Interfacial charge-transfer Mott state in iridate–nickelate superlattices
Abstract
We investigate SrIrO3/LaNiO3 superlattices in which we observe a full electron transfer at the interface from Ir to Ni, triggering a massive structural and electronic reconstruction. Through experimental characterization and first-principles calculations, we determine that a large crystal field splitting from the distorted interfacial IrO6 octahedra surprisingly dominates over the spin–orbit coupling and together with the Hund’s coupling results in the high-spin (S = 1) configurations on both the Ir and Ni sites. This demonstrates the power of interfacial charge transfer in coupling lattice, charge, orbital, and spin degrees of freedom, opening fresh avenues of investigation of quantum states in oxide superlattices.
- Authors:
-
- Rutgers Univ., Piscataway, NJ (United States)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Chinese Academy of Sciences (CAS), Beijing (China)
- Chinese Academy of Sciences, Zhejiang (China)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Cornell Univ., Ithaca, NY (United States)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC); Gordon and Betty Moore Foundation; US Department of the Navy, Office of Naval Research (ONR); USDOD; National Science Foundation (NSF)
- OSTI Identifier:
- 1574930
- Alternate Identifier(s):
- OSTI ID: 1637298
- Grant/Contract Number:
- AC02-06CH11357; SC0012375; GBMF4534; N000014-17-1-2770; DMR-1629346; DMR-1629059; N00014-16-1-2951
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Proceedings of the National Academy of Sciences of the United States of America
- Additional Journal Information:
- Journal Volume: 116; Journal Issue: 40; Journal ID: ISSN 0027-8424
- Publisher:
- National Academy of Sciences
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS; interfacial charge transfer; iridates; nickelates; superlattice
Citation Formats
Liu, Xiaoran, Kotiuga, Michele, Kim, Heung-Sik, N’Diaye, Alpha T., Choi, Yongseong, Zhang, Qinghua, Cao, Yanwei, Kareev, Mikhail, Wen, Fangdi, Pal, Banabir, Freeland, John W., Gu, Lin, Haskel, Daniel, Shafer, Padraic, Arenholz, Elke, Haule, Kristjan, Vanderbilt, David, Rabe, Karin M., and Chakhalian, Jak. Interfacial charge-transfer Mott state in iridate–nickelate superlattices. United States: N. p., 2019.
Web. doi:10.1073/pnas.1907043116.
Liu, Xiaoran, Kotiuga, Michele, Kim, Heung-Sik, N’Diaye, Alpha T., Choi, Yongseong, Zhang, Qinghua, Cao, Yanwei, Kareev, Mikhail, Wen, Fangdi, Pal, Banabir, Freeland, John W., Gu, Lin, Haskel, Daniel, Shafer, Padraic, Arenholz, Elke, Haule, Kristjan, Vanderbilt, David, Rabe, Karin M., & Chakhalian, Jak. Interfacial charge-transfer Mott state in iridate–nickelate superlattices. United States. https://doi.org/10.1073/pnas.1907043116
Liu, Xiaoran, Kotiuga, Michele, Kim, Heung-Sik, N’Diaye, Alpha T., Choi, Yongseong, Zhang, Qinghua, Cao, Yanwei, Kareev, Mikhail, Wen, Fangdi, Pal, Banabir, Freeland, John W., Gu, Lin, Haskel, Daniel, Shafer, Padraic, Arenholz, Elke, Haule, Kristjan, Vanderbilt, David, Rabe, Karin M., and Chakhalian, Jak. Mon .
"Interfacial charge-transfer Mott state in iridate–nickelate superlattices". United States. https://doi.org/10.1073/pnas.1907043116. https://www.osti.gov/servlets/purl/1574930.
@article{osti_1574930,
title = {Interfacial charge-transfer Mott state in iridate–nickelate superlattices},
author = {Liu, Xiaoran and Kotiuga, Michele and Kim, Heung-Sik and N’Diaye, Alpha T. and Choi, Yongseong and Zhang, Qinghua and Cao, Yanwei and Kareev, Mikhail and Wen, Fangdi and Pal, Banabir and Freeland, John W. and Gu, Lin and Haskel, Daniel and Shafer, Padraic and Arenholz, Elke and Haule, Kristjan and Vanderbilt, David and Rabe, Karin M. and Chakhalian, Jak},
abstractNote = {We investigate SrIrO3/LaNiO3 superlattices in which we observe a full electron transfer at the interface from Ir to Ni, triggering a massive structural and electronic reconstruction. Through experimental characterization and first-principles calculations, we determine that a large crystal field splitting from the distorted interfacial IrO6 octahedra surprisingly dominates over the spin–orbit coupling and together with the Hund’s coupling results in the high-spin (S = 1) configurations on both the Ir and Ni sites. This demonstrates the power of interfacial charge transfer in coupling lattice, charge, orbital, and spin degrees of freedom, opening fresh avenues of investigation of quantum states in oxide superlattices.},
doi = {10.1073/pnas.1907043116},
journal = {Proceedings of the National Academy of Sciences of the United States of America},
number = 40,
volume = 116,
place = {United States},
year = {Mon Sep 16 00:00:00 EDT 2019},
month = {Mon Sep 16 00:00:00 EDT 2019}
}
Web of Science
Works referenced in this record:
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
Interfaces of Correlated Electron Systems: Proposed Mechanism for Colossal Electroresistance
journal, December 2005
- Oka, Takashi; Nagaosa, Naoto
- Physical Review Letters, Vol. 95, Issue 26
Projector augmented-wave method
journal, December 1994
- Blöchl, P. E.
- Physical Review B, Vol. 50, Issue 24, p. 17953-17979
Two-Dimensional Antiferromagnetic Insulator Unraveled from Interlayer Exchange Coupling in Artificial Perovskite Iridate Superlattices
journal, July 2017
- Hao, Lin; Meyers, D.; Frederick, Clayton
- Physical Review Letters, Vol. 119, Issue 2
Oxide Interfaces--An Opportunity for Electronics
journal, March 2010
- Mannhart, J.; Schlom, D. G.
- Science, Vol. 327, Issue 5973, p. 1607-1611
Correlated Quantum Phenomena in the Strong Spin-Orbit Regime
journal, March 2014
- Witczak-Krempa, William; Chen, Gang; Kim, Yong Baek
- Annual Review of Condensed Matter Physics, Vol. 5, Issue 1
Two-Dimensional Electron Gases at Complex Oxide Interfaces
journal, July 2014
- Stemmer, Susanne; James Allen, S.
- Annual Review of Materials Research, Vol. 44, Issue 1
Novel Magnetism of Ions in the Double Perovskite
journal, February 2014
- Cao, G.; Qi, T. F.; Li, L.
- Physical Review Letters, Vol. 112, Issue 5
Orbital Order and Possible Superconductivity in Superlattices
journal, January 2008
- Chaloupka, Jiří; Khaliullin, Giniyat
- Physical Review Letters, Vol. 100, Issue 1
Charge transfer across transition-metal oxide interfaces: Emergent conductance and electronic structure
journal, December 2014
- Chen, Hanghui; Park, Hyowon; Millis, Andrew J.
- Physical Review B, Vol. 90, Issue 24
From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999
- Kresse, G.; Joubert, D.
- Physical Review B, Vol. 59, Issue 3, p. 1758-1775
Charge transfer driven emergent phenomena in oxide heterostructures
journal, May 2017
- Chen, Hanghui; Millis, Andrew
- Journal of Physics: Condensed Matter, Vol. 29, Issue 24
Orbital polarization in strained : Structural distortions and correlation effects
journal, July 2014
- Peil, Oleg E.; Ferrero, Michel; Georges, Antoine
- Physical Review B, Vol. 90, Issue 4
Engineered Mott ground state in a LaTiO3+δ/LaNiO3 heterostructure
journal, January 2016
- Cao, Yanwei; Liu, Xiaoran; Kareev, M.
- Nature Communications, Vol. 7, Issue 1
Density-functional theory and strong interactions: Orbital ordering in Mott-Hubbard insulators
journal, August 1995
- Liechtenstein, A. I.; Anisimov, V. I.; Zaanen, J.
- Physical Review B, Vol. 52, Issue 8
Sub-monolayer nucleation and growth of complex oxides at high supersaturation and rapid flux modulation
journal, June 2011
- Kareev, M.; Prosandeev, S.; Gray, B.
- Journal of Applied Physics, Vol. 109, Issue 11
Colloquium : Emergent properties in plane view: Strong correlations at oxide interfaces
journal, October 2014
- Chakhalian, Jak; Freeland, John W.; Millis, Andrew J.
- Reviews of Modern Physics, Vol. 86, Issue 4
Controlling entangled spin-orbit coupling of states with interfacial heterostructure engineering
journal, March 2018
- Kim, J. -W.; Choi, Y.; Chun, S. H.
- Physical Review B, Vol. 97, Issue 9
Phase-Sensitive Observation of a Spin-Orbital Mott State in Sr2IrO4
journal, March 2009
- Kim, B. J.; Ohsumi, H.; Komesu, T.
- Science, Vol. 323, Issue 5919
Fabrication of (111)-oriented Ca 0.5 Sr 0.5 IrO 3 /SrTiO 3 superlattices—A designed playground for honeycomb physics
journal, April 2015
- Hirai, Daigorou; Matsuno, Jobu; Takagi, Hidenori
- APL Materials, Vol. 3, Issue 4
Asymmetric Orbital-Lattice Interactions in Ultrathin Correlated Oxide Films
journal, September 2011
- Chakhalian, J.; Rondinelli, J. M.; Liu, Jian
- Physical Review Letters, Vol. 107, Issue 11
Testing the Validity of the Strong Spin-Orbit-Coupling Limit for Octahedrally Coordinated Iridate Compounds in a Model System
journal, October 2012
- Liu, X.; Katukuri, Vamshi M.; Hozoi, L.
- Physical Review Letters, Vol. 109, Issue 15
Pressure Tuning of the Spin-Orbit Coupled Ground State in
journal, July 2012
- Haskel, D.; Fabbris, G.; Zhernenkov, Mikhail
- Physical Review Letters, Vol. 109, Issue 2
Atomic-scale control of magnetic anisotropy via novel spin–orbit coupling effect in La 2/3 Sr 1/3 MnO 3 /SrIrO 3 superlattices
journal, May 2016
- Yi, Di; Liu, Jian; Hsu, Shang-Lin
- Proceedings of the National Academy of Sciences, Vol. 113, Issue 23
Interplay of Spin-Orbit Interactions, Dimensionality, and Octahedral Rotations in Semimetallic
journal, January 2015
- Nie, Y. F.; King, P. D. C.; Kim, C. H.
- Physical Review Letters, Vol. 114, Issue 1
Tuning Perpendicular Magnetic Anisotropy by Oxygen Octahedral Rotations in Superlattices
journal, August 2017
- Yi, Di; Flint, Charles L.; Balakrishnan, Purnima P.
- Physical Review Letters, Vol. 119, Issue 7
Spin-Orbit Physics Giving Rise to Novel Phases in Correlated Systems: Iridates and Related Materials
journal, March 2016
- Rau, Jeffrey G.; Lee, Eric Kin-Ho; Kee, Hae-Young
- Annual Review of Condensed Matter Physics, Vol. 7, Issue 1
Strongly correlated perovskite lithium ion shuttles
journal, August 2018
- Sun, Yifei; Kotiuga, Michele; Lim, Dawgen
- Proceedings of the National Academy of Sciences, Vol. 115, Issue 39
Strain and composition dependence of orbital polarization in nickel oxide superlattices
journal, September 2013
- Wu, M.; Benckiser, E.; Haverkort, M. W.
- Physical Review B, Vol. 88, Issue 12
Interplay between spin-orbit coupling and Hubbard interaction in SrIrO and related perovskite oxides
journal, August 2012
- Zeb, M. Ahsan; Kee, Hae-Young
- Physical Review B, Vol. 86, Issue 8
Novel Mott State Induced by Relativistic Spin-Orbit Coupling in
journal, August 2008
- Kim, B. J.; Jin, Hosub; Moon, S. J.
- Physical Review Letters, Vol. 101, Issue 7
Engineering Correlation Effects via Artificially Designed Oxide Superlattices
journal, September 2013
- Chen, Hanghui; Millis, Andrew J.; Marianetti, Chris A.
- Physical Review Letters, Vol. 111, Issue 11
Orbital Engineering in Symmetry-Breaking Polar Heterostructures
journal, January 2015
- Disa, Ankit S.; Kumah, Divine P.; Malashevich, Andrei
- Physical Review Letters, Vol. 114, Issue 2
Rare-earth nickelates R NiO 3 : thin films and heterostructures
journal, February 2018
- Catalano, S.; Gibert, M.; Fowlie, J.
- Reports on Progress in Physics, Vol. 81, Issue 4
Habituation based synaptic plasticity and organismic learning in a quantum perovskite
journal, August 2017
- Zuo, Fan; Panda, Priyadarshini; Kotiuga, Michele
- Nature Communications, Vol. 8, Issue 1
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996
- Kresse, G.; Furthmüller, J.
- Physical Review B, Vol. 54, Issue 16, p. 11169-11186
Interface Physics in Complex Oxide Heterostructures
journal, March 2011
- Zubko, Pavlo; Gariglio, Stefano; Gabay, Marc
- Annual Review of Condensed Matter Physics, Vol. 2, Issue 1
Modifying the Electronic Orbitals of Nickelate Heterostructures via Structural Distortions
journal, May 2013
- Chen, Hanghui; Kumah, Divine P.; Disa, Ankit S.
- Physical Review Letters, Vol. 110, Issue 18
Magnetism in Ca 2 CoOsO 6 and Ca 2 NiOsO 6 : Unraveling the Mystery of Superexchange Interactions between 3d and 5d Ions
journal, May 2016
- Morrow, Ryan; Samanta, Kartik; Saha Dasgupta, Tanusri
- Chemistry of Materials, Vol. 28, Issue 11
Spin and Orbital Contributions to Magnetically Ordered Moments in Layered Perovskite
journal, January 2014
- Fujiyama, S.; Ohsumi, H.; Ohashi, K.
- Physical Review Letters, Vol. 112, Issue 1
Anisotropic magnetoresistance in an antiferromagnetic semiconductor
journal, September 2014
- Fina, I.; Marti, X.; Yi, D.
- Nature Communications, Vol. 5, Issue 1
Recent progress on correlated electron systems with strong spin–orbit coupling
journal, August 2016
- Schaffer, Robert; Kin-Ho Lee, Eric; Yang, Bohm-Jung
- Reports on Progress in Physics, Vol. 79, Issue 9
Emergent phenomena at oxide interfaces
journal, January 2012
- Hwang, H. Y.; Iwasa, Y.; Kawasaki, M.
- Nature Materials, Vol. 11, Issue 2
Engineering 1D Quantum Stripes from Superlattices of 2D Layered Materials
journal, October 2016
- Gruenewald, John H.; Kim, Jungho; Kim, Heung Sik
- Advanced Materials, Vol. 29, Issue 1, Article No. 1603798
Photoinduced expansion of cuprate superconductors: Evidence of strong electron-lattice coupling
journal, March 2008
- Radović, Z.; Božović, N.; Božović, I.
- Physical Review B, Vol. 77, Issue 9
Confinement-driven transitions between topological and Mott phases in / (111) superlattices
journal, March 2014
- Doennig, David; Pickett, Warren E.; Pentcheva, Rossitza
- Physical Review B, Vol. 89, Issue 12
Dimensionality-Controlled Insulator-Metal Transition and Correlated Metallic State in Transition Metal Oxides ( , 2, and )
journal, November 2008
- Moon, S. J.; Jin, H.; Kim, K. W.
- Physical Review Letters, Vol. 101, Issue 22
Synthesis and electronic properties of Ruddlesden-Popper strontium iridate epitaxial thin films stabilized by control of growth kinetics
journal, December 2017
- Liu, Xiaoran; Cao, Yanwei; Pal, B.
- Physical Review Materials, Vol. 1, Issue 7
Charge Transfer in Iridate-Manganite Superlattices
journal, March 2017
- Okamoto, Satoshi; Nichols, John; Sohn, Changhee
- Nano Letters, Vol. 17, Issue 4
Quantum confinement of Mott electrons in ultrathin LaNiO /LaAlO superlattices
journal, April 2011
- Liu, Jian; Okamoto, S.; van Veenendaal, M.
- Physical Review B, Vol. 83, Issue 16
Emerging magnetism and anomalous Hall effect in iridate–manganite heterostructures
journal, September 2016
- Nichols, John; Gao, Xiang; Lee, Shinbuhm
- Nature Communications, Vol. 7, Issue 1
Improved tetrahedron method for Brillouin-zone integrations
journal, June 1994
- Blöchl, Peter E.; Jepsen, O.; Andersen, O. K.
- Physical Review B, Vol. 49, Issue 23
Interface-driven topological Hall effect in SrRuO 3 -SrIrO 3 bilayer
journal, July 2016
- Matsuno, Jobu; Ogawa, Naoki; Yasuda, Kenji
- Science Advances, Vol. 2, Issue 7
Epitaxial growth and thermodynamic stability of SrIrO 3 /SrTiO 3 heterostructures
journal, July 2016
- Groenendijk, D. J.; Manca, N.; Mattoni, G.
- Applied Physics Letters, Vol. 109, Issue 4
Reducing Dzyaloshinskii-Moriya interaction and field-free spin-orbit torque switching in synthetic antiferromagnets
journal, May 2021
- Chen, Ruyi; Cui, Qirui; Liao, Liyang
- Nature Communications, Vol. 12, Issue 1
Electronic structure of AlFeN films exhibiting crystallographic orientation change from c- to a-axis with Fe concentrations and annealing effect
journal, February 2020
- Tatemizo, Nobuyuki; Imada, Saki; Okahara, Kizuna
- Scientific Reports, Vol. 10, Issue 1
Asymmetric orbital-lattice interactions in ultra-thin correlated oxide films
text, January 2010
- Chakhalian, J.; Rondinelli, J. M.; Liu, Jian
- arXiv
Correlated quantum phenomena in the strong spin-orbit regime
text, January 2013
- Witczak-Krempa, William; Chen, Gang; Kim, Yong Baek
- arXiv
Engineering spin-orbital magnetic insulator by tailoring superlattices
text, January 2014
- Matsuno, Jobu; Ihara, Kota; Yamamura, Shugen
- arXiv
Spin-Orbit Physics Giving Rise to Novel Phases in Correlated Systems: Iridates and Related Materials
text, January 2015
- Rau, Jeffrey G.; Lee, Eric Kin-Ho; Kee, Hae-Young
- arXiv
Recent progress on correlated electron systems with strong spin-orbit coupling
text, January 2015
- Schaffer, Robert; Lee, Eric Kin-Ho; Yang, Bohm-Jung
- arXiv
Epitaxial growth and thermodynamic stability of SrIrO3/SrTiO3 heterostructures
text, January 2016
- Groenendijk, D. J.; Manca, N.; Mattoni, G.
- arXiv
Interface-driven topological Hall effect in SrRuO$_3$-SrIrO$_3$ bilayer
text, January 2016
- Matsuno, J.; Ogawa, N.; Yasuda, K.
- arXiv
Synthesis and electronic properties of Ruddlesden-Popper strontium iridate epitaxial thin films stabilized by control of growth kinetics
text, January 2017
- Liu, Xiaoran; Cao, Yanwei; Pal, B.
- arXiv
Works referencing / citing this record:
Carrier localization in perovskite nickelates from oxygen vacancies
journal, October 2019
- Kotiuga, Michele; Zhang, Zhen; Li, Jiarui
- Proceedings of the National Academy of Sciences, Vol. 116, Issue 44
High-density electron doping of from first principles
journal, November 2019
- Kotiuga, Michele; Rabe, Karin M.
- Physical Review Materials, Vol. 3, Issue 11
Emergent electric field control of phase transformation in oxide superlattices
text, January 2020
- Yi, Di; Wang, Yujia; Erve, Olaf M. J. van 't
- arXiv