Inkjet Printing of Magnetic Particles Toward Anisotropic Magnetic Properties

Al-Milaji, Karam Nashwan; Hadimani, Ravi L.; Gupta, Shalabh; Pecharsky, Vitalij K.; Zhao, Hong

doi:10.1038/s41598-019-52699-0

Title: Inkjet Printing of Magnetic Particles Toward Anisotropic Magnetic Properties

Journal Article · 07 November 2019 · Scientific Reports

DOI: https://doi.org/10.1038/s41598-019-52699-0 · OSTI ID:1574819

Al-Milaji, Karam Nashwan ^[1]; Hadimani, Ravi L. ^[1]; Gupta, Shalabh ^[2]; Pecharsky, Vitalij K. ^[3]; Zhao, Hong ^[1]

Virginia Commonwealth Univ., Richmond, VA (United States). Dept. of Mechanical and Nuclear Engineering
Iowa State Univ., Ames, IA (United States); Ames Lab., Ames, IA (United States). Division of Materials Science and Engineering
Iowa State Univ., Ames, IA (United States). Dept. of Materials Science and Engineering; Ames Lab., Ames, IA (United States). Division of Materials Science and Engineering

Unique properties of one-dimensional assemblies of particles have attracted great attention during the past decades, particularly with respect to the potential for anisotropic magnetism. Patterned films can be created using inkjet printing; however, drying of particle-laden colloidal droplets on solid surfaces is usually accompanied by the well-known coffee-ring effect, deteriorating both the uniformity and resolution of the printed configurations. Here, we examine the effect of externally applied magnetic field on particle deposition patterns. Ferromagnetic Gd₅Si₄ particles were formulated in terpineol oil and directly deposited via magnetic field-assisted inkjet printing on a photopaper to generate patterned films with suppressed coffee-ring effect. The particle deposition morphology is determined by both solvent imbibition and particle-magnetic field interactions. Three characteristic times are considered, namely, the critical time for solvent imbibition into the substrate (t_im), the time it takes for particles to form chains in the presence of the magnetic field (t_ch), and the time in which the particles reach the substrate in the direction normal to the substrate (t_pz). The characteristic time ratios (t_pz/t_im) and (t_pz/t_ch) determine the final deposition morphology in the presence of magnetic field. Finally, the ability to control particle deposition and assembly, thus tuning the magnetic anisotropic properties of nanostructured materials is a promising approach for many engineering applications.

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Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1574819

Report Number(s):: IS-J--10081

Journal Information:: Scientific Reports, Journal Name: Scientific Reports Journal Issue: 1 Vol. 9; ISSN 2045-2322

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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