skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Inkjet Printing of Magnetic Particles Toward Anisotropic Magnetic Properties

Abstract

Unique properties of one-dimensional assemblies of particles have attracted great attention during the past decades, particularly with respect to the potential for anisotropic magnetism. Patterned films can be created using inkjet printing; however, drying of particle-laden colloidal droplets on solid surfaces is usually accompanied by the well-known coffee-ring effect, deteriorating both the uniformity and resolution of the printed configurations. Here, we examine the effect of externally applied magnetic field on particle deposition patterns. Ferromagnetic Gd 5Si 4 particles were formulated in terpineol oil and directly deposited via magnetic field-assisted inkjet printing on a photopaper to generate patterned films with suppressed coffee-ring effect. The particle deposition morphology is determined by both solvent imbibition and particle-magnetic field interactions. Three characteristic times are considered, namely, the critical time for solvent imbibition into the substrate (t im), the time it takes for particles to form chains in the presence of the magnetic field (t ch), and the time in which the particles reach the substrate in the direction normal to the substrate (t pz). The characteristic time ratios (t pz/t im) and (t pz/t ch) determine the final deposition morphology in the presence of magnetic field. Finally, the ability to control particle deposition andmore » assembly, thus tuning the magnetic anisotropic properties of nanostructured materials is a promising approach for many engineering applications.« less

Authors:
 [1];  [1];  [2];  [3];  [1]
  1. Virginia Commonwealth Univ., Richmond, VA (United States). Dept. of Mechanical and Nuclear Engineering
  2. Iowa State Univ., Ames, IA (United States); Ames Lab., Ames, IA (United States). Division of Materials Science and Engineering
  3. Iowa State Univ., Ames, IA (United States). Dept. of Materials Science and Engineering; Ames Lab., Ames, IA (United States). Division of Materials Science and Engineering;
Publication Date:
Research Org.:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1574819
Report Number(s):
IS-J-10081
Journal ID: ISSN 2045-2322
Grant/Contract Number:  
AC02-07CH11358
Resource Type:
Accepted Manuscript
Journal Name:
Scientific Reports
Additional Journal Information:
Journal Volume: 9; Journal Issue: 1; Journal ID: ISSN 2045-2322
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
42 ENGINEERING

Citation Formats

Al-Milaji, Karam Nashwan, Hadimani, Ravi L., Gupta, Shalabh, Pecharsky, Vitalij K., and Zhao, Hong. Inkjet Printing of Magnetic Particles Toward Anisotropic Magnetic Properties. United States: N. p., 2019. Web. doi:10.1038/s41598-019-52699-0.
Al-Milaji, Karam Nashwan, Hadimani, Ravi L., Gupta, Shalabh, Pecharsky, Vitalij K., & Zhao, Hong. Inkjet Printing of Magnetic Particles Toward Anisotropic Magnetic Properties. United States. doi:10.1038/s41598-019-52699-0.
Al-Milaji, Karam Nashwan, Hadimani, Ravi L., Gupta, Shalabh, Pecharsky, Vitalij K., and Zhao, Hong. Thu . "Inkjet Printing of Magnetic Particles Toward Anisotropic Magnetic Properties". United States. doi:10.1038/s41598-019-52699-0. https://www.osti.gov/servlets/purl/1574819.
@article{osti_1574819,
title = {Inkjet Printing of Magnetic Particles Toward Anisotropic Magnetic Properties},
author = {Al-Milaji, Karam Nashwan and Hadimani, Ravi L. and Gupta, Shalabh and Pecharsky, Vitalij K. and Zhao, Hong},
abstractNote = {Unique properties of one-dimensional assemblies of particles have attracted great attention during the past decades, particularly with respect to the potential for anisotropic magnetism. Patterned films can be created using inkjet printing; however, drying of particle-laden colloidal droplets on solid surfaces is usually accompanied by the well-known coffee-ring effect, deteriorating both the uniformity and resolution of the printed configurations. Here, we examine the effect of externally applied magnetic field on particle deposition patterns. Ferromagnetic Gd5Si4 particles were formulated in terpineol oil and directly deposited via magnetic field-assisted inkjet printing on a photopaper to generate patterned films with suppressed coffee-ring effect. The particle deposition morphology is determined by both solvent imbibition and particle-magnetic field interactions. Three characteristic times are considered, namely, the critical time for solvent imbibition into the substrate (tim), the time it takes for particles to form chains in the presence of the magnetic field (tch), and the time in which the particles reach the substrate in the direction normal to the substrate (tpz). The characteristic time ratios (tpz/tim) and (tpz/tch) determine the final deposition morphology in the presence of magnetic field. Finally, the ability to control particle deposition and assembly, thus tuning the magnetic anisotropic properties of nanostructured materials is a promising approach for many engineering applications.},
doi = {10.1038/s41598-019-52699-0},
journal = {Scientific Reports},
number = 1,
volume = 9,
place = {United States},
year = {2019},
month = {11}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Save / Share:

Works referenced in this record:

XMCD and XMCD-PEEM Studies on Magnetic-Field-Assisted Self-Assembled 1D Nanochains of Spherical Ferrite Particles
journal, May 2017

  • Zhang, Wen; Wong, Ping Kwan Johnny; Zhang, Dong
  • Advanced Functional Materials, Vol. 27, Issue 29
  • DOI: 10.1002/adfm.201701265

Nanostructured Soft Matter with Magnetic Nanoparticles
journal, March 2016

  • Tokarev, Alexander; Yatvin, Jeremy; Trotsenko, Oleksandr
  • Advanced Functional Materials, Vol. 26, Issue 22
  • DOI: 10.1002/adfm.201504443

Magnetic recording beyond the first 100 Years
journal, March 1999


Printed Thin Magnetic Films Based on Diblock Copolymer and Magnetic Nanoparticles
journal, January 2018

  • Xia, Senlin; Metwalli, Ezzeldin; Opel, Matthias
  • ACS Applied Materials & Interfaces, Vol. 10, Issue 3
  • DOI: 10.1021/acsami.7b16971

The Magnetocaloric Effect and Magnetic Refrigeration Near Room Temperature: Materials and Models
journal, August 2012


Bioinspired 1D Superparamagnetic Magnetite Arrays with Magnetic Field Perception
journal, May 2016

  • Jiang, Xiangyu; Feng, Jiangang; Huang, Lei
  • Advanced Materials, Vol. 28, Issue 32
  • DOI: 10.1002/adma.201601609

One-dimensional magnetic inorganic–organic hybrid nanomaterials
journal, January 2011

  • Yuan, Jiayin; Xu, Youyong; Müller, Axel H. E.
  • Chemical Society Reviews, Vol. 40, Issue 2
  • DOI: 10.1039/c0cs00087f

A magnetic protein biocompass
journal, November 2015

  • Qin, Siying; Yin, Hang; Yang, Celi
  • Nature Materials, Vol. 15, Issue 2
  • DOI: 10.1038/nmat4484

Printing 1D Assembly Array of Single Particle Resolution for Magnetosensing
journal, March 2018


Inkjet printing of magnetic materials with aligned anisotropy
journal, May 2014

  • Song, Han; Spencer, Jeremy; Jander, Albrecht
  • Journal of Applied Physics, Vol. 115, Issue 17
  • DOI: 10.1063/1.4863168

Inkjet printing as a deposition and patterning tool for polymers and inorganic particles
journal, January 2008

  • Tekin, Emine; Smith, Patrick J.; Schubert, Ulrich S.
  • Soft Matter, Vol. 4, Issue 4
  • DOI: 10.1039/b711984d

Controlling Coffee Ring Formation during Drying of Inkjet Printed 2D Inks
journal, September 2017


Manipulating the Coffee-Ring Effect: Interactions at Work
journal, July 2015


A review on suppression and utilization of the coffee-ring effect
journal, February 2018


Recent Advances in Controlling the Depositing Morphologies of Inkjet Droplets
journal, December 2015

  • Sun, Jiazhen; Bao, Bin; He, Min
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 51
  • DOI: 10.1021/acsami.5b07006

Protein Adsorption and Reorganization on Nanoparticles Probed by the Coffee-Ring Effect: Application to Single Point Mutation Detection
journal, September 2016

  • Devineau, Stéphanie; Anyfantakis, Manos; Marichal, Laurent
  • Journal of the American Chemical Society, Vol. 138, Issue 36
  • DOI: 10.1021/jacs.6b04833

Pattern formation in drying drops
journal, January 2000


Capillary flow as the cause of ring stains from dried liquid drops
journal, October 1997

  • Deegan, Robert D.; Bakajin, Olgica; Dupont, Todd F.
  • Nature, Vol. 389, Issue 6653, p. 827-829
  • DOI: 10.1038/39827

Contact line deposits in an evaporating drop
journal, July 2000

  • Deegan, Robert D.; Bakajin, Olgica; Dupont, Todd F.
  • Physical Review E, Vol. 62, Issue 1
  • DOI: 10.1103/PhysRevE.62.756

Effect of Substrate Temperature on Pattern Formation of Nanoparticles from Volatile Drops
journal, March 2015


Effect of relative humidity on contact angle and particle deposition morphology of an evaporating colloidal drop
journal, December 2010

  • Chhasatia, Viral H.; Joshi, Abhijit S.; Sun, Ying
  • Applied Physics Letters, Vol. 97, Issue 23
  • DOI: 10.1063/1.3525167

Overcoming the “Coffee-Stain” Effect by Compositional Marangoni-Flow-Assisted Drop-Drying
journal, May 2012

  • Majumder, Mainak; Rendall, Clint S.; Eukel, J. Alexander
  • The Journal of Physical Chemistry B, Vol. 116, Issue 22
  • DOI: 10.1021/jp3009628

Control over Coffee-Ring Formation in Evaporating Liquid Drops Containing Ellipsoids
journal, July 2014

  • Dugyala, Venkateshwar Rao; Basavaraj, Madivala G.
  • Langmuir, Vol. 30, Issue 29
  • DOI: 10.1021/la500803h

Suppression of the coffee-ring effect by shape-dependent capillary interactions
journal, August 2011

  • Yunker, Peter J.; Still, Tim; Lohr, Matthew A.
  • Nature, Vol. 476, Issue 7360
  • DOI: 10.1038/nature10344

Deposition and drying dynamics of liquid crystal droplets
journal, May 2017

  • Davidson, Zoey S.; Huang, Yongyang; Gross, Adam
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms15642

Suppression of the Coffee-Ring Effect and Evaporation-Driven Disorder to Order Transition in Colloidal Droplets
journal, September 2017

  • Das, Shyamashis; Dey, Atreya; Reddy, Govardhan
  • The Journal of Physical Chemistry Letters, Vol. 8, Issue 19
  • DOI: 10.1021/acs.jpclett.7b01814

Evaporation Stains: Suppressing the Coffee-Ring Effect by Contact Angle Hysteresis
journal, June 2013

  • Li, Yueh-Feng; Sheng, Yu-Jane; Tsao, Heng-Kwong
  • Langmuir, Vol. 29, Issue 25
  • DOI: 10.1021/la400948e

Surfactant-driven flow transitions in evaporating droplets
journal, January 2016

  • Marin, Alvaro; Liepelt, Robert; Rossi, Massimiliano
  • Soft Matter, Vol. 12, Issue 5
  • DOI: 10.1039/C5SM02354H

Printing Small Dots from Large Drops
journal, February 2015

  • Talbot, Emma L.; Yow, Huai N.; Yang, Lisong
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 6
  • DOI: 10.1021/am5087177

Auto-production of biosurfactants reverses the coffee ring effect in a bacterial system
journal, April 2013

  • Sempels, Wouter; De Dier, Raf; Mizuno, Hideaki
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms2746

Controlled Uniform Coating from the Interplay of Marangoni Flows and Surface-Adsorbed Macromolecules
journal, March 2016


Influence of Evaporation on Contact Angle
journal, July 1995


Flow Transition within an Evaporating Binary Mixture Sessile Drop
journal, May 2011


Nanochromatography Driven by the Coffee Ring Effect
journal, March 2011

  • Wong, Tak-Sing; Chen, Ting-Hsuan; Shen, Xiaoying
  • Analytical Chemistry, Vol. 83, Issue 6
  • DOI: 10.1021/ac102963x

Self-Pinning by Colloids Confined at a Contact Line
journal, January 2013


Ordered patterns and structures via interfacial self-assembly: superlattices, honeycomb structures and coffee rings
journal, January 2011

  • Ma, Hongmin; Hao, Jingcheng
  • Chemical Society Reviews, Vol. 40, Issue 11
  • DOI: 10.1039/c1cs15059f

Probing the Colloidal Particle Dynamics in Drying Sessile Droplets
journal, January 2019


Ink-Jet Printing of Zirconia: Coffee Staining and Line Stability
journal, July 2011


Formation of Coffee Stains on Porous Surfaces
journal, March 2012


Coffee stains on paper
journal, June 2015


Influence of magnetic field on evaporation of a ferrofluid droplet
journal, October 2017

  • Jadav, Mudra; Patel, R. J.; Mehta, R. V.
  • Journal of Applied Physics, Vol. 122, Issue 14
  • DOI: 10.1063/1.4990665

Minimal Size of Coffee Ring Structure
journal, April 2010

  • Shen, Xiaoying; Ho, Chih-Ming; Wong, Tak-Sing
  • The Journal of Physical Chemistry B, Vol. 114, Issue 16
  • DOI: 10.1021/jp912190v

An Analytic Solution for the Force Between Two Magnetic Dipoles
journal, January 1998

  • Yung, Kar W.; Landecker, Peter B.; Villani, Daniel D.
  • Magnetic and Electrical Separation, Vol. 9, Issue 1
  • DOI: 10.1155/1998/79537