Hideki; Kodiyath, Rajesh
  • Journal of Materials Chemistry A, Vol. 5, Issue 24
  • DOI: 10.1039/C7TA00353F

Laser-Prepared CuZn Alloy Catalyst for Selective Electrochemical Reduction of CO 2 to Ethylene
journal, October 2018


Screening of material libraries for electrochemical CO2 reduction catalysts – Improving selectivity of Cu by mixing with Co
journal, November 2016


Electrochemical Reduction of Carbon Dioxide on Zinc-Modified Copper Electrodes
journal, January 2017

  • Keerthiga, Gopalram; Chetty, Raghuram
  • Journal of The Electrochemical Society, Vol. 164, Issue 4
  • DOI: 10.1149/2.0421704jes

Scanning Electrochemical Flow Cell with Online Mass Spectroscopy for Accelerated Screening of Carbon Dioxide Reduction Electrocatalysts
journal, August 2019


Electrochemical CO 2 Reduction over Compressively Strained CuAg Surface Alloys with Enhanced Multi-Carbon Oxygenate Selectivity
journal, October 2017

  • Clark, Ezra L.; Hahn, Christopher; Jaramillo, Thomas F.
  • Journal of the American Chemical Society, Vol. 139, Issue 44
  • DOI: 10.1021/jacs.7b08607

Efficient Pt/carbon electrocatalysts for proton exchange membrane fuel cells: Avoid chloride-based Pt salts!
journal, October 2013


Activity Descriptors for CO 2 Electroreduction to Methane on Transition-Metal Catalysts
journal, January 2012

  • Peterson, Andrew A.; Nørskov, Jens K.
  • The Journal of Physical Chemistry Letters, Vol. 3, Issue 2
  • DOI: 10.1021/jz201461p

Electrochemical Reduction of Carbon Dioxide to Syngas and Formate at Dendritic Copper–Indium Electrocatalysts
journal, July 2017

  • Hoffman, Zachary B.; Gray, Tristan S.; Moraveck, Kasey B.
  • ACS Catalysis, Vol. 7, Issue 8
  • DOI: 10.1021/acscatal.7b01161

Nickel–Iron Oxyhydroxide Oxygen-Evolution Electrocatalysts: The Role of Intentional and Incidental Iron Incorporation
journal, April 2014

  • Trotochaud, Lena; Young, Samantha L.; Ranney, James K.
  • Journal of the American Chemical Society, Vol. 136, Issue 18
  • DOI: 10.1021/ja502379c

Direct Observation of the Local Reaction Environment during the Electrochemical Reduction of CO 2
journal, April 2018

  • Clark, Ezra L.; Bell, Alexis T.
  • Journal of the American Chemical Society, Vol. 140, Issue 22
  • DOI: 10.1021/jacs.8b04058

Review of fuel processing catalysts for hydrogen production in PEM fuel cell systems
journal, October 2002


New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
journal, January 2012

  • Kuhl, Kendra P.; Cave, Etosha R.; Abram, David N.
  • Energy & Environmental Science, Vol. 5, Issue 5
  • DOI: 10.1039/c2ee21234j

High-throughput calculations of catalytic properties of bimetallic alloy surfaces
journal, May 2019


Coupling of a scanning flow cell with online electrochemical mass spectrometry for screening of reaction selectivity
journal, October 2014

  • Grote, Jan-Philipp; Zeradjanin, Aleksandar R.; Cherevko, Serhiy
  • Review of Scientific Instruments, Vol. 85, Issue 10
  • DOI: 10.1063/1.4896755

Differential Electrochemical Mass Spectrometer Cell Design for Online Quantification of Products Produced during Electrochemical Reduction of CO 2
journal, July 2015


Tuning the Selectivity of Carbon Dioxide Electroreduction toward Ethanol on Oxide-Derived Cu x Zn Catalysts
journal, November 2016


Differential electrochemical mass spectrometry
journal, December 2004


Progress and Perspectives of Electrochemical CO 2 Reduction on Copper in Aqueous Electrolyte
journal, April 2019


Electroreduction of Carbon Dioxide on Copper-Based Electrodes: Activity of Copper Single Crystals and Copper–Gold Alloys
journal, April 2012


Electrodeposited Cu-Sn Alloy for Electrochemical CO2 Reduction to CO/HCOO−
journal, November 2017


In-situ grown nanoporous Zn-Cu catalysts on brass foils for enhanced electrochemical reduction of carbon dioxide
journal, July 2018